DICAM DEPARTMENT OF CIVIL, CHEMICAL, ENVIRONMENTAL AND MATERIALS ENGINEERING RESEARCH PROJECTS AND ACTIVITIES 2015 Bononia University Press Bononia University Press Via Farini 37, 40124 Bologna tel. (+39) 051 232 882 fax (+39) 051 221 019 www.buponline.com e-mail: [email protected] © 2015 Bononia University Press Tutti i diritti riservati ISBN 978-88-6923-028-8 Impaginazione: Sara Celia Stampa: MIG - Moderna Industrie Grafiche (Bologna) Prima edizione: aprile 2015 CONTENTS DICAM OVERVIEW5 FOREWORD7 DICAM FIGURES 9 OVERVIEW OF THE INTERNATIONAL MASTER DEGREE PROGRAMMES 10 PhD PROGRAMME 14 RESEARCH PROJECTS AND ACTIVITIES 2015 DIFFUSION IN POLYMERS AND MEMBRANE SEPARATIONS 23 GEOENGINEERING AND NATURAL RESOURCES 39 GEOTECHNICAL AND GEOLOGICAL ENGINEERING 57 INDUSTRIAL AND ENVIRONMENTAL BIOTECHNOLOGIES AND FLUID-DYNAMICS 73 INDUSTRIAL SAFETY AND ENVIRONMENTAL SUSTAINABILITY 89 GEOMATICS 109 MATERIALS CHEMISTRY 123 MATERIALS SCIENCE AND TECHNOLOGY 139 STRUCTURES 155 TRANSPORTATION INFRASTRUCTURES AND TRANSPORTS 207 WATER ENGINEERING 227 Research Projects and Activities 2015 DICAM OVERVIEW It is with great pleasure that I welcome this publication of the Department of Civil, Chemical, Environmental and Materials Engineering (DICAM). The present volume is aimed to present a concise and comprehensive overview of the DICAM research projects and scientific activities, carried out by its numerous research groups. Obviously, this publication provides only a still image of the ongoing activities, thus requiring continuous update, thanks to the constant evolution and liveliness already shown since the birth of the Department. To such purposes, the Department has also developed a dynamic web site, which represents a precious source of information and a valuable tool to promote scientific exchange and technological transfer. What emerges from this picture is a rich and articulated portrait of the varied skills and potentials of the Department, the first one of the University of Bologna to succeed in the recent strategic plan of resources and people aggregation of different but interrelated engineering branches. DICAM currently comprises more than 150 Researchers and Professors, including a large number of PhD students and Research fellows. It incorporates researchers and collaborators from different former Departments of the School of Engineering and Architecture of the University of Bologna. Since 2013, the Department also manages the education activities. Together with the traditional BS and MS Courses taught in Italian (in the areas of Civil Engineering, Chemical Engineering and Environmental Engineering, with a total of more than 1500 students enrolled), the Department also manages the following two-year international master programmes completely taught in English: Chemical and Process Engineering (curriculum “Sustainable Technologies and Biotechnologies for Energy and Materials”), Environmental Engineering (curriculum “Earth Resources Engineering”), Civil Engineering, and, in collaboration with the Department of Architecture, the international curriculum “Rehabilitation of Historic Buildings” within the master programme in Engineering of Building Processes and Systems, held in Ravenna Campus. Thanks to agreements with top Universities in the world (including Columbia University, NY), students can earn two Master degrees in two years, by spending the second year abroad. The collaboration with companies operating in the Ravenna area and with international research institutes has lead to the development of a new field of specialization and to the implementation of a new curriculum in “Offshore Engineering” to be offered as an option for students enrolled in our international Master Degree Programmes. Finally, the Department is involved in the following postgraduate 1-year professional master programs: Timber Contructions (Assolegno) and Design of Oil & Gas Plants (ENI). All courses are given in English. 5 Research Projects and Activities 2015 The Department has also a very active PhD program in Civil, Chemical, Environmental and Materials Engineering, with more than 80 students enrolled. The PhD program encompasses the following internal curricula: 1) Infrastructure, Resource and Land Engineering; 2) Structural and Geotechnical Engineering; 3) Chemical and Process Engineering; 4) Materials Engineering and Industrial Biotechnologies. The high quality, interdisciplinary nature and collaborative work of the research groups enable the Department to provide, worldwide, an effective answer to the demands of today’s modern society and of professional world. This was possible as a result of clear leadership with international individual recognition at the management level but also extending to many of the individual members who progressively assume greater visibility in the international arena. The Department faces many challenges for its future. Continuing its quest for excellence, with real impact in science and technology, is a clear goal. This goal relies on people and this is the most important asset of DICAM. Now and for the future our mission is to make the Department an ever more challenging place to be for young researchers. For all of them, my warmest thanks for the privilege of leading an enthusiastic team. Francesco Ubertini Department Head 6 Research Projects and Activities 2015 FOREWORD The Department of Civil, Chemical, Environmental and Materials Engineering (DICAM) is the result of a large aggregation of research skills and laboratory facilities of diverse but interrelated engineering branches traditionally developed at the University of Bologna. The department integrates the scientific expertise of various research groups, such as Structural, Transport, Hydraulic, Survey and Territory Engineering, Applied Chemistry and Materials Science, Chemical, Mining, Petroleum and Environmental Engineering. The main objective of the aggregation was bringing together, within a large scientific and administrative organization, many of the multifaceted activities of the School of Engineering and Architecture at the University of Bologna. The mission of the Department is to create and develop advanced research in the areas of civil, chemical, environmental and materials engineering, starting from evaluation, design, construction and service of manmade structures and infrastructures (including industrial production facilities), through the study and characterization of the constituent materials, up to the environmental analysis and impact assessment of the footprint on the territory and the environment. More than 320 people currently team up to the Department research activities: 105 academic staff, 45 technical, administrative and librarian staff and 174 Ph.D. students, research assistants and research fellows. The Department is based in the two main locations of the School of Engineering and Architecture of the University of Bologna, the historical building of downtown Bologna and the new building in the strategic urban development of Via Terracini, in the close outskirt of the historical downtown, which houses the largest part of the Laboratory facilities and many modern offices for Researchers and Professors. However, staff ’s activity also takes place at the satellite University of Bologna Campuses of Cesena and Ravenna. As far as Research activities are concerned, the Department encompasses 14 specialized laboratories, which represent a large propulsive element to the research in all the specific disciplines, as well as an essential element for the teaching activities. The following are the Labs facilities currently operating in the Department: Laboratory of Bioreactors, Photocatalytic Processes and Applied Fluid-dynamics (LABIOFF), Laboratory of Computational Mechanics (LAMC), Laboratory of Environmental Biotechnology and Biorefineries (LABIOTEC), Laboratory of Geoengineering and Natural Resources (LAGIRN), Laboratory of Hydraulic Engineering (LIDR), Laboratory of Industrial Safety