Introduction This document provides a brief summary of the activities carried out at the Coherentia-INFM R&D Center from June 2004 to December 2005 and represents an integration to the Activity report 2002-2004. The advances of the main Center research lines (A1-3) are first presented, followed by the reports on the original “seed” activities that have been approved for continuation after the first two years (S2 and S4), the tree new seed activities (SN1-3) selected by the international Scientific Council and the four “esplorative“ activities (EX1-4) approved by the Executive Committee in October 2004. A list of the papers published or submitted in the same period is also enclosed, as well as the list of the Lectures held at Coherentia Center in Napoli. During 2005 we have been experiencing uncertainties and difficulties due to the institutional changes and the need to become fully integrated with the CNR (National Research Council) structure. This process should be completed in 2006, and will imply a deep reconstruction of the full organization and management structure. However the overall budget situation has been fairly stable in the last year (about 2.6 million euros, not considering the salaries of the associated personnel and all building costs), and the foreseen budget for 2006 is also expected to be at the same level, guaranteeing the funding, at a reasonable level, of our research efforts. I am happy to say that in any case the level of scientific achievements of our Center has been fairly high in 2005, keeping, or in some cases improving, the high standards of the first years. Internationally recognized results have been obtained in the study of superconductors and strongly correlated oxides and in the development of new devices also using and integrating ultrafast optical techniques. In 2005, following the suggestions of the International Scientific Committee, we have held a number of “internal” scientific meetings, including very successful workshops on Manganites, Optical Technologies, Organic Materials for Electronics, and Superconductivity. We have also held a very stimulating meeting selforganized by our Post-Docs and young Researchers. Among the most significant issues in the growth of Coherentia in 2005, let me emphasize the set up of our laser ablation deposition system MODA, which, thanks to the efforts of the working team dedicated to this important facility, is now fully operative. MODA will certainly act as an important reference point at national and international level, bringing new research (and funding) opportunities. Finally in 2005 an important Project on the physics and applications of oxides materials, named “NANOXIDE”, lead by INFM (LAMIA and Coherentia) has been approved and funded by the European Community (STREP Projects). Coherentia researchers have also organized an important meeting of the European Science Fundation Project “PI-SHIFT” in 2005, underling the important role of our researchers in this Project. Moreover the organization of the prestigious International Workshop on Oxide Electronics (WOE13, October 8-11, 2006) has been assigned to Coherentia .This further underlines the increasing role of Coherentia at an international level in the field . Let me conclude by thanking the International Scientific Committee for the critical analyses and stimulating suggestions, and all our researchers for their constant efforts. Naples, December 31st, 2005 Prof. Ruggero Vaglio Coherentia Director MODA A1: Deposition and diagnostics of thin films of innovative materials Coordinator: F. Miletto Granozio Our Activity assembles, at a national level, a substantial fraction of the expertise and instrumentation on the deposition of high Tc superconductors and related transition metal oxides, plus a specific competence regarding the physics of plasmas generated in physical vapour deposition processes. We aim at a) coordinating and comparing sample fabrication activities and film growth studies performed by different PVD methods, b) coordinating collaborations for sample characterisation, with peculiar focus on experiments held at large scale facilities, and c) providing to the Center and in general to the national/international community innovative, high quality samples with certified properties. Researchers S. Amoruso, C. Aruta, G. Balestrino, R. Bruzzese, G. Ghiringhelli, L. Maritato, P. Medaglia, F. Miletto Granozio, M. Salluzzo, U. Scotti di Uccio, A. Tebano, X. Wang, M. Angeloni, N. Boggio; G. de Luca; A. Fragneto, A. Oropallo, P. Perna, M. Radovic, A. Sambri, M. Vitello. Thin film growth at Coherentia-CNR-INFM Research activity has been mainly focused on two kind of compounds: the superconducting cuprates, traditional field of research of all the participating groups, and ferromagnetic manganites, which have rapidly reached a comparable weight in our research. The interaction with other laboratories of the Center, in particular those participating to A3, has further expanded the variety of analytical technique which have been employed on our samples. As cases of special relevance, we would like to point out the increased effort towards magnetic characterizations - mostly boosted by research on manganites - and towards experiments at large scale facilities. Development of the new deposition and characterization facility MODA. The so called MODA system (Modular facility for Oxide Deposition and Analysis) has been set up in all its major components. The full system includes a) a fully software controlled PLD chamber, equipped with a 6 target carousel, a KF excimer laser, a high pressure RHEED, a mass spectrometer, and suitable access flanges for performing optical characterization of the sample and of the laser plume; b) an analytical chamber equipped with Fig. 1 - The new MODA Lab in Naples an electron spectrometer and an X-ray source for XPS and a spot profile analysis LEED (SPA-LEED), plus extra flanges for adding further future characterization tools; c) a chamber for variable temperature STM/AFM; d) a distribution chamber and a load lock chamber. Thin film fabrication in MODA has started in late year 2005. Growth of high quality YBCO and LSMO films by PLD has been immediately demonstrated. Grown samples of both compounds show very high critical temperatures, a high degree of structural perfection, the rocking curves having FWHM < 0,1°, and good morphologies, with a tiypical RMS of 0,2 nm measured on LSMO samples. XPS measurements on in-situ grown samples are routinely performed, and provided until now a number of interesting preliminary results. The STM/AFM has demostrated the capability of atomic resolution on simple materials (Si and HOPG), and of very clearly resolving the step structure on oxides. Starting of the research on electron diffraction in MODA is foreseen in early year 2006. We will both employ the SPALEED, which is already partially working, and the high pressure RHEED, which will be presumably mounted in next months. The integration in the MODA apparatus of a preexiting sputtering system is also under way. Research on thin films of superconducting oxides Resonant Inelastic X-ray Scattering (RIXS) and X-ray Absorption Spectroscopy (XAS) measurements were performed in different samples of (BaCuO2+x)M/(CaCuO2)N superlattices, both at the Advanced Berkeley Light Source and at the European Syncrothron Radiation Facility in Grenoble. The samples were formed by a charge transfer (CR) block composed by two BaCuO2 layers and different infinite layer nh ligand holes 0.32 (IL) blocks with different numbers of CaCuO2 layers. XAS out-of-plane in-plane 0.28 measurements were performed at different angle orientations 0.24 and polarizations, in order to obtain information on the 0.20 symmetry of unoccupied orbitals. XAS spectra showed the 0.16 transitions from the 3d9 and 3d9L initial state configurations. 0.12 The 3d9L configuration (where L stands for ligand) is related to 0.08 the hybridisation of Cu2+ with O-, therefore giving rise to the -1 0 1 2 3 4 5 6 7 Ca blocks Fig. 2 – Hole doping in a multilayer composed of two BaCuO2 block and a variable number of CaCuO2 blocks doping holes. The number of ligand holes is obtained by the relative intensity of the 3d9L peak respect to the total intensity of the 3d9 and 3d9L peaks. The results obtained both in-plane and out-of-plane confirm the charge transfer interaction between the blocks. Data analysis is still in progress, expecially on RIXS spectra. The thickness effect on the superconducting-insulator (S-I) transition of epitaxial untwinned Nd1+xBa2-xCu3O7-d epitaxial films deposited on SrTiO3 (100) has been analysed. Using high resolution x-ray diffraction and CuL and OK edge polarized X-ray Absorption Spectroscopy we have at the same time studied the change of the electronic properties and of the structure as a function of the thickness. Two structural transformations are observed. The first one is a crossover from the orthorhombic and twinned structure, typical of thick samples, to a pseudotetragonal phase at thickness lower than 60 unit cells. The second one, starting at a thickness lower than 20 unit cells and completing below 8 u.c., is assigned to a pseudotetragonal-tetragonal transition, and corresponds to a substantial decrease in Tc and in hole doping. In particular a S-I transition is observed when the film thickness is reduced from 9 to 6 unit cells. While the ab-plane unoccupied electronic states, associated to CuO_2 layers, are similar in 9 and 6 u.c films, we observed in the insulating sample a large reduction of the chain oxygen O(1) 2px,y states together with a decrease of the Cu(1) and Cu(2) out of plane 3d states and of the apical O(4) 2pz states. Our results suggest that the structural rearrangement and the transport properties are explained by the ordering/disordering of the CuO chains. Moreover the relevant role of holes present in layers adjacent to the CuO2 layers for the high critical temperature superconductivity has been demonstrated. Research on thin films of magnetic oxide Activity in Naples was dedicated to the analysis of epitaxial strain and of its effect on the properties of fully strained (100) and (110) oriented LSMO films, to the analysis of phase separation and to the fabrication of magnetoresistive devices. The strain tensor was obtained by X-ray diffraction, and on the base of the elastic tensor the stress tensor was calculated. The strain deformation of the LSMO cell grown on (110) STO substrates is particularly interesting, because of the presence of a shear component. Furthermore, the strain is anisotropic with respect to the in-plane directions. This affects not only the magnetization cicles, as demonstrated in last years, but also the resistivity itself, and its temperature dependence, that can be also shown to be anisotropic. As shown in fig. 3, the resistance vs. T behaviour above the Curie temperature, measured along the in plane [1-10] direction, is different, and this is attributed to the peculiar kind of cell deformation taking place in such Fig. 3 – R-T curves along the principal crystallographic directions, for a (‘’1) and a (110) film, and along the [1-10] direction of a (110) film are compared direction, that leaves the bond lengths unchanged. The research activity on phase separation and on the fabrication of magnetoresistive devices has been performed in collaboration with members of the other Activities, and will be described in the reports of Activity 3 and 2, respectively. A careful study searching for conditions for low pressure growth of manganites in a PLD system was performed in Rome. It has been shown that by decreasing the fluence it is possible to optimise the oxidation process in low background pressure, i.e. 10-4 - 10-3 mbar molecular oxygen plus 12% ozone, allowing the in situ use of a conventional Reflection High Energy Electron Diffraction diagnostic. Films deposited at low fluence (corresponding to a deposition rate per pulse of <10-2 unit cells per laser shot) show a two-dimensional growth mode and possess optimised magnetotransport properties without the necessity of any further postgrowth annealing treatment. The resistivity versus temperature measurements of LSMO films grown at a rate of about about 300 laser pulses/unit, show metallic behaviour with Tp as high as 370 K, comparable with the values obtained for the best single crystals (fig. 4, Fig. 4 - Tp for low pressure grown films as a function of the pulse number/cell. Inset: R-T plots as explained in text. red plot). The fluence for such growths is only 0.3 J/cm2, just above the ablation threshold. Tp gradually decreases as the deposition rate per pulse increases, and films grown at a deposition rate per pulse of 20 laser pulses/unit cell showed an insulating behaviour (fig. 4, black plot). To analyze the conducting/magnetic properties near the film/substrate interface in manganites, ultrathin films (thickness <400Å) of La0.7Sr0.3MnO3 were epitaxially grown by Molecular Beam Epitaxy in Salerno. Structural, magnetic and magneto-resistive properties were investigated. Highly anisotropic behavior in both transport and magnetic properties were measured along the in-plane directions parallel to the substrate crystallographic axes. In particular, the negative magneto-resistance measured at about 120K with the current along one of the crystallographic direction, is larger than the room temperature colossal value. In the same low temperature range, with the current along the other in-plane crystallographic direction (fig. 5), the magneto-resistance changes sign (resulting magnetic-field independent for T~150K). The low-temperature (<60K) transport properties of ultra-thin films have been investigated as a function of the sample thickness (from 40 to 3.5 nm) and in the presence of an external magnetic field. With decreasing thickness, a clear low temperature resistivity minimum slightly affected by the application of the magnetic field has 2 50 2 00 been observed, and its presence has been possibly 1 50 Resistance (Ohm) 1 00 interpreted in terms of quantum interference effects. As a function of the thickness, a cross-over from a 50 0 50 10 0 three-dimensional (3D) to a two-dimensional (2D) 15 0 Lsm o231s - thickness ~ 100Å Zero Field Cooled H = 1.0 Tesla H = 3.5 Tesla H = 7.0 Tesla 0 100 200 300 Tem perature (K) Fig. 5 - Inversion from negative to positive magnetoresistance at decreasing temperature behaviour of the system takes place below 20 nm. A re-entrant 3D behaviour is induced in ultra-thin films by the application of large (> 2 T) magnetic field. Plume analysis The research activity was devoted to the characterization of a LaMnO3 plume expansion in O2 with optical emission spectroscopy, ion probe diagnostics and fast photography, in order to correlate the plume properties it with the properties of manganite films. Fast photography proved to be very effective, since it allows snapshots of the plume propagation by recording images of its emission at different time delays with respect to the laser pulse (see figure 6). We have been able to study the effect of the pressure on different interesting parameters, such as: i) plume stopping length; ii) plume temporal broadening during the expansion; iii) asymptotic plume angular width. a) at low background gas pressure (<10-2 mbar) the plume expands freely, resembling the plume expansion in high vacuum conditions; b) at -2 intermediate pressures (≈10 1 mbar) the interaction with the background gas progressively influences the plume evidencing propagation, a number of effects (change in the internal structure of the plume and formation of a double-peak distribution of the emission; Fig. 6 - Images of the LaMnO3 plume at an oxygen background pressure of 3×10 mbar. τ represents the time delay with respect to the laser pulse -3 plume front braking and oscillating dynamics, followed by plume sharpening and stopping of the plume front; c) at high pressure level (few mbar) the plume becomes very confined with a typical stopping distance of less than 1 cm. In collaboration with Dr. J. Schou (OPL, Risø National Laboratory, Denmark) and Prof. J.G. Lunney (Trinity College, Dublin, Ireland), the propagation of the plume produced by laser ablation of a silver target in different background gases of different noble gases (He, Ne, Ar and Xe) was analyzed. The plume angular distribution broadens for all gases except for a minor pressure range for the helium background gas, in which a distinct plume narrowing occurs. The different expansion in helium background gas was ascribed to the collision dynamics in a helium plume. This and other aspects of the process merits further investigations, and will be considered in the next future. A2: Superconducting devices and fundamental issues in superconductivity under laser irradiation Coordinator: G. P. Pepe Josephson junctions (JJs) represent a powerful tool both to study fundamental issues in condensed matter physics and to envisage new original applications based on superconducting devices. JJs based on BCS-like low critical temperature superconductors (LTS) and well established fabrication techniques, are the most appropriate to test new device concepts such as those based on non-equilibrium effects. On the other hand, high critical temperature superconductors (HTS) JJs may represent the 'desirable system' to study fundamental issues ranging from the unconventional order parameter symmetry to quantum effects. One of the main aims of this activity is to investigate the effect of short and ultrashort (< 30 fs) optical laser pulses on both LTS and HTS superconducting systems trying to evidence effects related to induced modifications of the superconductive properties. The capability of controlling laser pulses' characteristics is also an important point of the proposed research. Moreover, fundamental studies on new coupled hetero-structures e.g. superconductor-ferromagnet multilayers, aned the possibility they offer to control the phase difference between two coupled superconductors in mesoscopic systems, represent another important challenging topic currently investigated in the framework of this Activity. Activity organization, laboratories and staff : INFM Napoli LTS based Josephson tunnel G.Peluso, G.P, Pepe, junctions devices: theory and L.Parlato, R. Latempa, experiment N. Marrocco HTS based grain Josephson junctions Ultrafast laser optical spectroscopy INFM Salerno G.Costabile, G.Carapella, V. Granata, N. Martucciello, F. Russo INFM Roma Other partners M. Casalboni, V. Merlo, P. Prosposito, M. Cirillo, F. Stella boundary A. Barone, F. Tafuri, D. Stornaiuolo, D. Dalena C. de Lisio, S. Solimeno, A. Porzio, Non-destructive testing using SQUID magnetometry Theoretical and computational investigation M.Valentino, C. Bonavolontà, A. Ruosi Tagliacozzo, P.Lucignano, G. Campagnano G. Rotoli (AQ) Laboratories and equipments The experiments performed within Activity 2 are mainly performed in the following laboratories: Napoli Low temperature JJs characterization (down to 0.3K); MSA-H27 MSA-H21b Napoli Femto-s laser source for cryogenic device characterization; MSA-1G23 Napoli Materials for optics & Optoelectronics ING-Peluso Napoli JJs characterization and cw laser irradiated test measurements; SA-Costabile Salerno Fabrication and characterization of tunnel Josephson devices; RM2-Casalboni Roma Preparation and characterization of sol-gel integrated optical waveguides. Main equipments: Diode laser for Millennia system pumpin, Computer-controlled acquisition system for escape measurements, Femto-Amperometer, Femtosecond Optical Parametric Amplifier. Activity progress and main scientific results: Nonequilibrium fast relaxation in proximised superconducting bilayers The investigation of nonequiilibrium properties of superconductor-ferromagnet heterostructures has been continued toward the development of a new detector experiment based on the fast bresponse of such hetero-structures. Part of the scientific work within this topic has been devoted to the development of a new detector design based on Nb/NiCu bilayers by following the approach of a strip-type detector: the schematic is proposed in Figure 1. The weak links have been realized through a photolithographic approach for width down to 5μm, and a Focused Ion Beam etching for widths less than 1μm. This latter configuration has been realized in collaboration with the Centro