Consiglio Nazionale delle Ricerche Institute for Microelectronics and Microsystems – Rome Advanced Large Area Electronic Devices and Integrated Circuits (ALADIN) Group Leader: Guglielmo Fortunato ([email protected]) The group has strong expertise in large area electronics (active matrix for flat panel display, sensors, organics electronics, etc.) with particular focus on thin film transistors (TFTs). This research activity has been supported, in the years, by different collaborations with companies like Philips, STMicroelectronics, THALES and European projects as ECAM III and FlexiDis. The key framebased research activity includes devices designing, fabrication and electrical testing. Devices and circuits analysis is performed by 2D3D numerical simulations. Recently, the group activity is mainly focused on realization of lowtemperature devices on polymeric flexible substrates, for applications in new generation of flat panel display and sensors. Two TFT fabrication technologies were developed, based on organic and inorganic materials. The principal inorganic semiconductor materials used in TFTs are amorphous, microcrystalline and polycrystalline silicon. In particular, the group has developed a strong knowhow on silicon excimer laser crystallization technique, being one of the groups pioneers in this field. In organic TFT field, the group has developed a innovative technology of buffer layers for devices based on pentacene, thus allowing electrical characteristics to be improved. via del Fosso del Cavaliere 100 00133 Roma (ITALY) Tel. : +39 06 4993 4594 Fax : +39 06 4993 4066 [email protected] 2.MATERIALS CHARACTERIZATION A SEM image of a laser crystallized amorphous silicon film (aSi). With the excimer laser irradiation technique it is possible to optimize the quality of polysilicon film, his uniformity and the mean grain size adjusting energy and shots number. 1m Atomic force microscope (AFM) analysis of polysilicon grain size after the effects of an annealing at low temperature (<300°C) plus the excimer laser irradiation. 1.DEVICE PHYSICS 2D numerical simulation for the impact ionization rate at the poly Si TFT drain junction. These models are implemented in order to analyze the device electrical behavior and to improve his characteristics. Temperature distribution in a TFT obtained by 3D simulation for self heating effect analysis. AFM analysis for a thin film of pentacene thermally evaporated by RADAK source. Interface state density (Nss) deduced from quasistatic characteristics by Khun method for SiO2 films deposited at room temperature by ECRPECVD and annealed at increasing temperatures Consiglio Nazionale delle Ricerche Institute for Microelectronics and Microsystems – Rome 3.ORGANIC THIN FILM TRANSISTORS ( OTFTs) Organic TFTs realization based on pentacene films thermally evaporated on flexible plastic substrates encapsulated by parylene. PolySi TFTs output characteristics at increasing Vg for a device realized on plastic. 5.POLYSI TFTs BASED CIRCUITS ON FLEXIBLE SUBSTRATES Organic common gate TFTs transfer characteristics for a device with channel length L= 10m. 4.POLYCRYSTALLINE SILICON SUBSTRATES Fivestages ring oscillator fabricated on flexible substrate. TFTs ON FLEXIBLE Low temperature (<350°C) Polysilicon TFTs fabricated on flexible substrates (polyimide). Inverter fabricated on polyimide. Consiglio Nazionale delle Ricerche Institute for Microelectronics and Microsystems – Rome LAB FACILITIES Equipment for electrical tests : 1. 2. 3. 