and Environmental Sustainability (LISES), Laboratory of Land Surveying and Geomatics (LARIG), Laboratory of Macromolecular Synthesis and Materials Characterization 7 Research Projects and Activities 2015 (LAMAC), Laboratory of Materials Science and Technology (LASTM), Laboratory of Membrane Processes, Bioseparations and Diffusion in Polymers (LABMEM), Laboratory of Road Constructions (LAS), Laboratory of Structural and Geotechnical Engineering (LISG), Laboratory of Transport Network (LART). The aim of collecting and making available all useful info about the life of the Department has been fundamental since its origin. To such purposes, an Editorial Board was established, originally aimed to plan and develop a modern website (www.dicam.unibo.it), which has now become more than just a source of constantly updated information, but also a remarkable working tool for all the Department staff, fostering its institutional relationships with the external world. In the website section illustrating the research projects and scientific activities, information and references have been progressively and constantly gathered, accounting for the scientific liveliness of the various research groups within the department. Therefore, it was deemed appreciable and useful to put together all these materials in this booklet, which represents a concise but comprehensive compendium of the Department scientific activities. All the research topics are presented in a 2-pages format which includes title and keywords, people of the research group, contact person, a short summary with figures and a list of the key publications. Each topic has been then grouped into homogeneous categories, which have been in turn classified under more general research areas, resulting in an overall picture, organized in 11 main research areas. Finally, I would like to acknowledge the Head of Department for having strongly supported the birth of such publication, along with all the members of the Editorial Board, whose tenacious efforts in file revision and graphic design have made this publication possible. Paolo Macini Coordinator of DICAM Editorial Board 8 Research Projects and Activities 2015 DICAM FIGURES Department organization Head of Department: Francesco Ubertini Deputy Head of Department: Fabio Fava Head of Administration Department: Vanessa Valisella Department Board: Maria Bignozzi, Roberto Bruno, Vittorio Di Federico, Fabio Fava, Giada Gasparini, Andrea Munari, Virginio Pilò, Lorenza Pucci, Roberta Rizzolo, Federico Rupi, Giulio Cesare Sarti, Elena Toth, Alessandro Tugnoli, Francesco Ubertini Department Council: full professors, associate professors, assistant professors and Head of Administration Department, representatives of technical and administrative staff, representatives of research fellows and representatives of BS, MS and Ph.D. students Chairmen of Committees: Research, Alessandro Paglianti; Education, Marco Savoia; Library, Andrea Munari; Laboratories, Andrea Simone; Editorial Board, Paolo Macini Staff: Full Professors and Associate Professors (68); Ph.D. Students (85); Research Assistants and Research Fellows (89); Administration Staff (28); Lab Technicians Staff (24) Laboratories Laboratory of Bioreactors, Photocatalytic Processes and Applied Fluid-dynamics – LABIOFF Laboratory of Computational Mechanics – LAMC Laboratory of Environmental Biotechnology and Biorefineries – LABIOTEC Laboratory of Geoengineering and Natural Resources – LAGIRN Laboratory of Hydraulic Engineering – LIDR Laboratory of Industrial Safety and Environmental Sustainability – LISES Laboratory of Land Surveying and Geomatics – LARIG Laboratory of Macromolecular Synthesis and Materials Characterization– LAMAC Laboratory of Materials Science and Technology – LASTM Laboratory of Membrane Processes, Bioseparations and Diffusion in Polymers – LABMEM Laboratory of Road Constructions – LAS Laboratory of Structural and Geotechnical Engineering – LISG Laboratory of Transport Network – LART Locations and Contacts Bologna Head Offices, School of Engineering and Architecture, 2 Viale del Risorgimento, 40136, Bologna – Italy, phone +39 051 20 93237/93502, fax 0039 051 20 93253; Bologna, new offices building and Labs, 28 Via Terracini, 40131, Bologna – Italy, phone +39 051 20 9031 2, fax +39 051 20 90322 Cesena Campus Offices, 55 Via Cavalcavia, 47521, Cesena – Italy, phone +39 0547 338311, fax +39 0547 338307 Ravenna Campus Offices, 5 Via Tombesi dall’Ova, 48121, Ravenna – Italy, phone +39 0544 936511, fax +39 0544 936503 Web sites www.dicam.unibo.it www.eng.dicam.unibo.it 9 Research Projects and Activities 2015 OVERVIEW OF THE INTERNATIONAL MASTER DEGREE PROGRAMMES International two-year Master in Civil Engineering The international two-year Master Programme in “Civil Engineering” (“Laurea Magistrale”), entirely taught in English, is open to students of any nationality. The main goal of the Master is to educate professionals with the necessary in-depth scientific and technical knowledge in the field of Civil Engineering, within a multi-cultural educational environment. The programme is meant to prepare students with firm technical bases while nurturing decision-making and leadership potential. It prepares graduates to practice their profession at an advanced level and with a unique exposure to an international environment to better understand the global issues of Civil Engineering. The programme is organized in core modules and curriculum courses. The core modules, common for all students, aim at consolidating fundamentals and improving modelling capabilities in the classical areas of Civil Engineering, such as Structural Mechanics and Engineering, Hydraulics and Hydrology, Geotechnical Engineering, Road and Transportation Engineering. Students will select their field of specialization within three different areas, opting for one of the following curricula: - Structural engineering - Infrastructure design in river basins - Offshore Engineering (with a second year held in Ravenna Campus) After the Master, civil engineers plan and design all types of buildings, houses, industrial plants, bridges, roads and railways, waterways and water reservoirs. Besides these traditional activities, in industrialised and rapidly evolving societies, the skills of Civil Engineers are increasingly requested in the fields of territory planning and environment preservation. Moreover, the arising demand for safety and protection against natural and industrial risks is the framework in which the skills of Civil Engineers meet the continuously evolving needs of Civil Protection. Main employers of civil engineers are national and international construction companies, engineering and consultancy agencies and, public authorities. Quite a number of civil engineers are self-employed and run their own company or office. International two-year Master in Environmental Engineering, ERE (Earth Resources Engineering) Curriculum The two-year Master Programme (“Laurea Magistrale”), entirely taught in English, is open to students of any nationality. The central theme of ERE is the conscientious stewardship of our finite natural resources, namely minerals, fuels, energy, water, and land. Students taking ERE Programme will attain a broad background in environmental engineering and earth resources covering water resources, pollution prevention, energy, resource economics, recycling, waste and biowaste valorization, alternative and renewable raw materials, reclamation, and health. It prepares graduates to practice their profession at an advanced level and with a unique exposure to an international environment to better understand the global issues of environmental engineering. ERE graduates will be prepared to move to higher levels of their careers, across a variety of industries and sectors. They will gain access to a wider range of positions both in engineering companies and in national and international government agencies. 