Foreword Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 191-192 Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Special Section: «Keynote lectures of the 16th Conference on Deformation mechanisms, Rheology and Tectonics (DRT)» Foreword This Thematic Section collects original contributions (mainly short papers) offered by the invited keynote lecturers of the 16th issue of the Conference on Deformation mechanisms, Rheology and Tectonics (DRT), held for the first time in Italy at Dipartimento di Scienze della Terra «A. Desio», Facoltà di Scienze MFN, Università di Milano, from Sept. 24 to Oct. 2, 2007. As a background it is significant to recall that the DRT Conference series represents one of the most relevant biennial event for the international community that operates in the fields of structural geology, tectonics, geodynamics, modeling, experimental deformation and rheology. The DRT Conference series was promoted in 1976 in Leiden by Henk Zwart, Richard Lysle, Gordon Lister and Paul Williams (a history of the DRT meetings until 2001 may be found in the Preface of London Geological Society Spec. Publication series n° 200, 2002). More recent DRT Conferences, organized after year 2000, were held in Neustadt, Utrecht, St. Malo-Rennes, Zuerich and then Milano. Since the beginning, the series of DRT meetings managed to bring together structural geologists, material scientists and geophysicists devoted to theoretical and experimental work; successively field investigators joined the group, that continued to debate periodically updated advances in tectonics, gained at any scale. In the Milano 2007 Conference, discussions on 10 topics were based on presentation of 14 keynote lectures, 38 oral communications and 135 posters. Subjects encompassed advances in the investigation of lithosphere-scale tectonic mechanisms, in connection with geological and geophysical results from various analytical scales. Besides these leading themes of oral and poster presentations, discussions during two field excursions and at the Workshop, spread over tectonic mechanisms of subduction-exhumation of ophiolites (Valle Po-Valle Varaita, excursion to Monviso) and of the continental crust (OropaBiella, excursion to Mucrone-Monte Mars metagranitoids) and on fitting of modelling predictions with structural and petrologic natural data on orogenic metamorphites. Workshop discussion helped to individuate non-consistent results and improvements, introduced by new approaches in gathering and processing field or laboratory data (P-T estimates, age data, tectonic units size, and others...) or by different modelling approaches. With the aim of leaving a published trace in the Bollettino della Società Geologica Italiana, most Keynote Lecturers accepted to summarize the main points of their invited contributions in the following short papers, that represent the summary of the main stream of the scientific contents of the conference sessions. The scientific sessions were grouped by topics and themes therein covered: 1) crust and mantle rheology from micro- to mega- scale (strength contrast between crust and upper mantle, structure and rheology of lithosphere scale shear/fault zones); 2) numerical and analogical modeling of deformation processes (role of rheology in mechanical models, identification of rheological ‘knowledge gaps’, (up)scaling and scale dependence of rheological relations, studies on consistency of field observations and laboratory-derived flow laws); 3) absolute dating vs deformation: the rate of tectonics (advances in geochronology necessary to discern the micro-scale separation of isotopic imprints and the relationships between fabrics and mineral assemblages that reflect step-like evolutions related to displacement of tectonic units in active lithosphere zones); 4) deformation-metamorphism interaction: what does condition the memory of a rock? Insigths from natural data, experiment and modeling (metamorphic reaction progress and deformation history confronted 192 SPECIAL SECTION with the activation in adjacent rock volumes of contrasted deformation mechanisms and/or strain rates); 5) interaction between magmatism and deformation: field studies, numerical models and analogue experiments (deformation and melting processes, crystallization, segregation, transport and emplacement of melts or magmas, and the flow of two-phase materials with very contrasted rheology); 6) palaeorheology (estimates of rock rheology based on natural rocks and modeling); 7) the geophysical signature of deformation processes in crust and mantle (global dynamics, and methodologies for inferring the viscosity profile of the mantle, from GPS data constrains upon predictive geophysical modeling); 8) quantitative microstructure (microstructures and textures in rocks: image analysis, electron diffraction, X-ray diffraction, neutron diffraction; focus on microstructure and texture development, including polyphase rocks, experimental microstructures and predictions); 9) brittle and ductile reactivation of compositional and structural heterogeneities (multi-scale reactivation of structures and strain localization; strain-stress patterns and rheological contrasts); 10) interaction between climate, erosion and tectonics (climate, surface processes and tectonics: search for testable predictions of models). In the post-conference Workshop in Oropa-Biella, conducted over one of the most intriguing subduction-exhumed Alpine rock associations, containing remnants of pre-Alpine continental crust, attention was driven to refinement of analytical strategies and techniques in Geology, that may improve realistic investigation of geophysical processes through numerical modeling. Guido Gosso, Anna Maria Marotta, Roberto Sabadini and Maria Iole Spalla formed the Organising Committee; the Scientific Committee of the 16th DRT Conference was formed by Ulf Bayer, Jean Pierre Brun, Stephane Bonnet, JeanPierre Burg, Luigi Burlini, Daniel Chateigner, Martyn Drury, Terry Engelder, Marnie Forster, Taras Gerya, Rob Govers, Harry W. Green II, Djordje Grujic, Gordon Lister, Giorgio Pennacchioni, Giorgio Ranalli, Claudio Rosenberg, Bernard Stoeckhert, Holger Stuenitz, Janos Urai, Jean Louis Vigneresse, Igor Villa, Paul F. Williams, and Michele Zucali; the post-Conference Workshop has been shaped by Daniele Castelli, Taras Gerya, Rob Govers, Anna Maria Marotta, and M. Iole Spalla; the field leaders of pre-Conference escursion were Daniele Castelli and Roberto Compagnoni and of post-Conference excursion were Daniele Castelli, Guido Gosso, Piergiorgio Rossetti, Maria Iole Spalla, Davide Zanoni and Michele Zucali. Field guides of pre- and post-conference excursions were published on volume 9 (2007) of Quaderni di Geodinamica Alpina and Quaternaria. The Organising Committee of the 16th Conference of the DRT series thanks the keynote speakers for their contributions; support is here gratefully acknowledged from Società Geologica Italiana, Gruppo Italiano di Geologia Strutturale and the Section of Milano of CNR-IDPA (Istituto per la Dinamica dei Processi Ambientali), that respectively sponsored and financially sustained the present publication and the other editorial activities. The editors of this thematic section are deeply grateful to the reviewers (Daniele Castelli, Martyn Drury, Taras Gerya, Stefano Poli, Claudio Rosenberg, Roberto Sabadini and other anonymous, belonging to the Conference Scientific Committee), for their support in the revision of the key-note contributions. The editors of the thematic section on 16th DRT Conference Guido GOSSO (*), (**) Anna Maria MAROTTA (**) Maria Iole SPALLA (*), (**) (Valle Po-Valle Varaita, Milano, Oropa-Biella, Sept. 24-Oct. 2, 2007) (*) CNR - Istituto per la Dinamica dei Processi Ambientali, Sezione di Milano. (**) Dipartimento di Scienze della Terra «A. Desio», Università di Milano. Buiter Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 193-198, 3 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Rheology in numerical models of lithosphere deformation SUSANNE J.H. BUITER (*) ABSTRACT Deformation of Earth’s crust and lithosphere is characterised by elastic, viscous and brittle material behaviour. The implementation of this complex rheology is a challenge for numerical models owing to variations in laboratory and natural data, the choice of equations to describe the deformation processes and the different flavours of their numerical representation. I discuss some of the current issues associated with the role of elasticity in crust- to lithosphere-scale processes, the implementation of brittle behaviour in continuum models and the use of laboratory viscous flow laws. Results of numerical models show that the style of lithosphere deformation is strongly influenced by strength contrasts between materials. Numerical models can be used to evaluate the role of such strength contrasts and of the individual rheological components by testing model sensitivity to variations in parameter values. KEY WORDS: Rheology, brittle failure, elasticity, flow law, numerical model. tions) and material behaviour. Deformation of the crust and lithosphere is characterised by a complex rheology with elastic, viscous and plastic (brittle) components (fig. 1). Laboratory measurements of the properties of rocks can be used to constrain the values of several of the material properties in models. In addition, models may not only use laboratory data in this ‘passive’ sense, but could also constrain rheological values by inversion of natural observations (e.g. KENIS et alii, 2005). The aim of this short paper is to discuss some of the choices and challenges associated with the implementation of an elasto-visco-plastic rheology in numerical models. A DISCUSSION OF NUMERICAL RHEOLOGY ELASTIC BEHAVIOUR RIASSUNTO Reologia nei modelli numerici della deformazione litosferica. La deformazione della crosta e della litosfera terrestre è caratterizzata da un comportamento elastico, viscoso e fragile. L’implementazione di tale reologia complessa è una sfida per i modelli numerici a causa delle variazioni nei dati naturali e di laboratorio, della scelta delle equazioni che descrivono i processi di deformazione e dei loro differenti modi di rappresentazione numerica. Vengono qui discussi alcuni problemi associati al ruolo dell’elasticità nei processi alla scala che va dalla crosta alla litosfera, all’implementazione del comportamento fragile nei modelli continui e all’uso delle leggi di flusso viscoso dedotte in laboratorio. I risultati dei modelli numerici mostrano che lo stile della deformazione litosferica è fortemente influenzato dai contrasti di resistenza fra i materiali. I modelli numerici possono essere utilizzati per valutare il ruolo di tali contrasti nella resistenza e delle componenti reologiche individuali, testando la sensibilità del modello alle variazioni nei valori dei parametri. TERMINI CHIAVE: Reologia, rottura fragile, elasticità, legge di flusso, modelli numerici. INTRODUCTION Numerical models are a useful tool to predict lithosphere deformation styles as a function of sensitivity to mechanical and thermal properties and driving forces. Since nature is more complex than can probably ever be captured in a numerical model, simplifications need to be made of geometry, driving forces (boundary condi- (*) Centre for Geodynamics, Geological Survey of Norway, Leiv Eirikssons vei, 39 - 7491 Trondheim, Norway; [email protected] Elastic behaviour is characterised by a linear relationship between stress and strain (fig. 1): σ ij = 2Gε ij (1) Here σij is the stress tensor, G the shear modulus and εij the strain tensor. Elastic stresses can grow with strain in an unlimited manner and will be released once strain is removed. This thus introduces a memory of deformation in materials. Elasticity is clearly important for processes on relatively short timescales (from seismic wave propagation to post-glacial rebound), but purely elastic models have also successfully been used to simulate longer-term processes such as the deflection of the lithosphere at a trench (TURCOTTE & SCHUBERT, 2002) and under the load of volcanic islands like Hawaii (WATTS, 2001). Elastic behaviour could be important for processes that have shorter duration than the Maxwell relaxation time, which is defined as the ratio of viscosity over shear modulus. For mantle processes the relaxation time is so small (on the order of 1000 yrs) that elasticity can safely be ignored. For processes on the scale of the lithosphere it may, however, be on the order of a million years, implying that elasticity may not always be neglected. A measure of the importance of elasticity is given by the Deborah number (REINER, 1965), which is defined by the ratio of Maxwell relaxation time to the characteristic deformation time. Small Deborah numbers imply viscous behaviour (though see its limitation in viscoelastic folding (SCHMALHOLZ & PODLADCHIKOV, 1995) and further discussion in MÜHLHAUS & REGENAUER-LIEB (2005)). The numerical implementation of elastic material behaviour has partly been hampered by technical challenges related to combining large deformations of materi- 194 S.J.H. BUITER Fig. 1 - Example of the mechanical and thermal setup of a numerical model and schematic representation of its rheology components (at top) consisting of elastic (spring), viscous (dashpot) and plastic (block sliding on a surface) material behaviour. – Esempio di un setup meccanico e termico di un modello numerico e rappresentazione schematica delle sue componenti reologiche (sopra) che consistono di comportamento elastico (molla), viscoso (condensatore) e plastico (blocco che scorre su una superficie). als (requiring remeshing or an Eulerian approach) with a stress history (requiring a Lagrangian approach or tracking of stresses with particles). Developments in Earth Science numerical codes now allow explicit investigation of the role of elasticity in processes on the lithosphere to upper mantle scale (MORESI et alii, 2003; MÜHLHAUS & REGENAUER-LIEB, 2005). KAUS & BECKER (2007) show that elasticity has negligible effects on the dynamics of density-driven (Rayleigh-Taylor) lithospheric instabilities, but that viscoelastic models may locally result in different stresses than purely viscous models. Elasticity will thus not significantly affect the dynamics of mantle convection or lithospheric instabilities. However, it could play a role on local scales in processes associated with folding or subduction. Elasticity may also play a role in shear band formation where stresses build up to their maximum at which failure occurs and elastic unloading takes place outside the shear band (VERMEER, 1990). In these cases, the importance of elasticity should preferably be tested. PLASTIC BEHAVIOUR Brittle behaviour (plasticity) limits stresses in regions in the upper and lower crust and upper mantle. Brittle stresses depend on the nature of the material, its water content, the stress regime (extension or compression) and whether material is newly fractured (failure) or sliding occurs on pre-existing failure planes (friction). The empirical Amonton’s law shows a linear relation between frictional shear stress (σt) and normal stress (σn) and can be written as: σ t = µσ n (1 − λ ) + C = tan(ϕ )σ n (1 − λ ) + C (2) Here µ is the friction coefficient, ϕ the angle of internal friction, λ pore fluid factor (ratio of pore fluid pressure over lithostatic pressure) and C cohesion. This equation can be written in terms of the principal stresses (σ1 and σ3): ( ) ( ) 1 1 σ 1 − σ 3 = σ 1 + σ 3 (1 − λ )sin(ϕ ) + C cos(ϕ ) 2 2 (3) The compilation by BYERLEE (1978) for dry materials (λ = 0) shows that µ~0.85 for σn < 200 MPa and µ~0.6 for 200 < σn < 2000 MPa. Rock cohesion in this compilation varies between 0 and 50 MPa. Using these values, extrapolation to depths below the Moho can lead to very high stresses (on the order of 1000 MPa for a compressional stress regime). These stresses are likely lower in nature owing to a different deformation mechanism on the transition between brittle and viscous behaviour (KOHLSTEDT et alii, 1995). Many numerical models need much lower RHEOLOGY IN NUMERICAL MODELS OF LITHOSPHERE DEFORMATION 195 Fig. 2 - Two examples of simple two-layer extension models with a brittle upper layer and a linear viscous lower layer. The models show that the number of shear zones in the upper layer depends on the strength contrast between the two layers. A) Results of 3 models after 30% extension. The viscosity of the lower layer is 1 and cohesion C of the upper layer varies from 10 to 7 (all values are scaled in these calculations). After MORESI & MÜHLHAUS (2006). B) Results of 3 models after 2.5% extension (top and middle figure) and 10% extension (bottom figure). The model is originally 400 km wide and 35 km high. The angle of internal friction is 30° softening to 4°, cohesion is 20 MPa softening to 2 MPa. The viscosity of the lower layer varies from 1019 to 1021 Pas. After BUITER et alii (2008). – Due esempi di semplici modelli di estensione a due strati con uno strato superiore fragile e uno strato inferiore viscoso lineare. I modelli mostrano che il numero delle zone di scorrimento nello strato superiore dipende dal contrasto della resistenza fra i due strati. A) Risultati di 3 modelli dopo il 30% di estensione. La viscosità dello strato inferiore è 1 e la coesione C dello strato inferiore varia da 10 a 7 (tutti i valori sono scalati). Da MORESI & MÜHLHAUS (2006). B) Risultati di 3 modelli dopo il 2.5% di estensione (figura superiore e centrale) e 10% di estensione (figura inferiore). Il modello è originariamente largo 400 km e alto 35 km. L’angolo di frizione interna varia da 30° a 4°, la coesione varia da 20 MPa a 2 MPa. La viscosità dello strato inferiore varia da 1019 a 1021 Pas. Da BUITER et alii (2008). values for the friction coefficient than reported by BYERLEE (1978) to reproduce lithosphere deformation as seen in nature, especially along subduction faults (e.g., GERYA et alii, 2007). It is an open question whether these low numerical coefficients point to weak faults in nature (e.g., by foliation development, mineral transformations or high pore fluid pressures) or to a special feature of the models. Some numerical (Lagrangian finite-element) models can implement a pre-existing failure plane along which the displacements are limited by the friction coefficient (e.g., MELOSH & WILLIAMS, 1989). The challenge of this approach is the need for remeshing as fault offsets become large. Alternatively, the implementation of plasticity in (finite-element or finite-difference) continuum models results in the formation of shear bands with a finite width. Mohr-Coulomb failure follows the above equations, but the values for ϕ and C may differ from their values in friction. Construction of the Mohr circle at yield results in a prediction for the angle of shear zones with the direction of maximum compressive stress of 45° – ϕ/2. Shear zones in compression are therefore expected to have shallow dip angles (30° for ϕ = 30°), while extensional shear zones are steep (60° for ϕ = 30°). Measurements on shear bands in sand show, however, also the Roscoe angle 45° – ψ/2 (ROSCOE, 1970; see also VERMEER, 1990) or an intermediate angle 45° – (ψ + ϕ)/2 (VARDOULAKIS, 1980). Here ψ is the dilation angle (the ratio of the rate of volumetric strain and the rate of shear strain). GERYA & YUEN (2007) obtain the intermediate (45° – (ψ + ϕ)/2) shear zone angle in their dilatant finite-difference experiments. In these types of models, the dilation angle keeps the same value throughout the deformation history. However, sand shows changes in dilation during loading. Shear zone formation is associated with dilation which reaches its maximum rate at peak failure and thereafter tends to zero when stable sliding is achieved (LOHRMANN et alii, 2003). This behaviour can be captured with dis- tinct element methods (EGHOLM, 2007) or sophisticated plasticity models (CROOK et alii, 2006). Many numerical models that do well in simulating large deformations are incompressible (ψ = 0°) and shear zone dip angles in these models could in theory range between 45° and the Mohr-Coulomb angle (45° – ϕ/2). Incompressible viscoplastic models, however, often seem to result in 45° shear zone dip angles. For this reason, MORESI & MÜHLHAUS (2006) developed an anisotropic viscosity method that gives Mohr-Coulomb dip angles. It remains, however, to be established whether incompressible viscoplastic models may not intrinsically be able to result in Mohr-Coulomb angles and whether the obtained 45° shear zone angles point to something overlooked in these types of models. The width of shear bands depends on the numerical resolution. This implies that shear bands can become extremely narrow for very fine grids and for this reason some models have introduced intrinsic minimum length scales (de BORST & SLUYS, 1991). The use of mean stress (or dynamic pressure) instead of lithostatic pressure in the numerical implementation of Mohr-Coulomb plasticity (see equation 3) improves localisation behaviour (e.g., BUITER et alii, 2006). In numerical models stresses are followed while they build up until the yield surface is reached. This stress build-up phase will be different for viscoelastic and viscous models. In nature, stresses will never exceed the yield stress, but in numerical models a stress overshoot can occur. Stresses then need to be brought back to yield and different techniques exist to do this (e.g., viscosity iteration or return mapping). It has not yet been clearly established if these differences in techniques could have a significant effect on numerical shear zones (see also BUITER et alii, 2005). After yielding, associated (ϕ = ψ) or non-associated (ϕ ≠ ψ) plastic flow occurs. This continued deformation after failure distinguishes many Earth Sciences problems from engineeringtype applications. 