4. Probe station Suss PM5HF Analytical Probe System for DC e HF electrical measurements of samples up to 6” Probe station for flexible substrates devices measures Variable Temperature MicroProbe System by MMR Technologies for electrical measurements of devices in vacuum in a temperature range of 80580K Probe station in clean room for samples check during the fabrication process Excimer laser system for aSi crystallization of devices fabricated on glass or flexible substrates. InkJet (DIMATIX) system for organic devices realization ECRPECVD system for lowtemperature deposition of dielectric films (silicon oxide and silicon nitride) and amorphous silicon layers. Consiglio Nazionale delle Ricerche Institute for Microelectronics and Microsystems – Rome Publications 2007 Riviste JCR 1) L. Mariucci, P. Gaucci, A. Valletta, F. Templier and G. Fortunato, Hot Carrier Effects in pChannel Polycrystalline Silicon Thin Film Transistors Fabricated on Flexible Substrates. Jpn. J. of Appl. Phys. Vol. 46, No. 3B, (2007) pp. 12991302 2) G. Lulli, M. Bianconi, M. Ferri, G. Fortunato, L. Mariucci, RBSchanneling analysis of ionirradiation effects in heavilydoped Si:As, Nuclear Instruments and Methods in Physics Research B 257 (2007) pp. 253–256 3) V. Privitera, A. La Magna, C. Spinella, G. Fortunato, L. Mariucci, M. Cuscunà, C. M. Camalleri, A. Magrì, G. La Rosa, B. G. Svensson, E. V. Monakhov, and F. Simon, Integration of Melting Excimer Laser Annealing in Power MOS Technology, IEEE Trans. on Electron Devices, Vol 54 (2007) pp. 852860 4) A.Valletta, P. Gaucci, L. Mariucci and G. Fortunato, Modelling velocity saturation and kink effects in pchannel polysilicon thinfilm transistors, Thin Solid Films, vol. 515 , (2007) pp.74177421 5) P. Gaucci, L. Mariucci, A. Valletta, A. Pecora and G. Fortunato, F. Templier, Electrical stability in selfaligned pchannel polysilicon Thin Film Transistors, Thin Solid Films, vol. 515, (2007) pp.75717575 6) Maria Losurdo, M.M. Giangregorio, A. Sacchetti, P. Capezzuto, G. Bruno, L. Mariucci and Guglielmo Fortunato, INSIGHT INTO EXCIMER LASER CRYSTALLIZATION EXPLOITING ELLIPSOMETRY: EFFECT OF Si FILM PRECURSOR, Thin Solid Films, vol. 515, (2007) pp.75087512 7) A. Bonfiglietti, M. Cuscunà , M Rapisarda, A. Pecora, L. Mariucci, G. Fortunato, C. Caligiore, E. Fontana, S. Leonardi, F. Tramontana, Asymmetric fingered polysilicon pchannel Thin Film Transistors structure for kink effect suppression, Thin Solid Films, vol. 515, (2007) pp. 74337436 8) S. Cipolloni, L. Mariucci, A. Valletta, D. Simeone, F. De Angelis and G. Fortunato, Aging effects in high performance Pentacene Thin Film Transistors, Thin Solid Films, vol. 515 , (2007) pp. 75467550 9) A. Valletta, A. Bonfiglietti, M. Rapisarda, L. Mariucci, and G. Fortunato, S. D. Brotherton, Grain boundary evaluation in sequentially laterally solidified polycrystalline silicon devices, J. Appl. Phys. Vol. 101, 094502 (2007) 10) A. Valletta, A. Bonfiglietti, M. Rapisarda, L. Mariucci, A. Pecora, G. Fortunato, and S. D. Brotherton,Grain Boundary Characterisation in Sequentially Laterally Solidified PolycrystallineSilicon Thin Film Transistors, ECS Trans. Vol. 8, (2007) p. 211 11) A. La Magna, V. Privitera, G. Fortunato, M Cuscunà, B.G. Svensson, E. Monakhov, E. Kuitunen, J. Slotte, F. Tuomisto,Vacancy generation in liquid phase epitaxy of Si, Phys. Rev. B 75, 235201 (2007) 12) L. Maiolo, A. Pecora, M. Cuscunà and G. Fortunato, Thermal annealing effects on the interface state density of metaloxidesemiconductor capacitors with electron cyclotron resonance plasma enhanced chemical vapor deposition Silicon dioxide, Thin Solid Films, vol. 515, (2007) pp. 75907593 Consiglio Nazionale delle Ricerche Institute for Microelectronics and Microsystems – Rome Publications 2006 Riviste JCR 1) A. Valletta, L. Mariucci and G. Fortunato, Hot carrierInduced Degradation of LDD Polysilicon TFTs, IEEE Trans. on El. Dev., 53, 43 (2006) 2) V. Teppati, V. Camarchia, S. Donati Guerrieri, M. Pirola, A. Ferrero, G. Ghione, M. Peroni, P. Romanini, C. Lanzieri, S. Lavanga, A. Serino, L. Mariucci, Fabrication and nonlinear characterization of GaN HEMT on SiC and sapphire for high power applications, International Journal of RF and Microwave ComputerAided Engineering, 16 , 70 (2006) 3) P. Gaucci, A. Valletta, L. Mariucci, G. Fortunato, and S. D. Brotherton, Numerical Simulation of Parasitic Resistance Effects in Polycrystalline Silicon TFTs, IEEE Trans. on El. Dev., 53, 573 (2006) 