10 Research Projects and Activities 2015 Besides these traditional activities, in industrialized and rapidly evolving societies, the skills of Environmental Engineers are increasingly needed in the fields of territory planning and environmental conservation. Moreover, the rising demand for safety and protection against natural and industrial risks is the framework in which the skills of Environmental Engineers meet the continuously evolving needs of civil protection agencies. The Laboratories support both teaching and research activities. During the courses and the preparation of the final thesis students will find in the laboratories and the facilities of the department a very interesting and exciting place to improve their knowledge and abilities. For their second year, students enrolled in the ERE Programme will be able to choose “Offshore Engineering” curriculum, held in Ravenna campus, gaining the possibility to carry out internships and to develop research projects in the companies operating in in the field. International two-year Master Programme in Chemical and Process Engineering, STEM (Sustainable Technologies and biotechnologies for Energy and Materials) Curriculum The conventional world-players, such as the chemical and Oil&Gas industry, are undergoing increasing innovation and internationalization, thus requiring global competences and higher qualifications from the chemical engineers recruited. The STEM curriculum of the Master Degree in Chemical and Process Engineering (“Laurea Magistrale”), entirely taught in English, was built to meet these needs. In the first year, courses deepen the understanding of fundamental concepts: advanced thermodynamics and transport phenomena, introduction to basic design, and introduction to industrial safety. In the second year, both compulsory and elective courses are offered on specialized topics, such as materials, energy and environmental processes and industrial biotechnologies. Graduates of the programme will be prepared to work in numerous fields, including the conventional chemical and process industry (petrochemical, specialty chemicals, pharmaceutical), the widespread energy industrial sectors (up-stream and down-stream Oil&Gas, energy generation, green energy production), and many other specialized sectors (material production, food technologies, industrial biotechnologies, etc.). The Programme includes the opportunity for students to carry out part of their Masters research project in the framework of the collaborative research project between the University of Bologna and private companies or various international research institutes. For their second year, students enrolled in the STEM Programme will be able to choose “Offshore Engineering” curriculum, held in Ravenna campus, gaining the possibility to carry out internships and to develop research projects in the companies operating in in the field. Among the more important professional sectors addressed by Master studies in Chemical Engineering are: The conventional Chemical and Process Industry, and in particular the petrochemical, polymers, specialty chemicals, and pharmaceutical sectors: this industry is characterized by increasing globalization and is steadily recruiting qualified chemical engineers throughout Europe. The Energy sector: Oil&Gas, both up-stream and down-stream, strongly requires qualified chemical engineers for design and operation in a framework of growing complexity and innovation towards increasing sustainability and environmental compatibility. The Material sector, with its development towards nanomaterials and smart materials requires qualified chemical engineers to answer the demand for innovation and life-cycle sustainability. 11 Research Projects and Activities 2015 The Biotechnology sector, with its evolution towards large-scale production, has a growing requirement of qualified chemical engineers able to support the industrialization of biotechnological processes and their operations. The Environmental sector, with the growing development of processes for the recovery of wastes, the valorization of biomass and the implementation of safe and sustainable technologies, needs qualified chemical engineers as a necessary support to its large-scale operations. International two-year Master Programme in Engineering of Building Processes and Systems, HBR (Rehabilitation of Historic Buildings) Curriculum The innovation in both technical and organizational structure is increasing the complexity of the building process. The emergence of more stringent requirements and the intense penetration of new materials and technologies take special relevance in consolidation, recovery and rehabilitation of historic buildings, which is a market segment in steady expansion. The growing cultural value attributed to the existing building and the economic and environmental benefits associated with its conservation are expanding this market, whose further development fuels a demand for high-profile skills, able to meet its specific characteristics and constraints. The HBR (Historic Buildings Rehabilitation) international curriculum of the Master in Engineering of Building Processes and Systems was built to meet these needs of new professionals, able to integrate the functions traditionally found within the process, by focusing on the critical analysis of the historical heritage, the diagnosis of conservation conditions, the definition of procedures and techniques for consolidation and rehabilitation of the artefacts, by applying effective methods and solutions, compatible with the protection of the heritage characters. In the first year, courses are mainly oriented to address basic issues of the Master’s studies: History of Italian and European Architecture; Conservation Theory of Historic Buildings and Heritage Conservation; Survey of Historic Buildings, Materials and Technologies for Historic Buildings; Advanced Structural Mechanics and Mechanics of Historic Masonry and Wood Structures. Additionally, a Design Project course aims at training the students in applying to a case-study the acquired knowledge. In the second year, both compulsory and elective courses are offered on specialized topics, such as Structural Diagnostics, Seismic Assessment and Rehabilitation; Geotechnical Engineering for the Preservation of Historic Buildings; Mineralogical and Petrographical Characterization of Natural and Artificial Stone Materials. At the end of the program, a degree titled “Master in Engineering of building processes and Systems” (Laurea Magistrale in Ingegneria dei Processi e dei Sistemi edilizi, Classe LM-24) is awarded. Graduates of the program will have the training to go on to work in numerous fields, including Public Administrations, Companies carrying out works of consolidation and recovery of historic buildings, and many other specific sectors, such as production of building components, diagnostic and survey services, facility management. DICAM international Master Degrees include Dual Degree joint education Programmes with Columbia University in New York (Civil Engineering, ERE, STEM), the University of Miami (Civil Engineering, ERE) and Tongji University in Shanghai (HBR). Students participating in the Dual Degree may obtain in two years the International Master Degree (Laurea Magis- 12 Research Projects and Activities 2015 trale Internazionale) at the University of Bologna and the Master of Science at the partner University. New Dual Degree agreements are in the process of being established, namely with Université de Liège (Belgium) and USP (University of San Paulo, Brasil). Completion of all Master Degrees can also lead to entering PhD. level studies. 