196 S.J.H. BUITER Fig. 3 - Shortening of a continental lithosphere with a 3 km high (200 km wide) mountain which is in isostatic equilibrium with a crustal root. A) The model is still stable after 10 Myr of shortening (at 1 cm/yr) if the mantle part of the lithosphere is strong. B) A weak mantle lithosphere leads to an unstable model. Modified from BUROV & WATTS (2006). – Raccorciamento di una litosfera continentale con una catena montuosa di altezza 3 km (ampia 200 km), che è in equilibrio isostatico con una radice crostale. A) Il modello è ancora stabile dopo 10 Ma di raccorciamento (a 1 cm/anno) se il mantello litosferico è resistente. B) un mantello litosferico debole porta ad un modello instabile. Modificato da BUROV & WATTS (2006). VISCOUS BEHAVIOUR Viscous behaviour of crustal and upper mantle rocks is described by an empirical flow law, which relates strain-rate to stress: Q + PV ε˙ = Aσ n d − p exp − RT (4) Here A is the pre-exponent, n the stress exponent, d grain size, p grain size exponent, Q activation energy, P pressure, V activation volume, R the gas constant and T temperature. The pre-exponent A may include melt fraction, oxygen fugacity and water content. Usually the . strain-rate (ε ) is uniaxial and stress (σ) is the differential stress. Measured flow laws need, therefore, to be converted to effective stress and strain-rate for a general implementation in numerical models (e.g., RANALLI, 1987). At low-stress conditions, grain boundary diffusion creep (e.g. Coble creep) is in general important, whereas deformation by movement of dislocations (dislocation creep) is more characteristic for high-stress conditions. Diffusion creep is characterised by n = 1 and is grain size dependent (p = 3 for olivine (HIRTH & KOHLSTEDT, 2003)). Dislocation creep is grain size independent (p = 0), while n ≥ 3. Diffusion and dislocation creep may occur simultaneously (they act in parallel), in which case the contributions from both mechanisms need to be taken into account. Flow laws are determined by measuring stresses for varying strain-rate and at different temperatures. Ideally, the conditions should be such that deformation occurs by one deformation mechanism and at steady state. The laboratory conditions imply that measurements are made on small rock samples (mm), at low strains and high strainrates (10-3 – 10-6 s-1) and need to be extrapolated to geological conditions. Many of the issues associated with this extrapolation and the implementation of laboratory flow laws in models are discussed in, among others, PATERSON (1987, 2001), RUTTER & BRODIE (1991) and HANDY et alii (2001). The uncertainty involved in the extrapolation to low strain rates (10-14 – 10-16 s-1), potentially different grain sizes and high strains is essentially unknown. However, support to the large extrapolations is given by similarities in microstructures between naturally and experimentally deformed materials (e.g., as discussed for quartzite by HIRTH et alii (2001)). Current challenges are to formulate flow laws for polymineral rocks and flow laws that quantify the effects of water (KORENAGA & KARATO, 2008) and melt content. Choosing the flow law to use in a geodynamic model is not straightforward (RANALLI, 2003; BUROV, 2003). Extrapolated published flow laws for crustal and mantle rocks show a large variation in strength, thus giving a choice of weak or strong materials in models. The best approach to dealing with this uncertainty in flow law data in numerical modelling is to treat flow laws as a variable and to examine model sensitivity to viscous strength variations. Simple two-layer models of a brittle RHEOLOGY IN NUMERICAL MODELS OF LITHOSPHERE DEFORMATION upper layer bonded to a linear viscous lower layer show, for example, that the number of shear zones in the brittle layer decreases as the strength contrast between the two layers increases (fig. 2) (MORESI & MÜHLHAUS, 2006; BUITER et alii, 2008). The rheology of subducted material and the surrounding mantle has been shown to influence the dynamics of subduction zones (e.g., BILLEN & HIRTH, 2005; 2007). BUROV & WATTS (2006) show that in their models a weak olivine mantle (which I infer to be wet Åheim dunite by CHOPRA & PATERSON (1981)) results in deformation styles which are incompatible with observed lithosphere stability and deformation at subduction zones, whereas a strong upper mantle (inferred to be dry olivine by Hirth & KOHLSTEDT (1996)) explains the persistence of mountains and the integrity of subducting slabs (fig. 3). CONCLUDING REMARKS Models of deformation processes in the crust and lithosphere require a sophisticated rheology description with elastic, viscous and plastic components. I have touched upon some of the open questions associated with especially numerical plasticity and the use of laboratory flow laws in models. Plastic behaviour in continuum models results in the formation of grid-size dependent shear bands. Their dip angle has been shown to vary between the Roscoe, Mohr-Coulomb or an intermediate angle and it has until now not been clearly established whether one of these representations should be preferred. Elasticity may play a role in deformation processes on the scale of the lithosphere (e.g. subduction) and its importance should be tested for crust- to lithosphere-scale models. Extrapolated published viscous flow laws for crustal and mantle rocks show a large variation in strength, giving modellers a choice between weak and strong numerical materials. Results of numerical models show that in many cases deformation depends on the strength contrasts between layers and less on the absolute values of the material strengths (e.g., BUROV & WATTS, 2006; MORESI & MÜHLHAUS, 2006). A useful approach is to treat rheology in numerical models as a variable and to test model sensitivity to reasonable variations in the values of the rheological components. ACKNOWLEDGEMENTS I would like to thank Janos Urai for his invitation to discuss numerical rheology at the 16th DRT conference, Florian Heidelbach for enlightening discussions of laboratory measurements of flow laws and Susan Ellis, Boris Kaus and Yuri Podladchikov for our many discussions of numerical plasticity. Florian Heidelbach, Susan Ellis and journal reviewer Roberto Sabadini provided helpful feedback on this text. REFERENCES BILLEN M.I. & HIRTH G. (2005) - Newtonian versus non-Newtonian upper mantle viscosity: Implications for subduction initiation. Geophys. Res. Lett., 32, do: 10.1029/2005GL023457. BILLEN M.I. & HIRTH G. (2007) - Rheologic controls on slab dynamics. G-cubed, 8, doi: 10.1029/ 2007GC001597. BUITER S., KAUS B. & MANCKTELOW N. (2005) - Discussion on designing a plasticity benchmark. 9th International workshop on Numerical modelling of mantle convection and lithospheric dynamics. BUITER S.J.H., BABEYKO A. 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(1980) - Shear band inclination and shear modulus of sand in biaxial tests. Int J. Num. Anal. Methods in Geomech., 4, 103-119. VERMEER P.A. (1990) - The orientation of shear bands in biaxial tests. Geotechnique, 40, 223-236. WATTS A.B. (2001) - Isostasy and Flexure of the Lithosphere. Cambridge University Press, 458 pp. Received 5 November 2007; revised version accepted 3 March 2008 Burg&Gerya Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 199-203, 4 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Modelling intrusion of mafic and ultramafic magma into the continental crust: numerical methodology and results JEAN-PIERRE BURG (*) & TARAS V. GERYA (*) ABSTRACT INTRODUCTION Field studies and geophysical imaging indicate that granitic and non-granitic plutons have both very variable and comparable shapes and sizes. We simulated numerically intrusion of partially molten mantle rocks from a sub-lithospheric magmatic source region (SMSR). Our systematic numerical modelling results show that intrusion typically spans a few hundred kyr spanning three stages: (1) magmatic channel spreading, (2) emplacement and (3) post-intrusive subsidence and cooling. The duration of each of these stages strongly depends on the viscosity of ascending magma. Upward magma transport from sublithospheric depth is driven by the positive buoyancy of the partially-molten rocks with respect to the overriding colder mantle lithosphere. By systematically varying the model parameters we document variations in intrusion dynamics and geometry that range from funnel- and fingershaped bodies (pipes, dikes) to deep seated balloon-shaped intrusions and flattened shallow magmatic sills. Relatively cold elasto-plastic crust (TMoho = 400oC) promotes a strong upward propagation of magma due to the significant decrease of plastic strength of the crust with decreasing confining pressure. Warmer crust (TMoho = 600oC) triggers lateral spreading of magma above the Moho. Field studies and geophysical imaging indicate that granitic and non-granitic plutons have both very variable and comparable shapes and sizes (e.g. BEST & CHRISTIANSEN, 2001; PETFORD, 1996; CRUDEN & MCCAFFREY, 2001; BOLLE et alii, 2002). The dimensions of plutons are therefore rock-type independent. It is generally accepted that plutons grow by collecting and transferring melt from a deep source to higher emplacement levels. Melting (anatexis and dehydration melting of hydrous minerals) of rocks generates these melts, with felsic to intermediate compositions when the source is the continental crust, or mafic and ultramafic compositions when partial melting affects the upper mantle (e.g. RUDNICK & GAO, 2004). However, evidence for sublithospheric magma sources indicates that transfer of non-kimberlitic magma also occurs on a larger scale, through the lithosphere (e.g. ANDERSON, 1994; SCHMIDT & POLI, 1998; ERNST et alii, 2005; WRIGHT & KLEIN, 2006). This is especially true for intrusions of mafic and ultramafic bodies into the lower density (by 100-500 kg/m3) continental crust that are documented for a large variety of tectonic settings spanning continental shields, rift systems, collision orogens and magmatic arcs. While accepting the conventional ideas concerning plutonism, we are confronting three intriguing questions: (1) How can magma move from sub-lithospheric molten regions to shallower storage chambers? (2) How highdensity, ultramafic and mafic magma can ascend into the lower density crust, at odds with the common acceptance that mafic and ultramafic magma stays deep and forms the lower crust (e.g. RUDNICK & GAO, 2004) and (3) how temperature-sensitive rheologies of both magma and country rocks together influence the emplacement of such ultramafic/mafic magmas? KEY WORDS: intrusion emplacement, numerical modelling, magmatic bodies. RIASSUNTO Modello di intrusione di magma femico e ultra-femico nella crosta continentale: metodologia numerica e risultati. Studi di terreno e immagini geofisiche indicano che plutoni granitici e non-granitici hanno forme e grandezze sia confrontabili che variabili. Abbiamo simulato numericamente l’intrusione di rocce di mantello parzialmente fuse da una regione di sorgente magmatica sub-litosferica (SMRS). I risultati della nostra modellizzazione numerica sistematica mostrano che l’intrusione tipicamente copre tre stadi su poche centinaia di migliaia di anni: (1) espansione del canale magmatico, (2) messa in posto e (3) subsidenza e raffreddamento post-intrusivi. La durata di ognuno di questi tre stadi dipende fortemente dalla viscosità del magma ascendente. Il trasporto di magma verso l’alto da profondità sub-litosferiche è guidato dalla galleggiabilità positiva delle rocce parzialmente fuse rispetto al mantello litosferico circostante più freddo. Variando sistematicamente i parametri del modello documentiamo variazioni nella dinamica e nella geometria dell’intrusione che varia da corpi a forma di imbuto e colonna (camini vulcanici, filoni eruttivi) a intrusioni profonde a forma di pallone (baloon) e filoni strato appiattiti superficiali. Una crosta continentale elasto-plastica relativamente fredda (TMoho = 400oC) favorisce una forte propagazione di magma verso l’alto a causa della significativa diminuzione della resistenza plastica della crosta con la diminuzione della pressione confinante. Una crosta più calda (TMoho = 600oC) stimola l’espansione laterale di magma sopra la Moho. TERMINI CHIAVE: messa in posto di corpi intrusivi, modellizzazione numerica, corpi magmatici. (*) Department of Geosciences – ETH and University Zürich, CH-8092 Zürich, Switzerland. MODELLING TECHNIQUES We decided to take advantage of recent progress in hardware and software capabilities to generate twodimensional visco-elasto-plastic numerical models of mafic-ulramafic intrusion emplacement incorporating in particular the temperature-sensitive properties of both magma and country rocks. Thermomechanical modelling of magma intrusion is numerically challenging because it involves simultaneous and intense deformation of materials with very contrasting rheological properties: the country, crustal rocks are visco-elasto-plastic while the intruding magma is a low viscosity, complex fluid (e.g. 200 J.-P. BURG & T.V. GERYA Fig. 1 - Enlarged 20-50 × 215 km areas of the original 1100 km × 300 km reference model. Distribution of rock layers in the intrusion area during emplacement of the ultramafic body into the crust from below the lithosphere via the magmatic channel. LEGEND: 1) weak layer (air, water); 2) sediments; 3, 4) upper crust (3 - solid, 4 - molten); 5, 6) lower crust (5 - solid, 6 - molten); 7, 8) mantle (7 - lithospheric, 8 - asthenospheric); 9, 10) peridotite (9 - molten, 10 - crystallized); 11, 12) gabbro (11 - molten, 12 - crystallized). Time (kyr) is given in the figures. White numbered lines are isotherms in °C. Vertical scale: depth below the upper boundary of the model. Initial numerical setting of this study is shown on the leftmost section of the model (0 Myr). The lithospheric and asthenospheric mantles have the same physical properties, different grey tones are used for a better visualization of deformation and structural development. This is also true for the passive colour-layering in the upper and the lower crust. Initial and boundary conditions are detailed in (GERYA & BURG, 2007). – Porzione estesa 20-50 × 215 km del modello di riferimento originale di dimensioni 1100 km × 300 km. Distribuzione dei livelli di roccia nell’area d’intrusione durante la messa in posto del corpo ultra-femico nella crosta da livelli sub-litosferici attraverso il canale magmatico. LEGENDA: 1) strato debole (aria, acqua); 2) sedimenti; 3, 4) crosta superiore (3 - solida, 4 - fusa); 5, 6) crosta inferiore (5 - solida, 6 - fusa); 7, 8) mantello (7 - litosferico, 8 - astenosferico); 9, 10) peridotite (9 - fusa, 10 - cristallizzata); 11, 12) gabbro (11 - fuso, 12 - cristallizzato). Il tempo (in migliaia di anni) kyr) è indicato nelle figure. Le linee bianche numerate sono isoterme in °C. Scala verticale: profondità sotto il bordo superiore del modello. La configurazione numerica iniziale di questo studio è mostrata nella sezione a sinistra del modello (0 Ma). I mantelli litosferico e astenosferico hanno le stesse proprietà fisiche; differenti toni di grigio sono utilizzati per visualizzare meglio lo sviluppo della deformazione e delle strutture. Ciò è vero anche per la stratificazione passiva della crosta superiore e inferiore. Le condizioni iniziali e al contorno sono dettagliate in GERYA & BURG (2007). PINKERTON & STEVENSON, 1992). We employ the 2-D code I2ELVIS (GERYA & YUEN, 2003a, 2007), which is based on finite-differences with a marker-in-cell technique. The code allows for the accurate conservative solution of the governing equations on a rectangular fully staggered Eulerian grid. New developments allow for both large viscosity contrasts and strong deformation of visco-elasto-plastic multiphase flow. The code was tested for a variety of problems by comparing results with both analytical solutions and analogue sandbox experiments (GERYA & YUEN, 2003, 2007). We simulated numerically intrusion of partially molten mantle rocks from a sub-lithospheric magmatic source region (SMSR, fig. 1, 0 Kyr). Developments introduced for intrusion simulation allow for both large viscosity contrasts and strong deformation of visco-elasto-plastic multiphase flow, incorporating temperature-dependent rheologies of both intrusive molten rocks and host rocks (GERYA & BURG, 2007). A magmatic channel is a vertical, 1.5 km wide zone characterised by a wet olivine rheology and a low 1 MPa plastic strength throughout the lithospheric mantle. The initial thermal structure of the lithosphere is as usually assumed, with a 35 km thick crust (fig. 1, 0 Kyr) corresponding to a sectioned linear temperature profile limited by 0°C at the surface, 400 oC at the bottom of the crust and 1300oC at 195 km depth. The temperature gradient in the asthenospheric mantle is 0.6oC/km below 195 km depth. The code grey (code colour in the coloured version) identifying rock types is given in figure 1. The discrimination between «peridotite» and «molten peridotite» is thermal, separating material points (pixels) above/below the wet solidus temperature of peridotite at a given pressure. Since the melt fraction is strongly changing with water content, variations within few % of melt fraction at given pressure-temperature condition are possible. Therefore, it MODELLING INTRUSION OF MAFIC AND ULTRAMAFIC MAGMA INTO THE CONTINENTAL CRUST is illusory to predict the exact melt fraction at any point of the models, in particular because the simplified linear melting model implemented here (GERYA & BURG, 2007) does not allow a very high precision on this question. DISCUSSION Modelling results (cf. GERYA & BURG, 2007, for details of experiments) show that intrusion typically lasts a few hundred kyr spanning three stages: (1) magmatic channel spreading (fig. 1, 0-16 Kyr), (2) emplacement (fig. 1, 22-41 Kyr, fig. 2) and (3) post-intrusive subsidence and cooling (fig. 1, 71-1171 Kyr, fig. 3). The duration of each of these stages strongly depends on the viscosity of ascending magma. Upward magma transport from sublithospheric depth is driven by the positive buoyancy of the partially-molten rocks with respect to the overriding colder mantle lithosphere. The gravitational balance controls the height of the Fig. 2 - Details of temperature distribution (numbered white lines = isotherms in °C) around intrusive body during the active stage of emplacement for the reference model. Rock types are the same as in fig. 1. – Dettagli della distribuzione della temperatura (linee bianche numerate = isoterme in °C) attorno al corpo intrusivo durante lo stadio di messa in posto attiva per il modello di riferimento. Le rocce sono le stesse di fig. 1. Fig. 3 - Details of culminate intrusive body shape for the reference model. Rock types are the same as in fig. 1. – Dettagli della forma finale del corpo intrusivo per il modello di riferimento. Le rocce sono le stesse di fig. 1. 201 202 J.-P. BURG & T.V. GERYA Fig. 4 - Stability of major intrusion shapes as a function of lower crust rheology and magma viscosity. Different color fields correspond to three different types of intrusive bodies (balloons, pipes/fingers and nappes/sills) obtained numerically (GERYA & BURG, 2007). – Stabilità dell’intrusione principale in funzione della reologia della crosta inferiore e della viscosità del magma. Differenti toni di grigio corrispondono ai tre diversi tipi di corpi intrusivi (palloni, filoni eruttivi e filoni strato) ottenuti numericamente (GERYA & BURG, 2007). column of molten rock but not the volume of magmatic rocks below and above the Moho. The molten rocks are pooling along the crust/mantle boundary only if the lower crust is ductile and very weak (fig. 4, deep grey field or red field in the colour version), which may be expected at the base of island arcs. It seems natural that otherwise, basic – ultrabasic magma is injected into the crust, most commonly as a finger/pipe-shaped body (fig. 4, intermediate grey field or pink field in the coloured version). Emplacement within the crust exploits the space opened by the displacement of tectonic crustal blocks bounded by localized zones of intense plastic deformation. Temperature is the important player in controlling crustal viscosities, hence either viscous or elasto-plastic mechanisms of crustal deformation, which defines modes and rates of emplacement. Early normal faults (fig. 1, 16 Kyr) produce early surface subsidence in grabens but rapidly become inverted into thrusts (fig. 1, 22 Kyr) responsible for surface uplift while the within-crust pluton inflates and rises in the crust (fig. 2). Late emplacement phases are responsible for cooling and subsiding of the magmatic body and partial return magma flow back into the magmatic channel below the Moho (fig. 3). This event is linked to subsidence of the surface. By systematically varying the model parameters we document variations in intrusion dynamics and geometry that range from funnel- and finger-shaped bodies (pipes, dikes) to deep seated balloon-shaped intrusions and flattened shallow magmatic sills (fig. 4). Relatively cold elasto-plastic crust (TMoho = 400oC) promotes a strong upward propagation of magma due to the significant decrease of plastic strength of the crust with decreasing confining pressure (fig. 4, intermediate and light grey fields or pink and blue fields in the coloured version). Emplacement in this case is controlled by crustal faulting and subsequent block displacements. Warmer crust (TMoho = 600oC) triggers lateral spreading of magma above the Moho, with emplacement being accommodated by coeval viscous deformation of the lower crust and fault tectonics in the upper crust (fig. 4, deep grey field or red field in the coloured version). CONCLUSION Emplacement of high density, mafic and ultramafic magma into low-density rocks is a stable mechanism for a wide range of model parameters that match geological settings in which partially molten mafic-ultramafic rocks are generated below the lithosphere. We expect this process to be particularly active beneath subductionrelated magmatic arcs where huge volumes of partially molten rocks produced from hydrous cold plume activity accumulate below the overriding lithosphere (GERYA & YUEN, 2003b). REFERENCES ANDERSON D.L. (1994) - The sublithospheric mantle as the source of continental flood basalts; the case against the continental lithosphere and plume head reservoirs. Earth Planet. Sci. Lett., 123, 269-280. BEST M.G. & CHRISTIANSEN E.H. (2001) - Igneous Petrology. Blackwell Science, Inc., Malden, 458 pp. BOLLE O., TRINDADE R.I.F., BOUCHEZ J.-L. & DUCHESNE J.-C. (2002) Imaging downward granitic magma transport in the Rogaland Igneous Complex, SW Norway. Terra Nova, 14, 87-92. 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Received 21 November 2007; revised version accepted 10 March 2008 Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 205-208, 3 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Magma-controlled tectonics in compressional settings: insights from geological examples and experimental modelling OLIVIER GALLAND (*), (**), PETER R. COBBOLD (*), ERWAN HALLOT (*) & JEAN DE BREMOND D’ARS (*) ABSTRACT INTRODUCTION Magmatic activity tends to concentrate at tectonic plate boundaries. At rapidly convergent margins, such as the Andes, intense magmatic activity is coeval with strong tectonic shortening, and some volcanoes and magmatic intrusions have been emplaced near active compressional structures, usually major thrust faults. In order to understand the links between magmatic systems and compressional deformation structures in the upper crust, we describe the structure of an active volcano (Tromen, Argentina) and an exhumed intrusion (Boulder Batholith, U.S.A.) emplaced during compressional deformation. In those examples, magmatic systems and thrust faults exhibit geometrical and chronological relationships. We also present results of experimental modelling of magma emplacement during compression. The comparison between geological examples and experiments show close similarities. That suggests that the presence of magma influences the deformation pattern in the brittle crust. The influence of deep magma bodies is also to be explored at the scale of the whole crust during the development of active margins. Magmatic activity mostly occurs at plate boundaries, where tectonic deformation also concentrates. Because magmatic bodies and their country rock have very contrasting rheological properties, one might expect deformation to be influenced by the presence of magmatic bodies at depth (e.g. BUROV et alii, 2003). Although this problem has been addressed in the lower crust (e.g. HOLLISTER & CRAWFORD, 1986; DAVIDSON et alii, 1992; BROWN & SOLAR, 1998; BROWN & SOLAR, 1999; ROSENBERG & HANDY, 2000; BARRAUD et alii, 2001), very little is known about the processes of such an interaction between magmatism and country rock deformation in the brittle upper crust. Which one comes first? Which one controls the other? Most of previous research has focused on deformation controlling magmatism (e.g. HUBBERT & WILLIS, 1957; MARRETT & EMERMAN, 1992). Here we also attempt to consider the opposite mechanism, i.e. magma-controlled deformation. At rapidly convergent margins, such as the Andes, one might expect that horizontal compression prevents the rise of magma through the brittle upper crust (HUBBERT & WILLIS, 1957; HAMILTON, 1995). Nevertheless, volcanic activity is also common in compressional environments. Such a contradiction highlights the lack of understanding of the mechanical interplay between magmatism and deformation. We therefore address the processes of magma-controlled deformation in compressional settings. We first describe two geological examples of magmatic complexes emplaced in such settings, Tromen volcano, Neuquén basin, Argentina, and the Boulder batholith, Montana, USA. Subsequently, we present results of experimental modelling of magma emplacement during shortening. Thus, we show that magma can transport in a shortening crust, and that magma-controlled deformation processes can play an important role in the structural development of the upper crust. KEY WORDS: magma-controlled tectonics, compressional tectonics, Tromen volcano, experimental modelling. RIASSUNTO Tettonica controllata dai magmi in contesti collisionali: approfondimenti da esempi geologici e modelli sperimentali. L’attività magmatica tende a concentrarsi ai margini delle placche litosferiche. Lungo i margini soggetti a rapida convergenza, come le Ande, l’intensa attività magmatica è coeva con elevato raccorciamento tettonico, ed alcuni vulcani e intrusioni magmatiche si sono messi in posto in corrispondenza di strutture compressionali attive, solitamente i sovrascorrimenti principali. Per comprendere i legami tra i sistemi