4) T. Toccoli, A. Pallaoro, N. Coppedè, and S. Iannotta, F. De Angelis, L. Mariucci, G. Fortunato, Controlling Field Effect Mobility in Pentacene Based Transistors by Supersonic Molecular Beam Deposition, Appl. Phys. Lett., 88, 132106 (2006) 5) F. De Angelis, L. Mariucci, S. Cipolloni, and G. Fortunato, Analysis of electrical characteristics of high performance Pentacene ThinFilm Transistors with PMMA buffer layer, Journ. of NonCryst. Solids, 352, 1765 (2006) 6) M. Cuscunà, G. Stracci, A. Bonfiglietti, A. di Gaspare, L. Maiolo, A. Pecora, L. Mariucci, G. Fortunato, Annealing temperature effects on the electrical characteristics of pchannel polysilicon thin film transistors, Journ. of NonCryst. Solids, 352, 1723 (2006) 7) G. Fortunato, V. Privitera, A. La Magna, L. Mariucci, M. Cuscunà, B.G. Svensson, E. Monakhov, M. Camalleri, A. Magrì, D. Salinas, F. Simon, Excimer Laser annealing for shallow junction formation in Si power MOS devices, Thin Solid Films, 504, 2 (2006) 8) F. De Angelis, S. Cipolloni, L. Mariucci and G. Fortunato, Aging effects in pentacene thinfilm transistors: analysis of the density of states modification, Appl. Phys. Lett., 88, 193508 (2006) 9) A. Bonfiglietti, A. Valletta, M. Rapisarda, L. Mariucci, G. Fortunato, Effects of Fabrication Parameters on the Electrical Stability of Gate Overlapped LDD Polysilicon TFTs, Jpn. Journ. of Appl. Phys., 45, p. 4384 (2006) 10) A. Valletta, P. Gaucci, L. Mariucci, G. Fortunato, Modelling Velocity Saturation Effects in Polysilicon ThinFilm Transistors, Jpn. Journ. of Appl. Phys., 45, 4374 (2006) 11) M. Cuscunà, L. Mariucci, G. Fortunato, A. Bonfiglietti, A. Pecora and A. Valletta, Improved electrical stability in asymmetric fingered polysilicon Thin Film Transistors, Appl. Phys. Lett., 89, 123506 (2006) 12) A. Valletta, A. Moroni, L. Mariucci, A. Bonfiglietti, and G. Fortunato, Selfheating effects in polycrystalline silicon thin film transistors, Appl. Phys. Lett., 89, 093509 (2006) 13) A. Pecora, L. Maiolo, G. Fortunato, C. Caligiore, A comparative analysis of silicon dioxide films deposited by ECRPECVD, TEOSPECVD and VapoxAPCVD, Journ. of NonCryst. Solids, 352, 1430 (2006) 14) L. Maiolo, A. Pecora, and G. Fortunato N. D. Young, Lowtemperature electron cyclotron resonance plasmaenhanced chemicalvapor deposition silicon dioxide as gate insulator for polycrystalline silicon thinfilm transistors, J. Vac. Sci. Technol. A 24, 280 (2006) 15) L. Mariucci, A. Valletta, P. Gaucci, and G. Fortunato, Hot carrier effects in pchannel polycrystalline silicon thin film transistors, Appl. Phys. Lett., 89, 183518 (2006) 16) V. Privitera, P. Alippi, M. Camalleri, M. Cuscunà, G. Fortunato, A. La Magna, G. La Rosa, A. Magrì, L. Mariucci, E. Monakhov, D. Salinas, F. Simon, C. Spinella, B. G. Svensson, Perspectives and advantages of the use of excimer laser annealing for MOS technology, Nuovo Cimento C, 29, 369 (2006) 17) G. Fortunato, L. Mariucci and M. Cuscunà V. Privitera, A. La Magna, C. Spinella, Magr, M. Camalleri and D. Salinas, F. Simon, B. Svensson and E. Monakhov, Advanced gate stack architecture for excimer laser annealing integration in power MOS fabrication, Appl. Phys. Lett., 89, 253502 (2006) 18) L. Romano, A.M. Piro , V. Privitera , E. Rimini , G. Fortunato, B.G. Svensson , M. Foad, M.G. Grimaldi, Mechanism of deactivation and clustering of B in Si at extremely high concentration, Nuclear Instruments and Methods in Physics Research B 253, 5054 (2006) 19) A. La Magna, P. Alippi, I. Deretzis, V. Privitera,G. Fortunato, L. Mariucci, A. Magrì, E. Monakhov, B. Svensson, Ultrashallow junction by laser annealing: Integration issues and modelling, Nuclear Instruments and Methods in Physics Research B 253, 1 (2006) Consiglio Nazionale delle Ricerche Institute for Microelectronics and Microsystems – Rome Publications 2005 Riviste JCR 1) G. Mannino,V. Privitera, A. La Magna, and E. Rimini, E. Napoletani, G. Fortunato and L. Mariucci, Depth distribution of B implanted in Si after excimer laser