13 Research Projects and Activities 2015 PhD PROGRAMME The Department provides a highly stimulating environment for PhD research and our doctoral programme attracts outstanding students from a variety of academic backgrounds. They form an integral part of the Department’s research life and numbers have risen to over 85 PhD students in 2013. At present, the Department manages a PhD Course in Civil, Chemical, Environmental and Materials Engineering (PhD@DICAM). The course aims to provide the PhD candidates with the skills required by managing authorities, engineering offices, firms, companies, private and public research centres, etc. Moreover, the doctoral programme provides students with research experience, the opportunity to pursue advanced studies in engineering fields (broadly defined), familiarity with appropriate methods and theories, and participation in an active research community. The scientific topics of PhD@DICAM are those characterizing the major disciplines in the field of Civil Engineering, Chemical and Process Engineering, Environmental Engineering, Materials Engineering and Industrial Biotechnologies. The PhD course covers a 3-year period and helps the candidates to build up and improve their base and specialized knowledge, through the development of an original and autonomous research activity. Periods of study and research abroad are also expected. Curricula and research areas The PhD Course is characterized by several disciplines in which the research can be developed: 1) Infrastructures, Resources and Land engineering: Hydraulics and Hydraulic works, Sanitary Engineering, Roads and Transports, Topography and Cartography, Geoengineering and Georesources, Applied Geology. 2) Structural and Geotechnical Engineering: Continuum Mechanics, Structures, Geotechnics. 3) Chemical and Process Engineering: Principles of Chemical Engineering, Chemical Plants, Fundamental of Chemical Process Development, Industrial and Technological Chemistry. 4) Materials Engineering & Industrial Biotechnology: Fundamental Chemistry of Technologies, Materials Science and Technology, Industrial and Environmental Biotechnologies, Applied Physical Chemistry. Training: Our PhD training aims to provide students with a qualification of international standing that is suited for an industrial or academic career. To achieve this, we complement work on the research project with Departmental base courses or modules on relevant topics, shared by different curricula, and specialized courses specific for each educational path. Specialized courses are defined also according to the specific targets of the research activity developed by each candidate. Research: Our PhD students are encouraged to interact with researchers working in different areas and are co-supervised by academics of the Department. Such interdisciplinary training fosters the intellectual capabilities and practical skills needed to cooperate with engineers and scientists from a variety of academic backgrounds. Research is carried out in three phases. The first one is aimed at properly setting up the research program, through an accurate literature overview and the planning of the specialized courses, and usually takes place in the first year in parallel with the courses. The second phase consists 14 Research Projects and Activities 2015 in an autonomous development of the research activity, through analyses, experimental tests and/or surveys in the field. This phase usually goes from the third to the fifth semester. The third phase is devoted to results dissemination and to the preparation of the final thesis. Fabio Fava Coordinator of PhD@DICAM 15 DICAM – Department of Civil, Chemical, Environmental and Materials Engineering School of Architecture and Engineering, new Building, Via del Lazzaretto School of Architecture and Engineering, historical building, Viale Risorgimento 17 DICAM – Department of Civil, Chemical, Environmental and Materials Engineering 18 DICAM – Department of Civil, Chemical, Environmental and Materials Engineering 19 DICAM – Department of Civil, Chemical, Environmental and Materials Engineering 20 RESEARCH PROJECTS AND ACTIVITIES 2015 Diffusion in Polymers and Membrane Separations Diffusion in Polymers and Membrane Separations – Separation of Liquids with Membranes MEMBRANES AND MEMBRANE PROCESSES FOR LIQUID MIXTURES RESEARCH GROUP: Serena Bandini, Carlo Gostoli, Valentina Morelli KEYWORDS: membrane processes, liquid mixtures, process development, Nanofiltration, food industry The activity focuses on membrane processes (Microfiltration (MF), Ultrafiltration (UF), Nanofiltration (NF), Reverse Osmosis (RO), Forward Osmosis (FO), Electrodialysis (ED)) for innovative separation and reaction techniques based on polymeric, inorganic and composite membranes for food, energy and process industry applications. Research activity is carried out on: i) experimental characterization of membrane properties and of membrane performances, ii) transport and partitioning phenomena modeling, iii) module performances characterization and iv) process development to industrial scale. The activities are in cooperation with international universities and industries and can be described as follows. General assessment of NF modeling. Development of a partitioning- transport model of electrolyte/ neutral solutes mixtures in NF membranes, accounting Donnan equilibrium, Dielectric Exclusion and hindered mass transport. The studies are basen on a wide experimentation on membrane performances and electrochemical characterization of membrane material. Nanofiltration in food industry. NF is a potential alternative to RO and UF for concentration operations. Pre-concentration of milk and/or whey for the production of iposodic cheese was developed. Separation of simple sugars from complex sugar mixtures and process development on industrial scale was patented in cooperation with a company. Separation of isomers by NF membranes is under investigation also. New frontiers in membrane engineering. New methods for energy production, new apparatuses including reaction and separation steps, new compact devices to perform conventional unit operations without flooding, channeling or backmixing problems are among the future challenges. New inorganic and composite membranes are under investigation to produce energy by Forward Osmosis or Reverse Electrodyalisis. A pilot plant for milk Nanofiltration. 25 Research Projects and Activities 2015 site-binding and competitive adsorption in determining the charge of nanofiltration membranes, Desalination, 241 (2009) 315-330. MAIN PUBLICATIONS G. Mucchetti, G. Zardi, F. Orlandini, C. Gostoli, The pre-concentration of milk by Nanofiltration in the production of fresh cheese Quarg type. Le Lait 80(2000)43-50. C. Mazzoni, F. Orlandini, S. Bandini, Role of the electrolyte type on TiO2 – ZrO2 nanofiltration membranes performances, Desalination, 240 (2009) 227-235. S.Bandini, Nafion Membranes for Conversion of Sodium Phenoxides into Undissociated Phenols, J. Membrane Sci., 207 (2002) 209-225. A.Szymczyk, P.Fievet, S.Bandini, On the Amphoteric Behavior of Desal DK Nanofiltration Membranes at Low Salt concentrations , J. Membrane Sci. 355 (2010) 60-68. S.Bandini, D.Vezzani, Nanofiltration modeling: the role of dielectric exclusion in membrane characterization, Chem. Eng. Sci., 58 (2003) 3303-3326 S.Bandini, L.Bruni, Transport phenomena in Nanofiltration membranes, in “Comprehensive Membrane Science and Engineering”, vol. 2: “Membrane operations in molecular separations”, (2010), 67-89, Oxford: Ac. Press, Elsevier. S.Bandini, J.Drei, D.Vezzani, The role of pH and concentration on the ion rejection in polyamide nanofiltration membranes, J. Membrane Sci, 264 (2005), 65-74. PATENTS S.Bandini, Modelling the mechanism of membrane charge formation in NF membranes: Theory and application, J. Membrane Sci., 264 (2005), 75-86. G. Mucchetti, C. Gostoli, D. Carlini, F. Orlandini, G. Zardi, G. Potena, Procedimento di preparazione di formaggio fresco da latte concentrato mediante Nanofiltrazione. Patent N. BO99A000269 Filed on 19/5/1999. S.Bandini, C.Mazzoni, Modelling the amphoteric behaviour of polyamide nanofiltration membranes, Desalination, 184 (2005) 1307-1316. Bandini S., Ketsman J., Nataloni L., Sanchez S., Process for increasing yield of Dextrose production