magmatici e le strutture di deformazione compressiva nella crosta superiore, descriviamo qui le strutture di un vulcano attivo (Tromen, Argentina) e di un’intrusione esumata (Boulder Batholith, U.S.A.) messi in posto durante deformazione compressiva. In questi esempi, sistemi magmatici e sovrascorrimenti mostrano relazioni geometriche e cronologiche. Presentiamo anche i risultati di modelli sperimentali di messa in posto di magmi in regime compressivo. Il confronto tra esempi geologici ed esperimenti analogici dimostra strette similitudini. Ciò suggerisce che la presenza di magma influenzi la configurazione della deformazione nella crosta fragile. L’infuenza di corpi magmatici profondi deve quindi essere esplorata alla scala dell’intera crosta durante l’evoluzione dei margini attivi. TERMINI CHIAVE: tettonica controllata dai magmi, tettonica compressiva, vulcano Tromen, modellazione sperimentale. (*) Géosciences-Rennes (UMR 6118), CNRS et Université de Rennes 1, Campus de Beaulieu - 35042 Rennes Cedex, France. (**) Physics of Geological Processes (PGP), Universitet i Oslo, Physics building, third floor, Sem Selands vei, 24 - NO-0316 Oslo, Norway (Fax: +47 22 85 51 01; E-mail: [email protected]). GEOLOGICAL OBSERVATIONS It is well known that magmatic activity is common at convergent margins. However, only a few studies have addressed the association between magmatic complexes and thrust faults (e.g. HOLLISTER & CRAWFORD, 1986; PARRY et alii, 1997; TIBALDI, 2005). Noticeable examples are Tromen volcano, Neuquén province, Argentina (GALLAND et alii, 2007b), and the Boulder batholith, Montana, USA (KALAKAY et alii, 2001). Tromen is a PleistoceneHolocene back-arc volcano, located in the northern segment of the Southern Andes (fig. 1). It lies in a thick- 206 O. GALLAND ET ALII Fig. 1 - Two geological examples of magmatic complexes emplaced in compressional tectonic setting: a) Simplified geological map of Tromen volcano, Neuquén basin, Argentina. Tromen is Andean alkaline back-arc Quaternary volcano, located on top of arcuate east-verging thrust. It built up during thrusting deformation. Modified after GALLAND et alii (2007b); b) Simplified geological map of Boulder batholith, Montana, USA. Boulder batholith was emplaced into Sevier fold-and-thrust belt, during thrusting deformation. Locally around Boulder batholith, thrust front exhibits strongly arcuate trace (Helena salient). Modified after KALAKAY et alii (2001). Structures of both Tromen volcano and Boulder batholith suggest control of magmatic complexes on deformation. – Due esempi geologici di complessi magmatici messi in posto in contesto tettonico collisionale: a) Carta geologica semplificata del vulcano Tromen, bacino di Neuquén, Argentina. Tromen è un vulcano quaternario andino alcalino di retro-arco, collocato sulla sommità di un sovrascorrimento arcuato vergente a Est. Si è sviluppato durante la deformazione che ha prodotto il sovrascorrimento. Modificato da GALLAND et alii (2007b); b) Carta geologica semplificata del batolite di Boulder, Montana, USA. Il batolite di Boulder si è messo in posto nella catena a pieghe e sovrascorrimenti di Sevier, durante la deformazione che ha prodotto i sovrascorrimenti. Localmente attorno a questo batolite il fronte di sovrascorrimento mostra un contorno molto arcuato (Helena salient). Modificato da KALAKAY et alii (2001). Le strutture del vulcano Tromen e del batolite di Boulder suggeriscono un controllo dei complessi magmatici sulla deformazione. Fig. 3 - a) Photograph of map view of typical model without injection. Piston (left) deformed model made of compacted silica powder. Straight thrusts accommodated shortening. Straight line locates cross section; b) Photograph and corresponding schematic drawing of cross section. Offset of horizontal markers locates faults (thrusts). Straight thrusts form at base of piston; c) Photograph of map view of typical model with injection. Straight and arcuate thrusts accommodated shortening. Poorly deformed plateau laid between straight and arcuate thrusts. Injected molten oil erupted along trace of arcuate thrust; d) Photograph and corresponding schematic drawing of cross section. Intruding oil (gray) forms basal sill. Straight thrusts form at base of piston. Arcuate thrust nucleate at leading edge of sill. Plateau lies above sill. – a) Immagine fotografica dall’alto di un tipico modello senza iniezione. A sinistra un modello deformato a pistone, composto di silice in polvere. I sovrascorrimenti rettilinei hanno accomodato il raccorciamento. La linea retta individua la sezione verticale; b) Fotografia e corrispondente disegno schematico della sezione verticale. La dislocazione dei riferimenti orizzontali individua le faglie (sovrascorrimenti). Alla base del pistone si formano sovrascorrimenti rettilinei; c) Immagine fotografica dall’alto di un tipico modello con iniezione. I sovrascorrimenti rettilieni e arcuati hanno accomodato il raccorciamento. Tra i sovrascorrimenti rettiliei e arcuati si trovano plateau poco deformati. Il liquido iniettato è eruttato lungo le tracce del sovrascorrimento arcuato; d) Fotografia e disegno schematico della sezione verticale. L’olio che s’intrude (grigio) forma sill basali. Alla base del pistone si formano sovrascorrimenti rettilinei. Alla terminazione frontale del sill nucleano sovrascorrimenti arcuati. Il plateau si trova al di sopra del sill. MAGMA-CONTROLLED TECTONICS IN COMPRESSIONAL SETTINGS 207 skinned fold-and-thrust belt in the western margin of the Neuquén basin (COBBOLD & ROSSELLO, 2003). Its volcanic products are unconformable upon Mesozoic strata of the basin. It built up above the hanging-wall of a major eastward-verging thrust fault (fig. 1). The Boulder batholith is a Cretaceous intrusive complex, east of the major Idaho-Bitterroot batholith (KALAKAY et alii, 2001). It was emplaced in the upper crust, within the Sevier fold-and-thrust belt (fig. 1). It has a flat-lying tabular shape, and an estimated thickness between 5 and 12 km. Both Tromen volcano and the Boulder batholith have close chronological and structural relationships with their substrata (fig. 1): 1) They lie close to major thrust faults. 2) Their emplacement was coeval with thrusting. 3) The thrust fronts have strongly arcuate shapes around the volcano or batholith. Geological observations on Tromen volcano and the Boulder batholith show close relationships between thrusting and magmatism (KALAKAY et alii, 2001; LAGESON et alii, 2001; GALLAND et alii, 2007b). They show that magma can ascend and be emplaced in compression and that thrust faults are likely to control magma transport. In addition, the arcuate thrusts around the volcano or batholith may result from the influence of magma upon Fig. 2 - Schematic drawing of experimental setup (see text for explanations). – Disegno schematico dell’impianto sperimentale (vedi il testo per le spiegazioni). the deformation pattern. The following experimental results illustrate how magmatic activity may control compressional deformation. Fig. 3. 208 O. GALLAND ET ALII EXPERIMENTAL MODELLING In order to study the mechanical interactions between compressional deformation and magmatic intrusion, we resorted to laboratory experiments, in which an analogue of the brittle crust shortened, while melt was intruding (fig. 2). We used (1) a cohesive fine-grained silica powder to represent the brittle crust, and (2) a molten low-viscosity vegetable oil to represent magma (GALLAND et alii, 2006). In the experiments, horizontal shortening and injection were coeval but independent. Shortening resulted in thrust faults, while overpressured oil formed tabular intrusions. In those experiments where there was no injection, shortening resulted in a classical thrust wedge, in which thrusts had straight traces and were 5-6 cm apart (fig. 3; GALLAND et alii, 2003; GALLAND et alii, 2007a); the apical angle of the wedge was about 15º. In the other experiments, where there was injection, oil formed a basal sill, and the structure of the wedge was very different. Once in place, the sill lubricated the base of the model, so that arcuate thrusts formed at the leading edge of the sill (fig. 3). The distance between thrusts increased, defining a non-deformed plateau. The apical angle of the wedge was smaller than 10º. Uplift of the plateau promoted further intrusion of oil at depth. In general, the pattern of deformation and intrusion depended on the kinematic ratio R between rates of shortening and injection (GALLAND et alii, 2007a). The lengths of the basal sill and plateau increased with decreasing R. Thus, from our experiments we infer that a small amount of magma in a deforming brittle crust strongly modifies the deformation pattern. Intrusions control the formation of arcuate thrusts and slightly deformed plateaus by lubricating their bases. DISCUSSION AND CONCLUSIONS There are close similarities between Tromen or the Boulder batholith and our experimental results. According to the geological observations, melts rose and was emplaced during thrusting. In addition, thrusts have similar arcuate shapes around the magmatic complexes, which are in the hanging walls of the arcuate thrusts. Thus we infer that arcuate structures around Tromen volcano and the Boulder batholith have resulted from the interaction between compressional deformation and nonsolidified magma. Similar relationships between thrusts and active volcanoes exist at Guagua Pichincha, Ecuador (LEGRAND et alii, 2002), Socompa, Chile (VAN WYK DE VRIES et alii, 2001), and Taapaca, Chile (CLAVERO et alii, 2004). We therefore suspect that similar processes were at work in those volcanoes. Our experimental results show that magmatic systems submitted to compression can control the formation and the shape of thrust faults in a upper brittle crust. Such magma-controlled processes are likely to be of firstorder importance in the development of compressional active margins, such as the Andes, and possibly beyond the scale of the upper crust. At large scale, the potential mechanical impact of deep magmatic intrusions should be explored in models of active margins. REFERENCES BARRAUD J., GARDIEN V., ALLEMAND P. & GRANDJEAN P. (2001) Analog modelling of melt segregation and migration during deformation. Phys. Chem. Earth, 26, 317-323. BROWN M. & SOLAR G.S. (1998) - Shear-zone systems and melts: feedback relations and self-organization in orogenic belts. J. Struct. Geol., 20, 211-227. BROWN M. & SOLAR G.S. (1999) - The mechanism of ascent and emplacement of granite magma during transpression: a syntectonic granite paradigm. Tectonophysics, 312, 1-33. BUROV E., JAUPART C. & GUILLOU-FROTTIER L. (2003) - Ascent and emplacement of buoyant magma bodies in brittle-ductile upper crust. J. Geophys. Res., 108, doi:10.1029/2002JB001904. 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(2006) - Use of vegetable oil and silica powder for scale modelling of magmatic intrusion in a deforming brittle crust. Earth Planet. Sci. Let., 243, 786-804. GALLAND O., DE BREMOND D’ARS J., COBBOLD P.R. & HALLOT E. (2003) - Physical models of magmatic intrusion during thrusting. Terra Nova, 15, 405-409. G ALLAND O., H ALLOT E., C OBBOLD P.R., R UFFET G. & DE B RE MOND D ’A RS J. (2007b) - Volcanism in a compressional Andean setting: A structural and geochronological study of Tromen volcano (Neuquén province, Argentina). Tectonics, 26, TC4010, doi:10.1029/2006TC002011. HAMILTON W.B. (1995) - Subduction systems and magmatism. In: J.L. Smellie (Editor), Volcanism Associated with Extension at Consuming Plate Margins. Geol. Soc. Lond. Spec. Pub., pp. 3-28. HOLLISTER L.S. & CRAWFORD M.L. (1986) - Melt-enhanced deformation: A major tectonic process. Geology, 14, 558-561. HUBBERT M.K. & WILLIS D.G. (1957) - Mechanics of hydraulic fracturing. In: M.K. Hubbert (Editor), Structural Geology. Hafner Publishing Company, New York, pp. 175-190. KALAKAY T.J., JOHN B.E. & LAGESON D.R. (2001) - Fault-controlled pluton emplacement in the Sevier fold-and-thrust belt of southern Montana. J. Struct. Geol., 23, 1151-1165. LAGESON D.R., SCHMITT J.G., HORTON B.K., KALAKAY T.J. & BURTON B.R. (2001) - Influence of Late Cretaceous magmatism on the Sevier orogenic wedge, western Montana. Geology, 29, 723-726. LEGRAND D., CALAHORRANO A., GUILLIER B., RIVERA L., RUIZ M., VILLAGOMEZ D. & YEPES H. (2002) - Stress tensor analysis of the 19981999 tectonic swarm of northern Quito related to the volcanic swarm of Guagua Pichincha volcano, Ecuador. Tectonophysics, 344, 15-36. MARRETT R. & EMERMAN S.H. (1992) - The relations between faulting and mafic magmatism in the Altiplano-Puna plateau (central Andes). Earth Planet. Sci. Let., 112, 53-59. PARRY M., STIPSKA P., SCHULMANN K., HROUDA F., JEZEK J. & KRONER A. (1997) - Tonalite sill emplacement at an oblique plate boundary: northeastern margin of the Bohemian Massif. Tectonophysics, 280, 61-81. ROSENBERG C.L. & HANDY M.R. (2000) - Syntectonic melt pathways during simple shearing of a partially molten rock analogue (Norcamphor-Benzamide). J. Geophys. Res., 105, 3135-3149. TIBALDI A. (2005) - Volcanism in compressional tectonic settings: Is it possible? Geophys. Res. Lett., 32, doi:10.1029/2004GL021798. VAN WYK DE VRIES B., SELF S., FRANCIS P.W. & KESZTHELYI L. (2001) - A gravitational spreading origin for the Socompa debris avalanche. J. Volcanol. Geotherm. Res., 105, 225-247. Received 30 October 2007; revised version accepted 28 February 2008 Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 209-211, 2 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Subduction zone earthquake mechanisms and the H2O content of subducting lithosphere H.W. GREEN, II (*) ABSTRACT Brittle fracture and frictional sliding are impossible below a few tens of km yet earthquakes occur in subducting lithosphere to ~700 km. Experimental work shows that at high pressure a small amount of low-viscosity «fluid» must be generated to enable shear failure and comparison with the earthquake distribution in the upper 300 km of subducting slabs strongly indicates that the method of earthquake initiation is dehydration of hydrous phases. In contrast, the earthquake distribution below 400 km shows no correlation with potential H2O-liberating reactions; indeed assuming that hydrous phases are present predicts earthquakes in places where they are not observed. Thus, the earthquake distribution suggests that H2Oreleasing reactions do not take place in the mantle transition zone. In addition, metastable olivine has now been detected by seismic means in 2 subduction zones. Such metastable olivine can explain the earthquake distribution and also is incompatible with the presence of H2O, even in very small amounts. I conclude that subduction zones are essentially dry below 400 km. KEY WORDS: antigorite serpentine, dehydration embrittlement, metastable olivine. RIASSUNTO I meccanismi sismici in zona di subduzione e il contento di H2O nella litosfera subdotta. Fratturazione fragile e scivolamento frizionale sono impossibili al di sotto di poche decine di chilometri, sebbene i terremoti avvengano nelle litosfere in subduzione sino a ~700 km. I risultati sperimentali dimostrano che ad alta pressione dev’essere generata una piccola quantità di «fluido» a bassa viscosità per permettere il cedimento per taglio e il confronto con la distribuzione dei terremoti nei 300 km superiori delle placche in subduzione indica fortemente che il modo d’inizio di un terremoto sia la deidratazione di fasi idrate. Al contrario, la distribuzione dei terremoti al di sotto di 400 km non mostra correlazione con potenziali reazioni che comportano il rilascio di H2O; inoltre l’assunzione che siano presenti fasi idrate predice terremoti dove questi non sono osservati. Quindi la distribuzione dei terremoti suggerisce che le reazioni che liberano H2O non avvengano nella zona di transizione del mantello. In aggiunta, olivina metastabile è stata di recente individuata con mezzi sismici in due zone di subduzione. Questa olivina metastabile può spiegare la distribuzione dei terremoti ed è anche incompatibile con la presenza d’acqua, pure in quantità ridotte. Io concludo che le zone di subduzione siano sostanzialmente anidre al di sotto dei 400 km. TERMINI CHIAVE: serpentino antigoritico, infragilimento da deidratazione, olivina metastabile. Unassisted brittle shear failure and/or frictional sliding on pre-existing faults, the mechanisms by which (*) Department of Earth Sciences and Institute of Geophysics & Planetary Physics, University of California, Riverside, CA, USA. [email protected] materials fail by shearing at low pressure are impossible at depths in excess of a few tens of km in Earth because brittle failure and friction are strongly inhibited by increasing pressure and plastic flow is enhanced exponentially by increasing temperature (see reviews by GREEN & HOUSTON, 1995; GREEN, 2007). Laboratory experiments show that shearing instabilities at pressures above ~3 GPa only occur in the presence of a small amount of a phase that has an effective viscosity very much lower than the dominant material. Generation of such «fluid» can be a natural consequence of the rising temperature and/or pressure in subducting material. Examples are: (a) dehydration embrittlement (RALEIGH & PATERSON, 1965); (b) transformation-induced faulting (GREEN & BURNLEY, 1989; GREEN et alii, 1990); (c) thermal runaway leading to melting (KARATO et alii, 2001; GREEN & MARONE, 2002). The requirement of presence of a small amount of «fluid» combined with the observed distribution of earthquakes at high pressure (restriction to subduction zones) indicates that such «fluid»-producing mineral reactions must be occurring at sites of earthquake generation. Dehydration embrittlement has been demonstrated in a variety of hydrous phases (e.g. RALEIGH & PATERSON, 1965; JUNG et alii, 2004) and is strongly implicated as the trigger mechanism of intermediate-depth earthquakes (70-300 km) (PEACOCK, 2001; HACKER et alii, 2003). Antigorite serpentine is capable of initiating such a shearing instability during dehydration under stress at pressures from 0.1 to 6 GPa in the laboratory (JUNG et alii, 2004), a range over which the volume change accompanying dehydration changes from positive to negative, yet the shearing instability occurs under all conditions. The instability does not disappear when the net volume change of reaction becomes negative (∆Vreaction < 0) because the instability is not dependent upon the net volume change but rather upon the ∆V of fluid and solid components independently; under all conditions the fluid remains less dense than the solid matrix (∆Vfluid > 0) and the nanocrystalline solid reaction products remain more dense (∆Vsolid < 0); rather than canceling each other out, they both participate in the instability via formation of microcracks and microanticracks, respectively (JUNG et alii, 2004). Exsolution of very small quantities of H2O from nominally anhydrous phases can also trigger instability in the laboratory (ZHANG et alii, 2004). It is thus highly likely that dehydration under stress of any reasonably abundant phase in subducting lithosphere can trigger earthquakes. Here I use this logic to argue that subducting lithosphere is progressively «wrung dry» over the depth interval 210 H.W. GREEN, II Fig. 1 - Cartoon of an oceanic subduction zone showing 3 populations of earthquakes: (1) grey dots (red in the colour version) symbolize earthquakes generated by dehydration embrittlement of hydrous crustal and mantle phases in the upper 10-12 km of subducting lithosphere; (2) white diamonds symbolize earthquakes generated by dehydration of antigorite and/or chlorite if hydration of mantle lithosphere at trenches extends sufficiently deep; some of these at depths < 100 km could also be generated by plastic instability of fine-grained material in recrystallized subducted outer-rise faults; (3) transition zone earthquakes (black dots) that could be initiated by dehydration of DHMS or wadsleyite/ringwoodite (collectively referred to in the fig. as «spinel»), or breakdown of metastable olivine-evidence presented in the text-favors the latter. Modified after GREEN (2005). – Schema di una zona di subduzione oceanica che mostra 3 popolazioni di terremoti: (1) i punti grigi rappresentano terremoti generati per infragilimento da deidratazione di fasi idrate nella crosta e nel mantello dei 10-12 km superiori di una litosfera che subduce; (2) i rombi bianchi rappresentano i terremoti generati per deidratazione di antigorite e/o di clorite se l’idratazione del mantello litosferico si estende sufficientemente in profondità sotto le fosse; alcuni di questi a profondità inferiore a 100 km possono anche essere generati da instabilità plastica di materiale a grana fine lungo faglie subdotte e ricristallizate; (3) terremoti della zona di transizione (punti neri) che potrebbero essere iniziati dalla deidratazione di DHMS o wadsleyite/ringwoodite (genericamente indicate in fig. come «spinel»), o destabilizzazione di olivina metastabile – le evidenze presentate nel testo favoriscono le ultime. Modificato da GREEN (2005). 50-400 km and that only very small amounts of H2O exist in such lithosphere below that depth (fig. 1). The evidence is the following: (1) Earthquake frequency declines exponentially between 70 and 300 km (suggesting that the cause of the instability is being exhausted) (fig. 2); (2) the resurgence of earthquakes in the transition zone could, in principle, be triggered by dehydration of dense hydrous magnesium silicates (DHMS, the «alphabet phases»; ANGEL et alii, 2001; POLI & SCHMIDT, 2002) but the continuous production of earthquakes with a maximum at ~600 km and the sudden termination before 700 km (correlating with the breakdown reaction of ringwoodite spinel to magnesium silicate perovskite + magnesiowüstite that, because slabs are colder than surrounding mantle, takes place somewhat deeper in subduction zones than elsewhere where it occurs at ~660 km; fig. 1) are inconsistent with the conditions under which the DHMS exhibit Fig. 2 - Semilog plot of global earthquake frequency expressed as a histogram of the number of earthquakes in 10-km thick concentric layers. At depths more shallow than ~30 km, earthquakes are distributed widely in the crust but at greater depths essentially all earthquakes are concentrated in subduction zones as shown in fig. 1. Although there is evidence for subduction to depths much greater than 700 km, no earthquake has ever been reliably located in the lower mantle (deeper than 700 km). Of principal note are the bimodal nature of the earthquake distribution, the exponential decrease in frequency between 30 and 300 km, and the abrupt termination below 600 km. Modified after FROHLICH (1989). – Diagramma semilogaritmico della frequenza globale espressa come un istogramma del numero di terremoti in livelli concentrici spessi 10-km. A profondità minori di ~30 km, i terremoti sono diffusi nella crosta ma a maggiore profondità sostanzialmente tutti i terremoti sono concentrati in zone di subduzione come appare in fig. 1. Nonostante l’evidenza di subduzione a profondità maggiori di 700 km, nessun terremoto è stato mai collocato attendibilmente nel mantello inferiore (a profondità maggiori di 700 km). Sono da notare soprattutto la natura bimodale della distribuzione dei terremoti, la decrescita esponenziale della frequenza fra 30 e 300 km e il drastico esaurimento al di sotto di 600 km. Modificato da FROHLICH (1989). mineral reactions (indicating that dehydration of these phases is unlikely to be involved in deep earthquakes); (3) significant amounts of DHMS can be stable only if the highly abundant phases wadsleyite and/or ringwoodite (collectively referred to as spinel in fig. 1) are fully saturated with H2O, which would require more water at depths of 200-300 km than could be consistent with the known mineral possibilities in the lithosphere and their seismic properties (CHEN & BRUDZINSKI, 2001; BRUDZINSKI & CHEN, 2003) (hence saturation is extremely unlikely); (4) tectonic stresses are not necessary for earthquakes to occur (BRUDZINSKI & CHEN, 2005) – local stresses generated by the ∆V between adjacent regions of unreacted and reacted mineral assemblages are sufficient (hence the ad hoc argument that earthquakes disappear because there are no stresses is unlikely to be valid); (5) if significant H2O is present in ringwoodite, wherever lithosphere passes through into the lower mantle there should be an abundance of earthquakes where that H2O is released during ringwoodite breakdown (the lack of such earthquakes implies that even small amounts of H2O in ringwoodite are unlikely); (6) if H2O gets passed from hydrous ringwoodite to phase D at the top of the lower mantle (hence avoiding constraint #5), there should be a SUBDUCTION ZONE EARTHQUAKE MECHANISMS flurry of earthquakes in the lower mantle during the dehydration of phase D, the last of the DHMS phases (such earthquakes are absent, strongly suggesting that phase D is also absent); (7) there is now strong seismic evidence for the presence of metastable olivine in two deep slabs (Tonga (e.g. CHEN & BRUDZINSKI, 2001) and Mariana (KANESHIMA et alii, 2007)), requiring that slabs in those subduction zones be essentially dry (because if significant H2O is present, the kinetics of the ol→spinel reactions would be enhanced sufficiently that metastable olivine would not be preserved (DU FRANE & SHARP, 2007). It could be argued that dehydration of antigorite at depths of 200-250 km should lead to enhanced dissolution of H2O into olivine and pyroxenes, with that H2O then carried into the transition zone. However, the empirical evidence cited above strongly suggests that doesn’t happen. One possible explanation is that the recent evidence for likely low oxygen fugacity at depths in excess of ~250 km (ROHRBACH et alii, 2007) drastically reduces the H2O fugacity, subverting its solubility in silicates and/or its catalytic effect on mineral reactions. In summary, the exponential decline in earthquake frequency between 70 and 300 km suggests exhaustion of a critical factor in their generation. The only factor that seems a logical possibility is exhaustion of the availability of hydrous phases to initiate the earthquakes. Despite the experimentally-demonstrated water-carrying capacity of the nominally anhydrous upper mantle phases and the DHMS, the abundance and distribution of earthquakes bears no recognizable relationship to their experimentally-determined properties and phase boundaries; there is a lack of earthquakes in locations where they would be expected if H2O is significantly present and being liberated, and an abundance of earthquakes in locations where H2O, if present, would not be expected to be liberated. In contrast, there are earthquakes where independent seismic evidence strongly suggests the presence of metastable olivine which is incompatible with the presence of significant H2O. These observations singly and in concert imply that (i) dehydration embrittlement is at best a minor trigger of earthquakes in the mantle transition zone and (ii) subduction zones deeper than ~400 km are essentially dry. 