Ricerche FIAT, Torino, Italy. Measurements are currently in progress at the University of Rochester, USA (Prof. R. Sobolewski). Pump Moreover, the investigation of the role of Beam Probe Beam nonequilibrium superconductivity on the electronDC current bias phonon cpupling in S/F hetero-structures is also pursued: this approach is based on the assumption that I the e-ph constant λe-ph can be derived from the Allen formula depending on the electronic constant γ, and hence the electronic heat capacity, and the Eliashberg Micro/nano bridge S/F (NiCu/Nb) electron-phonon coupling function α2F. A detailed EO Crystal transmission line ) (LiTaO Contact pad study based also on the proximity model describing these S/F hetero-structures is actually under Figure 1: Schematics of the S/F detection development configuration 3 The investigation of the interplay between superconductivity and ferromagnetism has opened the way for the development of novel researches named “spintronics" due to the main role played by spins and their control through the spin injection and accumulation, the investigation of the Giant Magneto Resistance (GMR), etc. The application of such a physics to ferromagnetic manganites in a heterostructure with a superconductor and insulator as tunnelling barrier, represents an interesting step toward the development of new concept spin-based devices. In parallel, the fabrication and characterization of conventional Al/AlOx/Co S-I-F type junctions have been also pursued within the activity of the group of the University of Salerno, for spin polarized tunnelling. in zero field. A preliminary measurement is shown in Figure 2 where a fit with a modified BTK model is also reported. Another interesting experiment which is currently developed within the Activity A2 concerns the investigation of the enhancement of the Josephson critical current IC in S/F weak links when the alternating F-layers forming the two electrodes are anti-parallel aligned. The configuration is summarized in S/F1/I/F2/S type tunnel junction where the F-layers are obtained by changing the relative composition of NiCu alloys. The multilayers are grown by electron beam deposition, and processed by Focused Ion Beam lithography. The magnetic state of the devices is directly determined by measuring the current perpendicular to plane (CPP) magneto-resistance (MR) at high bias. Preliminary results show that IC is larger when the F-layers are antiparallel aligned. The maximum change of IC corresponds to the maximum change of MR. Possible effects in the presence of small Figure 2: IV and conductance curve of an Al-ICo tunnel junction. A BTK fit is also shown magnetic fields, related to charging activation energy, are also under investigation. In Figure 3 a photograph of the realized device is shown. Figure 3: FIB image of a final device from 65°. Advanced HTS JJs for fundamental studies and novel circuit implementation The activity on HTS devices can be briefly outlined into two main projects. The former is addressed to study quantum effects in high critical temperature superconductors Josephson junctions, and the latter to investigate vortex quantum tunnelling in ultra-thin films characterized by vortices with extremely large Pearl lengths. In both projects the A2 Coherentia team (Napoli and Rome-Tor Vergata) had great benefits from the collaborations with international partners, and in particular IBM T.J. Watson Research Center (USA) and Chalmers University (Sweden). The YBaCuO grain boundary biepitaxial Josephson junctions have shown high values of the quality factor Q, crucial in order to observe quantum behavior of Josephson junctions. In addition, the overall behavior of the biepitaxial junctions has been proved to be dominated by d-wave induced effects allowing a unique possibility to combine the features of dwave order parameter symmetry with a remarkable tunnel-like behavior. In collaboration with the University of Chalmers the junctions properties at very low temperatures have been measured providing an evidence of truly quantum behavior. The first step has been to prove macroscopic quantum tunnelling with some evidence of effects induced by the presence of a second harmonic. The second decisive step has been the demonstration of energy level quantization through resonant activation. These results are of great relevance and represent one of the most advanced and promising achievements in the field. They seem to indicate that the dissipation in a d-wave Josephson junction expected because of the presence of low energy quasi-particles (that might prevent the occurrence of macroscopic quantum phenomena, the key element for qubits) is low enough (hence allowing “sharp” energy levels, which is a major requirement for a qubit). Several efforts on the Coherentia side are devoted to improve junctions properties, which might guarantee high quality submicron devices. Some efforts include experimental and theoretical studies in the mesoscopic regime, bridging the existing experimental gap between high temperature superconducting structures and nanophysics. The fabrication process has been extended to LaAlO3 substrates in view of quantum measurements in presence of microwaves. The second project deals with dissipation in ultra-thin current-carrying superconducting bridges and with evidence for quantum tunneling of Pearl vortices. Zero-field current-voltage (IV) measurements of artificially layered high-Tc (CaBaCuO) thin-film bridges have been performed. The films are produced in Rome and patterned and measured in Napoli (photolithography handling of superconducting monolayers is an interesting technological achievement, which is also used for other experiments in Coherentia). Scanning SQUID microscopy of these films (realized by Dr. John Kirtley at IBM) provides values for the Pearl lengths that exceed the bridge width, and shows that the current distributions are uniform across the bridges. At high temperatures a thermally activated vortex motion is observed as expected, while at low temperatures, the IV's are better fit by ln V linear in I-2. This is expected if the low temperature dissipation is dominated by quantum tunneling of individual Pearl vortices. The extremely challenging objectives proposed at the beginning have been realized, and now the group is ready for next steps, for instance the preparation of the layout of the device for the measurement of Rabi oscillations, A fundamental role has been played by the prestigious and functional collaborations mentioned above: these joint experiments are accelerating exchange between the various groups and bridging Coherentia to very advanced topics on superconducting quantum devices. Toward superconducting opto-electronics The objective the A2 group at the University of Rome “Tor Vergata” has successfully realized chips containing high quality Nb-based Josephson tunnel junctions coupled to waveguides operating at low temperatures, connected directly to an external optical fiber. The aim is to produce a direct interface between a signal externally travelling along the fiber to the first stage of the superconducting electronics. Moreover, this technique allows a direct control of the impinging radiation position, a challenging issue in many fundamental experiments concerning the interaction between any optical radiation and the superconducting matter. In particular, a 3D structuring of the silicon substrate has been obtained by wet chemical etching processes with liquid reagents. The realized geometries are isotropic U-shaped and V-shaped grooves. The starting solution was a mixture of HNO3, HF, and CH3COOH at different concentrations. The photoresist is not compatible with such processes, and hence the lithographic pattern must be realized on an artificial mask. The best results have been obtained on NbN, and dry etchings by Ion Gun have been settled up. The used fiber for preliminary experiments was single mode with a diameter of 127 μm, and a core 3÷6 μm. The angle of the profile was 54.7 ° with respect to the wafer, and the Fig. 4 Monomodal fiber ∅ = 127μm within the etched width of the window for fiber allocation was 155μm in grove order to use the Si (111) planes as stop etching layer. In Figure 4 a photograph of the allocated fiber is shown. Theoretical actitivty on mesoscopic physics Resonant conduction through a Quantum Dot for correlation aong electron spins (Kondo effect). The electron correlation plays a very important role in quantum dots characterized by a low transmission from contacts. Under these conditions it can produce a Kondo effect with a conductivity equal to one at low temperatures even in the presence of an insulating state at higher temperatures. In the case of open dots, it has been demonstrated that resonances in the conductance curve can arise from the coupling between states localized within the QD: the role of the correlation can be negligible in this case (Fano-type resonances ). A Fano-resonance can arise also from the presence of a continuum spectrum of energies, which corresponds to a very spreaded Kondo resonance strongly coupled tolocalized states in the QD. The investigation of such a possibility has been developed by noting that a similar mechanism can led to the so-called “charge sensing”. This later will become a very important detection technique in the next future, and it consists of the modification of the conductance by a “ Quantum Point Contact “, realized by the adding of charge to a QD capacitively coupled.. Spin-orbit coupling in nanodevices and manipulation of spin by external e.m. fields. Recently, it has been demonstrated that it is possible to manipulate the electron spin by means of electrical fields perpendicular to the device plane (Rashba effect). The quantum interference of electrons moving balistically in an annular geometry has been studied by using a Feynman-type approach. In the presence of strong magnetic fields, the spin of few electrons in a QD can be totally polarized: this feature increases the importance of spin manipulation with a gate potential. By numerical methods the coupling between the radiation and the QD has been investigated through the creation of a spin exciton. Non-destructive testing by SQUID sensors on composite materials (mm) The high probability to damage composites material during their manufacture, service and maintenance, requires to test the integrity of such structure and components using adequate predictive methods. Traditional Non Destructive Evaluation (NDE) techniques are often not entirely adequate to detect subsurface flaws and delaminations inside fibre reinforced plastic components, usually because of their limited spatial and depth resolution. An alternative to eddy current sensor has been demonstrated to be represented by magnetic sensor such as a high-Tc SQUID. Thanks to its high magnetic field sensitivity and its ability to work down to very low frequencies it can detect much deeper defects and related effects. The activity of the A2 group focused on measurements 75 on composite materials in the presence of impact at 60 different low energies. A proper post processing of data 45 has been also developed in order to produce an output 30 of the sensor which is comparable to the convectional 15 technique, e.g. ultrasounds and eddy Current with 0 0 10 20 30 40 50 induction coils. An example of such a similarity is (mm) proposed in Figure 5. Moreover, in order to Figure 5 (a) magnetic map as detected by SQUID, (b) demonstrate the sensitivity of the SQUID sensor, an the result of the post-processing analysis, (c) an imaging of a 4mm thick sample impacted at very low ultrasound photograph. energies (down to 0.18J) has been carried out. Scientific Collaborations: 0,9 25,0 0,7 15,0 0,6 B(V) module (pT) 0,8 20,0 10,0 impact at 12 J impact at 20 J impact at 36 J 5,0 0,0 -60 0,5 0,4 0,3 0,2 0,1 -40 -20 0 mm 20 40 60 5 10 15 20 25 Energy 30 35 40 Figure 6 (a) Magnetic field along the impacted areas at different energies; (b) the minimum of B as a function of the impact emergy. Experimental results demonstrate the possibility to monitor the delamination between intralayers and interlayers in advanced FGAs (Fiber-glass Aluminium) composite, and to discriminate the impact damage even in the presence of a permanent surface deformation. The magnetic field as measured by a SQUID magnetometer along a line scan over the impacted area is shown in Figure 6. Moreover, the minimum value of the magnetic field as a function of the impact energy clearly evidence the presence of three energy regions corresponding to only deformation, fractures of the inner layer of FGA, and finally breaking of the rear surface of the specimen, as expected in the case of loaded composite materials’ analysis. CNR Institute of Cybernetics, Naples: LTS JJs fabrication on electro-optical substrates (LiNbO3 and LiTaO3) and for junction modelling; University of S. Luis de Potosi and South Caroline University USA (Prof. B. Ivlev), Mexico: nonequilibrium superconducitivty and quantum physics University of Twente NL (Prof. A. Golubov, H. Rogalla): nonequilibrium superconductivity and proximity effect in superconductor/ferromagnet hybrid heterosctructures and devices; development of digital SQUID for advanced NDE testing. University of Erlangen D (Prof. A. Ustinov): quantum escape measurements in Josephson escape measurements; IBM T.J. Watson Research Center USA (Dr. J. Kirtley) HTS device characterization University of Chalmers, Sweden (Dr. F. Lombardi): low temperature quantum measurements on HTS systems; CSNSM, Orsay, Paris F (Prof. M. Aprili): design and realization of three terminal devices employing superconductor/ferromagnetic structures. A3: Fundamental issues in perovskitic oxides Coordinator: Lorenzo Marrucci This research activity is focused on theoretical and experimental investigations of perovskite oxides and other strongly correlated electron systems. The main experimental approach is based on linear and nonlinear optical spectroscopies. These optical techniques are however complemented by other electromagnetic spectroscopies, such as in the microwave and x-ray domains, and by electronic techniques, such as STM or photoelectron spectroscopies. This research is mainly aimed at understanding key fundamental issues, but with a long-term view on the potential applications of the investigated materials in superconducting, optoelectronics and spintronics devices. Researchers Owing to its breadth of scientific goals and investigation methods, this activity is organized in the following four overlapping research lines: 1) Infrared and Raman spectroscopy. Location: Roma I–La Sapienza and Trieste-ELETTRA. People: P. Calvani, P. Dore, S. Lupi, A. Nucara, P. Postorino, D. Di Castro, M. Ortolani, A. Perucchi, A. Perla, A. Sacchetti, M. C. Guidi, E. Arcangeletti, L. Baldassarre, M. Baldini, F. Crispoldi 2) Nonlinear optical spectroscopy. Location: Naples-MSA. People: L. Marrucci, D. Paparo, F. Miletto, U. Scotti di Uccio, C. Manzo, A. Rubano, A. Savoia, A. Oropallo, P. Perna. 3) Transport properties, STM and microwave spectroscopies. Location: Naples-MSA and Naples-Engineering. People: A. Andreone, R. Vaglio, M. Salluzzo, F. Miletto, U. Scotti di Uccio, A. Cassinese, R. Di Capua, G. Lamura, M. Aurino, G. Cifariello, E. Di Gennaro, P. Orgiani, M. Giura, R. Fastampa, E. Silva. 4) Theory. Location: Naples-MSA, Roma II-Tor Vergata, Salerno. People: V. Cataudella, G. De Filippis, V. Marigliano Ramaglia, A. A. Varlamov, C. A. Perroni, D. Bercioux, S. de Siena, F. Illuminati. Activity progress and main scientific results In the period covered by this report, from July 2004 to November 2005, the research work of this activity has gone much as planned in the original workplan and is making good progress. We also have obtained many noteworthy results. In the following, we present a selection of results and progresses, organized according to the four main lines listed above. Please note that this is not intended as an exhaustive presentation of all scientific results (refer to the publication list of the whole Center for a complete list of results). Infrared and Raman spectroscopy One of the most interesting results of ours in the last year has been a study of the temperature dependence of the IR spectral weight W of La2-xSrxCuO4 (LASCO) obtained integrating the real part of the optical conductivity from dc to some given frequency Ω [M. Ortolani et al., PRL 94, 067002 (2005)]. This study has revealed a temperature behavior of LASCO that obeys to the same simple law W(Ω,T) = W0(Ω) − B(Ω)T2 followed by normal metals, such as gold (see figure 1 on the side). However, the value of the coefficient B taken at the plasma edge frequency was found to be much larger than that expected from a simple metal behavior, and this clearly indicates that two independent energy scales rule the electronic Figure 1 – Cut-off frequency Ω and temperature T behavior of the integrated spectral weight W (see text) in gold and LASCO at two different doping levels. Further details are discussed in the text and in the referenced paper. behavior in LASCO. This double-energy-scale behavior is a strong hint of the presence of an important contribution of electronic correlations. This idea was confirmed in our subsequent theoretical work [A. Toschi et al., PRL 95, 097002 (2005)], in which a Hubbard-model solved with a dynamical mean field theory approach has been used to predict a behavior quite similar to that observed experimentally. Another very important result obtained in September 2005 and still unpublished [S. Lupi et al., submitted], is the first sub-terahertz IR spectroscopy of B-doped diamond. This experiment is pioneering both for the technique used, which allowed the measurement of the reflectivity of diamond with an excellent signal-to-noise ratio well below 1 THz (33 cm−1), and for the samples (produced in the laboratory of Y. Takano at Tsukuba), which are the first diamond films with a critical temperature well higher than 4.2 K. We measured both the optical gap and the London penetration depth and we showed that B-doped diamond is a BCS superconductor. Among other noteworthy results, we mention the following: (i) an infrared study on NaxCoO2 [S. Lupi et al., PRB 72, 024550 (2005)], which confirmed the existence of charge ordering for suitable doping values; (ii) a Raman and IR spectroscopic study of SrMnO3 (a parent compound of the much studied LaxSr1-xMnO3) as a function of temperature, which led us to identifying a novel structural transition in this material [A. Sacchetti et al., PRB 72, 172407 (2005)]; (iii) a far-infrared study on pure, Al-doped and neutron-irradiated MgB2 samples, which allowed Adjustable aperture Sample visualisation Synchrotron beam us to investigate the conduction regime in the two bands (σ and π), by measuring the reflectivity ratio (Rsuper/Rnormal), and to measure the gap for the first time with FIR measurements [M. Ortolani et al., PRB 71, 172508 (2005)]. Finally, in 2005 the new infrared synchrotron beamline SISSI has been completed by our Coherentia team located at ELETTRA (see figure 2 on the side). Schwarzschild Objectives X-Y microstages Adjustable aperture Interferometer White light IR detector Figure 2 – Schematic layout of Coherentia experimental station at the SISSI IR beamline, ELETTRA. The beamline has rapidly reached performances comparable with those of similar devices, like that mounted on the ALS ring at Berkeley, and is now fully operative. Once the optimization and calibration of the beamline will be completed, a 25% of the beamtime will be reserved to Coherentia experiments. Nonlinear optical spectroscopy The new nonlinear optical apparatus for pump-probe coherent antistokes Raman spectroscopy (CARS) applied to perovskitic films and crystals, completed in 2004, has been carefully tested and several small technical problems were detected and solved. Figure 3 shows an example of one of our nonlinear CARS spectra of an YBCO film (close to optimal doping) at room temperature. All the main Raman-active phonons are visible, together with other features which we are currently trying to interpret [A. Rubano et al., unpublished results]. We emphasize that these resonances, apparently similar to “ordinary” Raman scattering lines, are actually obtained by driving the vibrational excitation by means of light itself, i.e., we do not rely on thermal or quantum agitation for excitation. This adds a possibility of external control which, in turn, will allow 0.16 us to investigate the dynamics and the coherence properties of the underlying 0.14 degrees of freedom, a kind of information 0.12 available with ordinary Raman spectroscopy. Transport properties, STM and microwave spectroscopies We applied STM spectroscopy to investigating the electronic properties of two materials, in the form of thin films: MgB2 and La0.7Sr0.3MnO3 (LASMO). In particular, in MgB2 we focused on studying the role of disorder, in order to investigate the mechanisms by which the critical temperature in this material appears Y Cu2 0.1 arbitrary units not Ba O2-O2 0.08 0.06 O2-O3 0.04 O4 0.02 0 -0.02 -0.04 0 100 200 300 400 500 600 700 -1 Raman Shift (cm ) Figure 3 – Coherent (nonlinear) Raman spectrum of an YBCO film (Tc = 85 K) at room temperature. These resonances are excited by a nonlinear coupling to grating created by two input laser pulses having different frequencies (one at 532 nm and the other set at the value given in the figure). to be so weakly sensitive to sample quality [M. Iavarone et al., PRB 71, 214502 (2005)]. In the case of LASMO, our tunneling conductance maps showed the presence of electronic inhomogeneities at room temperature, slightly below the metal-insulator transition, which disappear at liquid nitrogen temperature and are not correlated with topographic features [R. Di Capua et al., submitted]. Moreover, the observed features clearly exhibit two very different spatial scales of the fluctuations, as shown in figure 4, as has been also reported for other manganites. The underlying mechanism of these fluctuations is still uncertain. We applied also microwave spectroscopy to studying MgB2 films, by measuring the two tone intermodulation distortion arising from the material nonlinear impedence, with the aim of understanding the influence of the two superconducting bands on the electrodynamic nonlinear response [A. Andreone et al., IEEE Trans. Appl. Supercond. 