process, by membrane technology, Application number: 12006676.6 - 2101/ EP12006676. Filed on 24/09/2012 with European Patent Office -Munich C. Gostoli, G. Mucchetti, New types of fresh cheese obtained by nanofiltration of milk and whey, in: E. DRIOLI, W. WEI, Sino-Italian workshop on the application of membrane technology in food processing, WEIHAI, 2005, pp. 61-64. C.Mazzoni, S.Bandini, On Nanofiltration Desal-5 DK performances with calcium chloride-water solutions, Separation & Purification Technology, 52 (2006) 232-240. RESEARCH PROJECTS Nanofiltration for the production of fresh cheese (NANOFRESH), 2000-2001, EU- Regione Emilia Romagna, C. Gostoli. C.Mazzoni, L.Bruni, S.Bandini, Nanofiltration: role of the electrolyte and pH on Desal DK performances, Industrial and Engineering Chemistry Research Journal, 46 (2007) 2254-2262. Analisi di fattibilità tecnica per l’arricchimento del destrosio in acque madri tramite Nanofiltrazione. Convenzione di ricerca tra DICMA e Cargill srl (SSE BUSINESS UNIT – Castelmassa (RO)) (2010-2012). L.Bruni, S.Bandini, The role of the electrolyte on the mechanism of charge formation in polyamide nanofiltration membranes, J. Membrane Sci. 308 (2008)136-151. CONTACTS [email protected] [email protected] L.Bruni, S.Bandini, Studies on the role of 26 Diffusion in Polymers and Membrane Separations – Separation of Liquids with Membranes MEMBRANE CONTACTORS RESEARCH GROUP: Serena Bandini, Carlo Gostoli, Felipe Varela Coredor KEYWORDS: membrane contactors, mass transfer operations, membrane reactors, pertraction, wine processing Membrane Contactors (MC) are mass transfer devices that allow two phases to come in contact without dispersion of one phase into the other. The membrane acts as a mere physical support for the interface and does not contributes to the separation through its selectivity, the separation being primarily based on the principle of phase equilibrium. The macroporous membrane, usually in the shape of hollow fibres, may be either hydrophilic or hydrophobic; the interface is immobilized at the pore mouth on the side in contact with the non-wetting phase, whereas the pores are filled by the wetting phase. Polymeric membranes were usually employed in membrane contactor studies and applications, especially Polypropylene and PVDF. Recently increasing efforts have been devoted to develop ceramic membranes, or hybrid membranes to get better chemical and thermal stability as well as higher mechanical strength. Membrane surface modification techniques to improve the hydrophobicity has also been investigated. The research group performed fundamental investigation on mass transfer rate in MC, especially in the shell side of hollow fibre modules as well as in strictly related processes, as Membrane Distillation and Osmotic Distillation. The applications considered are typical of chemical and process engineering as well as of food and biotechnology industry: - recovery of bioproducts (Vanillin) from fermentation broths by using selective solvents; - removal of Volatile Organic Compounds from - aqueous streams and/or solvent recovery; - membrane reactors: chemical reactions and stripping operations for absorbents regeneration at high temperature and average pressures. - alcohol level adjustment of wines; production of alcohol free wine; - juices concentration at room temperature. Membrane contactor: operation concept with hydrophobic membranes. Pilot plant for fruit juice concentration and ethanol removal from wine. 27 Research Projects and Activities 2015 C. Boi, S.Bandini, G.C.Sarti, Pollutants removal from wastewaters through membrane distillation, Desalination, 183 (2005) 899-910. MAIN PUBLICATIONS C. Gostoli, R. Ferrarini, Applications of osmotic distillation in food and wine processing: the critical points, their weaknesses and the potentialities, in: E. Dioli, G. Di Profio, M.A. Liberti, proc. of: International Workshop on Membrane Distillation and Related Technologies, Ravello (SA) – Italy, October 9-12, 2011) pp. 80-82. M. Celere, Gostoli C., Osmotic distillation with propylene glycol, glycerol and glycerol-salt mixtures, J.Membrane Sci , 229 (2004)159-170. A. Versari, R. Ferrarini, G.B. Tornielli, G.P. Parpinello, C. Gostoli, E. Celotti, Treatment of grape juice by osmotic distillation, J. of Food Sci., 10 (2004), E422 - E427. C. Gostoli, Recovery of Biosynthetic Products Using Membrane Contactors, in: Hironori Nakaajima, Mass Transfer - Advanced Aspects, Rijeka, InTech d.o.o., 2011, pp. 619 -644. Celere M., Gostoli C., The heat and mass transfer phenomena in osmotic membrane distillation, Desalination 147(2002) 133-138 Sciubba L., Di Gioia D., Fava F., Gostoli C., Recovery of vanillin obtained via microbial bioconversion using membrane contactors, in: International Biotechnology Simposium and Exhibiotion IBS 2010, S.N., s.n, 2010, pp. F119, Rimini, 14-18 September 2010). C. Gostoli, Thermal Effects in Osmotic Distillation, J.Membrane Sci. 163/1(1999)75-91. S.Bandini, A.Saavedra and G.C. Sarti, Vacuum Membrane Distillation: Experiments and Modeling. AIChE J., 43 (1997) 398-408. L. Sciubba, D. Di Gioia, F. Fava, C. Gostoli, Recovery of vanillin obtained via microbial bioconversion using membrane contactors, J. Biotechnology, 150, (2010) 340. RESEARCH PROJECTS Attività di test di moduli di Membrane Contactors Ceramici - Progetto di ricerca n. 658283 Convenzione fra DICMA e SAIPEM (Milano), responsabile Serena Bandini, 2012-2014 Sciubba L., Di Gioia D., Fava F., Gostoli C., Membrane-based solvent extraction of vanillin in hollow fiber contactors, Desalination 241 (2009) 357-364. Sviluppo di processi a membrana in Enologia, Convenzione tra DICMA e Juclas S.r.l. (Verona), responsabile Carlo Gostoli, 2011-2012 Ferrarini R., Bocca E., Gostoli C., Membrane techniques for the product quality and identity, in: Preceedings of XXXI World Congress of Vine and Wine, PARIS, OIV (International Organization of Vine and Wine), 2008, pp. 185-191 Dealcolazione di vini con tecnologie a membrana, Convenzione fra DICMA e Terranera S.r.l. (Grottolella, AV), responsabile Carlo Gostoli, 2007-2008. Sciubba L., Di Gioia D., Fava F., Gostoli C., Membrane based solvent extraction of vanillinin hollow fiber contactors, in: BEKASSY-MOLNAR, BELAFI-BAKO, PERMEA 2007, Membrane Science and Technology Conference of Visegrad Countries, pp. 1-5, Siofok (H), Sept. 2-6 2007. Pilot plant for juice concentration by direct osmosis, CONFROD Project, 1999-2000, Progetto cofinanziato con fondi Europei nell’ambito della misura 1.6 (sviluppo dell’innovazione) Obiettivo 2, della Regione Emilia Romagna, responsabile Carlo Gostoli Bruni L., Gostoli C., Membrane Contactors in Wine Processing, in: BEKASSI-MOLNAR, BELAFI-BAKO, PERMEA 2007, Membrane Science and Technology Conference of Visegrad Countries, Siofok (H), Sept. 2-6 2007 Study of a Process for the Production of Superior Quality Juices, U. E. (BRITE/EURAM), contract N. BRE2-CT94-1499, 1 February 1995 - 31 January 1997, Italian Coordinator: Carlo Gostoli. M. Celere, C. Gostoli, Heat and mass transfer in osmotic distillation with brines, glycerol and glycerol-salt mixtures, J.Membrane Sci. 257 (2005) 99110. CONTACTS [email protected] [email protected] 28 Diffusion in Polymers and Membrane Separations – Membrane Bioseparations BIOMOLECULES PURIFICATION WITH AFFINITY MEMBRANES: EXPERIMENTAL AND THEORETICAL STUDIES RESEARCH GROUP: Cristiana Boi, Giulio Cesare Sarti KEYWORDS: affinity membranes, monoliths, chromatography, protein purification, mathematical modelling The aim of the research is the purification of biomolecules for therapeutic use, biomedical and biotechnology applications using affinity convective chromatography. In this area two classes of separations are considered: purification of biomolecules and selective apheresis. The research activity is both experimental and theoretical, with a particular emphasis on mathematical modelling. The experimental activity is focused on the functionalization and characterization of membranes