irradiation, Appl. Phys. Lett., vol. 86, 051909 (2005) 2) A. Pecora, L. Maiolo, A. Bonfiglietti, M. Cuscunà, F. Mecarini, L. Mariucci, G. Fortunato and N. D. Young, “Silicon dioxide deposite d by ECRPECVD for low temperature Si devices”, Microelectronics reliability, vol. 45, p. 879882 (2005) 3) A. Valletta, L. Mariucci, A. Bonfiglietti,G. Fortunato, S. Brotherton, “Dopant and defect interactions in polycrystalline silicon thinfilm transistors”, J. Appl. Phys. vol 97, p. 104515 (2005) 4) A. Di Gaspare, L. Mariucci, A. Pecora and G. Fortunato, “Stable pchannel polysilicon TFTs fabricated by laser doping technique” , Thin Solid Film, vol. 487, pp. 232 236 (2005) 5) A Valletta, L Mariucci, A Bonfiglieti, G Fortunato, S D Brotherton, “Channel Doping Effects in polySi TFTs”, Thin Solid Film, vol. 487, pp. 242246 (2005) 6) G. Fortunato, A. Valletta, P. Gaucci, L. Mariucci, and S. D. Brotherton, “Short channel effects in polysilicon TFTs”, Thin Solid Film, vol. 487, pp. 221226 (2005) 7) M. Cuscunà, L. Mariucci, G. Fortunato, A. Bonfiglietti, A. Pecora and A. Valletta, “Improved electrical stability in asymmetric fingered polysilicon Thin Film Transistors”, Thin Solid Film, vol. 487, pp. 237241 (2005) 8) E. V. Monakhov, B. G. Svensson, M. K. Linnarsson, A. La Magna, C. Spinella, C. Bongiorno, V. Privitera, G. Fortunato, and L. Mariucci, “Enhanced boron diffusion in excimer laser preannealed Si”, Appl. Phys. Lett. 86, 151902 (2005) 9) F. De Angelis, S. Cipolloni, L. Mariucci and G. Fortunato, “High field effect mobility Pentacene Thin Film Transistors with Polymethylmetacrylate buffer layer”, Appl. Phys. Lett., vol. 86, p.203505 (2005) 10) E. V. Monakhov and B. G. Svensson, M. K. Linnarsson, A. La Magna, M. Italia, and V. Privitera, G. Fortunato, M. Cuscunà, and L. Mariucci, “Boron distribution in silicon after multiple pulse excimer laser annealing”, Appl. Phys. Lett., vol. 86, p. 081901 (2005) 11) A. Bonfiglietti, A. Valletta, P. Gaucci, L. Mariucci, and G. Fortunato, S. D. Brotherton, “Electrical characterization of directionally solidified polycrystalline silicon”, J. Appl. Phys. vol 98, p. 033702 (2005) 12) E. V. Monakhov_ and B. G. Svensson, M. K. Linnarsson, A. La Magna, M. Italia, and V. Privitera, G. Fortunato, M. Cuscunà, and L. Mariucci, “The effect of excimer laser pretreatment on diffusion and activation of boron implanted in silicon”, Appl. Phys. Lett., vol. 87, 192109 (2005) 13) E.V. Monakhov, B.G. Svensson, M.K. Linnarsson, A. La Magna, M. Italia, V. Privitera, G. Fortunato, M. Cuscunà, L. Mariucci, “Excimer laser annealing of B and BF2 implanted Si”, Materials Science and Engineering B, vol. 124–125 p. 232–234 (2005) 14) E.V. Monakhov, B.G. Svensson, M.K. Linnarsson, A. La Magna, M. Italia,V. Privitera, G. Fortunato, M. Cuscunà, L. Mariucci, “Boron distribution in silicon after excimer laser annealing with multiple pulses”, Materials Science and Engineering B, vol. 124–125 p. 228–231 (2005) 15) A. La Magna, P. Alippi, V. Privitera and G. Fortunato, “Role of light scattering in excimer laser annealing of Si”, Appl. Phys. Lett., 86, 161905 (2005) 16) Sean Whelan, Michael J. Kelly, John Yan and Guglielmo Fortunato, “Radiation damage annealing (thermal and laser) in Mg implanted GaN”, Phys. Stat. Sol. (c) 2, No. 7, 2472–2475 (2005) Consiglio Nazionale delle Ricerche Institute for Microelectronics and Microsystems – Rome Staff Name Position Tel. Email Guglielmo Fortunato Senior Researcher 06.4993.4594 [email protected] Luigi Mariucci Researcher 06.4993.4706 [email protected] Alessandro Pecora Researcher 06.4993.4064 [email protected] Antonio Valletta Researcher 06.4993.4541 [email protected] Massimo Cuscunà Researcher 06.4993.4580 [email protected] Antonio Minotti Technician 06.4993.4064 [email protected] Daniela Simeone Post Doctoral Fellowship 06.4993.4492 [email protected] Luca Maiolo PhD Student 06.4993.4064 [email protected] Paolo Gaucci PhD Student 06.4993.4580 [email protected] Matteo Rapisarda PhD Student 06.4993.4580 [email protected]