15, 3612 (2005) and G. Cifariello et al., Figure 4 – STM conductance map of a surface of LASMO at room temperature, showing two-scales strong spatial fluctuations (see also inset). submitted]. It has been shown that these samples are not in a fully clean limit. They present a higher level of intrinsic nonlinearities at low temperature and low circulating power in comparison with conventional s- and d-wave superconductors like YBCO and Nb respectively. Considering that the level of nonlinearity can be decreased changing the scattering rates in the two bands with substitutional doping, the nonlinear response of this superconductor can be suitably tuned to make possible the development of new passive superconducting devices. Moreover, a new microwave-domain inductive contactless method has been developed for measuring the critical current density of a superconducting film, by working out a detailed analytical model of the inducing and induced currents distribution [M. Aurino et al., J. Appl.Phys., in press]. Finally, in the last year, a new activity on the electrical transport properties of hybrid organic-inorganic materials of interest for the fabrication of non conventional electronic and optoelectronic devices was started. In particular, our attention has been focused on non conventional semiconductors, where an organic component is integrated with an inorganic framework, so that the thermal stability and high crystalline order of the inorganic part is combined with the properties of Figure 5 – A possible layered structure of the organic-inorganic hybrid materials we investigated (see text for details). flexibility and easy processing of the organic compounds (see figure 5). More in detail, we started investigating the family of perovskitic based compounds, composed of amines and metal haloids with composition (R-NH3)2MX4 and CH3NH3MX3, where M is a bivalent metal, R a generic organic radical and X is an halogen. These materials have been prepared in the form of thin films on solid substrates and contacted for measuring their transport properties and for developing simple field-effect devices [A. Cassinese et al., unpublished work]. Theory Many experimental works described in the previous sections have actually benefited from the collaboration with our theoreticians. One such collaboration has been actually led by the theory group and has led to a detailed study of the temperature behavior of the resistivity in manganite thin films. The main result of this study has been the identification of an intriguing correlation between the amount of disorder present in the film and the temperature exponent in the resistivity [S. Mercone et al., PRB 71, 064415 (2005)]. Other results are purely theoretical. Correlations in the Holstein-Hubbard model at half filling have been studied by using a variational approach introduced by us [C. A. Perroni et al., PRB 71, 113107 (2005)]. The model is relevant for cuprates and other strongly correlated electron-phonon systems. The research activity on the polaron physics, one of the main research lines of our theory group, has continued focusing on more general el-ph interactions (long range effects) relevant for one-dimensional systems like DNA and carbon nanotubes [C. A. Perroni et al., PRB 71, 054301 (2005) and E. Piegari et al., Eur. Phys. J. B 44, 415 (2005)] and developing an original computational scheme for the Holstein model [G. De Filippis et al., PRB 72, 014307 (2005)]. A recently started investigation of spin-dependent transport in bidimensional heterostructures has also led to several interesting results. An electrical field, perpendicular to the plane where the electrons are confined, gives rise to a magnetic field parallel to the plane that couples with the spin electronic magnetic moment (Rashba effect). We have studied in particular networks of quantum wires, which exhibit peculiar localization behavior due to spin interference effects [D. Bercioux et al., PRL 93, 056802 (2004) and PRB 72, 075305 (2005)], and proposed a new kind of spin-field-transistor device based on the electron spin double refraction effect induced by Rashba spin-orbit coupling [D. Bercioux et al., Superlattices and Microstructures 37, 337 (2005)]. The contribution of vortex anti-vortex pairs to the temperature-dependent heat capacity of a type-II superconductor has been evaluated and found to be dominant in a wide range of temperatures below Tc [Y. N. Ovchinnikov and A. A. Varlamov, PRL 94, 107007 (2005)]. Finally, it is worth mentioning the publication of the new monograph by A. I. Larkin and A. A. Varlamov on the “Theory of fluctuations in superconductors”, Oxford University Press (2005). S2: Femtosecond laser pulse interaction with solid targets and investigation of the ablation plume. Coordinator: Salvatore Amoruso Participants: C. Altucci, G. Ausanio, R. Bruzzese, C. de Lisio, R. Velotta, M. Vitiello, X. Wang. Coherentia collaborations: Strong collaborations have been established with Activity 1 and Seed “Characterization and applications of nanogranular films produced by femtosecond laser ablation” (Main Investigator: Prof. L. Lanotte). External collaborations: Dr. Jørgen Schou, OPL, Risø National Laboratory, Roskilde (Denmark). Prof. Petar Atanasov, Institute of Electronics, Bulgarian Academy of Sciences, Sofia (Bulgaria). Introduction The present seed research activity deals with the interaction of ultrashort laser pulses with solid targets and the investigation of the ablation plume. In the previous two years, the ≈100 fs, 1 mJ Ti:sapphire laser source facility of the Coherentia R&D Center was used demonstrating some of the peculiar features of fs laser ablation [see e.g. ref. 1]. Among others, our experimental results indicated that ablation driven into vacuum by intense fs laser pulses offers a practical route for generation and deposition of nanoparticles (NPs) of different materials [2,3]. This feature was employed to produce nanogranular films of nickel with very peculiar magnetic properties [4]. At the end of year 2004, a new laser source was installed in the Coherentia Laser Laboratory. This laser source is a compact, fully integrated ps/fs laser based on a Nd:glass, chirped pulse amplified system producing pulses of ≈1ps at 1055 nm and ≈200-300 fs at 527 nm. The new system allowed us to carry out investigations at two different pulse durations and wavelengths, and also to compare the experimental results with those obtained with the ≈100 fs-800 nm Ti:sapphire laser employed in the previous investigations. x (mm) 0 0 5 10 15 τ=25ns Scientific activity a) Experimental characterization of ultrashort laser ablation. The properties of the 5 z (mm) The research activity was carried out along the following lines: 10 material blow-off produced during ablation with laser pulses of different durations (≈300 fs and ≈1 ps), and wavelengths (527 and 1055 nm) have been studied. A 15 thorough analysis has been carried out on silicon and nickel addressing two 0 x (mm) 0 5 10 15 τ=22.5μs fundamental features of the ablation process, namely the vacuum expansion of the Moreover, other materials were also investigated in the frame of the present z (mm) 5 ablated material and the generation of nanoparticles of the target material. 10 collaborations (e.g., TbDyFe, Ag, Al). Fast photography and emission spectroscopy allowed ascertaining the presence of a fast atomic plume component formed by atoms and ions of the target material and a slow component of nanoparticles (see Fig. 1). The atomic plume readily separates from the target, while the nanoparticles 15 Fig. 1: typical images of the plume showing the expansion of the atomic (upper layer) and NPs (lower layer) components. component remains in contact with the target surface for much longer times. The NPs size distributions have been analyzed through AFM analysis of less than one layer deposits. Our results show that the most probable NPs radii generally do not exceed 10 nm for Si and 15 nm for Ni, respectively. Moreover, the NPs size distributions are pretty narrow, with ≈85% of the Si and Ni NPs having a radius below ≈20 nm. The comparison of the data with previous results obtained with ≈100 fs Ti:sapphire laser pulses indicates that the properties characterizing the plume expansion and the size distribution of the produced NPs are almost independent of the specific laser pulse duration and wavelength, in the investigated range. This, in turn, suggests that these properties can be considered as general features of the process which are specific of the timescales involved in ultrashort laser heating and following material relaxation, and almost independent of the specific material properties and of the laser pulse characteristics [5]. b) Comparison of experimental data with MD simulations. Molecular Dynamics simulations were performed to elucidate the mechanisms of matter relaxation following ultrashort pulse laser irradiation. The main outcomes of the analysis are: i) the presence in the produced plume of two different classes of particles, atoms and nanoaggregates (see Fig. 2); ii) the nanoparticles are directly produced from the irradiated material through phase explosion, and do not result from condensation processes in the gas phase in the first stages of the plume evolution [6]. These Fig. 2: Snapshot of an MD simulation showing atoms and NPs. features are both in very good agreement with the results of our experimental analysis. c) Deposition of nanogranular films of magnetic materials. Finally, several films of elemental (Ni, Fe, e.g.), multicomponent (TbDyFe) as well as mixed systems (TbDyFe and Fe with different volume fractions of the two constituents, e.g.) were produced in the frame of the collaboration with the seed activity “Characterization and application of nanogranular magnetic films produced by femtosecond laser ablation. Instrumentation development A new ps/fs laser source with was installed in the Coherentia Laser Laboratory at the end of year 2004. Summary and perspectives The interaction of ultrashort laser pulses with solid targets and the ablation plume were studied both experimentally and theoretically. Our results suggest that the production of NPs can be considered as general feature of ultrashort laser pulse heating and following material relaxation, and almost independent of the specific material properties and of the laser pulse characteristics. In the next future, the different aspects of the process will be furtherly analyzed. In particular, we anticipate experiments on: i) other materials (dielectrics, e.g); ii) tailoring of the NPs size by using a second laser pulse. The experimental characterization will be also extended in the UV, in the next future, by frequency doubling the 527 nm laser pulse. References [1] INFM Research and Development Center Coherentia – Biennal Activity Report 2002-2004 (available at: http://coherentia.infm.it/struttura.htm). [2] S. Amoruso, R. Bruzzese, N. Spinelli, R. Velotta, M. Vitiello, and X. Wang, Europhys. Lett. 67, 404 (2004). [3] S. Amoruso, G. Ausanio, R. Bruzzese, M. Vitiello, and X. Wang, Phys. Rev. B 71, 033406 (2005). [4] G. Ausanio, A.C. Barone, V. Iannotti, L. Lanotte, S. Amoruso, R. Bruzzese, and M. Vitiello, Appl. Phys. Lett. 85, 4103 (2004). [5] S. Amoruso, G. Ausanio, A.C. Barone, R. Bruzzese, L. Gragnaniello, M. Vitiello, and X. Wang, J. Phys. B 38, L329 (2005). [6] S. Amoruso, R. Bruzzese, M. Vitiello, N.N. Nedialkov, and P.A. Atanasov, J. Appl. Phys. 98, 044907 (2005). S4: Quantum systems and computing Coordinator: Francesco Tafuri Participants: Antonio Barone, Detlef Born, Virginia D'Auria, Pier Gianni Medaglia, Pasquale Orgiani, Alberto Porzio, Salvatore Solimeno, Daniela Stornaiuolo Coherentia collaborations: Collaborations have been established with Activity 2 and 1. External collaboration: IBM T.J.Watson Research Center, Yorktown, NY (USA), Chalmers University of Technology, Goteborg (Sweden), Ames Labs (USA), Università di Milano e Roma I Superconductivity The activity can be briefly outlined into two main projects. The former is addressed to study quantum effects in high critical temperature superconductors Josephson junctions and the latter to investigate vortex quantum tunnelling in ultra-thin films characterized by vortices with extremely large Pearl lengths . 1)The YBaCuO grain boundary biepitaxial Josephson junctions have shown high values of the quality factor Q, which revealed to be crucial in order to observe quantum behavior of Josephson junctions. In addition we have proved that the overall behavior of the biepitaxial junctions is dominated by d-wave induced effects. We can therefore combine the unique features of d-wave order parameter symmetry with a remarkable tunnel-like behavior. In collaboration with Chalmers we have measured junctions properties at very low temperatures providing evidence of truly quantum behavior. The first step has been to prove macroscopic quantum tunnelling with some evidence of effects induced by the presence of a second harmonic. The second decisive step has been the demonstration of energy level quantization through resonant activation. These results are of great relevance and represent one of the most advanced and promising achievements in the field. They seem to indicate that the dissipation in a d-wave Josephson junction expected because of the presence of low energy quasi-particles (that might prevent the occurrence of macroscopic quantum phenomena, the key element for qubits) is low enough (hence allowing “sharp” energy levels, which is a major requirement for a qubit). Several efforts on the Coherentia side are devoted to improve junctions properties, which might guarantee high quality submicron devices. Some efforts include experimental and theoretical studies in the mesoscopic regime, bridging the existing experimental gap between high temperature superconducting structures and nanophysics. Magneto-conductance fluctuations are signatures of an intriguing coherent quantum diffusion, which may shed light on the actual transport regimes for these types of junctions. 2) The second project deals with dissipation in ultra-thin current-carrying superconducting bridges and with evidence for quantum tunneling of Pearl vortices. We have made zero-field current-voltage (IV) measurements of artificially layered high-Tc (CaBaCuO) thin-film bridges. The films are produced in Rome and patterned and measured in Napoli (photolithography handling of superconducting monolayers is an interesting technological achievement, which is also used for other experiments in Coherentia). Scanning SQUID microscopy of these films provides values for the Pearl lengths L that exceed the bridge width, and shows that the current distributions are uniform across the bridges. At high temperatures and high currents the voltages follow the power law V proportional to In, with n= 2 0 /(8 2 kBT)+1, and at high temperatures and low-currents the resistance is exponential in temperature, in good agreement with the predictions for thermally activated vortex motion. At low temperatures, the IV's are better fit by ln V linear in I-2. This is expected if the low temperature dissipation is dominated by quantum tunneling of individual Pearl vortices. We have achieved the extremely challenging objectives proposed at the beginning, and we are ready for next steps, for instance the preparation of the layout of the device for the measurement of Rabi oscillations, and further insights in key topics such as dissipation and coherence in HTS Josephson junctions, and in quantum transport processes. We remind that the merit in achieving several results cannot be disjointed from the prestigious and functional collaborations mentioned above. We consider very positive the fact that these arguments are pushing to establish some tradition of low noise measurements at ultra-low temperatures (limited to 300 mK at the moment) also in Napoli. It is fair to mention that all economical support and basic instrumentation come from other Institutions and Projects (European Project QUACS, PRIN, STINT Sweden-Italy collaboration, Second University of Napoli). Optics Aims of the scientific program were: a) set-up of a frequency degenerate type-II below threshold OPO based on PPKTP crystal; b) characterization of the bipartite entanglement of the generated modes by homodyne measurements. a) A type-II crystal, contrarily to a type-I device, allows the realisation of CV entanglement. A type-II crystal, working at frequency degeneration while pumped @532 nm, was not commercially available and has been designed on purpose for our experiment. It has been acquired from the RAICOL Crystals ltd (Israel). A first crystal was tested at the beginning of 2005 and, unfortunately, it has shown an absorption higher than the expected so that it was not possible to use it in the set-up. After some months, at the end of July, a new crystal with appropriate characteristics has been delivered. Since then the apparatus has been set-up and the exact frequency degeneracy temperature (54°C) has been determined and the temperature control for the crystal has been optimised so to obtain a stability of <1mK (RMS over 1h). At the moment the OPO is ready to operate. b) Below threshold a type-II OPO, seeded with a weak beam @1064 nm, is able to generate two quantum correlated modes. The modes are cross polarized and they form a bipartite entangled system so that the state of one of them can be inferred by measuring the state of the other. At the same time their superposition is a squeezed state. Field quadratures are the entangled variables. To properly characterize this CV entangled system it is necessary to perform several homodyne measurements on the field at the OPO output. In the experiment a homodyne detector already operating on the optical bench at the beginning of the project will be employed. During the first months the homodyne has been used for completing the characterization of the state at the output of type-I OPO previously operating in the laboratory. In particular two experiments have been performed: the first concerning the analysis of the state properties with the OPO operating close to the threshold, the second in which the radiation produced by the OPO has been used as a probe in absorption measurements. The first experiment has evidenced that the usual Langevin