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Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Non-equilibrium thermodynamics and the coupling between deformation and metamorphism BRUCE HOBBS (*) & ALISON ORD ABSTRACT The concept of non-equilibrium phase diagrams is explored and an example presented for the quartz-coesite reaction. The equilibrium phase boundary is relevant for systems undergoing mineral reactions only for very high temperatures and very low strain rates. The influence of strain rate is to modify the equilibrium ClausiusClapeyron slope by a factor that is similar in magnitude to that slope. Increases in strain rate remove the non-equilibrium phase boundary further from the equilibrium phase boundary. This explains the common observation that mineral reactions proceed to completion in shear zones rather than in adjacent undeformed material. KEY WORDS: non-equilibrium phase diagrams, entropy production, deformation enhanced reactions. RIASSUNTO Termodinamica di disequilibrio ed interazione tra deformazione e metamorfismo. In questo contributo si analizza il concetto di diagrammi di fase in non-equilibrio a cui è associato un esempio sulla transizione quarzo-coesite. Il limite di fase in equilibrio è rilevante per sistemi che subiscono reazioni mineralogiche solo in condizioni di temperatura molto alta e di bassa velocità di deformazione. L’influenza della velocità di deformazione è di modificare la pendenza dell’equilibrio di un fattore dello stesso ordine di grandezza della pendenza. Gli aumenti di velocità di reazione allontanano il limite di fase in nonequilibrio dal limite di fase in equilibrio. Questo spiega l’osservazione comune che le reazioni minerali procedono a compimento nelle zone di taglio piuttosto che nel materiale adiacente indeformato. TERMINI CHIAVE: diagrammi di fase di non-equilibrio, produzione d’entropia, reazioni amplificate dalla deformazione. INTRODUCTION Non-equilibrium thermodynamics increasingly has very wide application in many fields of science and engineering (COUSSY, 2004; OTTINGER, 2005) but apart from a flurry of activity in the 1960’s to 1980’s (KAMB, 1959; KORZHINSKII, 1959; PATERSON, 1973; FISHER, 1973) there has been relatively little application within geology. Recently there has been a resurgence of interest in nonequilibrium thermodynamics with respect to damage mechanics in seismology (LYAKHOVSKY & BEN ZION, (*) CSIRO Exploration and Mining, Perth, Australia; University of Western Australia, Perth, Australia. Corresponding author - Telephone: +61 418 395 545. E-mail: [email protected] 1997) and in structural geology/geodynamics (REGENAUER-LIEB & YUEN, 2003; HOBBS et alii, 2007a; HOBBS et alii, in press). In this abstract we set out to discuss some important applications of non-equilibrium thermodynamics to deforming, reacting metamorphic systems. We make a distinction between classical chemical thermodynamics (CEM) where minimisation of the Gibbs Free Energy defines the stable states and non-equilibrium thermodynamics where either minimisation or maximisation of the entropy production rate defines the stable phases. The problem in applying non-equilibrium thermodynamics to geological problems derives from the apparent lack of a set of guiding principles that would allow progress. In any system, whether at equilibrium or not, one can define a function, The Gibbs Free Energy. This function is minimised at equilibrium and so one can proceed to define equilibrium assemblages of minerals. Another function, the entropy, is maximised at equilibrium. For non-equilibrium systems, it has never been clear, until recently, that a similar principle was available. In fact, two apparently opposing views seemed to emerge in the literature. One is due to PRIGOGINE (1955) who claimed that in non-equilibrium systems, the rate of entropy production is minimised. The other view is due to ZEIGLER (1980) who claimed that the rate of entropy production is maximised in non-equilibrium systems. This apparent paradox is resolved when one understands that the Prigogine principle holds for linear steady state systems whereas the Zeigler principle holds for systems that are not constrained to be at steady state. This now opens the way to describe the evolution of geological systems that are forced out of equilibrium by continued deformation, fluid flow, heat flow and chemical reactions. We employ the Prigogine principle below to understand the construction of non-equilibrium phase diagrams and why deformation enhances the progress of metamorphic reactions. To focus the discussion we concentrate on metamorphic rocks undergoing only deformation and chemical reactions and exclude the effects of fluid transport; an introduction to this area is given by COUSSY (2004). As such, the energy dissipated during deformation and metamorphism consists of four parts: (i) That due to mechanical processes; this comprises dissipation arising from deformation and from introducing chemical components into a deforming system by chemical reaction. (ii) That arising from the flux of chemical components across gradients in chemical potential and temperature. (iii) That arising from chemical reactions and (iv) That arising from thermal conduction. 214 B. HOBBS In many metamorphic rocks there is evidence of nonequilibrium in the form of partially reacted mineral assemblages and/or melting. An example is the Monte Mucrone in the Italian Alps (ZUCALI et alii, 2002). It is also commonly observed in such areas that in immediately adjacent rocks, the metamorphic reactions reach completion only in the highly deformed shear zones. The two important questions are: (i) In regions where the metamorphic reactions have not proceeded to completion, are estimates of P, T conditions derived from equilibrium theory relevant and/or accurate? and (ii) What role does deformation play in promoting metamorphic reactions? THE NON-EQUILIBRIUM CHEMICAL POTENTIAL (1) where σij is the deviatoric stress, P is the pressure, in this case, the mean stress, T is the absolute temperature and ξK is the extent of the chemical reaction that produces the Kth component. Explicit forms of this state equation are given by PATERSON (1973) and SHIMIZU (1997). To be explicit here the pressure is – 1 (σ 11 + σ 22 + σ 33 ). 3 Even in a system not at equilibrium, at a phase boundary the difference in the sum of the chemical potentials of the phases on either side of the boundary is zero, as is also the difference in the affinities of the reactions involved. An important difference between the nonequilibrium and the classical chemical potential is that the pressure for the non-equilibrium situation is measured by the mean stress. As the stress relaxes to hydrostatic and the chemical reactions proceed to completion, the non-equilibrium chemical potential evolves to become the classical chemical potential. From equation (1), dµ K = or, ∂µ K ∂µ K ∂µ K ∂µ K dσ ij + dP + dT + dξ K K ∂σ ij ∂P ∂T ∂ξ dµ K = ε ijK dσ ij + V K dP − S K dT + A K dξ K (2) (3) K where εΚ ij is the elastic strain of component K, V is the K volume of component K, S is the entropy of component K and AK is the affinity of the reaction that produces K. At this stage we focus in on a particular simple kind of chemical reaction, namely, A⇔B Then, for example, equation (3) becomes dµ coesite = ε ijcoesitedσ ij + V coesitedP − S coesitedT + A coesitedξ coesite (5) – We define A = Acoesite – Aquarz. Then arguments presented by KONDUPEDI & PRIGOGINE (1998) mean that for the entropy production rate to be a minimum, A coesite = Lquartz A ( Lquartz + Lcoesite ) and A quartz = Lcoesite A ( Lquartz + Lcoesite ) (6) where LK is the coefficient that links the extent of reaction K to the affinity of that reaction (KONDEPUDI & PRIGOGINE, 1998). NON EQUILIBRIUM PHASE DIAGRAMS The chemical potential of a component is a quantity that measures the energy required to insert 1 mole of that component into a system under adiabatic conditions. This definition is relevant whether the system is or is not at equilibrium. Consider a system with K chemical components. We define the non-equilibrium chemical potential, µK, of the Kth component inserted into a deforming, chemically reactive system as (KONDEPUDI & PRIGOGINE, 1998; COUSSY, 2004): µK = µK(σij, P, T, ξK) & A. ORD (4) where A is, for example, quartz or graphite and B is coesite or diamond respectively. From equation (3) we obtain: d( ∆µ ) = ∆ε ij dσ ij + ∆VdP − ∆SdT + ∆Adξ (7) where ∆(.) is the change in (.) during the chemical reaction and deformation. That is ∆S = Scoesite – Squarz and so on. At a phase boundary, d(∆µ) = 0 and ∆A = 0 hence, dP ∆S ∆ε ij dσ ij = − dT ∆V ∆V dT (8) Thus, at a phase boundary the classical ClausiusClapeyron slope at equilibrium, ∆S/∆V is modified in the non-equilibrium case by a term involving the elastic strain contrast between the two phases and the temperature derivative of the deviatoric stress tensor. If the strains are elastic then this latter term involves only the temperature dependence of the elastic moduli. If the total strains arise from steady state power-law creep of the . form σij = L–1/N ε ij (J2)1/(N–1) exp(Q/RT) then, dP ∆S ∆ε ij Q = + L−1/ N ε˙ ij ( J2 )1/( N −1) exp(Q / RT ) (9) dT ∆V ∆V RT 2 at a phase boundary. Hence, for a fixed strain rate, dP/dT approaches the non-equilibrium Clausius-Clapeyron slope at high temperatures but at low temperatures, the second term on the right hand side of (9) can be of similar magnitude to the classical Clausius-Clapeyron slope, ∆S/∆V. As the strain rate decreases at constant temperature, dP/dT approaches the classical equilibrium Clausius-Clapyron dP/dT slope. This behaviour is illustrated in fig. 1. The non-equilibrium phase boundary between two phases, A and B, represents the boundary between two regions where A is stable on one side and B on the other so long as the stress is maintained on the system. Although these states are stable they are not stable equilibrium states; nor are they unstable equilibrium states so that terms such as «overstepping» should not be used to describe these states. INFLUENCE OF DEFORMATION ON THE EXTENT OF A CHEMICAL REACTION Following COUSSY (2004) we can write ξK = ∂Ψ(ε ij , P, T , A K ) ∂A K NON-EQUILIBRIUM THERMODYNAMICS Fig. 1 - Non-equilibrium pressure-temperature phase diagram with the equilibrium phase boundary shown dashed. The full line is the non-equilibrium phase boundary asymptotic to the equilibrium phase boundary at high temperatures. The non-equilibrium phase boundary moves to the left with decreasing strain rate. The assemblage at point A is not stable under equilibrium conditions but is stable under non-equilibrium conditions. – Diagramma di fase pressione-temperatura di non-equilibrio, con il limite di fase d’equilibrio a tratteggio. La linea a tratto continuo è il limite di fase di non-equilibrio asintotico al limite di fase d’equilibrio ad alta temperatura. Il limite di fase di non-equilibrio si sposta a sinistra con velocità di deformazione decrescente. La paragenesi al punto A non è stabile alle condizioni d’equilibrio ma è stabile alle condizioni di non-equilibrio. 215 Fig. 2. - Non-equilibrium phase boundaries at two different strain ra. tes, εijI (slow) and ε ijII (faster). The assemblage at point A is unstable at the slow strain rate but stable at the higher strain rate. In this way an assemblage may grow only in shear zones undergoing higher strain rates than in the adjacent relatively undeformed rocks. – Limiti. di fase di non-equilibrio a due differenti velocità di deforma. zione, εijI (bassa) ed ε ijII (alta). La paragenesi al punto A è instabile a bassa velocità di deformazione ma stabile a velocità di deformazione più elevata. In tal modo una paragenesi si può sviluppare solo in zone di taglio soggette ad alta velocità di deformazione piuttosto che nelle rocce adiacenti relativamente poco deformate. CONCLUSIONS where Ψ is the Helmholtz Free Energy. We then obtain: dξ K = ∂2 Ψ ∂A K ∂ε ij dε ij + ∂2 Ψ ∂A K ∂P dP + ∂2 Ψ ∂A K ∂T dT + ∂2 Ψ ∂A K 2 dA K (10) At constant pressure and temperature this reduces to dξK = αdεij + βdAK (11) where α is the parameter that measures how the extent of a reaction changes with strain and β is a parameter that measures how the extent of a reaction depends on the affinity of that reaction. For the reaction described by (4) KONDEPUDI & PRIGOGINE (1998) discuss the form of β for a situation corresponding to minimum entropy rate production. The relation between the extent of a reaction and the strain is discussed by COUSSY (2004). Without proceeding to detail here, equation (11) says that the extent of a reaction is increased by increases in strain and by increases in the affinity of the reaction. Thus increased strain enhances the progress of a chemical reaction although we need to point out that this is true so long as α ≠ 0. This means that the reaction must contribute to the strain either through a volume change or through the preferred diffusion of chemical components. However there is another important factor involved in the enhancement of chemical reaction by deformation. Fig. 2 shows the influence of strain rate on the position of the non-equilibrium phase boundary. At low strain rates a particular P, T environment may be below a phase boundary for low strain rates but be above the phase boundary for higher strain rates. Thus a region may be such that a phase such as coesite or diamond is not stable at the ambient strain rate but is stable within shear zones in that same environment. (i) In regions where the metamorphic reactions have not proceeded to completion, estimates of P, T conditions derived from equilibrium theory are relevant only at high temperatures and low strain rates. If reactions have not proceeded to completion, the relevant measure of pressure is the mean stress and not the lithostatic pressure. (ii) Deformation plays an important role in promoting metamorphic reactions through a direct influence on the extent of the reaction. High strain rates displace the nonequilibrium stability field for a particular reaction from the equilibrium field so that reactions commonly are observed to proceed to completion within shear zones and not in adjacent relatively undeformed rocks. ACKNOWLEDGEMENTS BEH thanks the organisers of the 16th DRT meeting for the opportunity to sit in the Italian Alps and think about non-equilibrium phase diagrams. REFERENCES COUSSY O. (2004) - Poromechanics. Wiley, Chichester, 298 pp. FISHER G.W. (1973) - Non-equilibrium thermodynamics as a model for diffusion-controlled metamorphic processes. Amer. J. Sci., 273, 897-924. HOBBS B.E., REGENAUER-LIEB K. & ORD A. (2007a) - Thermodynamics of folding in the middle to lower crust. Geology, 35, 175178. HOBBS B.E., REGENAUER-LIEB K. & ORD A. (in press) - Folding with thermal-mechanical feedback. Jour. Struct. Geol. KONDEPUDI D. & PRIGOGINE I. (1998) - Modern Thermodynamics. Wiley, Chichester, 486 pp. KORZHINSKII D.S. (1959) - Physiochemical basis of the analysis of the paragenesis of minerals. Consultants Bureau, New York, 142 pp. LYAKHOVSKY V. & BEN-ZION Y. (1997) - Distributed damage, faulting, and friction. Jour. Geophys. Res., 102, 27635-277649. 216 B. HOBBS O TTINGER H.C. (2005) - Beyond Equilibrium Thermodynamics. Wiley, Hoboken, 617 pp. PATERSON M.S. (1973) - Nonhydrostatic thermodynamics and its geologic applications. Rev. Geophys. Space Phys., 11, 355. PRIGOGINE I. (1955) - Introduction to the Thermodynamics of Irreversible Processes. Charles C. Thomas, Springfield, Ill. 115 pp. REGENAUER-LIEB K. & YUEN D.A. (2003) - Modeling Shear Zones in Geological and Planetary Sciences: Solid- and Fluid- ThermalMechanical Approaches. Earth Science Reviews, 63, 295-349. & A. ORD SHIMIZU I. (1997) - The non-equilibrium thermodynamics of intracrystalline diffusion under non-hydrostatic stress. Phil. Mag., 75, 1221-1235. ZIEGLER H. (1983) - An Introduction to Thermomechanics. NorthHolland Publishing Company, Amsterdam, 2nd edition, 356 pp. ZUCALI M., SPALLA M.I. & GOSSO G. (2002) - Strain partitioning and fabric evolution as a correlation tool: the example of the Eclogitic Micaschists Complex in the Sesia-Lanzo Zone (Monte MucroneMonte Mars, Western Alps, Italy). Schweiz. Mineral. Petrogr. Mitt. 82, 429-454. Received 14 November 2007; revised version accepted 5 March 2008. Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 217-220, 4 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Interaction between brittle fracture and ductile flow during crustal deformation NEIL S. MANCKTELOW (*) La maggior parte dei modelli teorici di deformazione crostale assume che le rocce si fratturino secondo qualche criterio di cedimento (solitamente considerato come una semplice dipendenza lineare Mohr-Coulomb dalla pressione) o fluiscano in modo viscoso grazie alla plasticità cristallina o alla diffusione. Le osservazioni di terreno mostrano che esiste un’interrelazione più stretta tra flusso e frattura, con fratture precoci che localizzano zone di taglio duttile successive che possono, a loro volta, sovrapporsi a fratture discrete, con la conseguente implicazione di cicli multipli di comportamento fragile-duttile. Frattura e flusso possono essere coevi su piccole distanze, con perturbazioni attorno alle fratture attive che producono le caratteristiche strutture collaterali (flanking structures). I modelli reologici devono includere questo comportamento di interazione fragile-duttile se sono rivolti a una modellazione realistica della deformazione delle rocce. rocks with increasing depth implies distinct «brittle» and «ductile» rheological layers, corresponding to MohrCoulomb failure or viscous flow respectively (fig. 1) although, depending on the assumed geotherm, a compositionally layered lithosphere could have several such brittle-ductile transitions (e.g. RANALLI & MURPHY, 1987). A «Christmas-tree» envelope as shown in fig. 1 predicts very high differential stress at the depth of the brittle ductile transition (at least for relatively dry rocks and high strain rates), which is an artefact of the simplifying assumptions of constant strain rate and constant linear dependence of Mohr-Coulomb yield on pressure. Models involving constant force (CF) or strain-rate-dependent force (SRDF) as boundary conditions overcome the problem of unrealistically high stress levels (e.g. PORTH, 2000) as does recent evidence for high-pressure brittle fracture with a weaker dependence on the confining pressure (SHIMADA, 1993; ZANG et alii, 2007). Nevertheless, these models still imply that large regions of the crust deform exclusively by either brittle fracture or viscous crystal-plastic flow. Increasing the strain rate (fig. 1a) will shift the brittleductile transition to greater depth and this effect may be enhanced if the pore fluid pressure is also increased (fig. 1b). Such a shift in the depth of the transition could occur at the tip of a downward propagating seismic fault localized in the upper crust (e.g. ELLIS & STÖCKHERT, 2004). Cycles of seismic reactivation and intervening aseismic creep could thereby lead to periodic brittle and ductile behaviour in the middle to lower crust. However, in this simple conceptual model, the major part of the lithosphere away from the relatively narrow brittle-ductile transition zone is still considered to be either brittle or ductile at any particular depth and time. TERMINI CHIAVE: deformazione, reologia, crosta, litosfera, fragile, duttile, faglie, zone di taglio. FIELD OBSERVATIONS ABSTRACT Most theoretical models of crustal deformation assume that rocks either fracture according to some yield criterion (usually taken as a simple linear Mohr-Coulomb dependence on pressure) or flow in a viscous manner due to crystal plasticity or diffusion. However, direct field observation shows a much more intimate interplay between fracture and flow, with precursor fractures localizing subsequent ductile shear zones that may in turn be overprinted by discrete fractures, implying multiple cycles of brittle-ductile behaviour. Fracture and flow may be coeval over small distances, with the perturbation flow surrounding active fractures producing characteristic flanking structures. Rheological models must include this linked brittle-ductile behaviour if they are to realistically model rock deformation. KEY WORDS: deformation, rheology, crust, lithosphere, brittle, ductile, faults, shear zones. RIASSUNTO Interazione tra fratturazione fragile e flusso duttile durante la deformazione crostale. INTRODUCTION The «yield-strength envelope» (GOETZE & EVANS, 1979) is a simple 1D, constant strain rate (CSR) concept that has been very commonly applied in numerical, analogue and conceptual models of crustal, and on a larger scale, lithospheric deformation (e.g. RANALLI & MURPHY, 1987). This representation of the mechanical behaviour of (*) Geological Institute, ETH Zurich, CH-8092 Zurich, Switzerland, E-mail: [email protected] Nevertheless, it is becoming increasingly clear from field observation that in reality there is an intimate interplay in space and time between precursor heterogeneities (either structural or compositional), brittle fracture, fluidrock interaction and more distributed «ductile flow» (e.g. SEGALL & SIMPSON, 1986; GUERMANI & PENNACCHIONI, 1998; MANCKTELOW & PENNACCHIONI, 2005). In particular, there are now many well-documented examples of brittle precursors localizing subsequent ductile deformation under metamorphic conditions ranging from upper greenschist to granulite facies, conditions that are typical of the middle to lower crust. Fig. 2 is an example of a «paired shear zone» from the