and other chromatographic supports for purification of virus, monoclonal antibodies, proteins and different biomolecules. The choice of appropriate materials, membranes, ligands and spacer arms, is the first step towards the development of affinity membranes. Ligand immobilization is the critical step of the process, since the ligand needs to maintain its functionality while immobilized on the support. The choice of the spacer arm, that acts as a linker between membrane and ligand is crucial for the process. Affinity membranes are initially characterized in batch using pure protein solutions, then the protein of interest is purified from the complex solution (e.g. surnatant of cell culture or serum) where it originates. The experimental characterization is mainly performed using a low pressure chromatographic system, FPLC, in which columns with the solid supports to be characterized (beads, membranes or monoliths) are operated. The relevant transport parameters and the kinetic parameters of adsorption and elution are determined from the experimental data, it is important to note that kinetic parameters need to be determined for every protein/ligand system. A mathematical model has been developed for the description of the whole chromatographic cycle: adsorption, washing and elution. Model validation has been performed with experimental data obtained with a bench scale apparatus for different affinity systems, using both membranes and monoliths, with different proteins and ligands. Scale-up studies using the model as a predictive tool for bioprocess design are also performed. 29 Fig. 1. Some of the laboratory instruments of the research group. Fig. 2. Comparison between experimental data (circles) and model results (line) for IgG adsorption on B14-TRZ-Epoxy2 affinity membranes at two different operating conditions. Research Projects and Activities 2015 MAIN PUBLICATIONS Progress, 24 (2008) 640-647. C. Boi, S. Dimartino, G.C. Sarti, S. Williams, S. Hofer, J. Horak, W. Lindner, Influence of different spacer arms on A2P affinity membranes for human IgG capture, Journal of Chromatography B, 879 (2011) 1633-1640. C. Boi, Membrane adsorbers as purification tools for monoclonal antibody purification, Journal of Chromatography B 848 (2007), 19-27. C. Boi, S. Dimartino, G.C. Sarti, Modelling and simulation of affinity membrane adsorption, Journal of Chromatography A, 1162 (2007) 2433. S. Dimartino, C. Boi, G. C. Sarti, Influence of protein adsorption kinetics on breakthrough broadening in membrane affinity chromatography, Journal of Chromatography A, 1218 (2011) 3966-3972. C. Boi, G.C. Sarti, Development and characterisation of affinity membranes for immunoglobulin purification, Separation Science and Technology, 42:13 (2007) 2987-3001. S. Dimartino, C. Boi, G.C. Sarti, A novel model for the simulation of protein purification through affinity membrane chromatography, Journal of Chromatography A, 1218 (2011) 1677-1690. C. Boi, F. Cattoli, R. Facchini M. Sorci, G.C. Sarti, Adsorption of lectins on affinity membranes, Journal of Membrane Science 273 (1-2), (2006), 12-19. C. Boi, V. Busini, M. Salvalaglio, C. Cavallotti, G.C. Sarti, Understanding ligand–protein interactions in affinity membrane chromatography for antibody purification, Journal of Chromatography A, 1216 (2009) 8687-8696. F. Cattoli, C. Boi, M. Sorci, G.C. Sarti, Adsorption of pure recombinant MBP-fusion proteins on amylose affinity membranes, Journal of Membrane Science 273 (1-2), (2006), 2-11. C. Boi, S. Bandini, G.C. Sarti, Pollutants removal from wastewaters through membrane distillation, Desalination 183 (1-3), (2005), 383-394. C. Boi, C. Algeri, G.C. Sarti, Preparation and characterization of polysulfone affinity membranes bearing a synthetic peptide ligand for the separation of murine immunoglobulins, Biotechnology Progress, 24 (2008) 1304-1313. RESEARCH PROJECTS EU FP6 NMP3-CT-2004-500160, Project: AIMs “Advanced Interactive Materials by Design”. C. Boi, S. Dimartino, G.C. Sarti, Experimental and simulation analysis of membrane adsorbers used for the primary capture step in antibody manufacturing. Chemical Engineering Transactions, ISBN: 889560802X, Vol. 14 (2008), pp. 91-96. IT PRIN 2008, Project: “Sviluppo di membrane di affinità per anticorpi monoclonali”. CONTACTS C. Boi, S. Dimartino, G.C. Sarti, Performance of a new Protein A affinity membrane for the primary recovery of antibodies, Biotechnology [email protected] [email protected] 30 Diffusion in Polymers and Membrane Separations – Gas Separation with Membranes GAS SEPARATION WITH POLYMERIC MEMBRANES RESEARCH GROUP: Luca Ansaloni, Matteo Minelli, Maria Grazia De Angelis, Marco Giacinti Baschetti, Giulio C. Sarti, Ferruccio Doghieri KEY WORDS: gas separation, CO2 capture, membranes, gas transport properties Membranes based on polymeric materials are known to offer a selective ability towards different gases and vapours. Membrane separations represent a clean and economic way to replace traditional separation and purification technologies based on high pressure or temperature gradients and on phase change. The research activity focuses on the characterization and modeling of the gas permeation into commercial as well as innovative membranes in order to design specific separation processes and to optimize material properties. The research is carried out in combination both with the final users of the separation processes, either in the industrial or pilot plant scale, and with material manufacturers and chemists. Separation of interest include: CO2 removal from natural gas, biogas or flue gas, purification of hydrogen from steam reforming or from fermentation (biohydrogen), separation of hydrocarbons from light gases, etc. The research also includes macroscopic modeling of the mass transport properties allowing to gain a deep understanding of the separation process. The current activity is particularly focused on: 1) Polyimide membranes (e.g. Matrimid) which exhibit good thermal and mechanical properties and interesting performances in CO2/CH4 and CO2/N2 separations. 2) high free volume glassy polymers (PTMSP, polynorbornenes, polymer of intrinsic microporosity PIM, Amorphous Teflon), with high gas permeability and selectivity. 3) mixed matrix membranes based on glassy polymers and nano-sized silica particles that enhances the permeation rates of gases, with different effects on selectivity. 4) rubbery polymers based on ethylene oxide or propylene oxide with high solubility for CO2. The lab is equipped with pure and mixed gas permeometers, balances and pressure decay devices for pure and mixed gas sorption. Also polymer swelling can be monitored. The research is carried on in collaboration with several Italian and Foreign groups. 31 Fig.1 a) effect of temperature and water absorbed on the gas permeability in Nafion® N117; b) effect of butane pressure and amount of silica filler on the butane permeability in Amorphous Teflon AF2400 mixed matrix membrane. Research Projects and Activities 2015 Giacinti Baschetti M., Ghisellini M., Quinzi M., Doghieri F., Stagnaro P., Costa G., Sarti G.C. (2005). Effects on sorption and diffusion in PTMSP and TMSP/TMSE copolymers of free volume changes due to polymer ageing. Journal of Molecular Structure 739, 75-86. MAIN PUBLICATIONS Minelli M., Friess K., Vopicka O., De Angelis M.G. (2013) Modeling gas and vapor sorption in a Polymer of Intrinsic Microporosity (PIM1). Fluid Phase Equilibria 347, 35-44. Minelli M., Giacinti Baschetti M. Hallinan D.T., Balsara N.P. (2013) Study of Gas Permeabilities through Polystyrene-block-poly(ethylene oxide) Copolymers. Journal Of Membrane Science 432, 83-89. De Angelis M.G., Sarti G.C., Sanguineti A., Maccone P. (2004). Permeation, Diffusion, and Sorption of Dimethyl Ether in Fluoroelastomers. Journal of Polymer Science. Part B, Polymer Physics 42, 1987-2006. Galizia M., De Angelis M.G., Sarti G.C., Finkelshtein E., Yampolskii Y. (2011, 2012). Sorption of hydrocarbons and alcohols in