equation with constant coefficient is not sufficient for describing the OPO dynamic close to threshold. In this situation residual fluctuations, namely laser noise and cavity vibrations, play a significant role giving rise to a deviation of the output state from a Guassian one. This deviation has been first evaluated experimentally and then a theoretical model that explains it has been developed (a paper on this subject is ready to be submitted). The second experiment was triggered by the fact that a squeezed vacuum field is very sensitive to losses while it consists of a very low average number of photons. The squeezed field become an interesting candidate as a probe in all the situations where the material changes under intense photon fluxes (strongly non-linear materials or samples whose structure may be altered). Moreover, the optimal strategy for entanglement characterization via a single homodyne has been studied.While this seed project is dedicated to CV variables, the group is taking also part to a preliminary experiment on discrete variables QC, under the leadership of Prof. C. De Lisio (Coherentia Activity A2). SN1: Characterisation and application of nanogranular magnetic films produced by femtosecond laser ablation Coordinator: L. Lanotte Partecipants: G. Ausanio, V. Iannotti, S. Amoruso, R.. Bruzzese, M. Vitiello Coherentia collaboration: A1, S2 External collaboration: P. Scardi, M D’Incau Department of Materials Engineering and Industrial Technologies, University of Trento Introduction We have focused our investigations on structural and magnetic properties of nanogranular films obtained by pulsed laser deposition with ultrashort pulses characterized by duration of some fraction of a picosecond, a technique dubbed ultrashort PLD (uPLD). Scientific Activity The schematic representation of the uPLD deposition process is shown in Fig. 1. Isolated nanoparticles (for deposition time shorter than 5 minutes) or nanogranular thin films (for longer deposition times) are deposited onto a suitable substrate hold parallel to the target at about 30 mm distance, and at room temperature. Co-deposition of two or more materials, in nanoparticles form, can be performed by using an ablation target formed by different materials (see Fig. 1, e.g.). Not only the average particles radius D determined from the AFM images of a surface parallel to the substrate plane, but also the particles profiles in different cross sections orthogonal to the substrate plane has been considered Fig. 1 Schematic representation of the uPLD in the case of a co-deposition of a target made by two different materials. (through the average particles thickness d). This deeper investigation shows clearly that all the deposited particles present a typical shape, very similar to an oblate ellipsoid. Moreover, the ellipsoidal particles have the major cross section preferentially oriented in a plane parallel to the deposition substrate. In particular, the results indicate that the production of lentiform particles, with thickness below 10 nm, can be reached [1]. The deposited films present unique magnetic properties, and, in specific conditions, very high Fig. 2 AFM images of the uPLD film surface and the corresponding cross section profiles at an early formation stage: 360 s in the cases (a) and after long deposition times: 3600 s in the cases (b). remanence ratios (up to 0.7) accompanied to relatively low values of saturation and coercive fields can be obtained (fig. 3). We have interpreted these results in terms of the nanoparticles shape and orientation anisotropy, and of the occurrence of a thermally induced tensile stress anisotropy, which is a function of the nanoparticles size and is caused by the specific fs laser deposition process [2]. In the case of multicomponent nanoparticles, the high temperature/time gradients favour the formation of a disordered structure in the quasi-liquid nano-fragments ejected from the target, and the preservation of an amorphous state during 1.0 the rapid solidification on the substrate. A proof of this process is fact, unlike thin films produced by standard PLD X-ray diffraction, 0.5 M/Ms provided by the study of the Terfenol-D films obtained by uPLD. In uPLD films do not show a crystalline pattern. In specific conditions, 0.0 PLD1 PLD2 -0.5 exchange magnetic interactions can be activated among the -1.0 -0.3 nanoparticles determining new interesting magnetic performances -0.2 -0.1 derived from the mixing of the components magnetic properties. The 0.0 μ0H(T) 0.1 0.2 0.3 Fig. 3 Hystheresis curves of the nickel nanogranular films. PLD1 D=45nm d=28nm; PLD2 D=92nm d=66nm. reported results were obtained by co-deposition of Fe and Tb0.3Dy0.7Fe2 (Terfenol-D), using a multi-target as that shown in Fig. 1. It is very interesting that the macroscopic magnetization curves (are not simply the sum of two separate responses, as expected if each magnetic component behaves separately. The 2.0 curves appear indeed as the response of a single magnetic material originated from the mixture of the two components. Terfenol100-X IronX changing of the iron content, while the iron seams to facilitate μ0M(T) This is confirmed by the magnetic parameters: coercive field and the saturation magnetization practically behave as deduced from x=100 x=65 x=15 x=0 1.5 1.0 0.5 both saturation and remanence more than that expected from its percentage increase. All this leads to the conclusion that exchange interactions are effective in the nanogranular composite films [4]. Summary and perspectives 0.0 0.0 0.1 0.2 0.3 0.4 0.5 μ0H(T) Fig. 4 First magnetization curves of the nanogranular films obtained by co-deposition of Fe and Tb0.3Dy0.7Fe2 (Terfenol-D) by uPLD, for different Fe contents. This seed activity demonstrate that the ultra-short pulsed laser deposition is a practical route to produce nanogranular films of different magnetic materials (mono- and multi-component), made of nanoparticles with oblate ellipsoidal shape of controllable eccentricity, ranging from 1 to 10, major diameter of 40-100 nm and minor diameter as small as ≈10 nm. The ellipsoidal particles composing the deposited films are characterized by a common orientation of the major cross section parallel to the substrate plane. The magnetic properties of the nanogranular films can be tailored by controlling the shape and size of the nanoparticles or by mixing different magnetic materials. Generally, the uPLD nanoparticles have crystalline structure, but in the case of complex compositions they can be obtained in disordered state more easily than by using standard PLD. Taking into consideration all the features of the uPLD technique used for the preparation of nanogranular thin films, there are two very promising future trends: 1) production of films made by oblate ellipsoidal shape nanoparticles with a thickness lower than 10 nm, characterized by Giant Hall effect or Giant Magnetoresistive effects similar to those occurring in multi-layers; 2) production of thin films for application in cantilever devices, microsensors and micro-actuators. References [1] G. Ausanio, S. Amoruso, A. C. Barone, R. Bruzzese, V. Iannotti, L. Lanotte, M. Vitiello accepted for publication on Applied Surface Science [2] G. Ausanio , A.C. Barone, V.Iannotti, L. Lanotte, S. Amoruso, R. Bruzzese, M. Vitiello Applied Physics Letters 85 (18), pp. 4103-4105 (2005) [3] L. Lanotte, G. Ausanio, A.C. Barone, C. Hison, V. Iannotti, S. Amoruso, R. Bruzzese, M. Vitiello, P. Scardi, M. D’Incau invited at ANMM 2005, accepted for publication on Journal of Optoelectronics and Advanced Materials [4] G. Ausanio, A. C. Barone, V. Iannotti, P. Scardi, M. D’Incau, S. Amoruso, M. Vitiello and L. Lanotte accepted for publication on Nanotechnology SN2: Fast Superconductive Optical Detectors Coordinator: Sergio Pagano Participants: Carolina Adamo, Vincenzo Boffa, Roberto Cristiano, Mikkel Ejrnaes, Emanuela Esposito, Mikhail Lisitskiy, Luigi Maritato, Sergio Pagano, Loredana Parlato, Gianpiero Pepe, David Perez de Lara Coherentia collaborations: Strong collaboration has been established with Activity 2. External collaboration: Enrico Pessina, Flavio Fontana, Optical Innovation Division, Pirelli Labs. Milano Roberto Leoni, Maria Gabriella Castellano, Istituto di Fotonica e Nanotecnologie del CNR, Roma, Italy Antonio Vecchione, Supermat CNR, University of Salerno, Salerno, Italy Introduction This research program is oriented to the investigation of optical detectors with advanced performances. More specifically, radiation detectors based on superconductive materials are investigated. The use of superconductors allows to reach elevated sensitivity (up to single photons) and very fast response time (up to few ps). Aim of this project is to investigate alternative solutions to current superconductive detectors (Superconductive Tunnel Junctions, Transition Edge Sensors), which require an extremely low operating temperature (<0.1K) and are relatively slow (μs), and in particular to study configurations based on ultra thin superconductive striplines called Superconductive Single Photon Detectors (SSPD). Various detection mechanisms, such as superconductor to normal transition and the kinetic inductance effects have been considered for the SSPD. Moreover, several geometrical configurations have been designed and characterized in order to optimize area coverage, sensitivity and response time. The specific superconductor to be employed depends on a number of material parameters, the most important being: critical temperature, coherence length, magnetic penetration length and of course non-equilibrium relaxation times. The expected performances, in terms of response time and operating temperature, exclude “standard” superconductors such as Nb, Ta, Pb, Al in favour materials having higher Tc, such as NbN, NbTi, NbTiN, MgB2, YBCO. The extremely fast response time achievable with the SSPD would optimally match a local processing of the generated signal with ultra fast superconductive circuits. However, the state of the art technology for superconductive electronics is based on Nb. Therefore specific solutions have been developed in order to abtain a compatible fabrication technology that could allow the integration of the advanced detectors with fast superconductive processing circuits. Scientific Description 1) Development of ultra thin NbN stripline detectors The activity on NbN SSPD has been carried on mainly with the aim of developing a fabrication technology compatible with the possible integration with other Nb-based circuits (e.g. Rapid Single Flux Quantum logic). This has been achieved developing a reactive dc sputtering room temperature deposition process that could allow the fabrication of high quality ultra thin NbN films. This is particularly important as typically good NbN films are produced by reactive sputtering on sapphire substrates at high temperatures (600-800°C). We have realized various films on different substrates, finding the best properties for films on MgO substrates. The fabricated NbN films have thickness down to 10 nm, with a surface roughness of 0.1 nm, and are typically covered by a native Nb2O5 oxide layer of 3 nm, as measured with low angle reflection x-ray analysis. Another important step for the realization of SSPD is the photolithographic definition of the stripline geometry. We have developed two processes: one at CNR-ICIB for fabrication of micrometer size striplines using standard UV lithography and based on a thin NbN sensor layer, a thick Nb contact layer and a thin AlN passivation layer for the NbN, and one, in collaboration with CNR-IFN, for the fabrication of sub-micrometric striplines using electron beam lithography and based on a thin NbN sensor layer and a thick Au contact layer. In Figure 1 a SEM photograph of one of the realized meander striplines is shown. The realized sensors have been tested using the Low Temperature Laser Scanning Microscope (LTLSM) facility at CNR-ICIB showing a response time of about 0.5 ns (limited by the readout electronics) and a sensitivity of few photons (500) per strip at a wavelength of 850 nm. 2) Development of ultra thin NbTi films As alternative material NbTi offers some advantages over NbN: a smaller coherence length (3 nm) and lower Tc. This would allow the realization of thinner detectors (smaller volume) thus boosting up the minimum energy sensitivity. However the technological problem of realization of high quality ultra thin NbTi films has to be solved. We have addressed this issue with the Molecular Beam Epitaxy facility available at the University of Salerno, using the atomic layer control achievable with this technique to produce highly controlled and high quality ultraFig. 1 Meander type NbN SSPD. Each stripline is thin films of NbTi. A number of NbxTiy thin films have been 100 nm wide with a filling factor 1:3 realized and their transport properties characterized. 3) Development of ultra fast pump probe measurements of detectors Beside the demonstration of the feasibility of the fabrication processes for the SSPD, based on either NbN or NbTi, it is very important to exploit the intrinsic physical mechanisms that govern the response to optical radiation in these materials. In particular it is important to determine the various relaxation times involved in the complex nonequilibrium processes involved in the photon absorption and in the subsequent energy relaxation through mediated by non-equilibrium phonons and quasiparticles. Given the extremely short times involved (ps) there are no electronic measurement devices available. A very useful system to investigate this time domain is the Pump-Probe time resolved spectroscopy facility available at the Coherentia labs. This facility has been upgraded to perform time resolved low temperature reflectivity measurements on superconductive structures with a time resolution better than 1 ps. Summary of obtained results and discussion on perspectives The main results of first year of activity are: the development of a room temperature deposition technology for ultra thin NbN films, the realization and dc and optical characterization of micrometer and submicrometer scale NbN detectors, the setup and characterization of a pump probe system for cryogenic reflectivity measurements, the development of MBE deposition technique and preliminary characterization of ultra thin films of NbTi. The project activity will continue with the realization of detectors based on NbTi and their characterization at the LTLSM. The NbN detectors will be further developed in the direction of integration with Nb based superconductive electronics. In case of availability, through external collaborators, of ultra thin films made of higher Tc superconductors, such as MgB2 and YBCO, stripline detectors will be fabricated and characterized. All the realized detector structures will also be investigated with the cryogenic pump probe system. SN3: Field Effect in ultra thin High Critical Temperature Superconducting Films Coordinator: Marco Salluzzo Participants: Antonio Cassinese, M. Barra, G. M. de Luca, A. Prigiobbo, Francesco Tafuri, Daniela Stornaiuolo Giuseppe Balestrino, Carmela Aruta, Pier Gianni Medaglia Coherentia collaborations: Strong collaborations have been established with Activity 1 and 3. External collaboration: Giacomo Ghiringhelli, CNR-INFM and Department of Physics, Politecnico di Milano Jean Marc Triscone, Université de Genève Département de Physique de la Matière Condensée Introduction In modern MOSFET devices the electric field effect is used to modulate the conductivity of a thin semiconducting channel. Substantial conductivity modulation, using practically accessible fields, can be obtained in materials that have carrier densities lower than 1014 cm-2 . While ordinary metals are not feasible for field effect devices, substantial carrier modulation can be induced in metal transition oxides materials, including the High Critical temperature Superconductors (HTS). Since these strongly correlated materials are extremely sensitive to the number of carriers, phase transitions can be in principle controlled by electrical field effect. The use of the electric field effect to modify the density of carriers in a thin layer, equal to the Thomas-Fermi screening length λTF, of an HTS film is extremely attractive for studying the electronic properties of HTS in function of doping. In this project we will investigate field effect doping in two classes of HTS materials that can be good candidates for such kind of applications: Nd1.2Ba1.8Cu3Oz (NdBCO) thin films and structures (M/N/M ). The main goal is to demonstrate that it is possible to modify the critical temperature of HTS films by field effect. As possible objective we will try to induce insulating-superconducting or metal-superconducting transition in these materials. As final goal we will try to induce electric field modulation of the Josephson current in bi-crystal Josephson Junctions. Scientific Description and summary of obtained results Field effect devices are composed of a stacked multilayer structure as shown in Fig.1. In order to reduce as much as possible complications in the fabrication process and in order to achieve clean interfaces, in the first year of the project, in the case of the (Ba0.9Nd0.1CuO2)M/(CaCuO2)N/(Ba0.9Nd0.1CuO2)M, we have fabricated FED using the SrTiO3 (100) single crystal substrate as dielectric insulator. On the contrary using a fully in situ fabrication technique, NdBCO FED have been realized by depositing a thin Al2O3 layer on thin NdBCO films, and Fig. 1: sketch of the FED device. sequentially gold gates deposited both on the Al2O3 dielectric, both on the back of the SrTiO3 single crystal. Using this configuration we were able to use both dielectrics to induce the field effect and in principle we were able to investigate different interfaces. In the fabrication process, a photolithographic step has been implemented for both structures. Geometries suitable for the field effect have been tested, and a special cryogenic ion beam etching technique has been employed in order to assure the minimum damage to the thin structures. M/N/M structures have been deposited using a pulsed laser deposition technique. In order to reduce the number of carriers, a series of sample deposited at low oxygen partial pressure have been grown. NdBCO FED have been realized using high oxygen pressure diode sputtering. During the first year of the project we have deposited 3 to 6 unit cells structures. Depending on the thickness insulating (3 u.c.) and superconducting (6 u.c.) films have been obtained. Experimental results In Fig.2 the comparison between the resistance modulation of 2 nm and 4 nm u.c. BaCuO2 (insulating) films and of 4 nm NdBCO in function of the gate voltage is shown. Form this results it is evident that screening in the BaCuO2 layer is quite strong, since the resistivity modulation in a 4 nm structure is very small, while in NdBCO 4 nm film strong modulation are achieved. This result is reflected in the negligible Tc shift observed in 5/2/5 and 5/3/5 structure. Indeed due to screening by the (BaCuO2)5 layer, a small charge induction on the CaCuO2 superconducting layer is expected. However this result is still controversial. One of the main complication in the interpretation of the field effect in the 5/2/5 structure is associated to the difficulty to discriminate effect on the CR(charge reservoir) BaCuO2 block from effects on the SC (Superconducting) CaCuO2 block. These effect can be also opposite in principle and may explain a reduced electric field effect. On the contrary Fig.2: resistance modulation by field effect the results on NdBCO are encouraging as far as insulating thin films are concerned, while again negligible shift of Tc are seen in SC samples. In order to better interpret the experimental results, a direct correlation between the gate voltage and the charge induced at the interface is needed. Capacitive vs voltage measurements have been implemented and preliminary results suggest that traps at the interface, in the case of M/N/M structure, reduce considerably the low temperature capacitance. This preliminary result gives another explanation of the reduced electric field effect observed in the M/N/M structures. Discussion and perspectives The experimental results has given indication about the possibility to modulate the transport