Validation of UV and Ozone EO based data used in PROMOTE/MEDSUN service, by means of on ground measurements Fabrizio Flore (1), Ronald van der A (2) , Gaetano Licitra (3) , Anna Fabozzi (4) , Emilio Simeone (1) and Vanni Nardino (1) (1) Flyby srl, via Puini 97 int.26, 57128 Livorno, Italy (2) KNMI (Royal Netherlands Meteorological Institute), P.O.Box 201, 3730AE De Bilt, Netherlands (3) ARPAT (Tuscany Agency for Environment Protection), via Porpora 22, 50144 Firenze, Italy (4) University of Pisa, Largo Pontecorvo 3, 56127 Pisa, Italy During Summer 2005 Flyby srl has delivered the MEDSUN public service with the supervision of Regional Agency for Environmental Protection of Tuscany (ARPAT). The MEDSUN service, funded by the GSE-PROMOTE ESA program, provided a personalized safe sun exposure time by correlating the EO based UV Index with the customized personal phototype. The UV-Index in the general (cloudy) case is calculated as a function of both EO based cloud coverage and UV-Index in clear-sky case. The clear-sky UV-Index is determined by RTM model calculations, using EO based columnar ozone data and spatial and temporal coordinates for each EO pixel. The Ozone is derived from SCIAMACHY by KNMI. The cloud coverage is derived from MSG images by Flyby. Here are presented the basic features of MEDSUN service and the results of two validations based on on-ground measurements. The first validation regards the EO based UV Index, the second validation regards the EO based total columnar Ozone. Measurements were made with Flyby's spectroradiometer SpectrAIRTM. The ground instrument Ozone remote sensing KNMI bases the ozone forecasts on a tracer-transport and assimilation model called TM3DAM. Within TM3DAM the three-dimensional advection of ozone is described by the flux-based second order moments scheme. The model is driven by 6-hourly meteorological fields (forecasts of wind, surface pressure, and temperature) from ECMWF. The total ozone data are assimilated in TM3DAM by applying a parameterized Kalman filter technique. SpectrAIRTM spectroradiometer 0.06 Spectral Irradiance [W/(m2nm)] Characteristics: • Resolution/spectral range: 0.5 nm / 290-850 nm SpectrAIR 0.03 0.02 0.01 0 200 400 500 600 700 800 900 calibration (NIST) • USB interface 0.025 Calibration Function 0.02 Spectral Irradiance/Counts • Software SpectrAIR for Windows • Lambertian diffuser with quartz window 0.015 0.01 0.005 • Anti-solarization quartz optic fiber, 400 µm south pole view 300 Lambda [nm] • Integrated optical shutter for automated subtraction of noise diffuser north pole view 0.04 • Accuracy UV: 8% (NIST) Assimilated SCIAMACHY ozone field (KNMI) global view spectrAIR_50cm NIST_50cm 0.05 0 200 300 400 500 600 700 800 900 Lambda [nm] UV Index remote sensing UV index validation The clear sky UV Index is calculated at Flyby with a Radiative Transfer Model as a function of the ozone (SCIAMACHY), the altitude of the locality (DEM model, GTOPO30 version), the aerosol (seasonal model in standard atmosphere) and the albedo of the surrounding wide area (standard value). The UV Index for the general case (cloudy sky) exploits a further model based on MSG images at 1 km resolution and with 15 min. update rate. The comparison between the UV Index calculated from satellite data and the UV Index derived from on-ground measurements made by ARPAT in Livorno using the SpectrAIRTM spectroradiometer shows an agreement better than 16% for Solar Zenith Angle < 40°, also including the most critical cases of partially clouded sky FBY-ASC-POS-001-10 The general case UV Index (compliant with WMO/WHO standards) is then correlated with the user Minimum Erythemal Dose and used by PROMOTE/MEDSUN service to calculate the safe exposure time tailored to the user specific phototype. Ozone validation The spectral irradiance data have been measured on 14 March 2006 and 4 April 2006, in clear-sky conditions, in Livorno, Italy (lat. 43.5092468 N; lon. 10.3249168 E). 180 160 140 120 100 80 5 25 45 55 60 65 70 SZA 400 60 375 40 20 0 200 250 300 350 400 O3 (DU) R = exp{B(SZA) + (a(SZA)/cos(SZA))! O3} 450 350 325 Ozone from SpectrAir 300 04/4-12.30 04/4-12.15 04/4-12.00 04/4-11.45 04/4-11.30 04/4-11.15 14/3-13.59 14/3-13.32 14/3-13.02 14/3-12.31 14/3-12.01 14/3-11.31 14/3-11.01 14/3-10.28 14/3-09.59 UTC time 325 Ozone from SpectrAir 300 with a and B depending only on SZA: 14/3-09.32 350 14/3-08.32 Ozone (DU) & cos(SZA) # !!(ln(R) - B(SZA)) O3 = $$ % a(SZA) " 275 375 14/3-14.29 then by inverting we obtain: 04/4-11.00 Ozone from SCIAMACHY 400 04/4-10.39 Writing R as: Ozone (DU) R = Irr(323.5nm) / Irr(305.5nm) The method has been developed using simulated data calculated by FastRT program. The algorithm uses the ratio R between the irradiance values in 323.0 nm and 305.0 nm bands, considering the HWHM for each band equal to 2.0 nm and weighing the shape function with a triangular function. Ground albedo and quote have been set to 0.05 and 0 km. Ozone from SCIAMACHY: 275 35 40 45 50 55 Solar Zenith Angle (degree) 60 65 The ozone measured by SpectrAIR shows a good agreement with satellite data. In the above figure a relative error of 5% is reported. The reported error on SCIAMACHY data is 5 DU. Bibliography • Sigrid Wuttke, Jean Verdebout and Gunther Seckmeyer (2003), “An Improved Algorithm for Satellite-derived UV Radiation”, Photochemistry and Photobiology, 77(1): 52–57 • A.Arola, S.Kalliskota, P.N. den Outer, K.Edwardsen, G.Hansen, T.Koskela, T.J.Martin, J. Matthijsen, R.Meerkötter, P.Peeters, G.Seckmeyer, P.Simon, H.Slaper, P.Taalas, J.Verdebout (2002), “Assessment of four methods to estimate surface UV radiation using satellite data by comparison with ground measurements from four stations in Europe”, J. Geophys. Res., 107, D16, (10.1029/2001JD000462), ACL 11-1. • Working Group 4 of the COST-713 Action (2000), “UV-Index for the Public - A guide for publication and interpretation of solar UV Index forecasts for the public”, European Communities, ISBN 92 828 81542 3. • M. Houët, C. Brogniez, D. Bolsée, D. Gillotay, H. De Backer (2002), “Ozone column retrieval from UV spectral irradiance measurement”, Sixth European Symposium on Stratospheric Ozone, Göteborg, Sweden, 2-6 Sept. 2002. • E.Simeone, F.Flore, V.Nardino, A.Masi, C.Lanzetta, G.Licitra, D.Palazzuoli, P.Gallo, S.Carpinello (2005), “Sistema di fotoprotezione solare mediante elaborazione di immagini ottiche satellitari”, Acta of 9th ASITA Conference, Catania, 15-18 Nov.2005