Neves area of the Tauern window in the eastern Alps (MANCKTELOW & PENNAC- 218 N.S. MANCKTELOW Fig. 1 - Simple 1D, constant strain rate «yield-strength envelope» for a 30 km thick crustal section approximated by brittle Mohr-Coulomb fracture with internal friction angle of 30º and power-law viscous flow of «average wet quartzite» according to PATERSON & LUAN (1990). The effect of increased strain rate (a) and a combination of increased strain rate and pore fluid pressure (b) on the depth of the brittle-ductile transition in a compressive tectonic regime is shown in cartoon form. – Semplice profilo di resistenza monodimensionale per una sezione di crosta spessa 30 km, approssimato da frattura fragile Mohr-Coulomb con angolo di frizione interna di 30° e da una legge esponenziale di flusso viscoso per una «quarzite idrata media» secondo PATERSON & LUAN (1990). L’effetto dell’aumento della velocità di deformazione (a) e della velocità di deformazione combinata alla pressione dei fluidi nei pori (b) sulla profondità della transizione fragile-duttile in un regime tettonico compressivo è mostrata in forma schematica. INTERACTION BETWEEN BRITTLE FRACTURE Fig. 2 - Precursor fracture localizing fluid infiltration, to produce a central epidote-rich vein and adjacent bleached zone of fluid-rock interaction, along the boundaries of which subsequent ductile shear has been localized to form a «paired shear zone» (see MANCKTELOW & P ENNACCHIONI , 2005). Sense of shear is dextral. Neves area, Eastern Alps. – Frattura precoce che localizza l’infiltrazione di fluidi, che produce una vena centrale ricca in epidoto e una zona di alterazione da interazione fluido-roccia, lungo i cui margini si localizza successivamente taglio duttile che genera una «zona di taglio appaiata» (vedi MANCKTELOW & PENNACCHIONI, 2005). Il senso di taglio è destro. Area di Neves, Alpi Orientali. CHIONI, 2005; PENNACCHIONI & MANCKTELOW, 2007). An initial precursor fracture has allowed fluid infiltration, with the development of a thin epidote-rich vein flanked by a bleached zone to either side as the result of fluidrock interaction. Most of these precursor structures are sealed joints and show no discernible shear offset prior to reactivation, even at the microscopic scale. Such joints, with lengths on the order of tens of metres and widths less than a millimetre, can only develop by extensional failure and not by localization of crystal plastic deformation. During dextral reactivation under amphibolite facies conditions, heterogeneous ductile shearing was localized on the boundaries of this bleached zone to develop the characteristic paired geometry. In rare cases, subsequent straight discrete fractures offset such ductile shear zones, and these fractures may themselves in turn be loci for localized shearing. These field relationships provide evidence for cycles of discrete brittle fracture and more distributed ductile shearing within a small area, although the time scale involved cannot be determined. Distributed ductile deformation and localized slip on discrete fractures can occur synchronously. A good example of this is seen in fig. 3, from the same general area as fig. 2. Precursor discrete fractures were sealed with newly grown quartz, plagioclase, biotite, and garnet indicating metamorphic temperatures consistent with regional peak metamorphic temperatures of around 550-600ºC. These fractures show a left-stepping geometry typical of Riedel fault development in an overall dextral shear. The sealed fractures have subsequently been reactivated, again in dextral shear, with the formation of a compressive bridge in the left-stepping zone. The compressive bridge develops a distributed foliation – a typical «ductile» structure – whereas slip on the precursor fractures remains localized (at least initially) on the fracture itself. Completely analo- 219 Fig. 3 - Ductile compressional bridge developed under amphibolite facies conditions at a step-over between two discrete fractures slipping with a dextral sense (see MANCKTELOW & PENNACCHIONI, 2005). Neves area, Eastern Alps. – Ponte duttile compressionale sviluppato in condizioni di facies anfibolitica in corrispondenza di una ripresa laterale (step-over) tra due fratture discrete che scorrono con un senso destro (vedi MANCKTELOW & PENNACCHIONI, 2005). Area di Neves, Alpi Orientali. Fig. 4 - Flanking fold structure developed around a discrete brittle fracture developed under amphibolite facies metamorphic conditions in calcite marble, Naxos, Greece. Sense of shear for this view is dextral; width of photograph ca. 15 cm. – Piega collaterale (flanking fold structure), intorno ad una frattura fragile discreta, sviluppatasi in un marmo in condizioni metamorfiche di facies anfibolitica, Naxos, Grecia. Il senso di taglio per questa vista è destro; ampiezza dell’immagine circa 15 cm. gous structures were described by PENNACCHIONI (2005) from the Adamello tonalite, with the interplay between slip on discrete fractures and distributed ductile strain in the stepovers also occurring under amphibolite facies conditions during cooling of the pluton. It is not necessarily the case that there are distinct periods of brittle and ductile behaviour, as would be implied by the models of fig. 1. Flanking structures developed around brittle faults (e.g. PASSCHIER, 2001; GRASEMANN & STÜWE, 2001; EXNER et alii, 2004; KOCHER & MANCKTELOW, 2005) are particularly clear examples of interacting brittleductile deformation, because their geometry can only be explained if discrete slip occurred synchronously 220 N.S. MANCKTELOW with the more distributed surrounding ductile flow. In fact, models assuming perfectly free slip on an isolated fracture within a viscous surrounding matrix best explain the observed flanking geometry and can be used to estimate both the amount of general shear and the kinematic vorticity number (KOCHER & MANCKTELOW, 2005). Examples of flanking structures developed in calcite marbles under amphibolite facies conditions (e.g. fig. 4) demonstrate that brittle fracturing can play an important role even in weak rocks at high temperature conditions generally taken to imply exclusively ductile or viscous behaviour. The interplay between fracture and flow can still occur at great depth, even under (ultra-) high pressure conditions. Initial seismic faulting under eclogite facies conditions in the Bergen Arcs of western Norway allowed water infiltration into otherwise dry rocks, localizing the transformation to eclogites and also localizing ductile shear zones on these precursor fractures (e.g. BOUNDY et alii, 1992). Both brittle fracture and ductile shearing occurred under the same metamorphic conditions, with the crucial factor being the influence of water and fluidrock interaction. A recent study by FUSSEIS et alii (2006) has also shown that shear zone localization in strongly anisotropic schists can also be controlled by brittle precursors, that shear zones lengthened by a combination of fracturing and mylonitic shearing, and that the overall geometry strongly reflects the interplay between brittle fracture and ductile flow. CONCLUSIONS Field-based studies in granitoids, schists, and even eclogite facies gneisses have established that brittle precursors and fluid-rock interaction may be critical for the initiation and localization of «ductile» shear zones in otherwise relatively homogeneous rocks. It follows that natural deformation structures and the bulk rheology and dynamics of the crust (and lithosphere) cannot be understood in terms of simple, non-interacting brittle and ductile models. More realistic models of lithospheric deformation must involve a combined elasto-visco-plastic rheology, also considering the importance influence of fluid-rock interaction and compositional heterogeneity on strain localization. ACKNOWLEDGEMENTS The ideas presented here are the result of many years of collaboration with Giorgio Pennacchioni, Bernhard Grasemann, Ulrike Exner, Thomas Kocher and Cees Passchier, whose contributions are gratefully acknowledged. REFERENCES BOUNDY T.M., FOUNTAIN D.M. & AUSTRHEIM H. (1992) - Structural development and petrofabrics of eclogite facies shear zones, Bergen Arcs, western Norway: implications for deep crustal deformational processes. J. Metam. Geol., 10, 127-146. ELLIS S. & STÖCKHERT B. (2004) - Elevated stresses and creep rates beneath the brittle-ductile transition caused by seismic faulting in the upper crust. J. Geophys. Res., 109, B05407. EXNER U., MANCKTELOW N.S. & GRASEMANN B. (2004) - Progressive development of s-type flanking folds in simple shear. J. Struct. Geol., 26, 2191-2201. FUSSEIS F., HANDY M.R. & SCHRANK C. (2006) - Networking of shear zones at the brittle-to-viscous transition (Cap de Creus, NE Spain). J. Struct. Geol., 28, 1228-1243. GOETZE C. & EVANS B. (1979) - Stress and temperature in the bending lithosphere as constrained by experimental rock mechanics. Geophys. J. R. Astr. Soc., 59, 463-478. GRASEMANN B. & STÜWE K. (2001) - The development of flanking folds during simple shear and their use as kinematic indicators. J. Struct. Geol., 23, 715-724. GUERMANI A. & PENNACCHIONI G. (1998) - Brittle precursors of plastic deformation in a granite: an example from the Mont Blanc massif (Helvetic, western Alps). J. Struct. Geol., 20, 135-148. KOCHER T. & MANCKTELOW N.S. (2005) - Dynamic reverse modelling of flanking structures: a source of quantitative kinematic information. J. Struct. Geol., 27, 1346-1354. MANCKTELOW N.S. & PENNACCHIONI G. (2005) - The control of precursor brittle fracture and fluid-rock interaction on the development of single and paired ductile shear zones. J. Struct. Geol., 27, 645-661. PASSCHIER C.W. (2001) - Flanking structures. J. Struct. Geol., 23, 951-962. PATERSON M.S. & LUAN F.C. (1990) - Quartzite rheology under geological conditions. In: Knipe R.J. & Rutter E.H. Eds., Deformation Mechanisms, Rheology and Tectonics. Geol. Soc. Lond. Spec. Publ., 54, 299-307. PENNACCHIONI G. (2005) - Control of the geometry of precursor brittle structures on the type of ductile shear zone in the Adamello tonalites, Southern Alps (Italy). J. Struct. Geol., 27, 627-644. PENNACCHIONI G. & MANCKTELOW N.S. (2007) - Nucleation and initial growth of a shear zone network within compositionally and structurally heterogeneous granitoids under amphibolite facies conditions. J. Struct. Geol., 29, 1757-1780. PORTH R. (2000) - A strain-rate-dependent force model of lithospheric strength. Geophys. J. Int., 141, 647-660. RANALLI G. & MURPHY D.C. (1987) - Rheological stratification of the lithosphere. Tectonophysics, 132, 281-295. SEGALL P. & SIMPSON C. (1986) - Nucleation of ductile shear zones on dilatant fractures. Geology, 14, 56-59. SHIMADA M. (1993) - Lithosphere strength inferred from fracture strength of rocks at high confining pressures and temperatures. Tectonophysics, 217, 55-64. ZANG S.X., WEI R.Q. & NING J.H. (2007) - Effect of brittle fracture on the rheological structure of the lithosphere and its application in the Ordos. Tectonophysics, 429, 267-285. Received 1 November 2007; revised version accepted 3 March 2008. Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 221-225, 6 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Relict meso and micro-structures in orogenic garnet peridotites as tracers of mantle dynamics and metasomatism at convergent plate margins M. SCAMBELLURI (*), H.L.M. VAN ROERMUND (**) & T. PETTKE (***) ABSTRACT At subduction zones, a number of geologic processes are caused by influx in the supra-subduction mantle wedge of fluid phases released by the subducting plates. The distribution of fluids in such settings affects the mineralogical, chemical and structural transformation of rocks and, hence, the survival of relict minerals and structures of previous events. These features can be investigated by means of field-based studies of high and ultrahigh-pressure (HP-UHP) orogenic terrains that contain mantle wedge materials tectonically sampled by the subducting plates. Here we review two examples of garnet peridotites hosted in HP-UHP continental crust, which record different P-T stories: (i) shallow spinel-facies lithospheric mantle wedge down-dragged to depth during subduction and recrystallized to garnet + amphibole assemblages due to the infiltration of crustderived fluids (Ulten Zone garnet peridotites, Eastern Alps, Italy); (ii) transition-zone mantle upwelled and accreted to cratonic roots, and involved in subduction-zone recrystallization at 200 km depth enhanced by crustal fluids (UHP garnet peridotites, Western Gneiss Region, Norway). Our textural and petrologic study shows that the water distribution controls development of the new assemblages and the metasomatic imprints of these rocks, independently on the depth and degree of metamorphism. We conclude that mantle re-fertilization by crust-derived subduction fluids is an effective mechanism working on a 100-200 km depth range. KEY WORDS: Convergent margins, mantle wedge, fluid, UHP metamorphism, mantle metasomatism. RIASSUNTO Meso e microstrutture relitte in peridotiti a granato orogeniche, traccianti della dinamica del mantello e del metasomatismo ai margini di placca convergenti. Una parte dei processi geologici che avvengono nelle zone di subduzione è causata dall’influsso nel cuneo (wedge) di mantello sopra-subduzione delle fasi fluide rilasciate dalle placche subdotte. La distribuzione delle fasi fluide in questi ambienti condiziona le trasformazioni mineralogiche, chimiche e strutturali delle rocce, determinando la preservazione dei minerali e delle strutture relitte di eventi geologici precedenti. Questi processi possono essere investigati mediante lo studio dei terreni orogenici di alta e altissima pressione (HP-UHP), che contengono scaglie di materiale proveniente dal wedge di mantello campionate tettonicamente dalle placche subdotte. In questo articolo vengono rivisti due esempi di peridotiti a granato ospitate da unità tettoniche crostali con impronta metamorfica di HP-UHP. Queste peridotiti registrano evoluzioni pressione-temperatura differenti: (i) porzioni superficiali del wedge di mantello (facies a spinello) trasportato in profondità durante la subduzione e cristallizzato in facies a granato + anfibolo a causa dell’infiltrazione di fluidi (*) Dipartimento per lo Studio del Territorio e delle sue Risorse, Università di Genova, Italy. (**) Faculty of Earth Sciences, University of Utrecht, Netherlands. (***) Institute of Geological Sciences University of Bern, Switzerland. rilasciati dalla crosta subdotta (peridotiti della Zona di Ulten, Alpi Orientali Italiane); (ii) mantello derivante dalla zona di transizione, risalito ed accresciuto alla litosfera cratonica ed infine interessato da metamorfismo di subduzione a profondità di 200 km, innescato dall’infiltrazione di fluidi crostali (Western Gneiss Region, Norvegia). Lo studio petrologico e strutturale di queste rocce indica che la distribuzione dell’acqua controlla lo sviluppo delle nuove paragenesi e le impronte metasomatiche delle rocce, indipendentemente dalla profondità e dal grado metamorfico a cui avvengono le trasformazioni. La rifertilizzazione del mantello guidata dall’infiltrazione di fluidi originati dalla crosta continentale è un processo operativo nell’intervallo di profondità comprese tra 100 e 200 km. TERMINI CHIAVE: Margini convergenti, cuneo di mantello, fluidi, metamorfismo di Ultra Alta Pressione, metasomatismo del mantello. INTRODUCTION Convergent plate margins are highly evolving environments, where significant physical and chemical changes affect the subducting plates and the overlying mantle wedges. At subduction zones, mass transfer, hydration and melting of the supra-subduction mantle domains is caused by the influx of fluid phases released by the subducting plates. The distribution of fluids and of deformation in such settings affects the extent of mineralogical and structural transformation of rocks and, hence, the survival of relict minerals and structures of previous events. The interplay of deformation, metamorphism and fluid infiltration at convergent margins can be investigated through field-based studies of the high- (HP) and ultrahigh-pressure (UHP) rocks exposed in mountain buildings, which represent excellent natural observatories on the Earth interiors and on subduction dynamics (CHOPIN, 2003; with references). An increasing number of studies has recently shown that, besides the oceanic and continental lithosphere recording prograde subduction metamorphism, the HP-UHP terrains contain mantle wedge materials tectonically sampled by the subducting crust (BRUECKNER, 1998; NIMIS & MORTEN, 2000; ZHANG et alii, 2000). Such mantle rocks may preserve phase transitions attained at exceptional depths, i.e. in the range of 200 to 350 km, representing the deepest transformations discovered in mantle rocks tectonically exposed at the surface (DOBRZHINETSKAYA et alii, 1996; VAN ROERMUND & DRURY, 1998; SPENGLER et alii, 2006; SONG et alii, 2004; SCAMBELLURI et alii, 2008). So far, much research has been focussed on the slabs and still few are the observations of mantle wedge peridotites, which are the least known pieces of the subduction 222 M. SCAMBELLURI ET ALII Fig. 1 - Cartoon reporting a subducting continental slab (grey) and the overlying mantle wedge. Thin solid lines refer to isotherms; dashed lines indicate the corner flow motion in the mantle wedge. The thick solid line shows the possible path of the Ulten Zone peridotites from spinel facies conditions (stage 1) to garnet + amphibole facies (stage 2). The deep seated Norway peridotites derive from upwelling of transition zone mantle, its accretion to the lithosphere much before the development of subduction. – Schema che mostra una placca continentale in subduzione (grigio) ed il cuneo di mantello soprastante. Le linee continue rappresentano le isoterme; le linee tratteggiate indicano il flusso nel cuneo di mantello. Le linee continue spesse rappresentano il possibile percorso delle peridotiti della Zona d’Ultimo dalla facies a spinello (stadio 1) alla facies granato + anfibolo (stadio 2). Le peridotiti profonde della Norvegia derivano dalla risalita di mantello dalla zona di transizione, la sua accrezione alla litosfera predata lo sviluppo della subduzione. factory. Information can be achieved from orogenic garnet peridotites of mantle wedge origin, which may be viewed as metre to kilometre-scale tectonic ‘xenoliths’ sampled at different depths by the subducted continental plates (fig. 1). These peridotites can preserve old events, pre-dating their engagement in the subducted crust and enabling to design the long-term mantle dynamics at convergent settings. Here we review two case-sudies of garnet peridotites hosted in subducted continental basements, which record different P-T, i.e. physical, trajectories prior to their uptake in the crust. The two examples correspond to (fig. 1): (i) shallow lithospheric mantle down-dragged to depth by corner-flow motion in the mantle wedge (Ulten Zone garnet peridotites, Eastern Alps, Italy); (ii) transition-zone mantle upwelled and accreted to cratonic roots (UHP garnet peridotites, Western Gneiss Region, Norway). In both cases the mantle rocks were flushed and metasomatized by incompatible element-rich fluids sourced from the continental crust, prior to or during their uptake in the subducting slabs. Such fluids are crucial to rock recrystallization and to the preservation of former structures. FIELD-BASED CASE STUDIES THE HP GARNET PERIDOTITES ITALIAN EASTERN ALPS FROM THE ULTEN ZONE, The Ulten Zone peridotite bodies are hosted by Variscan high-pressure migmatites (GODARD et alii, 1996). They are porphyroclastic spinel peridotites (T=1200°C; P=1.5 GPa) recrystallized into fine-grained garnet + Fig. 2 - Textures of the garnet peridotites from the Ulten Zone: A) coronitic garnet peridotites. The coarse porphyroclastic texture of this rock is inherited from the shallow spinel-facies crystallization: spinel grains (black) are contoured by light grey garnet coronas formed during low-strain re-crystallization of the mantle peridotite; B) mylonitic garnet + amphibole peridotite. The main foliation dips from left to right side of the photograph. It consists of amphibole and finegrained garnet associated with olivine, clino and orthopyroxene. – Tessiture nelle peridotiti a granato della Zona d’Ultimo: A) peridotiti a granato coroniche. La tessitura porfiroclastica della roccia è ereditata dalla cristallizazione superficiale nella facies a spinello: i granuli di spinello (nero) sono circondati da corone di granato grigio chiaro durante la ricristallizzazione delle peridotiti di mantello in condizioni di basso strain; B) peridotiti a granato + anfibolo milonitiche. La foliazione principale immerge da sinistra verso destra della fotografia. È marcata da anfibolo e granato a grana fine associato a olivina, clinopirosseno e ortopirosseno. RELICT MESO AND MICRO-STRUCTURES IN OROGENIC GARNET PERIDOTITES 223 Fig. 3 - Pb and Sr versus modal amphibole contents in the spinel- and garnet + amphibole-facies peridotites from the Ulten Zone. The incompatible element contents increase with increasing amounts of amphibole, i.e. with increasing bulk-rock H2O contents. This shows that the metasomatic imprint affecting the Ulten garnet peridotites is due to fluid infiltration. – Pb e Sr vs il contenuto di anfibolo modale nelle peridotiti della facies a spinello ed a granato + anfibolo, della Zona d’Ultimo. Il contenuto di elementi incompatibili aumenta con la quantità crescente di anfibolo, cioè con il crescente contenuto di H2O nella roccia totale. Ciò mostra che l’impronta metasomatica che registrano le peridotiti a granato della Val d’Ultimo è dovuta a infiltrazione di fluidi. amphibole peridotites (T = 850°C; P max = 3 GPa) in response to corner-flow inside a mantle wedge and slicing into a subducted continental slab (OBATA & MORTEN, 1987; NIMIS & MORTEN, 2000; TUMIATI et alii, 2003). The rock textures change from coarse porphyroclastic in the spinel-facies high-temperature domain of the mantle wedge, to coronitic and mylonitic in the lower-temperature (garnet-facies) hydrated region over the slab (fig. 2). The coronitic garnet peridotites display relict porphyroclastic textures where spinel (the black mineral spots in fig. 2A) is contoured by coronitic garnet associated with minor amounts of amphibole. The highly sheared garnet peridotite mylonites (fig. 2B) are significantly enriched in amphibole (up to 20% modal amphibole), suggesting an open-system fluid influx in the highly deformed zones. These features indicate that localized aqueous fluid infiltration in such wedge domains highly enhanced deformation development and chemical changes in rocks. The incompatible element-enriched signature of the garnet + amphibole peridotites clearly indicate that the incoming aqueous fluids determined a new, metasomatic, geochemical imprint of the garnet peridotites (RAMPONE & MORTEN, 2001; SCAMBELLURI et alii, 2006). In particular, the significant enrichment in Sr, Pb and H2O of the garnet + amphibole peridotites (fig. 3) indicate that the fluid phase carried cust-derived components. In the Ulten Zone peridotites, the heterogeneity in the fluid flow patterns enabled survival of the precursor Fig. 4 - Two different generations of majoritic garnets in UHP ultramafic rocks from the Western Gneiss Region of Norway: A) Exsolved px lamellae in Archean garnet from Ugelvik (Otrøy Island): the lamellae are about 50 µm– thick and several hundred µm– long; B) Scandian subduction zone garnet, showing the fine-grained exsolved px needles, maximum 5 µm– thick and up to 100 µm long. Same magnification as in fig. 4A, to show the different size of px lamellae in the Archean and in the subduction zone majoritic garnets. – Due differenti generazioni di granato majoritico nelle rocce ultrafemiche di Ultra Alta Pressione provenienti dalla Western Gneiss Region della Norvegia: A) Lamelle di pirosseno smistate nel granato archeano (Ugelvik, Isola di Otrøy): le lamelle sono spesse circa 50 µm e lunghe diverse centinaia di µm; B) Granato della zona di subduzione Scandinava che contiene finissimi smistamenti aciculari di pirosseno, spessi fino a 5 µm e lunghi fino a 100 µm. Stesso ingrandimento che in fig. 4A per permettere di confrontare la taglia delle lamelle di smistamento. 