properties of NdBCO and M/N/M structures. In the latter case the results indicates that a reduction of the thickness of the CR layer is needed in order to directly influence the CaCuO2 layer. Moreover an interpretation of the results requires a study of electric field effect on each layer separately. Finally an improvement of the film/substrate interface is necessary in order to reduce charge trapping. This can be achieved by controlling the surface properties of the SrTiO3 single crystal. Suitable chemical etching procedure and annealing in oxygen atmosphere will be used in order to assure a perfect STO/film interface. Surface analysis technique, like STM/AFM, XPS and LEED will be used to check the properties of the STO substrate before the deposition. EX1: Lasing In Tunable Photonic Nano-Structures Based On Active Soft Materials Coordinator: Giancarlo Abbate Participants: Vladimir Tkachenko, Antigone Marino, Francesco Vita External collaboration: Diederik Wiersma, LENS – Florence – Complex Systems group and CNR-INFM (IMM-Catania) Giuseppe Strangi, CNR-INFM (Licryl) and Dipartimento di Fisica - Università della Calabria, Physics of condensed matter group Introduction Photonic lasing materials range from fully ordered systems like photonic crystals to disordered materials that scatter light diffusively. Novel laser sources based on soft-matter can potentially fulfil all of the scientific and technological features required to such sources. Soft materials, namely polymers and liquid crystals (LC) are extremely promising for the realization of photonic structures to be employed both as single devices or as part of innovative integrated systems. In this seed we are investigating two different nano-structures to realize compact, tuneable mirror-less laser sources operating in the visible: 1. disordered systems of liquid crystal droplets inside a polymer matrix, where scattering is responsible for the lasing action, and 2. ordered systems like cholesterics liquid crystals that can be considered as a photonic band-gap material. The most interesting aspect of these lasing systems is that optical and geometrical parameters can be modified by applying weak external fields, hence resulting in a direct control of lasing features (wavelength tunability, bandwidth, emission direction). Next step will be investigating quasi-periodic lasing structures. Scientific Description The propagation of optical waves in complex dielectric systems is an intriguing research subject. Complex dielectrics are dielectric structures in which the refractive index varies over length scales comparable to the wavelength of light. In disordered materials light waves undergo a multiple scattering process and are subject to unexpected interference effects like weak and strong localization of light waves and correlations in speckle fluctuations. On the other extreme, periodic dielectric structures behave as a crystal for light waves. Optical amplification in complex dielectric structures can be Figure 1 used to realize fascinating new light sources. In a one-dimensional (1D) periodic structure, laser action is expected at the photonic band edge, where the photon group velocity approaches zero. Cholesteric liquid crystals are chiral nematics, where the handedness of the constituent molecules causes the orientation of the local nematic director to vary in space. The result is a self-organized helical structure that is. a 1D periodic structure, hence a 1D photonic bandgap is formed. When a fluorescent dye is dissolved in the cholesteric host (see Figure 1a), laser action is observed at the edge of the band above a threshold (see Figure 1b). In particular we studied the threshold dependence from the sample thickness and from the dye concentration [1]. In random systems on the other hand, multiple scattering is used as a trapping mechanism to obtain laser action. Random laser materials have both a high degree of disorder and exhibit optical gain, leading to a random walk with optical gain. Such diffusive random laser materials have several properties that resemble a regular laser: above threshold the spectrum narrows down and the emission can show a spiking behavior. Diffusive random lasing has been observed in a variety of materials including liquid crystals. Summary of obtained results and discussion on perspectives The results of the Naples group concern the study of the threshold dependence on dye concentration and cell thickness [1] and the optical and morphological characterization of the composite structures on which lasing devices will be based. Two of these have been Figure 2 deeply studied, namely Holographic Polymer Dispersed Liquid Crystals (H-PDLC) and new materials known as Policryps or Poliphem that are layered structures made by an alternate sequence of polymer slices and liquid crystal films [2]. Important results towards the understanding of light propagation in quasi-crystals, in view of the realization of such patterned lasing systems have been obtained by the associated LENS group in Florence [3]. An array of microlaser in cholesteric liquid crystal micro-channels in a Policryps structure has been firstly demonstrated and realized by the associated group at Licryl lab in Cosenza [4]. A wide-band tuning capability has been also shown. The collaborations and activities related to the present seed will be strengthened in the next year, when hopefully this project will be also financially supported. Instrumentation development With the aim of performing a linear optical characterization of all the employed materials and of realized samples in the whole spectral range from near UV to near IR (270-1700 nm) we have designed and realized a custom sample holder for a VASE Spectroscopic Ellipsometer in order to execute measurements in guided configurations, also in association with the half-leaky guided mode technique. A further improvement in order to obtain temperature control in the range 20°-220° with a resolution of 0.01° (Celsius degrees) has been designed and its implementation is ongoing. References [1] W. Cao, A. Marino, G. Abbate, P. Palffy-Muhoray, B. Taheri, Mol. Cryst and Liq. Cryst., 429 101-110 (2005) [2] F. Vita, A. Marino, V. Tkachenko, D. E. Lucchetta, L.i Criante, F. Simoni, and G. Abbate “Near infrared characterization and modeling of nanosized holographic-polymer dispersed liquid crystal”, Phys. Rev. E, 72, 011702 (2005) [3] Ghulinyan, M.; Oton, C. J.; Negro, L. D.; Pavesi, L.; Sapienza, R.; Colocci, M.; Wiersma, D. S. Light pulse propagation in Fibonacci quasicrystals, Phys. Rev. B 71: 94204 (2005) [4] G. Strangi, V. Barna, R. Caputo, A. de Luca, C. Versace, N. Scaramuzza, C. Umeton, R. Bartolino, G. Price; Physical Review Letters 94 063903 (2005). EX2: Molecular dynamic modeling of complex polymeric systems Coordinator : Antonio Coniglio, Main proponent group: Mario Nicodemi, Annalisa Fierro, Lucilla de Arcangelis, Emanuela Delgado, Tiziana Abete, Antonio de Candia (Institution: INFM – Coherentia) Other partecipant groups: 1) Antonio Sasso, Giuseppe Pesce, Sabato Fusco (Institution: INFM – Coherentia) 2) Paolo Antonio Netti, Assunta Borzacchiello, Enrica De Rosa, Sabato Fusco (Institution: Interdisciplinary Research Center in Biomaterials (CRIB), Piazzale Tecchio 80, Napoli Introduction Complex systems, such as polymers or colloidal gel, possess structures at a mesoscopic level that determine their macroscopic physical properties. The aim of the project is to model the structure and dynamic of polymeric systems at mesoscopic scale to understand the role of those in determining and controlling the macroscopic properties. In details, we model the sol-gel transition of polymeric systems and compare the model prediction to experimental results at different measurements scale, (from nano to micro-metric), correlating the structure and dynamics of the systems to the macroscopic physical properties. We study polymeric solutions of associative polymers and saccharidic polymers that undergo to sol- gel transition by changing systems parameters , like temperature or concentration. We have studied these systems both theoretically, by molecular dynamics or Monte Carlo simulations, and experimentally by optical techniques. Scientific Description 1) Measure of complex shear modulus with optical tweezers. Most polymer solutions exhibit both viscous and elastic properties. The physical quantity commonly employed to quantify the viscoelasticity of such solutions is the complex shear modulus G*(f). The most frequently used methods to measure the shear modulus involve placing the samples with volumes of order milliliters in conventional rheometers. The shear modulus is extracted from the relation between applied shear force and measured strain or vice versa. Frequency response of such instruments is limited by mechanical inertia and can reach only few tens of Hz. Recently, several techniques, called microrheology have been developed to probe, on microscopic scales, the material viscoelastic properties of systems. Motivations for miniaturization are: (i) Only small volumes of material, typically microliters, are available. (ii) Inhomogeneities in the elastic properties of the polymer network on micrometer scales can be explored. (iii)Microrheology readily allows for measuring viscoelasticity at higher frequencies, above 1 kHz or even up to MHz, because inertia of both the probe and embedding medium can be neglected at such small length scales. We have developed a passive microrheological technique based on optical tweezers. An optically trapped micrometric bead (1 micrometer diameter) is used as a probe to explore the viscoelastic response of the fluid in which it is embedded. The complex single-particle response function (f)= ’(f)+i ’’(f) relates the Fourier transform x(f) of the bead displacement x(t) to the Fourier transform F(f) of the force F(t) acting on the bead: x(f)= a(f)F(f). The fluctuation-dissipation theorem provides the link between the single-sided Power Spectral Density (PSD) S(f) and the imaginary part of the response function by ’(f) =( /2kbT) f S(f). A Kramers-Kronig relation has then been used to calculate the real part of the response function, provided that ’(f) is known over a large enough frequency range. Finally, from the generalized Stokes-Einstein relation the viscoelastic moduli G’ have been calculated. We have first calibrated our apparatus by testing it with a known fluid (water). In this way we have characterized the trap stiffness and the calibration factor of the position sensor (a quadrant photodiode in our case) used to monitor the x, y and z coordinates of the trapped bead. We have analyzed several complex fluids: hyaluronic acid solutions and CMC solutions at several concentrations (0.01, 0.05 and 0.1 mg/ml). The behaviours of G’ and G’’ and the viscosity have been obtained in a frequency range up to 10 kHz. These results have been compared with those obtained by Netti’s group finding a good agreement at low frequencies, where these data are available with conventional rheometers. 2) Modeling of polymeric systems by Monte Carlo and molecular dynamics. We have used Monte Carlo and molecular dynamics techniques to study the relation between the mesoscopic structure and macroscopic properties of polymeric systems under investigations. The first model studied consists in monomers occupying elementary cells of a cubic lattice, and therefore eight vertices of the lattice. Permanent bonds are randomly quenched between monomers. The dynamic evolution of the system is based on the bond fluctuation dynamics, with hard core interactions between monomers (i.e. two nearest neighbours monomers cannot have common sites). Increasing the density of the system, the model undergoes a percolation transition, so that an infinite spanning cluster of connected monomers appears. At this critical point, the viscosity of the system, which is proportional to the autocorrelation time of density fluctuations, diverges, while a finite elastic modulus appears. If bonds between monomers have a finite lifetime, then a drastic change in the dynamical behaviour is produced. The percolation transition does not coincide with the divergence of relaxation times, but with a crossover to a different regime, where the relaxation time is of the same order of the lifetime of the bonds. The results suggest that this could be a unifying model to study the phenomenology of gelling systems, where bonds between monomers and hard core interactions play the role of the attractive and repulsive part of the potential respectively. To study the dynamics of bond formation in polymeric systems, we have modified the model in the following manner: monomers are linked by permanent bonds to form chains of specified lenght. Moreover, specific sites of the chain can react with a different kind of molecules diffusing in the system, that act as cross-linkers. We study therefore the dynamics of bond formation as a function of the number of active sites on the chain, and the density of cross-linkers in the system. Moreover, we can study how the structure of the formed network depends on these parameters, and how this structure influences the rheology of the system. We plan to study the diffusivity of probes inside the polymeric network, as a function of the relative size of the probe with respect to the mesh size of the network. These results will be then compared to the ones obtained experimentally, as described in the previous section. Many results of the model have been confirmed using molecular dynamic simulations. We simulate particles interacting with a short range hard core repulsion, and a finitely extensible non-harmonic spring, that represents the chemical bond between monomers. Molecular dynamics simulation are indeed more realistic, and allow to study the system also at constant pressure, which is nearer to experimental conditions. Adding a long range repulsion between monomers, the model is able to account for many features of different experimental systems, like colloidal systems or physical gels like gelatin. The structures observed are surprisingly similar to the ones observed experimentally. At low density particles form nearly spherical clusters, while at higher densities they form elongated tube-like structures, that due to defects in the structure branch at a characteristic scale to form a disordered random network. EX3: Size-Dependent Electron Confinement in Polymer-Embedded Metal and Semiconducting Nanoparticles Coordinator: Pasqualino MADDALENA Participants: Corrado de Lisio Giovanni Piero Pepe N. Marrocco Stefano Lettieri Massimo Valentino Coherentia collaborations: Strong collaborations have been established with Activity 2. External collaborations: Gianfranco Carotenuto, Istituto per i Materiali Compositi e Biomedici (IMCB-CNR) Napoli Girolamo Di Francia, CRIF-ENEA, Portici (NA) Antonio Parretta, ENEA, Bologna L. De Stefano, Istituto Microelettronica e Microsistemi (IMM-CNR), Napoli Introduction Nanostructured materials are becoming one of the most important class of advanced functional materials and the technology of their production and use is rapidly growing into a powerful industry. These fascinating materials whose dimension is of just few nanometers include microclusters, nanotubes, nanoparticles, etc. It is clear that the number and significance of new nanomaterials and application will grow explosively in the future. The research interest in this field is principally devoted to the development of novel methods for the preparation and characterization of polymeric nanocomposites materials in which the surface properties of metal and semiconductor microclusters and their quantum-size effects are used to provide polymeric matrix of advanced functional characteristics. Thanks to the nanometric dimensions of the dispersed particles these new materials are characterized by several peculiar properties: -They have a high surface-to-volume ratio;-The small material crystallites (<10000 atoms) exhibit structure and physical properties distinct from the corresponding bulk system;-Nanostructure electronic properties are size dependent and quantum effects are relevant if the dimensions are smaller;-The electronic properties of the small crystallites can be modified by surface chemical interaction;-Optical and transport properties will therefore be sensitive to the interactions between the nanostructure surface and the gas environment. It should be stressed, however, that some of the mechanisms underlying the physical properties are not completely clear and assessed, so that basic research work is still required even if some possible applications of these materials in gas and environmental sensing are under way. Scientific Description and summary of obtained results In this year we performed stationary photoluminescence (CW-PL) measurements on metal oxide nanostructured samples such as nanobelts and nanowires. Thermal and optical properties of silicon (crystalline, amorphous and porous) were also investigated in view of 3.5 3.0 300 K Intensity (a.u.) 2.5 its applications in photovoltaic and gas sensing applications. The samples were found to have strong CW-PL even at ambient 2.0 1.5 temperature (Fig. 1). 1.0 Measurements have been performed, at varying temperatures and 0.5 environmental 0.0 -0.5 400 500 600 700 conditions. Photoluminescence spectra show a quenching when the sample is exposed to oxidizing gas such as NO2 800 λ (nm) Fig. 1 Room temperature PL spectrum of ZnO nanobelts (Fig. 2). This can be expected when nanostructured materials are considered, since they are characterized by a large specific surface. The effect promotes the investigated nanostructures among the most interesting gas sensing base materials. A Time Resolved PhotoLuminescence (TR-PL) apparatus has been set up in order to investigate the radiative and nonradiative contribution to the recombination process of the charge carriers. Moreover, CW-PL measurements have been performed in natural 5x10 6 4x10 6 3x10 6 2x10 6 1x10 6 PL intensity (a.u.) silica nanostructures, such as marine diatoms, showing their ability to sense the surrounding gas presence: a PL quenching has been observed in presence of electronegative molecule vapours (NO2, Acetone, Ethanol) (Fig. 3), while an enhancement is observed in presence of nucleophilic vapours (Xylene, Pyridine) (Fig. 4). The 280 533.4 1,5 Acetone Ethanol Air 400 538.1 440 480 557.1 Xylene Pyridine Air 15 533.4 1,2 P.L. (a.u.) P.L. (a.u.) 20 NO2 1,8 360 Fig. 2 Quenching of the PL intensity of ZnO nanobelts in NO2 Physics Research. 