addition-type poly(trimethyl silyl norbornene) and other high free volume glassy polymers. I. experimental data; II: NELF model predictions. Journal of Membrane Science 385-386, 141-153 and 405-406, 201-211. De Angelis M.G., Merkel, T.C., Bondar, V.I., Freeman, B.D., Doghieri, F. Sarti, G.C. (2002). Gas Sorption and Dilation in Poly(2,2-bistrifluoromethyl-4,5- difluoro -1,3- dioxole-co-tetrafluoroethylene): Comparison of Experimental Data with Predictions of the Non Equilibrium Lattice Fluid Model. Macromolecules 35, 1276-1288. Catalano J., Myezwa T., De Angelis M.G., Giacinti Baschetti M., Sarti G.C. (2012). The effect of relative humidity on the gas permeability and swelling in PFSI membranes. International Journal of Hydrogen Energy 37, 6308-6316. RESEARCH PROJECTS BIOHYDRO 2010-2012: Combined biological production of methane and hydrogen from wastes of the agro-food industry Ferrari M.C., Galizia M., De Angelis M.G., Sarti G.C. (2010). Gas and Vapor Transport in Mixed Matrix Membranes Based on Amorphous Teflon AF1600 and AF2400 and Fumed Silica. Industrial & Engineering Chemistry Research 49 11920-11935. Accordo di Programma MSE-ENEA sulla Ricerca di Sistema Elettrico: “Studio di membrane polimeriche e processi a membrana per l’arricchimento in metano del biogas” 2011-2012. Fossati P., Sanguineti A., De Angelis M.G., Giacinti Baschetti M., Doghieri F., Sarti G.C. (2007). Gas solubility and permeability in MFA. Journal Of Polymer Science. Part B, Polymer Physics 45, 1637-1652 FP6 Project: Multimat Design 2005-2008: Computer aided molecular design of multifunctional materials with controlled permeability properties. Convenzione CNR, progetto “Carbone pulito” PAR 2011. CONTACTS Prabhakar R.S., De Angelis M.G., Sarti G.C., Freeman B.D., Coughlin M.C. (2005). Gas and Vapor Sorption, Permeation, and Diffusion in Poly(tetrafluoroethylene-co-perfluoromethyl vinyl ether). Macromolecules 38, 7043-7055. [email protected] [email protected] [email protected] [email protected] 32 Diffusion in Polymers and Membrane Separations – Gas Separation with Membranes MEMBRANES FOR ENERGY APPLICATIONS RESEARCH GROUP: Giulio C. Sarti, Marco Giacinti Baschetti, Maria Grazia De Angelis KEYWORDS: proton exchange membrane fuel cells (PEMFC), ionomers, hydrogen, palladium membranes The activity focuses on the study of novel techniques for the processing of new energy carriers (hydrogen) and the optimization of new energy production devices (fuel cells). Palladium Membranes for Hydrogen purification. Hydrogen is one of the most promising energy carriers, due to its intrinsically clean combustion and possible use in fuel cells. Hydrogen is mainly produced by the reforming of natural gas; an efficiency increase in that process is a first step toward a more sustainable future. Palladium membranes can be used to purify hydrogen produced via steam reforming, reducing costs and improving efficiency of the whole process, due to high permeability and selectivity, and lower energy consumption than currently used systems (e.g. pressure swing absorber). Moreover membrane systems and can be assembled within the steam reforming reactor, to increase the reaction efficiency and yield. The activity is aimed at testing and modeling transport of hydrogen-containing mixtures in palladium membranes, in order to design the most appropriate membranes and modules in a real separation environment, in the presence of poisoning gases, such as CO and water vapour. Ionomer Membranes for Fuel Cells. Proton Exchange Membranes Fuel Cells (PEMFCs) are energy production devices that use hydrogen (or methanol) as fuel and polymeric membranes as electrolytes (e.g. Nafion®, Aquivion®). The membrane conductivity depends on the humidity absorbed and the study of mass transport through the membrane is essential for controlling its performance. The activity is focused at the experimental and theoretical study of fluid transport through membranes as a function of operative conditions and membrane properties, especially at temperatures above 60°C as they allow the use of alternative fuels and reduce electrode catalyst poisoning. The analysis is carried out with the aid of infrared spectroscopy, dry and humid gas permeometers, balances and pressure decay devices for sorption, TGA measurements. 33 Fig. 1. Rubotherm Magnetic Balance for hydrogen transport in palladium membranes. Fig. 2. Relative permeability of gases in humidified Nafion® N117 membranes for fuel cells, versus water volume fraction in the membrane. Research Projects and Activities 2015 branes deposited on ceramic supports. Journal of Membrane Science 325(1), 446-453. MAIN PUBLICATIONS Ferrari M.C., Catalano J., Giacinti Baschetti M., De Angelis M.G., Sarti G.C. (2012). FTIR-ATR Study of Water Distribution in a Short-Side-Chain PFSI Membrane. Macromolecules 45, 1901-1912. D. Gorri, MG De Angelis, M Giacinti Baschetti, GC Sarti (2008). Water and methanol permeation through short-side-chain perfluorosulphonic acid ionomeric membranes, Journal of Membrane Science 322, 383-391. Catalano J., Myezwa T., De Angelis M.G., Giacinti Baschetti M., Sarti G.C. (2012). The effect of relative humidity on the gas permeability and swelling in PFSI membranes. International Journal of Hydrogen Energy 37, 6308-6316. Y. Yamamoto, M. C. Ferrari, M. Giacinti Baschetti, M. G. De Angelis, G. C. Sarti (2006). A quartz crystal microbalance study of water vapor sorption in a short side-chain PFSI membrane, Desalination 200 (1-3), 636-638 Catalano, J., Giacinti Baschetti, M., Sarti, G. C. (2011). Influence of water vapor on hydrogen permeation through 2.5 μm Pd–Ag membranes. International Journal of Hydrogen Energy 36, 8658-8673. M.G. De Angelis, S. Lodge, M. Giacinti Baschetti, G.C. Sarti, F. Doghieri, A. Sanguineti, P. Fossati (2006). Water sorption and diffusion in a short-side-chain perfluorosulfonic acid ionomer membrane for PEMFCS: effect of temperature and pre-treatment. Desalination 193, 398-404. Catalano, J., Giacinti Baschetti, M., & Sarti, G. C. (2010). Hydrogen permeation in palladium-based membranes in the presence of carbon monoxide. Journal of Membrane Science 362(12), 221-233. RESEARCH PROJECTS FISR DM 17/12/2002 “Idrogeno puro da gas naturale mediante reforming a conversione totale ottenuta integrando reazione chimica e separazione a membrana. Funded by the Italian government through the “Contributo del Fondo Integrativo Speciale Ricerca” (2005-2009). Hallinan DT, De Angelis MG, Giacinti Baschetti M, Sarti GC, Elabd Yossef A. (2010). Non-Fickian Diffusion of Water in Nafion, Macromolecules 43, 4667-4678. Coroneo, M., Montante, G., Giacinti Baschetti, M., Paglianti, a. (2009). CFD modelling of inorganic membrane modules for gas mixture separation. Chemical Engineering Science, Vol. 64(5), pp. 1085-1094. Sviluppo di una filiera integrata dell’idrogeno per lo sfruttamento delle fonti energetiche alternative e la decarbonizzazione. Funded within the “Accordo Programma Quadro tra il Ministero dello Sviluppo Economico, il Ministro dell’Università e della Ricerca e la Regione Emilia-Romagna - II Integrativo - Sostegno allo sviluppo dei laboratori di ricerca nei campi della nautica e dell’energia per il Tecnopolo di Ravenna” (2012-2013). Catalano J., Giacinti Baschetti M., De Angelis M.G., Sarti G.C., Sanguineti A., Fossati P. (2009). Gas and water vapor permeation in a short-side-chain PFSI membrane. Desalination 240, 341-346. Catalano, J., Giacinti Baschetti, M., Sarti, G. C. (2009). Influence of the gas phase resistance on hydrogen flux through thin palladium–silver membranes. Journal of Membrane Science, 339(1-2), 57-67. Funded Collaboration with Ausimont (20002005) and Solvay-Solexis (2005-2009). CONTACTS [email protected] marco,[email protected] [email protected] Pizzi, D., Worth, R., Giacinti Baschetti, M., Sarti, G. C., Noda, K.