224 M. SCAMBELLURI ET ALII Fig. 5 - Chondrite-normalized REE patterns (ANDERS & GREVESSE, 1989) of the reconstructed bulk REE compositions of the early (Archean) and of the later subduction-zone majoritic garnets. The REE concentrations in the majoritic garnets have been calculated adding to the Archean and to the subduction garnet compositions respectively 20 and 1.5 volume % of the coexisting clino and orthporyoxene compositions (after SCAMBELLURI et alii, 2008). – Concentrazioni delle REE normalizzate alla chondrite (ANDERS & GREVESSE, 1989) nei granati majoritici della Norvegia Occidentale. Le concentrazioni delle REE originarie in questi granati sono state calcolate aggiungendo alle composizioni dei granati archeani e di subduzione rispettivamente le quantità di REE corrispondenti al 20 e 1,5% in volume di clino- e ortopirosseno coesistenti (da SCAMBELLURI et alii, 2008). anhydrous spinel-facies domains unaffected by fluid influx and by garnet-facies recrystallization aside of highly sheared mylonitic hydrated garnet peridotites. Once engaged in the crust, the peridotite lenses behaved as rigid bodies which escaped the exhumation tectonics that mostly involved the surrounding softer gneisses. THE UHP GARNET PERIDOTITES WESTERN NORWAY AND WEBSTERITES FROM The UHP gneisses of the Western Gneiss Region (Norway) record subduction to the coesite and to the diamond stability fields (SMITH, 1984; DOBRZINETSKAYA et alii, 1995; VAN ROERMUND et alii, 2002). The diamond-facies gneisses host garnet peridotites and websterites recording uprise from extraordinary depths prior to uptake in the continental slab. These ultramafic rocks (exposed in the islands of Otrøy and Bardane) derive from depleted Archean transition-zone mantle upwelled and accreted to a cratonic lithosphere (VAN ROERMUND & DRURY, 1998; SPENGLER et alii, 2006). Evidence for this Archean story are decimetric garnets preserved in Otrøy, hosting orthopyroxene and clinopyroxene exsolved from precursor ultradeep majoritic garnet (up to 20 volume % pyroxene component). Majoritic garnets form above 5 GPa through the progressive, pressure-dependent, incorporation of pyroxene into garnet, leading to formation of supersilicic garnets with Si exceeding 3 atoms per formula unit (RINGWOOD & MAJOR, 1971; AKAOGI & AKIMOTO, 1977; see GRIFFIN, 2008 for a short review). The Archean garnets from Otrøy contained up to 20 volume % pyroxene, now exsolved as intercrystalline grains and as coarse exsolution lamellae inside garnet. Fig. 4A reports such pyroxene lamellae (20-30 µm thick, hundreds µm long lamellae), exsolved under high-temperatures, as shown by the garnet/cpx REE distribution (SPENGLER et alii, 2006). The high amounts of pyroxene exsolutions in this garnet indicates provenance from the transitions-zone, 350 km deep, mantle. These pyroxenes and garnets display REE-depleted compositions, indicating that the original majorite crystallized in extremely refractory peridotite after high degrees of partial melting during the Archean upwelling history. This ultradeep mantle was involved in the 430 Ma-old Scandian subduction cycle, forming new clinopyroxene + orthopyroxene + phlogopite + garnet + spinel + carbonate, which host microdiamond-bearing inclusions precipitated by circulating COH silicate fluids (VAN ROERMUND et alii, 2002; CARSWELL & VAN ROERMUND, 2005). This stage is mostly recorded in the island of Bardane. The circulating subduction fluids also crystallized new majoritic garnet at grain boundaries and in microveins. This new majoritic garnet hosts maximum 1.5 volume % thin px needles (5 mm thick, 100 mm long; fig. 4B) exsolved under low-temperatures, as indicated by the garnet/cpx REE distribution. The amounts of pyroxene needles exsolved indicate that the new majoritic garnet formed at 7 Gpa and 900-100°C (SCAMBELLURI et alii, 2008). Pictures in fig. 4 are taken at the same magnification and refer to the Archean high temperature majorite (fig. 4A) and to the Scandian subduction majorite (fig. 4B) from Western Norway. They emphasize Fig. 6 - Trace element compositions of clinopyroxene from the HP assemblage of the Ulten Zone garnet peridotites (open dots) and from the UHP assemblage of the Norwegian ultramafic rocks (black dots). – Composizione degli elementi in traccia del clinopirosseno dalle paragenesi di Alta pressione delle peridotiti a granato della Zona d’Ultimo (cerchi vuoti) e dalle paragenesi di Ultra Alta Pressione delle rocce ultrafemiche norvegesi (cerchi pieni). RELICT MESO AND MICRO-STRUCTURES IN OROGENIC GARNET PERIDOTITES the different size of pyroxene exsolutions in these garnets, which may be taken as textural evidence for distinct exsolution temperatures and geologic environments. The majorites of fig. 4 also display significantly different trace element compositions. The subduction majorite has flat REE patterns (fig. 5): this contrasts with the REE depleted composition of the Archean majorite and indicates re-fertilization of the starting depleted peridotite by crust-derived fluid at 200 km depth. Distinct generations of majoritic garnet thus survive in the same terrain, displaying distinct textures, compositions, and exsolution temperatures. The majorite microstructures and compositions enable to discriminate between different crystallization environments: hot sub-cratonic lithosphere vs. colder subduction-zones. Crystallization of the new majoritic assemblage in Bardane was fluid induced, the archean transition zone majorites in Otrøy likely escaped fluid infiltration and survived the subduction event. CONCLUSIVE REMARKS Our study shows that continental crustal slabs subducted to variable depths entrain mantle wedge peridotites, the relict structures of which emphasize the stories and fate of the subcontinental mantle through time. The water distribution controls development of the new assemblages and the preservation of relics, independently on the depth and degree of metamorphism. Comparison of the trace element compositions of clinopyroxenes pertaining to the metasomatic HP and UHP subduction assemblages in Ulten and Bardane emphasizes a strong similarity in the Light Rare Earth Elements and in the Large Ion Litophile Elements of such phases (fig. 6; data from SCAMBELLURI et alii, 2006; 2008). Since the clinopyroxenes exchanged components with the incoming metasomatic fluids, this similarity indicates that the fluid phase compositions did not change dramatically with depth and implies that mantle refertilization by crust-derived subduction fluids is an effective mechanism working on a 100-200 km depth range. ACKNOWLEDGEMENTS MS acknowledges Iole Spalla, Guido Gosso and Anna Maria Marotta for the invitation at the DRT Conference in Milano, a great oportunity to discuss the structure and petrology of deep mantle rocks. We thank Stefano Poli and an anonymous reviewer for their comments. This research has been financially supported by the Italian MIUR, the University of Genova, the Utrecht Institute of Geodynamic Research and the Swiss National Science Foundation. REFERENCES AKAOGI M. & AKIMOTO S. (1977) - Pyroxene garnet solid-solution equilibria in the systems Mg4Si4O12-Mg3Al2Si3O12 and Fe4Si4O12Fe3Al2Si3O12 at high pressures and temperatures. Phys. of Earth and Planet. 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(2006) - Deep origin and hot melting of an Archean orogenic peridotite massif in Norway. Nature, 440, 913-917. TUMIATI S., THOENI M., MARTIN S., NIMIS P. & MAIR V. (2003) Mantle-crust interactions during Variscan subduction in the Eastern Alps (Nonsberg-Ulten zone): geochronology and new petrological constraints. Earth Planet. Sci. Lett., 210, 509-526. VAN ROERMUND H.L.M. & DRURY M.R. (1998) - Ultra-high pressure (P>6Gpa) garnet peridotites in western Norway: exhumation of mantle rocks from more than 185 km. Terra Nova, 10, 295- 301. VAN ROERMUND H.L.M., CARSWELL D.A., DRURY M.R. & HEIJBOER T.C. (2002) - Microdiamonds in a megacrystic garnet websterite pod from Bardane on the island of Fjortøft, western Norway: Evidence for diamond formation in mantle rocks during continental subduction. Geology, 30, 959-962. ZHANG R.Y., LIOU J.G., YANG J.S. & YUI T.-F. (2000) - Petrochemical constraints for dual origin of garnet peridotites from the Dabie-Sulu UHP terrane, eastern-central China. J. Metam. Geol., 18, 149-166. Received 9 November 2007; revised version accepted 14 February 2008. Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 227-230, 4 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Estimation of palaeorheology from buckle-fold geometries STEFAN M. SCHMALHOLZ (*) & NEIL S. MANCKTELOW (*) ABSTRACT The geometry of a natural single-layer fold train is investigated to estimate the effective viscosity ratio between the folded layer and the surrounding medium. Different methods based on analytical solutions for folding yield consistent estimates for the range of viscosity ratios of between 20 and 70 and for values of the power-law exponent of the layer of between 1.8 and 5. The error range for such viscosity ratio estimates is roughly on the order of a factor of 2. KEY WORDS: buckling, folding, power-law rheology, strain estimation, palaeorheology. RIASSUNTO Stima della paleoreologia dalle geometrie delle pieghe per buckling. In questo contributo viene studiata la geometria di un treno di pieghe naturali su un singolo strato per stimare il rapporto della viscosità effettiva tra il livello piegato ed il mezzo circostante. Differenti metodi, basati su soluzioni analitiche del piegamento, forniscono stime consistenti per i rapporti di viscosità nell’intervallo tra 20 e 70, per valori tra 1.8 e 5 dell’esponente della legge di flusso per il livello. L’intervallo d’errore per tali stime del rapporto di viscosità è grossolanamente dell’ordine di un fattore 2. TERMINI CHIAVE: buckling, piegamento, reologia esponenziale, stima della distorsione, paleoreologia. INTRODUCTION Geological structures as observed in the field can be regarded as results of natural rock deformation experiments. However, in contrast to laboratory or numerical rock deformation experiments, in nature only the final geometry is directly measurable and the initial and boundary conditions, as well as the rock rheology at the time of deformation, are unknowns that cannot be immediately established. Indeed, one of the main aims of structural geologists is to reconstruct both the kinematics and dynamics of the natural deformation history from the observed structures. This study focuses on buckle-fold structures and aims to assess the rheology and effective strength ratio (or «competence» contrast) between the folded layer and the embedding matrix at the time of folding. In the framework of continuum mechanics, as applied in this study, rheology means the constitutive equations relating stress (*) Geological Institute, ETH Zurich, 8092 Zurich, Switzerland. Tel.: +41 44 632 8167. Fax: +41 44 632 1030. E-mail: schmalholz@ erdw.ethz.ch tensor components to strain or strain rate tensor components (e.g. JOHNSON & FLETCHER, 1994). In this sense, this study aims to estimate the effective rheology on the scale of observation (i.e. the folded layer and the embedding medium). This effective rheology may differ from the rheology on the micro-scale (i.e. on the scale of individual small crystals building the rock layer). There are several rheologies, such as elastic or viscous, that can potentially describe the deformation behaviour of folded layers (fig. 1). However, a purely elastic rheology is unlikely to be appropriate for buckle-fold formation, because elastic strains are very small (<<1%). An elastoplastic rheology is also unlikely to be dominant during buckle-fold formation, because elastoplastic deformation causes localized shear bands (i.e. bifurcation, e.g. VERMEER & DE BORST, 1990) and not distributed deformation as observed in natural buckle-folds. The remaining and most likely candidates for the rheology generating buckle-folds are viscoelastic (SCHMALHOLZ & PODLADCHIKOV, 1999; MANCKTELOW, 1999), linear viscous (BIOT, 1961) and power-law (FLETCHER, 1974) rheologies. This study focuses on folding of powerlaw layers (e.g. FLETCHER, 1974; JOHNSON & FLETCHER, 1994) embedded in a viscous (Newtonian) matrix. The power-law rheology includes the Newtonian case when the power-law exponent is 1. The aims of this study are (i) to present methods for estimating the effective viscosity ratio and power-law exponent of a folded layer and (ii) to discuss the accuracy and reliability of such palaeorheology estimates. METHOD AND RESULTS The two interfaces of the natural buckle-fold train were digitized using MATLAB (fig. 1). The slope of the two interfaces (i.e. the derivative of the Y-coordinate with respect to the X-coordinate, fig. 2) was analyzed with an algorithm that determines the sign of the slope. Every position on the interface at which the slope of the interface changes its sign was identified and marked with a diamond-shaped symbol (fig. 2). These locations represent potential fold hinges. Due to natural irregularities, sometimes more than one hinge position was identified (fig. 2). Representative fold hinge positions were determined by personal interpretation and five individual buckle-folds were identified within the fold train. The ratio of fold-span to layer thickness of the individual folds varies between 4.6 and 10.6. The average ratio is about 8. In addition, the Fourier spectrum was calculated (using the MATLAB fast fourier transform, fft, function) for the top, bottom and averaged layer interface (fig. 2). The 228 S.M. SCHMALHOLZ & N.S. MANCKTELOW Fig. 1 - The photograph shows a natural folded quartz vein embedded in shale from Vale Figueiras, SW Portugal, with the digitized top and bottom interface of the folded quartz vein given below. – La fotografia mostra una vena naturale di quarzo piegata, incassata in argillite, a Vale Figueiras, Portogallo SO; nell’immagine sottostante sono rappresentate le superfici digitalizzate di tetto e di letto della vena di quarzo piegata. Fig. 2. ESTIMATION OF PALAEORHEOLOGY FROM BUCKLE-FOLD GEOMETRIES Fig. 3 - Contours of the dominant wavelength (dashed lines) and the maximal growth rate (solid lines) versus the viscosity ratio and the power-law exponent of the layer (matrix is Newtonian). – Tracce della lunghezza d’onda dominante (linee a tratteggio) e della massima velocità di crescita (linee continue) confrontate al rapporto di viscosità e all’esponente della legge di flusso esponenziale per il livello (la matrice è Newtoniana). three Fourier spectra are significantly different. The best Fourier representation of the layer shape is presumably the Fourier spectrum of the averaged interface, because the averaged interface is least sensitive to natural interface irregularities around the fold hinges (because such irregularities are smoothed in the process of averaging). The Fourier spectrum of the averaged layer interface yields the largest amplitude at a ratio of wavelength to layer thickness of about 9. This value is close to the value of 8 obtained by using the distances between fold hinges, i.e. the fold-span. The ratio of fold-span to layer thickness and the ratio of wavelength to layer thickness can be used to estimate the viscosity ratio and the power-law exponent of the layer. In the current analysis, the analytical solution of FLETCHER (1974) is used. This provides values for the ratio of dominant wavelength to thickness and for the maximal growth rate (normalized against the background shortening rate) as a function of the viscosity ratio and the power-law exponent of the layer (the embedding matrix is assumed to be Newtonian, fig. 3). The measured ratios of fold-span to thickness (about 8) and of wavelength to thickness (about 9) are used as lower and upper bounds for the ratio of dominant wavelength to thickness. No correction for the shortening of the dominant wavelength, as described in SHERWIN & CHAPPLE (1968), has been applied. Furthermore, analytical folding solutions (e.g. JOHNSON & FLETCHER, 1994) and numerical simula- 229 Fig. 4 - The strain map with A, H and λ being the amplitude, thickness and wavelength, respectively. Solid lines with numbers indicate strain estimates in per cent and dashed lines with numbers indicate estimates of effective viscosity ratio. The circles represent the values corresponding to the five individual folds identified in fig. 2. The average of the five values is marked with a plus symbol. – Mappa della distorsione con A, H e λ che corrisondono ripettivamente ad ampiezza, spessore e lunghezza d’onda. Le linee continue con i numeri indicano le percentuali stimate di distorsione e le linee tratteggiate e numerate indicano le stime del rapporto di viscosità effettiva. I cerchi rappresentano i valori che corrispondono alle cinque singole pieghe individuate in fig. 2. La media dei cinque valori è rapprentata da una croce. tions of folding show that values of the maximal growth rate should be greater than about 10, in order to generate observable buckle-folds with a more or less constant layer thickness. The analytical solution shows that values of the power-law exponent between 1.8 and 5 and viscosity ratios between 20 and 70 yield values for the ratio of dominant wavelength to thickness between 8 and 9 and values of the maximal growth rate larger than 10 (gray patch in fig. 3). Additionally, the values of the amplitude, A, wavelength, λ (i.e. horizontal hinge distance), and thickness, H, of the five individual folds shown in fig. 2 have been measured and the corresponding ratios H/λ and A/λ plotted on the strain map developed by SCHMALHOLZ & PODLADCHIKOV (2001). This strain map can be used to estimate the amount of shortening and the viscosity ratio from buckle-fold geometries and includes a correction for the shortening of λ and thickening of H during folding. The individual values are distributed and the average value for H/λ and A/λ is close to the dashed line for a viscosity ratio of 50 (plus symbol in fig. 4). This is in agreement with the viscosity ratio estimates using the analytical solution of FLETCHER (1974), with values between 20 and 70 (fig. 3). Fig. 2 - The upper figure shows the top, bottom and averaged fold interfaces. X and Y are the horizontal and vertical coordinates and Tav is the average layer thickness. Diamond symbols indicate the location of potential hinge points at which the slope of the interface changes its sign. Different grey levels (colors in the colored version) separate five individual folds. The lower figure shows the Fourier spectra of the top, bottom and averaged interface of the fold train. – L’immagine superiore mostra tetto, letto e la superficie media piegate. X e Y sono rispettivamente la coordinata orizzontale e verticale e Tav è lo spessore medio del livello. I rombi indicano la posizione dei potenziali punti di cerniera ai quali la pendenza dell’interfaccia cambia di segno. I differenti toni di grigio (colori nella versione a colori) separano cinque singole pieghe. L’immagine inferiore mostra gli spettri di Fourier di tetto, letto e superficie media del treno di pieghe. 230 S.M. SCHMALHOLZ DISCUSSION AND CONCLUSIONS The analytical solution for folding of a power-law layer embedded in a Newtonian matrix (fig. 3, FLETCHER, 1974) shows that there is no unique solution for the dominant wavelength because it depends on both the viscosity ratio and the power-law exponent. The range of possible solutions can be reduced by using the fact that fold growth rates should be at least ten times larger than the shortening rate in order to generate observable folds with more or less constant layer thickness. Smaller growth rates produce fold shapes with strongly varying layer thickness due to deformation that is significantly affected by layer thickening (e.g. JOHNSON & FLETCHER, 1994). Potentially the best method to quantify a fold shape is by calculating the Fourier spectrum of the averaged interface of the folded layer, because no interpretations and decisions concerning the positions of fold hinges have to be made. However, several individual folds should be present within a fold train to yield a representative Fourier spectrum. Also, if the folds have overturned limbs, i.e. more than one vertical coordinate corresponds to one horizontal coordinate, then it is not possible to calculate a Fourier spectrum. In such cases, the more interpretative method of defining fold hinge positions has to be used. The analysis presented here shows that effective viscosity ratios and power-law exponents can be estimated from buckle-fold geometries, but the error range is roughly on the order of a factor of 2 (i.e. between 25 and 100 for an estimate of 50). Better accuracy is difficult to obtain due to (i) the natural irregularities of fold shapes that are considerably affected by the initial perturbation geometry of the layer (e.g. MANCKTELOW, 1999, 2001) and (ii) by the non-uniqueness of the buckling process, which means that different combinations of material parameters can generate the same fold shape with a particular dominant wavelength. & N.S. MANCKTELOW The estimates for the effective viscosity ratio between 20 and 70 and for the power-law exponent of the layer between 1.8 and 5 are well within the range of experimentally confirmed values for mechanically strong quartz within mechanically weak shale (e.g. CARTER & TSENN, 1984). Additional constraints on the rheology may be obtained from microstructural observations of the folded vein, but such observations were not available for the investigated fold. REFERENCES BIOT M.A. (1961) - Theory of folding of stratified viscoelastic media and its implications in tectonics and orogenesis. Geological Society of America Bulletin, 72, 1595-1620. CARTER N.L. & TSENN M.C. (1987) - Flow properties of continental lithosphere. Tectonophysics, 136, 27-63. FLETCHER R.C. (1974) - Wavelength selection in the folding of a single layer with power-law rheology. Am. Jour. Sci., 274, 1029-1043. JOHNSON A.M. & FLETCHER R.C. (1994) - Folding of viscous layers. Columbia University Press, New York. MANCKTELOW N.S. (1999) - Finite-element modelling of single-layer folding in elasto-viscous materials: the effect of initial perturbation geometry. Journal of Structural Geology, 21, 161-177. MANCKTELOW N.S. (2001) - Single layer folds developed from initial random perturbations: the effects of probability distribution, fractal dimension, phase and amplitude. In: H.A. Koyi & N.S. Mancktelow (Eds.), Tectonic Modeling: A Volume in Honor of Hans Ramberg. Geol. Soc. of Am., Boulder, pp. 69-87. SCHMALHOLZ S.M. & PODLADCHIKOV Y. (1999) - Buckling versus folding: Importance of viscoelasticity. Geophysical Research Letters, 26, 2641-2644. SCHMALHOLZ S.M. & PODLADCHIKOV Y.Y. (2001) - Strain and competence contrast estimation from fold shape. Tectonophysics, 340, 195-213. SHERWIN J. & CHAPPLE W.M. (1968) - Wavelengths of single layer folds: a comparison between theory and observation. Am. Jour. Sci., 266, 167-179. VERMEER P.A. & DE BORST R. (1984) - Non-associated plasticity for soils, concrete and rock. Heron, 29, 1-64. Received 8 November 2007; revised version accepted 28 February 2008. Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 231-234, 2 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Shallow earth rheology from glacial isostatic adjustment constrained by GOCE L.L.A. VERMEERSEN (*) & H.H.A. SCHOTMAN (**), (*) ABSTRACT The Earth’s asthenosphere and lower continental crust can regionally have viscosities that are one to several orders of magnitude smaller than typical mantle viscosities. As a consequence, such shallow low-viscosity layers could induce high-harmonic (spherical harmonics 50-200) gravity and geoid anomalies due to remaining isostasy deviations following Late-Pleistocene glacial isostatic adjustment (GIA). Such high-harmonic geoid and gravity signatures would depend also on the detailed ice and meltwater loading distribution and history. ESA’s GOCE satellite mission, scheduled for launch summer 2008, is designed to map the quasistatic geoid with centimeter accuracy and gravity anomalies with milligal accuracy at a resolution of 100 kilometers or better. This might offer the possibility of detecting gravity and geoid effects of low-viscosity shallow earth layers and differences of the effects of various Pleistocene ice decay scenarios. For example, our predictions show that for a typical low-viscosity crustal zone GOCE should be able to discern differences between ice-load histories down to length scales of about 150 km. One of the major challenges in interpreting such high-harmonic, regional-scale, geoid signatures in GOCE solutions will be to discriminate GIA-signatures from various other solid-earth contributions. It might be of help here that the high-harmonic geoid and gravity signatures form quite characteristic 2-D patterns, depending on both ice load and low-viscosity zone model patterns. KEY WORDS: Glacial Isostatic Adjustment, Crust and Mantle Rheology, GOCE, Gravity Anomalies and Geoid. RIASSUNTO Reologia superficiale della terra dall’aggiustamento isostatico glaciale sulla base di GOCE. L’astenosfera terrestre e la crosta continentale inferiore possono avere regionalmente una viscosità da uno ad alcuni ordini di grandezza inferiore alla viscosità tipica del mantello. Conseguentemente, tali strati superficiali a bassa viscosità possono indurre anomalie di gravità e del geoide alle armoniche elevate (armoniche sferiche da 20 a 200) a causa della deviazione isostatica residua, conseguente all’aggiustamento isostatico glaciale tardo-pleistocenico (GIA). Tali segnali ad elevate armoniche nella gravità e nel geoide dipenderebbero anche dalla distribuzione e storia del carico di ghiaccio e dell’acqua di fusione. La missione satellitare ESA GOCE, programmata per essere lanciata nell’estate 2008, è designata a costruire mappe del geoide quasi statico con un’accuratezza del centimetro e le anomalie di gravità con un’accuratezza del milligal, alla risoluzione di 100 km o migliore. Ciò potrebbe offrire la possibilità di rivelare effetti sulla gravità e sul geoide dovuti agli strati superficiali a bassa viscosità e differenze degli effetti di vari scenari di riduzione del ghiaccio pleistocenico. Per esempio, la nostra previsione mostra che per una tipi- (*) DEOS, Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg, 1 - 2629 HS Delft, The Netherlands. (**) SRON, Sorbonnelaan, 2 - 3584 CA Utrecht, The Netherlands. ca zona crostale a bassa viscosità GOCE sarebbe in grado di distinguere differenze fra storie di carico di ghiacciai fino a scale di lunghezza di 150 km circa. Una delle sfide principali nell’interpretazione di tale segnale del geoide ad armoniche elevate e a scala regionale sarà di distinguere il contributo del GIA da vari altri contributi della Terra Solida. Sarebbe d’aiuto che i segnali di gravità e del geoide ad armoniche elevate avessero delle configurazioni caratteristiche bi-dimensionali, che dipendono sia dal carico del ghiaccio che dal modello della zona a bassa viscosità. TERMINI CHIAVE: aggiustamento isostatico glaciale, reologia della crosta e del mantello, GOCE, anomalie di gravità e geoide. INTRODUCTION In Summer 2008 ESA’s Gravity and steady-state Ocean Circulation Explorer (GOCE) satellite will be launched. GOCE will observe the Earth’s gravity field with unprecedented resolution down to 100 km and accuracies down to 1-2 cm in geoid height and down to 1 mgal in gravity anomaly (e.g., VISSER et alii, 2002). Such high resolution and accuracies, with almost uniform coverage, have some interesting prospects for the solid-earth sciences, notably for the shallow parts of the Earth. One example of this is glacial isostatic adjustment (GIA). In earlier studies (VERMEERSEN 2003; VAN DER WAL et alii, 2004; SCHOTMAN & VERMEERSEN, 2005; SCHOTMAN et alii, 2007a) we have shown that crustal and asthenospheric low-viscosity zones can induce geoid and gravity signatures that are above accuracy and resolution thresholds of expected GOCE performance. Here we will concentrate on the question whether it might be possible to discern the effects of lateral variations in earth structure, including regional crustal and asthenospheric low-viscosity zones. Continental crust can have zones of low viscosity for regions with a larger than average heat flow. Generally such areas can be expected to occur in regions that are under extension. In order to give an impression of the perturbations that such lowviscosity zones can give on present-day GIA-induced geoid anomalies we model resulting GIA geoid anomalies over the northern part of Europe for a specific laterally varying earth model and a Late-Pleistocene ice mass decay scenario. EARTH AND ICE MODEL In order to compare the effects of a laterally varying crustal low-viscosity zone with those obtained from a lat- 232 L.L.A. VERMEERSEN & H.H.A. SCHOTMAN Fig. 1 - Spherical earth model. – Modello di Terra sferica. Fig. 2 - a) Difference in geoid anomalies triggered by the standard earth model of fig. 1, that has no low-viscous lower crust, and the earth model that has the low-viscous lower crust for Northern Europe; b) Difference in geoid anomalies with respect to fig. 2a, assuming that the Baltic Shield is not underlain by the low-viscosity zone of the inset in fig. 1. – a) Differenza nelle anomalie del geoide indotte dal modello di Terra standard mostrato in fig. 1, senza crosta inferiore a bassa viscosità, e il modello di Terra che ha una crosta inferiore a bassa viscosità nel Nord Europa; b) Differenza nelle anomalie del geoide rispetto alla fig. 2a, assunto che sotto lo Scudo Baltico non ci sia la zona a bassa viscosità indicata in fig. 1. SHALLOW EARTH RHEOLOGY FROM GLACIAL ISOSTATIC ADJUSTMENT CONSTRAINED BY GOCE erally homogeneous one, we use the earth model as depicted in fig. 1 as standard model. This model consists of an inviscid core, viscoelastic lower and upper mantle and elastic upper part. In this elastic upper part a low-viscosity lower crust is sandwiched between the elastic upper crust and the elastic lithosphere below. Here we will not model the indicated asthenosphere explicitly, but consider it to be part of the upper mantle with the same viscosity as the upper mantle. Results from asthenospheric low-viscosity zones can be found in SCHOTMAN et alii (2008). Elastic parameters and radial density profile are based on PREM (DZIEWONSKI & ANDERSON, 1981). For laterally homogeneous, self-gravitating, spherical earth models we use the normal mode technique as described in SABADINI & VERMEERSEN (2004). The rheology is a simple linear Maxwell viscoelastic one. Lower mantle viscosity is five times the Haskell value, while upper mantle viscosity is half the Haskell value. Values for other parameters and variables are indicated in the figure. Computations with the laterally varying earth model are performed by means of the finite-element package ABAQUS (e.g., WU et alii, 2005). The earth model we use is a viscoelastic halfspace model with the same layering as the laterally homogeneous spherical earth model, but it is not self-gravitating. However, it has been shown in, e.g., SCHOTMAN et alii (2008) that the lack of self-gravitation is partly compensated by the lack of sphericity. Furthermore, long-wavelength differences largely cancel out for the small-scale perturbation signatures related to the shallow crustal low-viscosity zone that we are interested in here. A validation of using finite elements for computing geoid height perturbations can be found in SCHOTMAN et alii (2008). It is assumed that the complete region has the same homogeneous lithospheric thickness as in the standard earth model in these finiteelement computations. For modeling results with varying thicknesses we refer again to SCHOTMAN et alii (2008). The Late-Pleistocene ice mass decay model is based on ICE-5G of PELTIER (2004), although we have also considered other ice models like RSES of LAMBECK et alii (1998). It turned out, however, that the background ice decay model has a negligible influence on the spectral characteristics associated with the crustal low-viscosity zone contributions to geoid and gravity anomalies (SCHOTMAN et alii, 2008). Spatial patterns of these geoid and gravity anomalies can differ considerably, of course, as individual ice sheets from various ice models can differ in position. MODELLING RESULTS Fig. 2a shows the difference in geoid anomalies triggered by the standard earth model of fig. 1 that has no low-viscous lower crust and the earth model that has the low-viscous lower crust for Northern Europe. Here the low-viscosity zone is taken as a laterally homogeneous layer, so also the Baltic Shield is (unrealistically) presumed to have this low-viscosity crustal layer. The geoid height perturbations are clearly above the expected accuracy level of 1 cm of maps that GOCE will deliver, at many places the differential signal will even be more than an order of magnitude larger than this 1 cm level. The contours with number «2» or «–2» signify differences between modelling results obtained with the 233 (spherical earth, self-gravitating) normal mode method and the (halfspace, non-self-gravitating) finite element model. The numbers are the difference in cm between the two modelling results, showing that the modeling results differences between those obtained by the normal mode approach and the finite element model are only slightly larger than the expected uncertainties in the GOCE data. This result illustrates what has already been mentioned in the former section: effects of selfgravitation and sphericity partly annihilate one another, specifically for small-scale signatures in geoid anomaly. Fig. 2b shows the effects of lateral heterogeneities. Depicted is the difference in geoid anomalies with respect to fig. 2a assuming that the Baltic Shield is now not underlain by the low-viscosity zone of the inset in fig. 1. It is obvious from fig. 2b that differences between the lateral and non-lateral results are generally small outside the Baltic Shield area and become most prominent prominent underneath those regions (i.e., the Baltic Shield) that do not have the crustal low-viscosity zone any longer. The differences are large enough compared to the expected performance of GOCE, even up to one order of magnitude, that the effects of lateral variations on the geoid might become discernable in GOCE data. Also the resolution should not be a problem: most of the patches in figs. 2a and 2b extend over more than 100 km up to even hundreds of km for the more elongated structures. These spatial geoid anomaly patterns, apart from spectral signatures, might help in identifying GIA-induced contributions coming from the effects of lateral, low-viscous, shallow crustal zones and discern them from other contributions like internal mass anomalies and topographic features from tectonic or geomorphological origins. Finally, it should be emphasized that the modelling results of figs. 2a and 2b are only meant to give an indication about what might possibly be deduced from GOCE data concerning (crustal) lateral variations and shallow low viscosity zones. More detailed earth models, based on detailed structural, compositional and rheological (also non-linear) data, seismic tomography, electrical conductivity studies, etc., are necessary before realistic comparisons can be made with data from GOCE. For further details we refer to SCHOTMAN et alii (2008). CONCLUSIONS GIA model simulations indicate that information on shallow low viscosity zones might be deduced from GOCE geoid solutions, although uncertainties in both ice load history and earth structure could hamper unique interpretations to some extent. Combining spectral information with spatial patterns could reduce these uncertainties, whereby the range of possible ice and earth models is already constrained through other geodetic and geophysical data (e.g., GPS, ice load dynamics, tide gauge records). Lateral variations in earth structure, specifically with respect to occurrence of low-viscosity zones as a function of tectonic province, do have discernable effects on geoid anomalies, although they appear to be constrained to those regions that do not have a low-viscosity zone (compared to the laterally homogeneous low-viscosity zone case) and to their immediate surroundings. 234 L.L.A. VERMEERSEN REFERENCES DZIEWONSKI A.M. & ANDERSON D.L. (1981) - Preliminary reference Earth model (PREM). Phys. Earth Planet. Inter., 25, 297-356. LAMBECK K., SMITHER C. & JOHNSTON P. (1998) - Sea-level change, glacial rebound and mantle viscosity of northern Europe. Geophys. J. Int., 134, 102-144. PELTIER W.R. (2004) - Global glacial isostasy and the surface of the iceage Earth: The ICE-5G (VM2) Model and GRACE. Annu. Rev. Earth Planet. Sci., 32, doi:10.1146/annurev.earth.32.082503.144359. SABADINI R. & VERMEERSEN L.L.A. (2004) - Global Dynamics of the Earth: Applications of Normal Mode Relaxation Theory to SolidEarth Geophysics. Modern Approaches in Geophysics Series, Volume 20, Kluwer Academic Publishers, Dordrecht, The Netherlands. SCHOTMAN H.H.A. & VERMEERSEN L.L.A. (2005) - Sensitivity of glacial isostatic adjustment models with shallow low-viscosity earth layers to the ice-load history in relation to the performance of GOCE and GRACE. Earth Planet. Sci. Lett., 236, 828-844. SCHOTMAN H.H.A, VERMEERSEN L.L.A. & VISSER P.N.A.M. (2007a) High-harmonic gravity signatures related to postglacial rebound. In: Dynamic Planet, P. Tregoning and C. Rizos (Editors), & H.H.A. SCHOTMAN Springer, International Association of Geodesy Symposia, 130, 103-111. SCHOTMAN H.H.A., WU P. & VERMEERSEN L.L.A. (2008) - Regional perturbations in a global background model of glacial isostasy. submitted to Phys. Earth Planet. Inter., doi: 10.1016/j.pepi.2008.02.010. VAN DER WAL W., SCHOTMAN H.H.A. & VERMEERSEN L.L.A. (2004) Geoid heights due to a crustal low viscosity zone in glacial isostatic adjustment modeling: a sensitivity analysis for GOCE. Geophys. Res. Lett., 31, L05608, doi:10.1029/2003GL019139. VERMEERSEN L.L.A. (2003) - The potential of GOCE in constraining the structure of the crust and lithosphere from post-glacial rebound. Space Sci. Rev., 108 (1-2), 105-113. VISSER P.N.A.M., RUMMEL R., BALMINO G., SUENKL H., JOHANNESSEN J., AGUIRRE M., WOODWORTH P.L., LE PROVOST C., TSCHERNING C.C. & SABADINI R. (2002) - The European Earth explorer mission GOCE: Impact for the geosciences. In: Ice Sheets, Sea Level and the Dynamic Earth, Mitrovica J.X. & Vermeersen L.L.A. (Editors), Am. Geophys. Union, AGU Geodynamics Series, 29, 95-107. WU P., WANG H. & SCHOTMAN H.H.A. (2005) - Postglacial induced surface motions, sea-levels and geoid rates on a spherical, self-gravitating, laterally heterogeneous Earth. J. Geodyn., 39, 127-142. Received 27 November 2007; revised version accepted 28 January 2008. Boll.Soc.Geol.It. (Ital.J.Geosci.), Vol. 127, No. 2 (2008), pp. 235-242, 3 figs. Queste bozze, corrette e accompagnate dall’allegato preventivo firmato e dal buono d’ordine, debbono essere restituite immediatamente alla Segreteria della Società Geologica Italiana c/o Dipartimento di Scienze della Terra Piazzale Aldo Moro, 5 – 00185 ROMA Instabilities development in partially molten rocks JEAN-LOUIS VIGNERESSE (*), JEAN-PIERRE BURG (**) & JEAN-FRANÇOIS MOYEN (***) ABSTRACT Partially molten rocks (PMR) are characterized by specific and contrasting behaviours. For instance, large-scale and smaller scale structures are consistently oriented in a migmatitic body with those of the surroundings, indicating that the migmatites were deformed as a whole. By contrast, ubiquitous strain partitioning and melt distribution are widely present in the same migmatitic body, reflecting highly heterogeneous strain and intrinsic rheological instabilities. A continuous transition from a liquid-like to a solid-like rheology, as many averaging processes implicitly assume, cannot explain this two-fold information. We develop a full analysis, considering the stress and strain rate, and the relative proportion of melt and solid phases. Temperature varies from Tsolidus to Tliquidus in a PMR. We also assume that the transition to melting is not dual to crystallization. However, we prefer using the viscosity rather than the stress, since the former is better constrained from experiments. The viscosity of the matrix, which deforms according to a power law, shows shear thinning, whereas that of the melt remains constant. The viscosity contrast between the two phases thus varies with strain rate. The lower the strain rate, the higher is the viscosity contrast, hence instabilities development is controlled by the rheology. The path followed during a transition also controls the intermediate state, and may lead to instabilities, resulting from mechanical reasons or from the respective amount in each phase. In the last case, the concentration in one phase induces instabilities. A surface describing viscosity in a 3D diagram (strain rate-amount of phase-viscosity) is constructed, that presents a cusp shape for low strain rates. The diagram depicts two types of behaviour and a critical state. At high strain, the viscosity contrast between melt and matrix is lowest. The rock behaves as a near-homogeneous body and a continuous description of its rheology may be estimated. Instabilities lead to fabric development resulting from crystals alignment. At low strain rate, three domains are separated by a critical state. When the proportion of one phase is very small, the material behaves as the other end-member. For intermediate proportions, the cusp indicates three possible viscosity values. Two are metastable, whereas the third is virtual. Hence, the viscosity of the mixture jumps back and forth from the viscosity of one phase to that of the other. A similar process occurs for temperature, since the cusp in the viscosity profile has also implications in a diagram linking temperature and stress. Different behaviours result, depending on whether the deformation takes place under a fixed content in each phase, a common stress, a common strain rate or common temperature. We list several implications for partially molten rocks that may explain fabric development, contact melting between crystals, strain localisation, mineral banding, shear heating, welding, stick-slip-like melt extraction, magma fragmentation or formation of strong or fragile glass. A phase diagram that incorporates temperature, stress and concentration is constructed for PMR that bears much similitude with those issued for other soft materials. KEY WORDS: rheology, two-phase material, migmatites. (*) Nancy-Université, G2R, BP 23, F-54501 Vandoeuvre Cedex, France, [email protected] (**) Geologisches Institut, ETH-Zentrum, Leonhardstrasse 19 LEB, CH-8006 Zurich, Switzerland, [email protected] (***) Department of Geology, Stellenbosch University, Private Bag X1, Stellenbosch 7802, South Africa, [email protected] RIASSUNTO Sviluppo di instabilità in rocce parzialmente fuse. Le rocce parzialmente fuse (PMR) sono caratterizzate da comportamenti specifici e contrastati. Ad esempio in un corpo di migmatiti le strutture a grande e piccola scala sono orientate coerentemente con quelle delle rocce circostanti e ciò indica che le migmatiti sono state deformate come un unico insieme. Al contrario, le ubiquitarie ripartizione della distorsione e distribuzione del fuso sono diffuse nello stesso corpo migmatitico e riflettono l’elevata eterogeneità della distorsione e delle instabilità reologiche intrinseche. Una transizione continua da una reologia di tipo-liquido a una reologia di tipo-solido, così come implicitamente si assume per molti processi mediati, non può spiegare questa duplice informazione. Sviluppiamo qui un’analisi completa considerando lo sforzo e la velocità di deformazione e le relative proporzioni di fuso e fasi solide. In una PMR la temperatura varia da Tsolidus a Tliquidus. Noi assumiamo anche che la transizione verso la fusione non riproduce quella alla cristallizzazione. Comunque noi preferiamo usare la viscosità anziché lo sforzo, poiché la prima è definita meglio dagli esperimenti. La viscosità della matrice che si deforma secondo una legge esponenziale manifesta un assottigliamento per taglio, mentre quella del fuso rimane costante. Il contrasto di viscosità tra le due fasi varia quindi con la velocità della distorsione. Più bassa è la velocità di distorsione, più si eleva il contrasto di viscosità, quindi lo sviluppo delle instabilità è controllato dalla reologia. Il percorso seguito durante una transizione controlla pure lo stato intermedio e può portare all’instabilità, come risultato di cause meccaniche oppure di diversa quantità relativa delle fasi. Nell’ultimo caso, la concentrazione di una delle fasi induce l’instabilità. Viene qui costruita una superficie che descrive la viscosità in un diagramma tridimensionale (velocità di distorsione-quantità della fase-viscosità) e che presenta una forma a cuspide a basse velocità di distorsione. Sul diagramma sono rappresentati due tipi di comportamento e uno stato critico. Ad alta distorsione, il contrasto di viscosità tra fuso e matrice è più basso. La roccia si comporta come un corpo quasi omogeneo e può essere approssimata una descrizione continua della sua reologia. Le instabilità portano allo sviluppo di un fabric che risulta dall’allineamento dei cristalli. A bassa velocità di distorsione, tre domini sono separati da uno stato critico. Quando la proporzione di una fase è molto piccola il materiale si comporta come l’altra fase. Per proporzioni intermedie, la cuspide indica tre possibili valori della viscosità. Due sono metastabili mentre il terzo è virtuale. Quindi, la viscosità della miscela retrocede o avanza dalla viscosità di una fase a quella dell’altra. Un simile processo si verifica per la temperatura, poiché la cuspide nel profilo di viscosità manifesta anche implicazioni in un diagramma che collega la temperatura e gli sforzi. Ne risultano differenti comportamenti, a seconda che la deformazione si sviluppi a proporzione delle fasi fissa, stesso stato di sforzi, stessa velocità di distorsione o stessa temperatura. Si propone la lista delle numerose implicazioni per le rocce parzialmente fuse che possono spiegare lo sviluppo del fabric, la fusione ai margini dei cristalli, la localizzazione della distorsione, l’alternanza di composizione mineralogica, il riscaldamento per shear, la risaldatura dei granuli, estrazione del fuso per scivolamento e bloccaggio (stick-slip), la frammentazione del magma o la formazione di vetro resistente o fragile. Si presenta qui un diagramma di fase per PMR che incorpora temperatura, sforzo e concentrazione che possiede un grande somiglianza con quelli noti per altri materiali deboli. TERMINI CHIAVE: reologia, materiali bifasici, migmatiti. 236 J.-L. VIGNERESSE ET ALII Most materials that constitute our direct environment are composed of several phases that all behave differently when submitted to stress. Rheology and continuum mechanics are usually the field of investigation for such behaviour. However, the basics hypotheses assume that the material presents continuous, or not too contrasted, properties between phases. Thus can be the case in solid rocks, where the minerals react similarly to a bulk stress. It is no more the case when one phase is solid, or highly viscous, and when the other phase is a liquid or a gas. For instance, sand usually flows under the wind, resulting in booming dunes whereas those keep a bulk pile shape. Conversely, mud saturated with water flows and spreads. Lavas adopt a similar behaviour. When a high temperature, they flow over kilometres, without any real structural control, except those imposed by the surrounding topography. Conversely, internal structures develop that can be used to infer flow directions and internal stress pattern. Such situations are hard to describe with usual methods, and any kind of averaging from the laws governing the end-members usually fail to describe instabilities that soon develop. Those are specifically observed into partially molten rocks, here referred to as PMR. The present paper started from field observations on migmatites and crystallizing magmas. Migmatites are rocks that were partially molten rocks before they crystallized in their actual state (MENHERT, 1968; ASHWORTH, 1985). In contrast, fabrics in magma record the shear flow of the melt during emplacement (PATERSON et alii, 1998). PMRs can accordingly be envisioned as two-phase materials. One phase is solid (the rock that melts or crystals in magma); it is hereafter referred to as matrix. Melt is the other phase, here, essentially referring to felsic melts, though general term of granitic melt should not be restricted to any specific composition. We develop a description of the PMR rheology that takes into consideration. RICHET, 2005), granite rheology (PETFORD, 2003), pastes (COUSSOT, 2007), polymers (DE GENNES, 1979), foam (KRAYNIK, 1979), dense suspensions (STICKEL & POWEL, 2005), analogue deformation (ROSENBERG, 2001), friction (PERSSON, 2000), granular flow (JAEGER et alii, 1996) and wet granular flow (MITARAI & NORI, 2006). Previously, we focused on identifying: 1) The amount of the solid phase (Φ), ranging from 0 to 1. It is similar to a volume. 