538.1 320 Temperature (K) December 1, 2005 issue of the Virtual Journal of Biological 2,1 air 0 related paper, which appeared in APL, was also selected for the 2,4 NO2 (5 p.p.m.) 542.9 0,9 533.4 10 x5 0,6 5 0,3 0,0 420 450 480 510 540 570 600 630 660 690 Wavelength (nm) Fig. 3 Room temperature PL quenching of marine diatoms 0 420 450 480 510 540 570 600 630 660 690 Wavelength (nm) Fig. 4 Room temperature PL enhancement of marine diatoms EX4: Matrix Assisted Pulsed Laser Evaporation of organic films for biomedical applications Coordinator: Luciano Vicari Participants: F. Bloisi, A. Cassinese, F. Chiarella, R. Papa, M. Zoncheddu External collaboration: L. E. Depero, E. Bontempi, R. Pedrazzani, P. Bergese, I. Alessandri, P. Colombi (INSTM, Univ. Brescia, Brescia) Introduction Polymers and most biomaterials (i.e. both natural and synthetic materials that interface with living tissues or biological fluids) are characterized by complex molecules having high molecular weight. They have a wide range of applications in biomedical (antifouling treatment, surface treatment of nano-devices and drug delivery systems, cell/genomic signalling micro-arrays, etc.) and in other (e.g. microelectronics, bioengineering, etc.) fields. Recently growing interest is occurring around a novel laser deposition technique (MAPLE: Matrix Pulsed Laser Evaporation) especially well suited for organic materials. Since the participant groups have large experience on optics, film deposition, biomaterials and thin film analysis, we have decided to activate (without COHERENTIA funding contribution) a thin film deposition system explicitly designed for MAPLE technique in order to use it for deposition of antifouling and other organic films of biomedical interest with contribution of University of Brescia group for film characterization. Instrumentation development The main efforts in this first stage has been the development of a thin film deposition system explicitly designed for thin film deposition using MAPLE technique. The target is a frozen matrix[1] of a dilute solution of the substance (polymeric or organic compound) in a relatively volatile solvent. A laser beam (usually UV) is focused on the target. Differently from traditional PLD (Pulsed Laser Deposition) technique, the majority of the laser energy is absorbed by the solvent (and not by the solute) molecules and so the photochemical damage of organic/polymeric compound is reduced. Volatile solvent is pumped away while organic/polymeric compound is deposited on the substrate surface. During film deposition, plume can be analysed by optical (i.e. fast CCD, with system upgrade) or spectroscopic techniques (LIBS: Laser Induced Breakdown Spectroscopy). Specific characteristics of our MAPLE system (see Table below) are “in situ” target freezing (controlled atmosphere or vacuum), use of different (currently 355 nm, and 266 nm with system upgrade) laser wavelength, (x,y) target movement (and consequent full target surface scanning). Scientific Description In biomedical applications several inorganic (e.g. metallic or ceramics) materials are used for use in the human body to measure restore and improve physiologic functions (heart valves, synthetic blood-vessels, devices for controlled drug delivery, etc.). Two relevant problems are biocompatibility and capability to be integrated into the biological environment. Biofouling (i.e. the accumulation of proteins, cells and other biological materials on a surface) is one of the causes of malfunctioning or failure of biomedical devices. Polyethylene glycol (PEG), i.e. polyethylene oxide (PEO, –CH2CH2O–) with hydroxyl groups at each end, with degree of polymerisation usually ranging from 600 to 9000, is widely used for its high biocompatibility. Recently it has been shown that PEG thin films can be deposited with MAPLE technique[2]. On the other end several techniques have been tested in order to improve film adhesion to substrate. One of the most promising and interesting is the use of a special proteins (e.g. DOPA or MEFP1) as functionalised end groups[3]. We plan to test improvement of film adhesion by testing different methods based on multiple MAPLE films deposition or polymeric growth on MAPLE deposited film substrate. Summary of obtained results and discussion on perspectives First important result obtained is the realization (without COHERENTIA financial support) of a system explicitly designed for film deposition using MAPLE technique, therefore having some advantages (e.g. controlled target freezing, full target surface scanning) with respect to systems adapted to MAPLE deposition. The MAPLE system has been tested and is now operating. It will be used, in next future, to deposit thin film for biofouling inhibition both in single and multi-layers (e.g. PEG, MAPD/PEG, etc.) and test the effectiveness of depositions. A subsequent step, subordinated to funding, will be MAPLE system improvement (e.g. FHG to operate at 266 nm, substrate masks, etc.). References [1] Cherisey D. B. et al. Chem. Rev. 103 (2003) 553-576 [2] Toftmann B. et al. Appl. Surf. Sci. 247 (2005) 211-216 [3] Dalsin J. L. et al. Materials today 9 (2005) 38-46 ; Dalsin J. L. et al. J. Am. Chem. Soc. 125 (2003) 4253-4258 A 1 International journals - Published and Submitted papers 1 2 3 4 5 6 7 8 S. G. Chiuzbian, G. Ghiringhelli, C. Dallera, M. Grioni, P. Amann, X. Wang, L. Braicovich, and L. Patthey, “Localized Electronic Excitations in NiO Studied with Resonant Inelastic X-Ray Scattering at the Ni M Threshold: Evidence of Spin Flip,” Phys. Rev. Lett. 95, 197402 (2005). L. Braicovich, G. Ghiringhelli, A. Tagliaferri, G. van der Laan, E. Annese, and N.B. Brookes, “Femtosecond dynamics in ferromagnetic metals investigated with soft x-ray resonant emission” Phys. Rev. Lett. 95 , 267402 (2005). J. Minár, H. Ebert, C. De Nadai, N.B. 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Nazionale per la Fisica della Materia Dipt. di Ingegneria Meccanica Univ. di Roma Tor Vergata, Italy), “Suppression of the metal-insulator transition temperature in thin La/sub 0.7/Sr/sub 0.3/MnO/sub 3/ films”. Source: Journal of Applied Physics, v 96, n 11, 1 Dec. 2004, p 6387-92. 15 Fan Yang, R. Mafhoum, R. Karim, A. Tebano, G. Balestrino, V. G. Harris, C. Vittoria “Manganese ferrite grown at the atomic scale, Xu Zuo” (Dept. of Electr. & Comput. Eng., Northeastern Univ., Boston, MA, USA) Source: IEEE Transactions on Magnetics, v 40, n 4, pt.2, July 2004, p 2811-13. 16 P. Dore (Coherentia CNR-INFM, Dipartimento di Fisica, Universita La Sapienza), Postorino, A. Sacchetti, M. Baldini, R. Giambelluca, M. Angeloni, G. Balestrino, “Raman measurements on thin films of the La0.7Sr 0.3MnO3 manganite: A probe of substrate-induced effects”. Source: European Physical Journal B, v 48, n 2, November, 2005, p 255-258. 17 C. Aruta (Coherentia CNR-INFM, Dipartimento di Ingegneria Meccanica, Università di Roma TorVergata), M. Angeloni, G. Balestrino, P. G. Medaglia, P. Orgiani, A. Tebano, J. Zegenhagen. “Synchrotron X-ray diffraction study of SrRuO3/SrTiO 3/SrRuO3 nano-sized heterostructures grown by laser MBE”. Source: European Physical Journal B, v 46, n 2, July, 2005, p 251-255. 18 V.Ferrando, P.Orgiani, A.Pogrebnyakov, J.Chen, Qi Li, J.M.Redwing, X.X.Xi, J.Giencke, C.B.Eom , Q.R.Feng, J.Betts, C.Mielke, “High upper critical field and irreversibility field in MgB2 coated-conductor fibers” Applied Physics Letter 87, 252509 (2005). 19 M. Iavarone, G. Karapetrov, A. Menzel, V. Komanicky, H. You, W. K. Kwok, P. Orgiani, V. Ferrando, “Characterization of off-axis MgB2 epitaxial thin films for planar junctions”,X.X.Xi. Applied Physics Letter 87, 242506 (2005). 20 P.Orgiani, Y.Cui, A.V.Pogrebnyakov, J.M.Redwing, V.Vaithyanathan, D.G.Schlom, “Investigations of MgB2/MgO and MgB2/AlN heterostructures for Josephson Devices” X.X.Xi, IEEE Transactions on Applied Superconductivity 15, 228 (2005). 21 Y.Cui, J.E.Jones, A.Beckley, R.Donovan, D.Lishego, E.Maertz, A.V.Pogrebnyakov, P.Orgiani, J.M.Redwing, “Degradation of MgB2 thin films in water” X.X.Xi, IEEE Transactions on Applied Superconductivity 15, 224 (2005). International journals – Yet unpublished papers 1 P.Orgiani, A. Yu. Petrov, C. Adamo, C. Aruta, C. Barone, G. M. De Luca, A. Galdi, M. Polichetti, D. Zola, L. Maritato, “In-plane anisotropy of transport properties in La0.7Sr0.3MnO3 ultra-thin films”. Appl. Phys. Lett., submitted 2 G. Ghiringhelli, M. Matsubara, C. Dallera, F. Fracassi, A. Tagliaferri, N.B. Brookes, A. Kotani, and L. Braicovich, “Resonant inelastic x-ray scattering of MnO: L edge measurements and assessment of their 2,3 interpretation” Phys. Rev. B in press (2005). 3 U. Scotti di Uccio, P. Perna, R. Di Capua, A. Oropallo, M. Salluzzo, and F. Miletto, “Strain in epitaxial La0.7Sr0.3MnO3 films grown on (001) and (110) SrTiO3” Phys. Rev. B, submitted 4 L. Maritato, C. Adamo, C. Barone, G.M. De Luca, A. Galdi, P. Orgiani, A.Yu. Petrov, “Low-Temperature Resistivity of La0.7Sr0.3MnO3 Ultra-thin Films: role of the Quantum Interference Effects”, Phys. Rev. B, submitted 5 M. Angeloni, C. Aruta, G. Balestrino, N.G. Boggio, B. Davidson, P.G. Medaglia, A. Tebano, M. Baldini, D. Di Castro, P. Postorino, P. Dore, A. Sidorenko, G. Allodi, R. De Renzi, “Preparation and characterization of LaMnO3 thin film grown by pulsed Laser deposition”, J. Appl. Phys., submitted. 6 P. Dore, P. Postorino, A. Sacchetti, M. Baldini, R. Gianbelluca, M. Angeloni, G. Balestrino, “Raman measurements on thin films of the La0.7Sr0..3MnO3 manganite: a direct probe of substrate induced effects”, Eur. Phys. J. B, in press. 7 S. Amoruso, A. Sambri, M. Vitiello, and X. Wang, “Propagation of LaMnO3 laser ablation plume in oxygen gas”, Appl. Surf. Sci. in press. 8 U. Scotti di Uccio, B. Davidson, R. Di Capua, F. Miletto Granozio, G. Pepe, P. Perna, A. Ruotolo, M. Salluzzo, J. All. “Effect of strain in LSMO epitaxial films with different crystallographic orientation”, Comp., submitted. 9 A.A. Sidorenko, G. Allodi, R. De Renzi, G. Balestrino and M. Angeloni “55Mn NMR and magnetisation studies of La0.67Sr0.33MnO3 thin films”. In press on Phys. Rev. B 10 B. Freelon, A. Augustsson, J.-H. Guo, P. G. Medaglia, A. Tebano, and G. Balestrino “Electron Correlation and Charge Transfer in Ba0 :9 Nd0 :1 CuO2 2 =CaCuO2 2 Superconducting Superlattices”. In press on Phys. Rev. Lett. Volumes 1 2 J. Schou, B. Toftmann, and S. Amoruso, “Pulsed laser deposition: from basic processes to film deposition”, in Laser Physics and Applications – 13th International School on Quantum Electronics, Eds. P.A. Atanasov, S.V. Gateva, L.A. Avramov, and. A.A. Serafetinides, Proceedings of SPIE vol. 5830, 1-10. J. Schou, S. Amoruso and J. G. Lunney, PLUME DYNAMICS, in Laser Ablation and Its Applications, Edited by C.R. Phypps (Springer), in press. A 2 International journals - Published and Submitted papers 1 2 G. Carapella, F. Russo, R. Latempa, and G. Costabile, “Preparation and read-out of a Josephson vortex in a double-well potentiall”, Phys. Rev. B 70, 092502 (2004). G. Carapella, R. Latempa, F. Russo, and G. Costabile, EUCAS 2003 Proc., IOP series (2005). 3 4 5 6 7 8 9 R. Latempa, G. Carapella, G. Costabile, G. P. Pepe, L. Parlato, and A. Ruotolo, EUCAS 2003 Proc., IOP series (2005). F. Tafuri and J.R. Kirtley “High Tc Superconductor Weak Links”, Rep. Prog. Phys. 68, 2573 (2005). T. Bauch, F. Lombardi, F. Tafuri, A. 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Tagliacozzo, “Manipulation of the spin electron in a quantum dot using a magnetic field and voltage gates”, Materials Science-Poland, 22, 81- 495(2004). 16 P. Lucignano, G.Rotoli, E. Santamato, A.Tagliacozzo “Coherent response of a low T_c Josephson Junction to an ultrafast laser pulse”. Phys.Rev.B 70,024520 (2004). 17 G. Campagnano, D.Giuliano, A.Naddeo, A.Tagliacozzo, “Josephson current in a quantum dot in the Kondo regime connected to two superconductors”, Physica C 406,1-8 (2004). 18 D. Giuliano, A. Tagliacozzo “Hamiltonian theory of the strongly-coupled limit of the Kondo problem in the overscreened case”, J. Phys. C:Condens. Matt.16, 6075-6098 (2004). 19 P. Lucignano, B. Jouault, A. Tagliacozzo, “Spin exciton in a quantum dot with spin-orbit coupling at high magnetic fields”, Phys.Rev B69,045314 (2004). 20 M. P. Lisitskiy, C. Nappi, M. Ejrnaes, R. Cristiano, M. Huber, K. Rottler, J. Jochum, F. von Feilitzsch, and A. Barone “X-ray energy spectrum measurements by an annular superconducting tunnel junction with trapped magnetic flux quanta”, Appl. Phys. Lett. 84, Issue 26, pp. 5464-546 (2004). 21 C. Nappi, M. P. Lisitskiy, G. Rotoli, R. Cristiano, and A. Barone, “New Fluxon Resonant Mechanism in Annular Josephson Tunnel Structures”, Phys. Rev. Lett. 93, 187001 (2004). 22 A. Barone, “The strong impact of the weak superconductivity”, J. of Supercond. 17, 585 (2004). 23 A. Barone, A. G. Kofman, G.Kurizki “Zeno and antiZeno effects in driven Josephson junctions: control of macroscopic quantum tunnel” in “Decoerence, entaglement and information protection in complex quantum systems” Kluver Amsterdam 2004. 24 G. P. Pepe, A. Ruotolo, L. Parlato, G. Peluso, G. Ausanio, G. Carapella and R. Latempa, “Nb/NiCu bilayers in single and stacked superconductive tunnel junctions: preliminary results”, J. Magn. and Magn. Mat. 272 .276 (2004). 25 L. Parlato, G. P. Pepe, R. Latempa, C. De Lisio, C. Altucci, P. D’Acunto, G. Peluso, A. Barone, T. Taneda and R. Sobolewski, “Time-resolved photoresponse of nanometer-thickness Nb/NiCu bilayers” Appl. Surf. Sci. 248, 177 (2005). 26 G. P. Pepe, L. Parlato, R. Latempa, P. D’Acunto, N. Marrocco, C. De Lisio, C Altucci, G. Peluso, A. Barone, T. Taneda, and Roman Sobolewski, “Fabrication and optical properties of ultrathin ferromagnet/superconductor metallic bilayers”, IEEE Transaction on Superconductivity 15, No. 2, 2942-2945, 2005. 27 R. Latempa, L. Parlato, G. Peluso, G. P. Pepe, A. Ruotolo, A. Barone and A. A. Golubov, “Proximity effect in NiCu-based Josephson tunnel junctions” IEEE Transaction on Superconductivity 15, No. 2, 133-136 2005. 28 L. Parlato, G. P. Pepe, R. Latempa, P. D’Acunto, G. Peluso, and A. Barone, C. Granata and M. Russo. “High quality superconducting Josephson junctions on LiNO3 electro-optical crystals”, Appl. Phys. Lett. 86, 202501 (2005). 29 L. Parlato, R. Latempa, G. Peluso and G.P. Pepe, R. Cristiano and R. 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Minutolo, “Time resolved fluorescence polarization anisotropy of carbonaceous particles produced in combustion systems”, OPTICS EXPRESS, 13, 5393 (2005). B. Ivlev, R. Escudero, G. P. Pepe, R. Latempa, A. Barone, F. Barkov, J. Lisenfield, A. Ustinov, “Extremely multiphoton phenomena in Josephson Junctions (Euclidean resonance)”, Phys. Rev B 72, 24507 (2005) A. Ruosi, “Nondestructive detection of e Damage in carbon fibre composites”, Phys. Stat. Sol.(c)2, No.5, 153355 (2005) C. Bonavolontà, G. Peluso, G. P. Pepe, M. Valentino, Eur. Phys. Journal B, 42, 491-496 (2004) C. Bonavolontà, G. P. Pepe, G. Peluso, M. Valentino, G. Caprino, V. Lopresto, “Electromagnetic nondestructive evaluation of fibreglass/aluminium laminates by using HTS SQUID magnetometers”, IEEE Transaction on Superconductivity, Vol. 15, No.2, 711-714 (2005) R. Salvati, A. Longo, G. Carotenuto, L. Nicolais, S. De Nicola, G. P. Pepe, A. 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B 72, 075305 (2005). 12 A. E. Koshelev, A. A. Varlamov, V. M. Vinokur, “Theory of fluctuations in a two-band superconductor: MgB2”, Phys. Rev. B 72, 064523 (2005). 13 T. Schneider and D. Di Castro, “Pressure and isotope effect on the anisotropy of MgB2”, Phys. Rev. B 72, 054501 (2005). 14 E. Di Gennaro, P. V. Parimi, W. T. Lu, S. Sridhar, J. S. Derov and B. Turchinetz, “Slow Microwaves in Lefthanded Materials”, Phys. Rev. B 72, 033110, (2005). 15 G. De Filippis, V. Cataudella, V. M. Ramaglia, C. A. Perroni, “Static and dynamic polaron features in a coherent-state basis”, Phys. Rev. B 72, 014307 (2005). 16 S. Sarti, C. Amabile, E. Silva, M. Giura, R. Fastampa, C. Ferdeghini, V. Ferrando, C. Tarantini, “Dynamic regimes in MgB2 probed by swept frequency microwave measurements”, Phys. Rev. B 72, 024542 (2005). 17 S. Lupi, M. Ortolani, L. Baldassarre, P. Calvani, D. Prabhakaran, A. T. Boothroyd, “Optical conductivity and charge ordering in NaxCoO2”, Phys. Rev. B 72, 024550 (2005). 18 C. Biagini, T. Caneva, V. Tognetti, A. A. Varlamov, “Weak localization effects in granular metals”, Phys. Rev. B 72, 041102 (2005). 19 M. Iavarone, R. Di Capua, A. E. Koshelev, W. K. Kwok, F. Chiarella, R. Vaglio, W. N. Kang, E. M. Choi, H. J. Kim, S. I. Lee, A. V. Pogrebnyakov, J. M. Redwing, Xi, XX; “Effect of disorder in MgB2 thin films”, Phys. Rev. B 71, 214502 (2005). 20 M. Ortolani, D. Di Castro, P. Postorino, I. Pallecchi, M. Monni, M. Putti, P. Dore, “Clean and dirty superconductivity in pure, A1-doped, and neutron irradiated MgB2: A far-infrared study”, Phys. Rev. B 71, 172508 (2005). 21 C. A. Perroni, V. Cataudella, G. De Filippis, V. M. Ramaglia, “Effects of electron-phonon coupling near and within the insulating Mott phase”, Phys. Rev. B 71, 113107 (2005). 22 A. A. Abrikosov, D. V. Livanov, A. A. Varlamov, “Electronic spectrum and tunneling properties of multiwall carbon nanotubes”, Phys. Rev. B 71, 165423 (2005). 23 C. A. Perroni, V. Cataudella, G. De Filippis, V. M. Ramaglia, “Effects of electron-phonon coupling range on the polaron formation”, Phys. Rev. B 71, 054301 (2005). 24 S. Mercone, C.A. Perroni, V. Cataudella, C. Adamo, M. Angeloni, C. Aruta, G. De Filippis, F. Miletto, A. Oropallo, P. Perna, A. Y. Petrov, U. Scotti di Uccio, L. Maritato, “Transport properties in manganite thin films”, Phys. Rev. B 71, 064415 (2005). 25 V. Braccini, A. Gurevich, J. E. Giencke, M. C. Jewell, C. B. Eom, D. C. Larbalestier, A. Pogrebnyakov, Y. Cui, B. T. Liu, Y. F. Hu, J. M. Redwing, Q. Li, Xi, XX; R. K. Singh, R. Gandikota, J. Kim, B. Wilkens, N. Newman, J. Rowell, B. Moeckly, V. Ferrando, C. Tarantini, D. Marre, M. Putti, C. Ferdeghini, R. Vaglio, E. Haanappel, “High-field superconductivity in alloyed MgB2 thin films”, Phys. Rev. B 71, 012504 (2005). 26 M. Salluzzo, A. Cassinese, G. M. De Luca, A. Gambardella, A. Prigiobbo, R. Vaglio, “Transport properties of Nd1.2Ba1.8Cu3OZ ultrathin films by field-effect doping”, Phys. Rev. B 70, 214528 (2004). 27 V. Cataudella, G. De Filippis, F. Martone, C. A. Perroni, “Variational approach to the optimized phonon technique for electron-phonon problems”, Phys. Rev. B 70, 193105 (2004). 28 C. Manzo, D. Paparo, L. Marrucci, “Photoinduced random molecular reorientation by nonradiative energy relaxation: An experimental test”, Phys. Rev. E 70, 051702 Part 1 (2004). 29 A. Di Lisi, S. De Siena, F. Illuminati, D. Vitali, “Quasideterministic generation of maximally entangled states of two mesoscopic atomic ensembles by adiabatic quantum feedback”, Phys. Rev. A 72, 032328 (2005). 30 G. Adesso, F. Illuminati, “Gaussian measures of entanglement versus negativities: Ordering of two-mode Gaussian states”, Phys. Rev. A 72, 032334 (2005). 31 A. Serafini, G. Adesso, F. Illuminati, “Unitarily localizable entanglement of Gaussian states”; Phys. Rev. A 71, 032349 (2005). 32 S. M. Giampaolo, F. Illuminati, G. Mazzarella, S. De Siena, “Influence of trapping potentials on the phase diagram of bosonic atoms in optical lattices”, Phys. Rev. A 70, 061601 (2004). 33 G. Adesso, A. Serafini, F. Illuminati, “Extremal entanglement and mixedness in continuous variable systems”, Phys. Rev. A 70, 022318 (2004). 34 E. Piegari, C. A. Perroni, V. Cataudella, “Signatures of polaron formation in systems with local and non-local electron-phonon couplings”, Eur. Phys. J. B 44, 415-421 (2005). 35 M. Barra, A. Cassinese, F. Chiarella, W. Goedel, D. Marczewski, P. Tierno, R. Vaglio, “Electrical properties of micrometric metallic dots obtained by porous polymeric membranes”, Eur. Phys. J. B 46, 497-500 (2005). 36 M. Barra, C. Collado, J. Mateu, J. M. O'Callaghan, “Miniaturization of superconducting filters using Hilbert fractal curves”, IEEE Trans. Appl. Superconduct. 15, 3841-3846 (2005). 37 M. Ortolani, P. Calvani, S. Lupi, P. Maselli, “Experimental uncertainty in the far-infrared reflectivity of uniaxial superconductors”, J. Opt. Soc. Am. B 22, 1994-2000 (2005). 38 G. Adesso, A. Serafini, F. Illuminati, “Entanglement, purity, and information entropies in continuous variable systems”, Open Systems & Information Dynamics 12 (2): 189-205 (2005). 39 F. Ricci, V. Boffa, G. J. Dai, G. Grassano, R. Mele, A. Tebano, D. Arena, G. Berlin, N. P. Magnani, G. Zarba, A. Andreone, A. Cassinese, R. Vaglio, “Design and development of a prototype of hybrid superconducting. receiver front-end for UMTS wireless network: First results and application perspectives”, IEEE Trans. Appl. Superconduct. 15, 988-991 (2005). 40 A. Andreone, M. Aurino, G. Cifariello, E. Di Gennaro, G. Lamura, P. Orgiani, R. Vaglio, Xi, XX; “Nonlinearity in the microwave properties of MgB2 thin films: Power dependence and intermodulation distortion”, IEEE Trans. Appl. Superconduct. 15, 3612-3615 (2005). 41 A. Cassinese, G. M. De Luca, A. Gambardella, A. Prigiobbo, M. Salluzzo, R. Vaglio, “Electrostatic modulation of conductivity in Nd1.2Ba1.8Cu3Oy thin films”, IEEE Trans. Appl. Superconduct. 15, 2946-2949 (2005). 42 M. Barra, A. Cassinese, W. Ciccognani, E. Limiti, R. Vaglio, “HTS miniaturized filter based on mixed resonators integrated with a two-stage low-noise amplifier”, Superconductor Science & Technology 18, 623627 (2005). 43 D. Bercioux, V. M. Ramaglia, “The spin-double refraction in two-dimensional electron gas”, Superlattices and Microstructures 37, 337-340 (2005). 44 A. Paolone, A. Sacchetti, P. Postorino, R. Cantelli, “Comment on effect of chromium substitution on the lattice vibration of spinel lithium manganate: A new interpretation of the Raman spectrum of LiMn2O4”, J. Phys. Chem. B 109, 7587-7588 (2005). 45 A. Serafini, M. G. A. Paris, F. Illuminati, S. De Siena, “Quantifying decoherence in continuous variable systems”; J. Opt. B 7 (4): R19-R36 (2005). 46 P. Fattibene, A. Carosi, V. De Coste, A. Sacchetti, A. Nucara, P. Postorino, P. Dore, “A comparative EPR, infrared and Raman study of natural and deproteinated tooth enamel and dentin”, Physics in Medicine and Biology 50, 1095-1108 (2005). 47 M. Barra, A. Cassinese, R. Vaglio, “Current redistribution effects in superconducting microwave measurements”, Superconductor Science & Technology 18, 271-276 (2005). 48 F. Chiarella, A. Zappettini, P. Ferro, T. Besagni, F. Licci, A. Cassinese, M. Barra, R. Vaglio, C. Aruta “Growth and characterization of hybrid (CnH2n+1NH3)(2)CuCl4 self-assembled films”, Crystal research and Technology 40, 1028-1032 (2005). 49 M. Piccinini, M. Cestelli Guidi, A. Marcelli, P. Calvani, E. Burattini, A. Nucara, P. Postorino, A. Sacchetti, E. Arcangeletti, E. M. Sheregii, J. Polit, A. Kisiel, “Far-infrared synchrotron radiation spectroscopy of solids in normal and extreme conditions”, Phys. Status Solidi C 2, 236 (2005). 50 A. Paolone, A. Sacchetti, P. Postorino, R. Cantelli, A. Congeduti, G. Rousse, C. Masquelier; “Stabilization of the orthorombic phase of LiMn2O4 by means of high-pressure”, Solid State Ionics 176, 635 (2005). 51 D. Bercioux, M. Governale, V. Cataudella, V. M. Ramaglia, “Quantum networks in the presence of the Rashba effect and a magnetic field”, Material Science - Poland 22 553-563 (2004). 52 V. M. Ramaglia, D. Bercioux, V. Cataudella, G. De Filippis, C. A. Perroni, “Spin polarization of electrons with Rashba double-refraction”, J. Phys. Condensed Matter 16, 9143-9154 (2004). 53 P. Postorino, A. Sacchetti, M. Capone, P. Dore, “Competitive effects on the high-pressure phase diagram of manganites”, Phys. Status Solidi B 241, 3381-3386 (2004). 54 L. Gianni, A. Cassinese, R. Vaglio, S. Zannella, “Observation and explanation of critical current anomalous peaks in transport measurements of YBCO coated conductors”, Superconductor Science & Technology 17, L38L40 (2004). 55 C. Manzo, D. Paparo, S. Lettieri, L. Marrucci, “Fluorescence-based investigation of the Janossy effect anomalous wavelength dependence”, Mol. Cryst. Liq. Cryst. 421, 145-155 (2004). 56 C. A. Perroni, G. Iadonisi, V. K. Mukhomorov, “Formation of polaron clusters”, Eur. Phys. J. B, 41, 163-170 (2004). 57 A. Sacchetti, P. Dore, P. Postorino, A. Congeduti, “Pressure and temperature dependence of optical phonons in La0.75Ca0.25MnO3”, J. Phys. Chem. Solids 65, 1431-1437 Sp. Iss. SI (2004). 58 E. Di Gennaro, G. Lamura, A. Palenzona, M. Putti, A. Andreone, “Observation of multiband effects in the microwave complex conductivity of pure and Al-doped MgB2 samples”, Physica C 408: 125-126 (2004). 59 M. Ortolani, S. Lupi, A. Lucarelli, P. Calvani, A. Perla, P. Maselli, M. Capizzi, N. Kikugawa, T. Fujita, “Imprints of charge stripe excitations in the infrared conductivity of La2-xSrxCuO4”, Physica C 408: 439-440 (2004). 60 A. Nucara, S. Lupi, P. Calvani, “The synchrotron infrared beamline SISSI at ELETTRA”, Infrared Physics & Technology 45 (5-6): 375-381 (2004). 61 M. C. Guidi, A. Nucara, P. Calvani, P. Postorino, A. Sacchetti, A. Congeduti, M. Piccinini, A. Marcelli, E. Burattini, “High-pressure far-infrared measurements at SINBAD”, Infrared Physics & Technology 45, 365-368 (2004). 62 J. Polit, E. M. Sheregii, J. Cebulski, M. Pociask, A. Kisiel, A. Mycielski, B. V. Robouch, E. Burattini, A. Marcelli, M. C. Guidi, M. Piccinni, P. Calvani, A. Nucara, “Manifestation of defects in phonon spectra of binary zinc-blende compounds”, Eur. Phys. J. – Appl. Phys. 27, 321-324 (2004). 63 F. Illuminati and A. Albus, “High-Temperature Atomic Superfluidity in Lattice Bose-Fermi Mixtures”, Phys. Rev. Lett. 93, 090406 (2004). 64 A. Cassinese, M. Barra, W. Ciccognani, M. Cirillo, M. De Dominicis, E. Limiti, A. Prigiobbo, R. Russo and R. Vaglio “Miniaturized Superconducting filter realized by using dual mode and stepped resonators”, IEEE Trans. On Microwave Theory and Technique Vol 52, pp 97-103 (2004). 65 A. Prigiobbo, M. Barra, A. Cassinese, M. Cirillo, F. Marafioti, R. Russo and R. Vaglio, “Superconducting resonators for telecommunication application based on fractal layout, Superconducting Science and Technology”, 17, S427 2004. 66 G. Malandrino, L. M. S. Perdicaro, G. Condorelli, I. L. Fragalà, A. Cassinese and M. Barra. “Synthesis and characterization of La2-xBaxCuO4+d thin film through a simple MOCVD approach”, Journal of Material Chemistry, 15,4718 (2005). 67 G. Malandrino, L. M.S.Perdicaro, G. Conderelli, A. Cassinese, A. Prigiobbo and I. L. Fragalà, “Fabrication of TlBa2CaCu2O7 c-axis oriented through a Hybrid In situ MOCVD Process”, Chemical Vapor ressare o 11, 381 (2005). 68 S. Sarti , E. Silva, M. Giura, R. Fastampa, M. Boffa, A. M. Cucolo, “Dynamic regimes in YBa2Cu3O(7-delta) in applied magnetic field probed by swept frequency microwave measurements”, Journal of Physics-Condensed Matter vol. 16, pp. 6969 (ott. 2004). 69 M. Giura, R. Fastampa, S. Sarti, E. Silva, “C-axis transport and phenomenology of the pseudogap state in Bi2Sr2CaCu2O(8+delta)”, Physical Review. B vol. 70, p 214530 (dic. 2004). 70 N. Pompeo, R. Marcon, L. Mèchin and E. Silva, “Effective surface impedance of YBa2Cu3O7−δ films on silicon substrates”, Supercond. Sci. Technol. 18 (2005) 531–537. International journals – Yet unpublished papers 1 R. Khasanov, D. Di Castro, M. Belogolovskii,, Yu. Paderno, V. Filippov, R. Brütsch, and H. Keller, “Anomalous electron-phonon coupling probed on the surface of ZrB12 superconductor”, Phys. Rev. B, in press. 2 A. Sacchetti, M. Baldini, P. Postorino, C. Martin, A. Maignan, “Raman Spectroscopy on cubic and hexagonal SrMnO3” , Journal of Raman Spectroscopy, in press. 3 P. Dore, P. Postorino, A. Sacchetti, M. Baldini, R. Gianbelluca, M. Angeloni, G. Balestrino, “Raman measurements on thin films of the La0.7Sr0..3MnO3 manganite: a direct probe of substrate induced effects”, Eur. Phys. J. B, in press. 4 P. Dore, P. Postorino, A. Sacchetti, A. Congeduti, F. A. Gorelli, L. Ulivi, D. D. Sarma, “Evidence of phase separation in the phase diagram of the La0.75Ca0.25MnO3 by infrared measurements”, Journal of Superconductivity, in press. 5 M. Ortolani, P. Calvani, S. Lupi, U. Schade, A. Perla, M. Fujita, and K. Yamada, “Use of Coherent Synchrotron Radiation in a study on cuprates exhibiting superconductivity and charge ordering”, Infrared Physics and Technology, in press. 6 M. Cestelli Guidi, M. Piccinini, A. Marcelli, A. Nucara, P. Calvani, and E. Burattini, “Optical performances of SINBAD, the Synchrotron Infrared Beamline At Dafne”, J. Opt. Soc. Am. A, 22, 2810-2817 (2005). 7 G. Lamura, A. Gauzzi, S. M. Kazakov, J. Karpinski, and A. Andreone, “High resolution measurements of the magnetic penetration depth on Yba2Cu4O8 single crystals”, J. Phys. Chem. Solids 66, in press. 8 M. Aurino, F. Di Iorio, E. Di Gennaro, G. Lamura, A. Gauzzi, and A. Andreone, “Discrete model analysis of the critical current density measurements in superconducting thin films by a single coil inductive method”, J. Appl. Phys. 98, in press. 9 L. Catani, A. Cianchi, J.Lorkiewicz, S. Tazzari, J. Langner, A. Andreone, G. Cifariello, E. Di Gennaro, G. Lamura, and R. Russo, “Cathodic Arc Grown Niobium films for RF Superconducting Cavity Applications”, Physica C, in press. 10 S. Lupi, M. Ortolani, L. Baldassarre, U. Schade, P. Calvani, Y. Takano, M. Nagao, T. Takenouchi, and H. Kawarada, “Sub-Terahertz electrodynamics of superconducting diamond”, Nature physics, submitted. 11 M. Ortolani, P. Calvani, S. Lupi, U. Schade, A. Perla, M. Fujita, and K. Yamada, “Effect of superconductivity and charge ordering on the sub-THz reflectivity of La1.875Ba0.125-ySryCuO4”, Phys. Rev. Lett. B, submitted. 12 A. Sacchetti, M. Cestelli Guidi, E. Arcangeletti, A. Calvani, A. Marcelli, A. Nucara, M. Piccinini, and P. Postorino, “Far-infrared absorption of La1-xCaxMnO3-y at high pressare” , Phys. Rev. Lett., in press. 13 M. Monni, M. Affronte, D. Di Castro, C. Ferdeghini, M .Lavagnini, P. Manfrinetti, A. Orecchini, A. Palenzona, C. Petrillo, P. Postorino, A. Sacchetti, F. Sacchetti, M. Putti, “Role of charge doping and lattice distortion in alloyed MgB2”, Phys. Rev. Lett., submitted. 14 R. Di Capua, C. A. Perroni, V. Cataudella, F. Miletto Granozio, M. Salluzzo, R. Vaglio, P. Perna, U. Scotti di Uccio, “Direct observation of multi-scale inhomogeneities on La0.7Sr0.3MnO3 thin films by scanning tunneling spectroscopy”, Phys. Rev. Lett., submitted. 15 G. Cifariello, M. Aurino, E. Di Gennaro, G. Lamura, P. Orgiani, J. C. Villegier, X. X. Xi, and A. Andreone, “Intrinsic non linearity probed by intermodulation distortion microwave measurements on MgB2 thin films grown by HPCVD”, Appl. Phys. Lett., submitted. 16 A. Nucara, P. Calvani, F. Crispoldi, D. Sali, S. Lupi, C. Martin, and A. Maignan, “Infrared observation of the Hund’s mechanism in an electron-doped manganite”, Phys. Rev. B, in press. 17 M. Angeloni, C. Aruta, G. Balestrino, N. G. Boggio, B. Davidson, P. G. Medaglia, A. Tebano, M. Baldini, D. Di Castro, P. Postorino, P. Dore, A. Sidorenko, G. Allodi, R. De Renzi, “Preparation and characterization of LaMnO3 thin film grown by pulsed Laser deposition”, J. Appl. Phys., submitted. 18 A. Sacchetti, P. Postorino, M. Capone, “High-pressure phase diagram in the manganites: a two-site model study”, New Journal of Physics, submitted. 19 A. Cassinese, M. Barra, M. Biasiucci and P. D’Angelo, “Field effect devices based on SrTiO3 gate dielectrics for the investigation of charge carrier mobility in macromolecular films”, Accepted on Macromolecular Symposia. Volumes 1 A. I. Larkin, A. A. Varlamov, “Theory of fluctuations in superconductors”, Monograph, 432 pages, Oxford University Press, (2005). 2 L. G. Aslamazov, A. A. Varlamov “Wonders of Physics”, English version, WSPC, (2005). Russian version Moscow, Добросвет, (2005). 3 V. M. Ramaglia, “Electronic structure of atoms (theory)”, in "Encyclopedia of Condensed Matter Physics" eds. F. Bassani, G. Liedl, P. Wyder, Elsevier (2005) 67-75. S 2 International journals - Published and Submitted papers 1 S. Amoruso, G. Ausanio, A. C. Barone, R. Bruzzese, L. Gragnaniello, M. Vitiello, X. Wang, “Ultrashort laser ablation of solid matter in vacuum: a comparison between the picosecond and femtosecond regimes”, J. Phys. B: At. Mol. Opt. Phys. 38, L329-L338 (2005). 2 S. Amoruso, R. Bruzzese, M. Vitiello, N. N. Nedialkov, P. A. Atanasov, “Experimental and theoretical investigations of femtosecond laser ablation of aluminum in vacuum”, J. Appl. Phys. 98, 044907 (2005). 3 S. Amoruso, G. Ausanio, R. Bruzzese, M. Vitiello, X. Wang, “Femtosecond laser pulse irradiation of solid targets as a general route to nanoparticle formation in a vacuum”, Phys. Rev. B 71, 033406 (2005). 4 M. Vitiello, S. Amoruso, C. Altucci, C. de Lisio, X. Wang, “The emission of atoms and nanoparticles during femtosecond laser ablation of gold”, Appl. Surf. Sci. 248, 163-166 (2005). 5 S. Amoruso, G. Ausanio, M. Vitiello, X. Wang, “Infrared femtosecond laser ablation of graphite in high vacuum probed by optical emission spectroscopy”, Appl. Phys. A 81, 981-986 (2005). 6 S. Amoruso, G. Ausanio, C. de Lisio, V. Iannotti, M. Vitiello, X. Wang, L. Lanotte, “Syntheis of Nickel nanoparticles and nanoparticles magnetic films by femtosecond laser ablation in vacuum”, Appl. Surf. Sci. 247, 71-75 (2005). 7 S. Amoruso, R. Bruzzese, N. Spinelli, R. Velotta, M. Vitiello, X. Wang, C. Altucci, C. de Lisio, “Study of the plasma plume generated during near IR femtosecond laser irradiation of silicon targets”, Appl. Phys. A 79, 1377-1380 (2004). 8 G. Ausanio, A. C. Barone, V. Iannotti, L. Lanotte, S. Amoruso, R. Bruzzese, M. Vitiello, “Magnetic and morphological properties of nickel nanoparticles produced by femtosecond laser ablation”, Appl. Phys. Lett. 85, 4103-4105 (2004). 9 S. Amoruso, R. Bruzzese, N. Spinelli, R. Velotta, M. Vitiello, X. Wang, “Emission of nanoparticles during ultrashort laser irradiation of silicon targets”, Europhys. Lett. 67, 404-410 (2004). 10 S. Amoruso, G. Ausanio, R. Bruzzese, L. Lanotte, P. Scardi, M. Vitiello and X. Wang, “Synthesis of nanocrystal films via femtosecond laser ablation in vacuum”, J. Phys.: Condens. Matter in press. 11 G. Ausanio, A. C. Barone, V. Iannotti, P. Scardi, M. D’Incau, S. Amoruso, M. Vitiello and L. Lanotte, “Morphology, structure and magnetic properties of (Tb0.3Dy0.7Fe2)100−xFex nanogranular films produced by ultrashort pulsed laser deposition”, Nanotechnology. In press. 12 G. Ausanio, S. Amoruso, A. C. Barone, R. Bruzzese, V. Iannotti, L. Lanotte, M. Vitiello, “Production of nanoparticles of different materials by means of ultrashort laser pulses”, Appl. Surf. Sci. In press. 13 S. Amoruso, G. Ausanio, R. Bruzzese, L. Gragnaniello, L. Lanotte, M. Vitiello, X. Wang, “Characterization of laser ablation of solid targets with near-infrared laser pulses of 100 fs and 1 ps duration”, Appl. Surf. Sci. In press. Volumes 1 S. Amoruso, M. Vitiello, X. Wang, “Characterization of plumes produced during ultrashort laser ablation of metals and semiconductors”, in Laser Physics and Applications – 13th International School on Quantum Electronics, Eds. P.A. Atanasov, S.V. Gateva, L.A. Avramov, and. A.A. Serafetinides, Proceedings of SPIE vol. 5830, 11-20 (2005). 2 S. Amoruso, M. Vitiello, X. Wang, “Femtosecond laser ablation and deposition”, in Pulsed Laser Deposition of Optoelectronic Films - Series "Optoelectronic Materials and Devices" edited by M. Popescu (INOE Publishing House, Sofia, 2005). J. Schou, S. Amoruso and J. G. Lunney, “Plume Dynamics”, in Laser Ablation and Its Applications, Edited by C.R. Phypps (Springer), in press. 3 S 4 International journals - Published and Submitted papers 1 F. Tafuri and J. R. Kirtley “High Tc Superconductor Weak Links”, Rep. Prog. Phys. 68, 2573 (2005). 2 T. Bauch, F. Lombardi, F. Tafuri, A. Barone, G. Rotoli, P. Delsing and T. Claeson, “Macroscopic Quantum Tunneling in d-wave YBaCuO Josephson Junctions”, Phys. Rev. Lett. 94, 87003 (2005). 3 F. Tafuri, J. R. Kirtley, D. Born, D. Stornaiuolo, P. G. Medaglia, P. Orgiani, G. Balestrino and V. G. Kogan, “Dissipation in ultra-thin current-carrying superconducting bridges; evidence for quantum tunneling of Pearl vortice”s, Europhys. Lett. (2006) 4 V. D’Auria, A. Chiummo, M. De Laurentis, A. Porzio, S. Solimeno, and M. G. A. Paris, “Tomographic characterization of OPO sources close to threshold”, Optics Express, 13:948, (2005); 5 V. D'Auria, A. Porzio, S. Solimeno, S. Olivares and M. G. A. Paris “Characterization of bipartite states using a single homodyne detector”, J. Opt. B: Quantum Semiclass. Opt. 7:S750–S753 (2005); A. Porzio, P. Aniello, A. Chiummo, V. D’Auria, S. Solimeno and M. G. A.Paris “Secure communication using bright twin-beam and polarization encoding”, accepted for publication in Optics and Laser in Engineering. In press. V. D’Auria, C. de Lisio, A. Porzio, S. Solimeno and M. G. A. Paris “Transmittivity measurements by means of squeezed vacuum light”, J. Phys. B (November 2005). In press. G. Cella, A. Di Virgilio, P. La Penna, V. D'Auria, A. Porzio, I. Ricciardi, and S. Solimeno, “Optical response of a misaligned and suspended Fabry-Perot cavity”, submitted to Phys. Rev. A (December 2005). In press. A. Di Virgilio, L. Barsotti, S. Braccini, C. Bradaschia, G. Cella, C. Corda, V. Dattilo, I. Ferrante, F. Fidecaro, I. Fiori, F. Frasconi, A. Gennai, A. Giazotto, P. La Penna, G. Losurdo, E. Majorana, A. Pasqualetti, D. Passuello, F. Piergiovanni, A. Porzio, P. Puppo, P. Rapagnani, F. Ricci, S. Solimeno, F. Vetrano, “Evidence of an optical spring”, submitted to Physical Review Letters (December 2005). In press. 6 7 8 9 SN 1 International journals - Published and Submitted papers 1 G. Ausanio, A. C. Barone, V. Iannotti, L. Lanotte, S. Amoruso, R. Bruzzese, M. Vitiello, “Magnetic and morphological characteristics of nickel nanoparticles films produced by femtosecond laser ablation”, Appl. Phys. Lett. 85, 4103 (2004) 2 S. Amoruso, G. Ausanio, A.C. Barone, R. Bruzzese, L. Gragnaniello, M. Vitiello , X. Wang, “Ultrashort laser ablation of solid matter in vacuum: A comparison between the picosecond and femtosecond regimes”, J. Phys. B-At. Mol. Opt. 38, L329 (2005) 3 S. Amoruso, G. Ausanio, M. Vitiello, X. Wang , “Infrared femtosecond laser ablation of graphite in high vacuum probed by optical emission spectroscopy”, Appl. Phys. A 81, 981 (2005) 4 S. Amoruso, G. Ausanio, C. De Lisio, V. Iannotti, M. Vitiello, X. Wang, L. Lanotte, “Synthesis of nickel nanoparticles and nanoparticles magnetic films by femtosecond laser ablation in vacuum”, Appl. Surf. Sci. 247, 71(2005) 5 S. Amoruso, G. Ausanio, R. Bruzzese, M. Vitiello, X. Wang, “Femtosecond laser pulse irradiation of solid targets as a general route to nanoparticle formation in a vacuum”, Phys.Rev. B 71, 1 (2005). S. Amoruso, G. Ausanio, R. Bruzzese, L. Lanotte, P. Scardi, M. Vitiello and X. Wang, “Synthesis of nanocrystal films via femtosecond laser ablation in vacuum”, J. Phys.: Condens. In press. G. Ausanio, A. C. Barone, V. Iannotti, P. Scardi, M. D’Incau, S. Amoruso, M. Vitiello and L. Lanotte, “Morphology, structure and magnetic properties of (Tb0.3Dy0.7Fe2)100−xFex nanogranular films produced by ultrashort pulsed laser deposition”, Nanotechnology. In press. G. Ausanio, S. Amoruso, A. C. Barone, R. Bruzzese, V. Iannotti, L. Lanotte, M. Vitiello, “Production of nanoparticles of different materials by means of ultrashort laser pulses”, Appl. Surf. Sci. In press. S. Amoruso, G. Ausanio, R. Bruzzese, L. Gragnaniello, L. Lanotte, M. Vitiello, X. Wang, “Characterization of laser ablation of solid targets with near-infrared laser pulses of 100 fs and 1 ps duration”, Appl. Surf. Sci. In press. 6 7 8 9 SN 2 International journals - Published and Submitted papers 1 L. Parlato, R. Latempa, G. Peluso and G.P. Pepe, R. Cristiano and R. Sobolewski, “Characteristic electronphonon coupling time in unconventional superconductors and implications for optical detectors”, Superconductor Science and Technology 18 1244–1251 (2005) 2 G. P. Pepe, L. Parlato, R. Latempa, P. D’Acunto, N. Marrocco, C. De Lisio, C Altucci, G. Peluso, A. Barone, T. Taneda, and Roman Sobolewski, “Fabrication and optical properties of ultrathin ferromagnet/superconductor metallic bilayers”, IEEE Transaction on Superconductivity Vol. 15, No. 2, 2942-2945, (2005) 3 L. Parlato, G. P. Pepe, R. Latempa, C. De Lisio, C. Altucci, P. D’Acunto, G. Peluso, A. Barone, T. Taneda and R. Sobolewski, “Time-resolved photoresponse of nanometer-thickness Nb/NiCu bilayers”, Applied Surface Science 248, 177 (2005) 4 S. Pagano, E. Esposito, M. Ejrnaes, C. Nappi, and R. Cristiano, “Kinetic Inductance Detectors for Mass Spectroscopy”, IEEE Transactions on Applied Superconductivity, vol. 15, no. 2, (2005) International journals – Yet unpublished papers 5 G. P. Pepe, M. Amanti, C. De Lisio, R. Latempa, N. Marrocco, L. Parlato, G. Peluso, A. Barone, R. Sobolewski, and T. Taneda “Ultrafast photoresponse of superconductor/ferromagnet Nb/NiCu heterostructures”, Phys.stat. Sol. In press. 6 R. Leoni, F. Mattioli, M. G. Castellano, S. Cibella, P. Carelli, S. Pagano, D. Perez de Lara, M. Ejrnaes, M. P. Lisitskyi, E. Esposito, R. Cristiano, C. Nappi, “Fabrication and Test of Superconducting Single Photon Detectors”, NIMA. In press. 7 D. Perez de Lara, M. Ejrnaes, S. Pagano, M. Lisitskiy, E. Esposito, C. Nappi, R. Cristiano, “Advanced superconducting optical detectors”, Journal of Physics: Conference Series. In press. 8 R. Cristiano, M. Ejrnaes, E. Esposito, M. P. Lisitskyi, C. Nappi, S. Pagano, and D. Perez de Lara, “Nonequilibrium superconducting detectors”, Superconductor Science and Technology. In press. SN 3 International journals - Published and Submitted papers 1 M. Salluzzo, A. Cassinese, G. M. De Luca, A. Gambardella, A. Prigiobbo, and R. Vaglio “Transport properties of Nd1.2Ba1.8Cu3OZ ultrathin films by field-effect doping”, Phys. Rev. B Vol. 70, 214528 (2004). 2 3 G. M. De Luca, G. Ausanio, M. Salluzzo and R. Vaglio, “Growth mode selection and transport properties in Nd1Ba2Cu3O7 superconducting films deposited by high oxygen pressure diode sputtering”, Supercond. Sci. Technol. (2005). A. Cassinese, G. M. De Luca, A.Gambardella, A. Prigiobbo, M. Salluzzo and R. Vaglio, “Electrostatic Modulation of Conductivity in Nd1.2Ba1 .8Cu3Oy Thin Films”, IEEE Trans on Appl. Supercond., (2005). EX 1 International journals - Published and Submitted papers 1 2 3 4 5 6 7 V. Tkachenko, A. Marino, F. Vita, F. D’Amore, L. De Stefano, M. Malinconico, M. Rippa, G. Abbate, “Spectroscopic Ellipsometry Study of Liquid Crystal and Polymeric Thin Films in Visible and Near Infrared”, Eur. Phys. J. E, 14, 185-192 (2004). A. Marino, G. Abbate, W. Cao, P. Palffy-Muhoray, B. Taheri, “Lasing Thresholds of Cholesteric Liquid Crystals Lasers”, Electronic Liquid Crystal Communications, 2004/Oct/10 11:20:18 (2004). A. Marino, G. Abbate, W. Cao, P. Palffy-Muhoray, B. Taheri, “Lasing Thresholds of Cholesteric Liquid Crystals Lasers”, Mol. Cryst and Liq. Cryst., 429, 101-110 (2005) L. Sirleto, G. Coppola, G. C. Righini, G. Abbate, “Photonics devices based on hybrid approach combining liquid crystals and sol-gel waveguides”, Mol. Cryst and Liq. Cryst. 