2) The intrinsic viscosity h of each phase, intimately linked with the strain rate (γ°). 3) The applied stress (σ). 4) The temperature (T) interval between solidus and liquidus. RHEOLOGY OF THE TWO END-MEMBERS OF A PMR The choice of the viscosity is for convenience, because it is better constrained by experiments than stress or strain rate. In consequence, after selection of stress as the intrinsic variable, a full description could be represented into a 3D diagram with coordinates stress, temperature and volume. The constraints taken into account relate to field observations. They consist in: 1) The changing viscosity contrast with strain rate. 2) The non-linear aspect of melting rate. 3) The different evolution of viscosity with temperature for melt and matrix 4) The difference between melting and crystallization. 5) The bulk motion «en bloc» at the scale of a magmatic body and the small-scale heterogeneous motion with instabilities. The present paper combines information about parameters identified in previous studies with important review papers about silicate melts (MYSEN & 1) The evidence of two thresholds during melting and crystallization (VIGNERESSE et alii, 1996). 2) The non-duality between melting and crystallization (VIGNERESSE et alii, 1996). 3) The importance of strain partitioning between phases (VIGNERESSE & TIKOFF, 1999). 4) The non-linear behaviour of the melting rate and melt distribution (BURG & VIGNERESSE, 2002). 5) The rheological contrast between melt and matrix (BURG & VIGNERESSE, 2002). 6) The presentation and solution of a double system of equations for melt extraction (RABINOWICZ & VIGNERESSE, 2005). 7) The necessity of including pure and simple shear for melt extraction (RABINOWICZ & VIGNERESSE, 2004; VIGNERESSE & BURG, 2005). 8) The discontinuous melt extraction rate (VIGNERESSE & BURG, 2005, RABINOWICZ & VIGNERESSE, 2004). 9) The cusped shape of the viscosity as a function of strain rate (VIGNERESSE & BURG, 2004). 10) The discontinuities the cusp shape induces on a stress-phase diagram (VIGNERESSE et alii, 2007). 11) The role of nonlinear melting in the melt production, i.e. on the phase proportion (VIGNERESSE et alii, 2007). 12) The importance of mapping those parameters for identifying instabilities development (VIGNERESSE et alii, 2007). Rheology commonly describes the relation between shear stress (σ) and shear strain (γ), whereas time dependent effects imply a strain rate (γ°) response to stress. We use a shear strain rather than a plane strain (ε) since most magmatic flows develop under shear. Melt and its matrix are the two end-members of the system. The melt behaves as a Newtonian body for moderate to low strain rates. A constant viscosity relates linearly strain rate to stress. Within the temperature range of melting (650-900°C), calc-alkaline granitic melts present viscosity value around 106 Pa.s (CLEMENS & PETFORD, 1999). It exponentially decreases with temperature, in function of the activation energy E, with a typical value about 300 kJ/mole (MAALØE, 1985). Around 800°C, viscosity decreases by 2.5-3.0 orders of magnitude for an increase of 100°C. In contrast, crustal rocks brought at the same temperature range (650-900°C) deform in a ductile manner. We adopt the case of dislocation creep of a single crystal, with a power law exponent of 3 (NICOLAS & POIRIER, 1976). Experimentally obtained values for amphibolites, with values log A = –4.9 and Q = 243 kJ/mole (KIRBY & KRONENBERG, 1987), are used as a proxy for the restitic matrix of PMR, yielding a melt of granitic composition. The effective viscosity is estimated from the local tangent to the stress-strain rate curve. INSTABILITIES DEVELOPMENT IN PARTIALLY MOLTEN ROCKS 237 Under those assumptions, the preceding numerical values provides the equations for the melt log η = 6 (1) log η = 10.66 – 2/3 log γ° (2) and for the matrix The rheology of mixed melt and matrix (PMR) cannot be simply defined as the combination of those two endmembers, depending on their relative proportion (fig. 1). During crystallisation, the solid particles interact which each other, leading to the Einstein-Roscoe law (EINSTEIN, 1906; ROSCOE, 1952; ARZI, 1978): η = η0 (1 – Φ/Φmax)-ne (3) in which η0 is the initial melt viscosity, Φmax is the maximum packing assemblage, and ne an experimentally determined coefficient (LEJEUNE & RICHET, 1995). It has been experimentally validated up to 0.40 of solid phase, less than maximum packing, about 0.75 (ROGERS et alii, 1994). Particle interactions become important at higher concentrations, changing the exponent into –ne.Φmax. This reduces the exponent value from 2.5 to about 1.8 (KRIEGER & DOUGHERTY, 1959). However, the viscosity increases by 4 to 5 orders of magnitude near maximum packing. Indeed, the mixture becomes thixotropic (BARNES, 1997) with departures from non-linearity in case of crystallization and pseudo-plastic in case of melting. Nevertheless, the viscosity contrast between melt and matrix ranges from 10 to 14 orders of magnitude (BURG & VIGNERESSE, 2002) when restricting the stress values in between 0.1 and 100 MPa. PMR SPECIFICITIES A PMR combines three possibilities to develop instabilities. One is mechanical or rheological, owing to the large viscosity contrast between melt and matrix. The second is driven by the respective amount of each phase. The third is chemical and relates to temperature, especially during the interval between melting and crystallization. A 3D diagram combining stress, temperature and the volume of one phase is suggested that would provide a complete mapping of the complex PMR rheology. However, before constructing this diagram, one should take into account the specific points that characterize PMR rheology. Those are the existence of two thresholds during the transition between the end-members (VIGNERESSE et alii, 1996), strain partitioning (VIGNERESSE & TIKOFF, 1999) and feedback loops that develop due to nonlinear processes (BURG & VIGNERESSE, 2002). The link between the rheology of a strong matrix and that of a concentrated suspension, drawn from Einstein-Roscoe equation (RENNER et alii, 2000; ROSENBERG, 2001) is seriously questioned since it does not allow any instability to develop (BURG & VIGNERESSE, 2002). The range of threshold values for melting and crystallization overlaps. Thus, a definite rheology cannot be ascertained in that domain, that sees overlapping of two behaviours, each being related to one end-member. In addition, this domain, with two metastable states varies in size depending on the strain rate or stress acting on the system. Instabilities develop during melting or crystallization, when the slope of the flow curve relating Fig. 1 - Log-log stress-strain rate diagram showing the behaviour of the melt and its matrix. Viscosity values are indicated in grey. – Diagramma bilogaritmico sforzi-velocità di ditorsione, che mostra il comportamento del fuso e della sua matrice. I valori di viscosità sono indicati in grigio. the transition from one phase to the other has becomes negative (SPENLEY et alii, 1993). In case of a system under common stress, fluid decomposes into a layered structure, with alternate layers of high and low strain rate. Conversely, in case of deformation under common stress, shear localisation develops (fig. 2). The bulk rheology of a PMR should be examined in a 3D (σ – γ° – Φ) diagram. However, the pair σ-γ° is poorly determined from experiments, that often develop under constant and fast strain rate. Hence, they are limited by the total duration of the experiments. We prefer adopting a 3D (η – γ° – Φ) diagram because the pair η-γ° is experimentally constrained. We start with the state equations for the melt and its matrix (Eqs. 1 and 2). Owing to large variations in viscosity, the strain rate response to stress plots in a log-log diagram. A line with constant slope represents the melt, whereas another line represents the matrix. In between, the Einstein-Roscoe curve is not strain rate dependent. The two surfaces constructed from the two end-members overlap over a wide range of Φ (0.50 to 0.75). The connection between the two end-members takes the form of a cusp surface in the (η – γ° – Φ) diagram. Temperature has a differential effect on the viscosity of melt and matrix, resulting from the activation energy values for those phases. They respectively plot as two lines with different slope on a semi-log diagram as a function of temperature. The viscosity for the transitional state must be computed for fixed values of strain rate from the 3D diagram (η – γ° – Φ). 238 J.-L. VIGNERESSE ET ALII cusp shape within this range of temperature. Instabilities may develop depending on the followed path, i.e. constant stress or constant temperature, identically to the instabilities with strain rate. Fig. 2 - Instability occurrence depending on whether the path occurs under a common strain rate (a) and (b), leading to banding, or under a common stress (c) and (d), leading to strain partitioning. – Dipendenza dell’instabilità dall’instaurarsi del percorso in condizioni di velocità di distorsione comune (a) e (b), che genera un’alternanza di composizione, oppure in condizioni di stress comune (c) e (d) che genera ripartizione della distorsione. All parameters are now settled to build a phase diagram that would determine the limits of PMR rheology, in function of the phase amount, viscosity and temperature. The strain rate should be introduced to determine the respective occurrence of instabilities. The basic ingredients to construct a 3D diagram (Φ – η – T) are the preceding diagrams (fig. 3). For a better readability, we use φ = 1 – Φ, the amount of liquid phase, and because it is better constrained, we use the viscosity instead of stress. The three axes (φ – η – T) determine the range of occurrence of PMR. Whereas the amount of melt ranges from 0 to 1, the temperature ranges from Tsolidus to Tliquidus, and the viscosity, which is plotted in a log scale ranges from the viscosity of the melt a Tliquidus to the value for the matrix at Tsolidus. The resulting diagram adopts the shape of a quarter of quasi-cylindrical body, the concavity of which faces the origin. This shape results from the two limiting values in temperature and phase amount, whilst the concave pattern results from the melting curve. In case of cusp development, the quasi-cylindrical body also presents a cusped surface, toward the origin. Such mapping is useful as much as it can prompt the design for new experiments through predicting the behaviour of a studied system. A first attempt has been to classify the instabilities in a two-phase material according to the shape of the flow curve. It corresponds to considering the concentration, spinodal decomposition, or strain rate, i.e. essentially adopting a mechanical, point of view (OLMSTED & LU, 1999). GEOLOGICAL IMPLICATIONS MAGMA EMPLACEMENT AND STRUCTURES Fig. 3 - 3D diagram showing the occurrence of a cusp in the PMR rheology surface, as a function of decreasing viscosity and temperature. – Diagramma tridimensionale che mostra la comparsa di una cuspide sulla superficie della reologia PMR in funzione della viscosità decrescente e della temperatura. Under high strain situation, the transition from the solid to the weak phase is monotonous, giving place to a smooth viscosity variation. In contrast, the low strain rate case has to take into account the cusp that develops in the (η – Φ) diagram. Cusp occurs in between 30 and 60% of the solid phase. The transition in viscosity also adopts a During felsic body emplacement, the strain rate is commonly higher than 10-12 s-1, implying a stress level over 10 MPa (HARRIS et alii, 2000; VIGNERESSE, 2005; HAWKESWORTH et alii, 2004). The viscosity contrast between melt and matrix is the lowest, thus relaxation times for both phases have similar amplitude. The bulk material responds as a single-phase body with a bulk viscosity. Two situations can be observed that relate the strain rate and the ability of PMR to flow. Migmatitic bodies present the same structural trends as surrounding rocks (NZENTI et alii, 1988) documenting «en masse» deformation of the PMR massif. Decreasing the strain rate implies increasing the viscosity contrast between melt and matrix. In a PMR, the rotation of the first formed crystals results in a fabric (BOUCHEZ, 1997; ARBARET et alii, 2000). When crystals interactions develop, it can lead to particle segregation, controlled by the concentration, as it has been described as Bagnold segregation (BAGNOLD, 1954). Conversely, when the strain rate locally exceeds the ability of a PMR to deform viscously, then it breaks into fragments like during brittle deformation (PAPALE, 1999), as observed during volcanic eruptions. Experiments on brittle fragmentation of magmatic melts suggest strain rates ranging from 50 to 150 s-1 (BÜTTNER et alii, 2006). INSTABILITIES DEVELOPMENT IN PARTIALLY MOLTEN ROCKS Mineral banding is one way to accommodate velocity continuity between phases, as described in flowing liquid crystals (BONN et alii, 1998). It manifests in PMR through schlieren and melt-rich segregation (CLARKE & CLARKE, 1998; WEINBERG et alii, 2001; CLARKE et alii, 2002). In this case, it manifests through crystal sorting by size or by composition. In obsidian, it also takes the form of alternating bands of different colour some tens of microns to decimeters in width (SWANSON et alii, 1989; SMITH, 2002). The occurrence of shear bands due to strain localisation in plastic material results from deformation concentration on planes. In PMR, the different viscosity between the two phases leads to strain partitioning (VIGNERESSE & TIKOFF, 1999). The discrete distribution of localised shear zones with only a few cm in width profoundly differs from the usual observation that ductile rocks should present diffuse deformation. In crystallizing magma, strain localisation develops within a non-yet consolidated framework of touching crystals, leading to formation of dilatant proto-faults (GUINEBERTEAU et alii, 1989; PONS et alii, 1995; SMITH, 2000). MELT SEGREGATION Melt segregation at incipient melting results when both pure and shear stress apply on a PMR (RABINOWICZ & VIGNERESSE, 2004). A compaction length describes the resulting space and time discontinuities. Melt-rich bands form at low angles (within 20°C) when observed on analogue material (ROSENBERG & HANDY, 2000; BARRAUD et alii, 2004) and natural samples (KATZ et alii, 2006). They occur both during partial melting (MARCHILDON & BROWN, 2002) and crystallization (GOURLAY & DAHLE, 2007). Instabilities in time result in cyclic periods of segregation, driven by the amount of melt (RABINOWICZ & VIGNERESSE, 2004; VIGNERESSE & BURG, 2005). Grain boundaries wetting by incipient melt is due to progressive depinning of the melt along the boundary surface, bearing relation to stick-slip motion observed during friction. Sliding motion is discontinuous and depends on the differential velocity between the two surfaces in contact leading to stick-slip motion (SCHOLZ, 1990; THOMPSON & ROBBINS, 1990). It results from a competition between nucleation and growth rate of the pinning zones on one hand and the sliding velocity on the other hand. Indeed, stick-slip vanishes as the velocity overcomes a critical value, just because pinning has no more chance to develop. At the end of crystallisation, the high proportion of the solid phase drastically reduces the melt mobility, isolating small-scale closed systems. The strain rate variation within the solid phase is analogue to pressure dissolution, resulting in important stress gradient between touching crystals. The gradient relaxes by dissolving one crystal to the benefit of another one (GRINFELD, 1993), leading to crystal impingement (MEANS & PARK, 1994; PARK & MEANS, 1996) in analogue experiments or in natural examples described in a crystallizing gabbro (NICOLAS & ILDEFONSE, 1996; ROSENBERG, 2001). At a larger scale, similar observations have been realised in metamorphic aureoles induced by granitic intrusions (MARCHILDON & BROWN, 2002). Sintering and high-pressure aggregation of particles into a solid bloc is observed in tuff welding (GRUNDER & RUSSELL, 2005). Competition between compaction and 239 viscous flow results in sintering, adhesion of molten fragments and deformation of glassy clasts (SMITH, 1960). Superplasticity is been widely observed as related either to micrograin or microstructural behaviour. It is interpreted as a transition between creep at low stresses and plastic flow near the yield stress. Viscous heating may lead to tachylites or pseudo-tachylites formation (SPRAY, 1995). Dilatancy is a volume expansion in response to an applied stress, also synonymous with shear thickening, induced by the increasing viscosity of the crystallising magma. Nevertheless some dilatant veins also show internal brecciation (SMITH, 1996) indicating that still present melt overcame the brittle/ductile transition. Dilatant regions are a sink for the residual melt in a flowing magma has been widely recognised by a more abundant glassy material (SMITH, 2000). MEMORY EFFECTS Most of the instabilities above described present hysteresis, i.e. memory effect. It means that the transition from one state to the other is not dual to the reverse transition in terms of energy balance. Hysteresis is commonly described for induced magnetization (BERTOTTI, 1998), but also for plastic deformation (PRANDTL, 1928). Indeed, a plastic body retains some strain (BRIDGMAN, 1950) when stress returns to its initial state. It profoundly contrasts with elastic deformation during which the strained body returns to its initial state when the stress is no more applied. Hysteresis is the manifestation of stored energy. The return to initial conditions requires additional forces. This is the case for plastic deformation, or magnetism through the magnetic coercive field. In the transition to melting, the additional energy takes the form of the latent heat. During crystallisation of viscous material, there is a continuous reduction in the mobility of elements, manifested by the viscosity increase. Energy is thus continuously released between the liquidus and the solidus, corresponding to the entropy step due to latent heat when considering the temperature. The correlation between latent heat and viscosity is linear (GARAI, 2004) for materials that show a good Arrhenius behaviour. This would correspond to a well-defined heat capacity gap between the liquid and the solid state, that is, to contrasted values of entropy of structural configuration (BOTTINGA, 1994). When this is not the case, as for instance in fragile glass material, the number of intermediate structural configurations is large allowing intermediate metastable states, hence departure to Arrhenian behaviour, and nonArrhenian viscosity (ANGELL, 1995) and consequently larger hysteretic loop. Indeed, hysteretic flow curves have been observed for non-Newtonian flows (BONN et alii, 1998). The memory effect or hysteresis in PMR is observed during successive phases of heating and cooling silicate melts above their liquidus temperature (YUE, 2004). The repeated heating and cooling phase lead to a gradual transition from non-equilibrium to equilibrium states. An ordered structure is observed up to 70°C above Tliquidus. The conversion from multi-crystalline phases to a single phase indicates that the liquid remembers the structures previously formed (YUE, 2004). Indeed, glassmakers use 240 J.-L. VIGNERESSE ET ALII cycles of rapid heating and cooling to transform a fragile crystalline phase into a stronger one (CONRADT, 2004). In our suggested model, hysteresis should be understood as a dissipation mechanism unable to return to its initial state without the addition of extra energy. However, repeated cycles of straining could lead to unexpected large strain, especially when the material has not the time to completely relax and return toward a state near its initial conditions. This is obviously the case when seismic waves, which are successive cycles of compression and extension, interact with a two-phase material. Nonlinear effects develop that indicate no return to initial conditions before the material is strained again. It usually leads to soil liquefaction when seismic waves propagate through saturated sediments (ISHIHARA, 1993). The preferential reusing of a vein by new magma is also a sign of hysteresis. Tubes offer a pathway for lava to flow over large distances (PETERSON et alii, 1994; CALVARI & PINKERTON, 1994). Finally, the reusing of already formed plastic shear zones is also a consequence of the memory effect. Grain reduction in a shear band or weakened material due to a former heating are potential sites to localise strain for a future deformation cycle. In that sense shear heating (SCHOLZ, 1980) could provide natural conditions for rapidly deforming magma-present material. IMPLICATIONS FOR EXPERIMENTAL DEFORMATION The present paper offers an explanation for the development of much instability observed in natural conditions. However, it should be better regarded as a short review on the conditions under which those instabilities are produced. It is a former guide for designing experimental or numerical studies in order to address such instabilities. One problem with experiments performed on natural rocks of analogue materials is the duration of the experiment. It directly points to the effect of strain rate. Adopting the time scale for a one year experiment, a long time indeed when considering the stability of one experiment, implies a strain rate of at least 3.2 *10-8 s-1. Each additional order of magnitude implies a factor of 10, that would results in a maximum strain rate of 10-10 s-1 obtained during a single experimentalist’s life. One possibility to overpass this difficulty would be to change the material for some analogue material, resulting in the application of more reasonable strain rate. Adopting a common value of 10-5 s-1, which is in use in many experimental press systems, limits in turn the viscosity contrast between a two-phases material. The idea of the paper started from a different point of view. Provided experiments are not able to address the development of instabilities in terms of viscosity, strain rate and stress, it should possible to design some specific experiment that would be designed to address only one type of instability, depending on the temperature, viscosity and relative percentage of each phase (fig. 3). CONCLUSIONS Partially molten rocks (PMR) are commonly described as inhomogeneous, with a locally variable and unpre- dictable amount of melt. They also show local heterogeneities in strain distribution, with a neat predominance of non-coaxial deformation and shear. In contrast, at a large scale, their internal structures are concordant with those of the surrounding. PMR are by evidence a place where instabilities develop. Examining the rheology of PMR, we suggest three types of instabilities, one related to mechanical reasons, as shear zone localization or stickslip motion, one linked with the concentration of solid phase, as banding or dilatant zones and a third one linked to temperature occurs when melting rate overcomes the rate of melt extraction. Our model of two-phase rheology presented through a 3D diagram (γ° – Φ – η) shows a transition between a low strain rate regime during which the transition from one phase to the other is continuous in terms of rheology. It corresponds to a bulk motion of magma as a solid body, as exemplified during magma crystallisation or when migmatitic bodies are tectonically deformed. In contrast, at low strain rate, a cusp develops within the surface that represents the effective viscosity. It is the place of successive jumps between the rheology of each phase. 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