429, 149-165 (2005) F. Vita, A. Marino, V. Tkachenko, D. E. Lucchetta, L. Criante, F. Simoni, and G. Abbate “Near infrared characterization and modeling of nanosized holographic-polymer dispersed liquid crystal”, Phys. Rev. E, 72, 011702 (2005) G. Abbate, F. Vita, A. Marino, V. Tkachenko, S. Slussarenko, “LC-Polymer composites for the realization of passive and active optoelectronic components”, Opt. Pur. y Apl. 38 (3), 11-19 (2005) M. Loulou, R. Gharbi, M. Fathallah, G. Ambrosone, U. Coscia, G. Abbate, A. Marino, S. Ferrero and E. Tresso, “Structural, optical and electrical properties of helium diluted a-Si1-xCx:H films deposited by PECVD”, Journal of Non-Crystalline Solids, accepted (2005) 8 A. Marino, F. Vita, V. Tkachenko, R. Caputo, C. Umeton, A. Veltri, G. Abbate, “Dynamical behaviour of holographic polymer-liquid crystal gratings”, Proceedings of LFNM 2004, p. 228 (2004). IEEE cat. # 04TH8741 9 J. N. Hilfiker, C. M. Herzinger, T. Wagner, A.Marino, G. Delgais, and G. Abbate, “Mueller-Matrix Characterization of Liquid Crystals”, Thin Solid Films, 455-456, 591 (2004). 10 A. Marino, F. Vita, V. Tkachenko, R. Caputo, C. Umeton, A. Veltri, G. Abbate, “Dynamical Behaviour of Policryps Gratings”, Eur. Phys. J. E 15, 47-52 (2004). 11 V. Tkachenko, A. Marino, F. Vita, F. D’Amore, L. De Stefano, M. Malinconico, M. Rippa, G. Abbate, “Spectroscopic Ellipsometry Study of Liquid Crystal and Polymeric Thin Films in Visible and Near Infrared”, Electronic Liquid Crystal Communications, 2004/Feb/26 (2004). 12 V. Tkachenko, A. Marino, F. Vita, F. D’Amore, L. De Stefano, M. Malinconico, M. Rippa, G. Abbate, “Spectroscopic Ellipsometry Study of Liquid Crystal and Polymeric Thin Films in Visible and Near Infrared”, Eur. Phys. J. E, 14, 185-192 (2004). EX 2 International journals - Published and Submitted papers 1 G. Pesce, A. Sasso, P. Netti, S. Fusco, “Optical tweezers as a tool for for microrheology of simplex and complex fluids”, Proceedings of SPIE, in “Optical Trapping and Optical Micromanipulation”, Vol. 5514 (2004). 2 3 4 5 E. Del Gado, A. Fierro, L. de Arcangelis and A. Coniglio, Physical Review E 69, 051103 (2004). A. de Candia, E. Del Gado, A. Fierro, N. Sator and A. Coniglio Physica A, 358, 239 (2005). E. Del Gado and W. Kob, Europhys. Lett. 72, 1032 (2005). A. Coniglio, L. de Arcangelis, E. Del Gado, A. Fierro and N. Sator, J. Phys. C: Condens. Matter 16, S4831 (2004). 6 F. Mallamace, S. H. Chen, A. Coniglio, L. de Arcangelis, E. Del Gado and A. Fierro, accepted in PRE Rapid Communications (2005). 7 A. Coniglio, A. Fierro, M. Nicodemi, M. Pica Ciamarra, and M. Tarzia, “Statistical mechanics of dense granular media”, J. Phys.: Condens. Matter. 17 (24), S2557-S2572 (2005). 8 M. Tarzia, A. Fierro, M. Nicodemi, M. Pica Ciamarra, and A. Coniglio, “Size segregation in granular media induced by phase transition”, Phys. Rev. Lett 95, 078001 (2005). 9 A. Fierro, M. Nicodemi, M. Tarzia, A. de Candia, and A. Coniglio, “Jamming transition in granular media: A mean-field approximation and numerical simulations”, Phys. Rev. E 71, 061305 (2005). 10 11 A. de Candia, “Effective potential in glass forming liquids”, J. Stat. Mech. L02001 (2005). 12 M. Tarzia, A. Fierro, M. Nicodemi and A. Coniglio, “Segregation in fluidized versus tapped packs”, Phys. Rev. Lett. 93, 198002 (2004). 13 A. Coniglio, L. De Arcangelis, E. Del Gado, A. Fierro and N. Sator, “Percolation, gelation and dynamical behaviour in colloids”, J. Phys.: Condens. Matter. 16 (42), S4831-S4839 (2004). 14 A. Coniglio, A. de Candia, A. Fierro, M. Nicodemi, and M. Tarzia, “Statistical mechanics approach to the jamming transition in granular materials”, Physica A 344 (3-4), 431-439 (2004). 15 16 A. Fierro, “Glass transition in models with controlled frustration”, Phys. Rev. E 70, 012501 (2004). T. Abete, A. de Candia, D. Lairez, and A. Coniglio, “Percolation Model for Enzyme Gel Degradation”, Phys. Rev. Lett. 93, 228301 (2004). 17 M. Nicodemi and H.J. Jensen, “Time dependent phenomena in transport properties and I-V characteristics of a model for driven vortex matter” Jour. Phys.: Cond. Matt. 16, 6789 (2004). 18 A. Caiazzo, A. Coniglio, and M. Nicodemi, “Glass glass transition and new dynamical singularity points in an analytically solvable $p$-spin glass like model”, Phys. Rev. Lett. 93, 215701 (2004). 19 M. Pica Ciamarra, A. Coniglio, and M. Nicodemi, “Shear-induced segregation of a granular mixture under horizontal oscillation”, Jour. Phys.: Cond. Matt. 17, S2549 (2005). 20 L. P. Oliveira, H. J. Jensen, M. Nicodemi, and P. Sibani, ”Record dynamics and the observed temperature plateau in the magnetic-creep rate of type-II superconductors”, Phys. Rev. B 71, 104526 (2005). Note: selected for the April 1, 2005 issue of Virtual Journal by the American Institute of Physics and the American Physical Society 21 M. Pica Ciamarra, A. Coniglio, and M. Nicodemi, “Shear instabilities in granular mixtures”, Phys. Rev. Lett. 94, 188001 (2005). 22 P. Richard, M. Nicodemi, R. Delannay, P. Ribi\`ere, D. Bideau, “Slow relaxation and compaction of granular systems”, Nature Materials 4, 121 (2005). Note: Nature Materials Highlight of February 2005 Compaction in a sand box. A. Gamba, A. de Candia, S. Di Talia, A. Coniglio, F. Bussolino, and G. Serini, “Diffusion limited phase separation in eukaryotic chemotaxis”, Proc. Nat. Acad. Sci. 102, 16927 (2005). International journals – Yet unpublished papers 1 P. Zemanek, V. Karasek, A. Sasso,“Optical forces acting on Rayleigh particle placed into interference field”, Opt. Commun., 240, 401-415 (2004). 2 A. Casaburi, G. Pesce, A. Sasso, P. Zemanek, “Two- and three-beam interferometric optical traps”, Opt. Commun., 251, 393-404 (2005) 3 A. Sasso and G. Pesce, “Optical tweezers calibration: a quantitative tool for local viscosity investigation”, Proceedings of SPIE, Vol. 5514, pp. 487-493 (2004). ISBN/ISSN: 0-8194-5452-4/0277-786X. 4 G. Pesce, A. Sasso, S. Fusco, “Optical tweezers for local rheological investigations”, Rev. Scient. Instr., 76, 115105 (2005). 5 6 M. Tarzia and A. Coniglio “Pattern Formation and Glassy phase in $\Phi4$ theory with screened electrostatic repulsion” Phys Rev Lett. In press. M. Pica Ciamarra, A. D. De Vizia, M. Tarzia, A. Fierro, M. Nicodemi and A. Coniglio “Granular segregation under vertical tapping” submitted to Phys Rev Lett. EX 3 International journals - Published and Submitted papers 1 L. Ferraioli, P. Maddalena, E. Massera, A. Parretta, M.A. Green, A. Wang, J. Zhao, “Evidence for generalized Kirchhoff’s law from angle-resolved electroluminescence of high efficiency silicon solar cells”, Appl. Phys. Lett., 85, 2484, (2004). 2 G. Ambrosone, U. Coscia, S. Lettieri, P. Maddalena, C. Minarini, S. Ferrero, S. Restello, V. Rigato “Deposition Of Microcrystalline Silicon-Carbon Films By PECVD”, Thin Solid Films, 451-452 (2004) 274-279. G. Ambrosone, G. Barucca, U. Coscia, S. Ferrero, S. Lettieri, P. Maddalena “Deposition Of µc-SiC:H Alloys In Low Power Regime” J. Non Cryst. Solids, 338-340, 163-167 (2004). S. Lettieri, F. Gesuele, P. Maddalena, M. Liscidini, L.C. Andreani, C. Ricciardi, V. Ballarini, F. Giorgis, “Second Harmonic Generation in a-Si1-xNx:H doubly resonant microcavities with periodic dielectric mirrors”, Appl. Phys. Lett., 87, , (2005). L. De Stefano, I. Rendina, M. De Stefano, A. Bismuto, P. Maddalena, “Marine Diatoms as Optical Chemical Sensors”, Appl. Phys. Lett., 87, 233902, (2005). L. Ferraioli, P. Maddalena, A. Parretta, A. Wang, J. Zhao, “Current-Voltage Characteristics of High Efficiency Silicon Solar Cells from Photoluminescence” Appl. Phys. Lett., 85, 4222, (2004). S. Lettieri, U. Bernini, E. Massera, P. Maddalena, “Optical investigations on thermal conductivity in n- and ptype porous silicon”, Phys. Stat. Sol. (c), 2, 3414 (2005). U. Coscia, G. Ambrosone, S. Lettieri, P. Maddalena, V. Rigato, S. Restello, E. Bobeico, M. Tucci, “Preparation of Microcrystalline Silicon-Carbon Films”, Sol. Energ. Mat. Sol. C., 87, 433 (2005) G. Ambrosone, U. Coscia, S. Lettieri, P. Maddalena, C. Minarini, V. Parisi, S. Schutzmann, “Crystallization of Hydrogenated Amorphous Silicon-carbon Films by Means of Laser Treatments”, Appl. Surf. Sc., 247, 471 (2005). 3 4 5 6 7 8 9 10 11 G. Di Francia, L. Quercia, I. Rea, P .Maddalena, S. Lettieri, “Nanostructure reactivity: confinement energy and charge transfer in Porous Silicon”, Sens. & Act. B, 111-112, 117, (2005). U. Bernini, P. Maddalena, E. Massera, P. Rucco, “Determination of Thermal Diffusivity of Suspended Porous Silicon Films by Thermal Lens Technique”, Appl. Phys. A, 81, 399, (2005). 12 G. Ambrosone, U. Coscia, S. Lettieri, P. Maddalena, M. Della Noce, S. Ferrero, S. Restello, V. Rigato, M. Tucci, “Silicon-Carbon Films Deposited at Low Substrate Temperature”, J. Non Cryst. Solids, accepted, (2005). 13 E. Luppi, E. Degoli, G. Cantele, S. Ossicini, R. Magri, D. Ninno, O. Bisi, O. Pulci, G. Onida, M. Gatti, A. Incze, R. Del Sole, “The electronic and optical properties of silicon nanoclusters: absorption and emission”, Optical Materials 27, 1008 (2005). 14 G. Festa, M. Cossi, V. Barone, G. Cantele, D. Ninno, G. Iadonisi, “A first-principle study of the adsorption of 1amino-3-cyclopentene on the (100) silicon surface”, J. Chem. Phys 122, 184714 (2005). 15 G. Cantele, E. Degoli, E. Luppi, R. Magri, D. Ninno, O. Bisi, S. Ossicini, G. Iadonisi, Electronic, “Structural and optical properties of hydrogenated silicon nanocrystals: the role of the excited states”, Phys. Stat. Sol. (c) 2, 3263 (2005). 16 E. Degoli, S. Ossicini, G. Cantele, E. Luppi, R. Magri, D. Ninno, O. Bisi, “Formation energies of silicon nanocrystals: role of dimension and passivation”, Phys. Stat. Sol. (c) 2, 3354 (2005). F. Trani, G. Cantele, D. Ninno, G. Iadonisi, “Tight binding calculations for the optical properties of ellipsoidal silicon nanocrystals”, Phys. Stat. Sol. (c) 2, 3435 (2005). 17 18 F. Trani, G, Cantele, D. Ninno, G. Iadonisi, “Tight-binding calculation of the optical absorption cross section of spherical and ellipsoidal silicon nanocrystals”, Phys. Rev. B 72, 75423 (2005). 19 G. Cantele, E. Degoli , E. Luppi, R. Magri, D. Ninno, G. Iadonisi, S. Ossicini, “First-principles study of n- and p-doped silicon nanoclusters”, Phys. Rev B 72 , 113303 (2005). 20 G. Iadonisi, V. K. Mukhomorov, G. Cantele, D. Ninno, “Criteria for the appearance of a periodical component in the polaron distribution function”, Phys. Rev. B 72, 94305 (2005). 21 S. Ossicini, E. Degoli, F. Iori, E. Luppi, R. Magri, G. Cantele, F. Trani, D. Ninno, “Simultaneously B- and Pdoped silicon nanoclusters: Formation energies and electronic properties”, Appl. Phys. Lett. 87, 173120 (2005). 22 C. A. Perroni, G. Iadonisi, and V. K. Mukhomorov, “Formation of polaron clusters”, Eur. Phys. J. B, 41, 163 (2004). V. Cataudella, G. De Filippis, G. Iadonisi, C. A. Perroni, “Variational approach to polarons, Proceedings of the International School "Enrico Fermi"”, Corso CLXI, 2005. G. Cantele, C. A. Perroni, V. K. Mukhomorov, D. Ninno, and G. Iadonisi, “Thermodynamical and dynamical instabilities in the homogeneous polaron gas, Proceedings of the International School "Enrico Fermi"”, Corso CLXI, 2005. C. A. Perroni, V. Cataudella, G. De Filippis, G. Iadonisi, and V. M. Ramaglia, “Infrared absorption in polaronic systems, Proceedings of the International School "Enrico Fermi"”, Corso CLXI, 2005. 23 24 25 26 S. Ossicini, E. Degoli, F. Iori, E. Luppi, R. Magri, G. Cantele, F. Trani, and D. Ninno, “Simultaneously P- and B-doped silicon nanoclusters: Formation energies and electronic properties”, Appl. Phys. Lett. 87, 173120 (2005). 27 G. Iadonisi, V. K. Mukhomorov, G. Cantele and D. Ninno, “Criteria for the appearence of a periodical component in the polaron distribution function”, Phys. Rev. B 72, 094305 (2005). 28 G. Cantele, E. Degoli, E. Luppi, R. Magri, D. Ninno, G. Iadonisi and S. Ossicini, “A first-principle study of nand p-doped silicon nanoclusters”, Phys. Rev. B 72, 113303 (2005). F. Trani, G. Cantele, D. Ninno and G. Iadonisi, Tight binding calculation of the optical absorption cross section of spherical and ellipsoidal silicon nanocrystals Phys. Rev. B 72, 075423 (2005). 29 30 F. Trani, G. Cantele, D. Ninno, and G. Iadonisi, “Tight binding calculations for the optical properties of ellipsoidal silicon nanocrystals”, Phys. stat. sol. (c) 2, 3435 (2005). 31 G. Cantele, E. Degoli, E. Luppi, R. Magri, D. Ninno, O. Bisi, S. Ossicini and G. Iadonisi, “Electronic, structural and optical properties of hydrogenated silicon nanocrystals: the role of the excited states” Phys. stat. sol. (c) 2, 3263 (2005). 32 E. Degoli, S. Ossicini, G. Cantele, E. Luppi, R. Magri, D. Ninno and O. Bisi, “Formation energies of silicon nanocrystals: role of dimension and passivation” Phys. stat. sol. (c) 2, 3354 (2005). 33 G. Festa, M. Cossi, V. Barone, G. Cantele, D. Ninno and G. Iadonisi, “A first-principle study of the adsorption of 1-amino-3-cyclopentene on the (100) silicon surface” J. Chem. Phys. 122, 184714 (2005). E. Luppi, E. Degoli, G. Cantele, S. Ossicini, R. Magri, D. Ninno, O. Bisi, O. Pulci, G. Onida, M. Gatti, A. Incze and R. Del Sole, “The Electronic and Optical Properties of Silicon Nanoclusters: Absorption and Emission” Opt. Mater. 27, 1008 (2005). E. Degoli, G. Cantele, E. Luppi, R. Magri, S. Ossicini, D. Ninno, O. Bisi, G. Onida, M. Gatti, A. Incze, O. Pulci, and R. Del Sole, “Ab-initio Calculations of the Electronic Properties of Silicon Nanocrystals: Absorption, Emission, Stokes Shift” in: AIP Conf. Proc. 772, 859 (2005) (27th International Conference on the Physics of Semiconductors, edited by J. Menéndez and C.G. Van de Walle). S. Ossicini, O. Bisi, G. Cantele, E. Degoli, R. Del Sole, M. Gatti, A. Incze, F. Iori, E. Luppi, R. Magri, D. Ninno, G. Onida, O. Pulci, “Ab-initio calculations of the electronic properties of hydrogenated and oxidized silicon nanocrystals: ground and excited states”, in: Atti del XVII Congresso dell'Associazione Italiana del Vuoto, Editrice Compositori (2005). 34 35 36 International journals – Yet unpublished papers 1 S. Ossicini, F. Iori, E. Degoli, E. Luppi, R. Magri, R. Poli, G. Cantele, F. Trani, and D. Ninno, “Understanding Doping in Silicon Nanostructures”, submitted to Ieee Journal Of Selected Topics In Quantum Electronics On Silicon Photonics. 2 L. E. Ramos, E. Degoli, G. Cantele, S. Ossicini, D. Ninno, J. Furthmuller, and F. Bechstedt “Effects of size and shape on doping of Si nanocrystallites”, submitted to Phys. Rev. B. 3 D. Ninno, F. Trani, G. Cantele, K. J. Hameeuw, G. Iadonisi, E. Degoli, S. Ossicini, “Microscopic Description of Point Charge Screening in Semiconductor Nanocrystals”, submitted to Europhys. Lett. K. J. Hameeuw, G. Cantele, D. Ninno, F. Trani, G. Iadonisi, The stoichiometric TiO2 (110) surface: obtaining converged structural properties from first principles calculations. J. Chem. Phys, (2005). In press. 4 EX 4 International journals - Published and Submitted papers 1 F. Bloisi, G. di Blasio, L. Vicari, M. Zoncheddu, “Laser Cleaning for Cultural Heritage”, Nova Science Publishers, 1-59454-859-5 (2006). LECTURES Author Institution Date Dr. Fabrizio Bobba Dipartimento di Fisica, Università degli Studi di Salerno “E.R. Caianiello”, Italy 26/05/2004 Title Prof. J.M. Triscone Title Dr. Marco Aprili Title Dr. Vladimir Belotelov Title Prof. Ivan Schuller Title Dr. Luigi Frunzio Title Prof. Paolo Scardi Title Dr. Vikass Monebhurrun Title Dr. Vittorio Pellegrini Title Prof. Marc Anglada Title Dr. Annalisa Bruno Title Prof. Igor A.Sukhoivanov Title Dr. Takuya Satoh Title Dr. Francesca Ferlaino Title Dr. Denis Grebenkov Title Prof. Umberto Scotti di Uccio Title Dr. Nathascia Lampis Title STM miscroscopy on conventional superconductors DPMC, University of Geneva, Switzerland 24/06/2004 Electric Field Effect in Correlated Oxides CSNSM-CNRS, Université Paris-Sud, Orsay, France 26/10/2004 Superconduttività pi M.V. Lomonosov, Moscow State University, Russia 24/11/2004 Optics and magneto-optics of nanostructures University of California, USA 10/12/2004 Confined Structures and the Proximity Effect Department of Applied Physics,Yale University, USA 16/12/2004 Circuit Quantum Electrodynamics: Doing Quantum Optics on a Chip Dipartimento di Ingegneria dei Materiali e Tecnologie Industriali, Università di Trento, Italy 15/02/2005 Diffraction Analysis of Imperfect Materials CRS Supelec Paris (France) Numerical Modelling of Eddy Current non-destructive evaluation of multi-layered planar structures (using the volume integral method) 29/04/2005 NEST – Scuola Normale Superiore di Pisa, Italy Nuove fasi elettroniche ed eccitoniche nei semiconduttori a bassa dimensionalità: evidenze nella diffusione anelastica di luce Universitat Politècnica de Catalunya - ETSEIB Barcelona (Spain) 03/05/2005 16/05/2005 Structural Integrity, Micromechanics and Reliability of Materials CRdC“Analisi e Monitoraggio del Rischio Ambientale”, Napoli, Italy Time resolved fluorescence polarization anisotropy of combustion-generated nanoparticles 09/06/2005 National University of Radio Electronics, Kharkov. Ukraine 15/06/2005 Modelling of photonic elements for telecommunication application Max-Born Institut, Berlino (Germany) 27/06/2005 Interface second-harmonic generation from manganite heterostructures LENS – European Laboratory for Non-Linear Spectroscopy, Italy 28/06/2005 Interactions in a Fermi-Bose mixture of ultracold atoms Laboratoire de Physique de la Matière Condensee Ecole Polytechnique Palaiseau, France Laplacian Transport towards Irregular Interfaces: A Theoretical, Numerical and Experimental Study Coherentia-CNR-INFM e DiMSAT Università di Cassino, Italy 01/07/2005 15/07/2005 Proprietà elettroniche, strain e disordine in film sottili di La0.7Sr0.3Mn0.3-d Dipartimento di Fisica – Università degli Studi di Cagliari, Italy Proprietà e caratterizzazione strutturale di ossidi magnetici 15/07/2005 Dr. Vladimir Belotelov Title Prof. Annalisa Bonfiglio Title Prof. Xiaoxing Xi Title Prof. Assa Auerbach Title Dr. Istvan Jànossy M.V. Lomonosov, Moscow State University, Russia 27/07/2005 Magnetophotonic crystals: properties and possible applications INFM-S3 & Dipartimento di Ingegneria Elettronica, Università di Cagliari. Italy 26/09/2005 Substrate-free structures of OTFTs: a perspective for new field effect based devices Department of Physics and Department of Materials Science and Engineering, The Pennsylvania State University 28/09/2005 MgB2 thin films and Josephson junctions Technion University – Haifa, Israel 03/10/2005 Tunneling of vortices in two-dimensional superfluids and superconductors Research Institute for Solid State Physics and Optics Hungarian Academy of Sciences, Budapest, Hungary 13/10/2005 Azimuthal anchoring and gliding of liquid crystals on polymers Prof. Robert B. Laughlin Università di Stanford e KAIST (Seul) 26/10/2005 Remarking physics from the bottom down: the search for the real frontier Dr. Angela Vella Université de Rouen, France 27/10/2005 La sonda atomica laser: potenzialità e questioni aperte Prof. Anatoli S.Sidorenko Institute of Applied Physics, Kishinev, Moldova 04/11/2005 Resistive transitions broadening in superconducting MgB2 Dr. Gabriele Campagnano Technische Universiteit, Delft, Germany 24/11/2005 Weak localization and the Distribution Function of Transmission Eigenvalues Prof. Emanuele Rimini Dipartimento di Fisica ed Astronomia, Università di Catania, Italy 06/12/2005 Nanotecnologie in Silicio: dai materiali ai dispositivi Prof. Ruggero Micheletto Prof. A.S. Mishchenko Kyoto University, Japan Introduzione allo Scanning Near field Optical Microscopi (SNOM) e sue applicazioni presso la Kyoto University in Giappone CREST, Japan Science and Technology Agency (JST), Tsukuba, Japan and RRC – Kurchatov Institute, Moscow, Russia Polaron and polaronic metal in high temperature superconductors: Insights from exact quantum Monte Carlo analysis 14/12/2005 19/12/2005