-ichi. (2008). Hydrogen permeability of 2.5μm palladium–silver mem- 34 Diffusion in Polymers and Membrane Separations – Gas Separation with Membranes SUSTAINABLE PACKAGING MATERIALS WITH IMPROVED BARRIER PROPERTIES RESEARCH GROUP: Matteo Minelli, Maria Grazia De Angelis, Marco Giacinti Baschetti, Ferruccio Doghieri KEYWORDS: barrier properties, nanocomposite materials, hybrid organic/inorganic materials, biodegradable packaging materials, PLA, nanocellulose The research activity on packaging materials started in early 2000s with the participation to National projects and networks aggregating different synthesis and characterization groups around the idea of building barrier nanocomposites as well as hybrid organic/inorganic coatings for traditional packaging materials. The goal was to reduce the amount of material required to protect the packaged goods against oxygen, humidity and other fluids passing through the film. In 2004 the group joined a large collaborative FP6 project named SUSTAINPACK which was specifically devoted to the development of new, sustainable eco-friendly composite packaging materials based on natural substances: cellulose, polylactic acid, and so on. The activity on sustainable packaging as then never stopped and is still ongoing due to constant collaboration with other European entities within different european project such as the International training netweork NEWGENPAK and COST Action BIOMATPACK, as well as in collaborations with other Italian Universities. In this research field the group is currently involved in the study of barrier properties of microfibrillated cellulose (MFC) and is higly specialised in the characterization of gas permeability in packaging materials, both in dry and humid conditions, as well as in the measurement of moisture absorption at different temperatures. Several modelling tools based on both numerical and analytical approach are available to describe the experimental data with particular reference to the case of nanocomposites materials. Apart from these activities in the same framework also other research are carried out such as the study of corrosion protective coatings or of polymer swelling during sorption. a)b) Fig. 1. Schematic of a random nanocomposite system (a) and calculated O2 concentration profile inside it (b). Fig. 2. Effect of water humidity on O2 permeability in microfibrillated cellulose (MFC) films. 35 Research Projects and Activities 2015 ings: I. Effects of organic–inorganic ratio and molecular weight of the organic component, European Polymer Journal, 44, pp. 2581-2588. MAIN PUBLICATIONS Minelli M., Giacinti Baschetti M., Doghieri F. (2011). A comprehensive model for mass transport properties in nanocomposites, Journal of Membrane Science, 381, pp. 10 - 20. Toselli M., Pilati F., Marini M., Doghieri F., De Angelis M.G., Minelli M. (2008). Oxygen permeability of novel organic–inorganic coatings: II. Modification of the organic component with a hydrogen-bond forming polymer, European Polymer Journal, 44, pp. 3256-3263 Deflorian F., Fedel M., Dirè S., Tagliazucca V., Bongiovanni R., Vescovo L., Minelli M., De Angelis M.G. (2011). Study of the effect of organically functionalized silica nanoparticles on the properties of UV curable acrylic coatings, Progress In Organic Coatings, 72, pp. 44-51. Malucelli G., Priola A., Amerio E., Pollicino A., di Pasquale G., Pizzi D., De Angelis M. G., Doghieri F. (2007). Surface and barrier properties of hybrid nanocomposites containing silica and PEO segments, Journal Of Applied Polymer Science, 103, pp. 4107-4115. Minelli M., Giacinti Baschetti M., Doghieri F., Ankerfors M., Lindström T., Siró I., Plackett D. (2010). Investigation of mass transport properties of microfibrillated cellulose (MFC) films, Journal of Membrane Science, 358, pp. 67-75. RESEARCH PROJECTS Minelli M., Giacinti Baschetti M., Doghieri F. (2009). Analysis of modeling results for barrier properties in ordered nanocomposite systems, Journal of Membrane Science, 2009, 327, pp. 208-215. NEWGENPAK Marie Curie Initial Training Network:” New Generation of Functional Cellulose Fibre Based Packaging Materials for Sustainability” BIOMATPACK COST ACTION “Impact of Renewable Materials in Packaging for Sustainability: Development of Renewable Fibre and Bio-based materials for New Packaging Applications” Minelli M., De Angelis M.G., Doghieri F., Rocchetti M., Montenero A. (2010). Barrier properties of organic-inorganic hybrid coatings based on polyvinyl alcohol with improved water resistance, Polymer Engineering and Science, 50, pp. 144-153 FP6 Large Collaborative Project SUSTAINPACK (Innovation and Sustainable Development in the Fibre Based Packaging Value Chain) Malucelli G., Amerio E., Minelli M., De Angelis M.G. (2009). Epoxy-siloxane hybrid coatings by a dual-curing process, Advances In Polymer Technology, 28, pp. 77-85 CONTACTS [email protected] [email protected] [email protected] [email protected] Minelli M., De Angelis M.G., Doghieri F., Marini M., Toselli M., Pilati F. (2008). Oxygen permeability of novel organic–inorganic coat- 36 Diffusion in Polymers and Membrane Separations – Diffusion in Polymers and Modelling MODELLING SOLUBILITY IN POLYMERS RESEARCH GROUP: Giovanni Cocchi, Matteo Minelli, Maria Grazia De Angelis, Marco Giacinti Baschetti, Giulio C. Sarti, Ferruccio Doghieri KEYWORDS: solubility, glassy polymers, non equilibrium, thermodynamics, polymer solutions. The solubility of fluids in polymers is relevant in many industrial applications such as membrane separations and packaging, as well as polymer processing and technology (desolventization, CO2 and solvent foaming). Starting from mid1990s, the group has developed a model specifically devoted to the prediction of solubility in glassy polymers named Non Equilibrium Thermodynamics for Glassy Polymers (NET-GP) and the relative versions NELF, NE-SAFT, NEPHSC which adopt the concepts of the Lattice Fluid (LF), SAFT and PHSC equations of state, respectively. Such approach indeed adopts, to identify univocally the out-of- equilibrium state of the system, the density of the glassy phase, and allows to extend to the non equilibrium domains the most accurate equation of state (EoS) models available for polymeric systems, such as the Lattice Fluid theory (LF), the Statistical Associating Fluid Theory (SAFT) and the related Perturbed Hard Sphere Chain theory (PHSC) model. The system parameters can be taken from the literature, from experimental data or molecular simulations. The approach has been applied to the prediction of pure and mixed gas, vapor and liquid solubility in glassy polymers in a wide range of temperatures and pressures. The approach can be applied to homopolymers, polymer blends and block copolymers, as well as to composite materials (mixed matrix membranes), and can span at temperatures above and below Tg. The approach can account for the effects of history and processing conditions on the sorption properties, and it has been recently implemented with molecular techniques to obtain the parameters of poorly characterized polymers. The model is downloadable from the group website and is interfaced to an user-friendly Excel spreadsheet, containing also a large database with the parameters of several fluids and polymers. Fig. 1. below: CO2 solubility in blends of Polystyrene and Poly(phenylene oxide) (PS/PPO) at 35°C, lines are NELF model prediction based on binary mixture data only (PS- CO2 and PPO-CO2), reported in the figure above. Fig. 2. Infinite dilution solubility coefficient of CO2 in polycarbonate at infinite dilution as a function of reciprocal temperature. Dashed line: SAFT EoS; Solid line: NE-SAFT model. 37 Research Projects and Activities 2015 in glassy polymer blends, In: I. Pinnau; B. Freeman, Advanced Materials For Membrane Separations, New York, Oxford Univ. Press, pp. 55-73. MAIN PUBLICATIONS M. Minelli, G. Cocchi, L. Ansaloni, M. Giacinti Baschetti, M.G. De Angelis, F. Doghieri (2013). Vapor and Liquid Sorption in Matrimid Polyimide: Experimental Characterization and Modeling. Ind. Eng Chem. Res., 52, pp. 8936-8945. Giacinti Baschetti, M., Doghieri, F., Sarti, G.C. (2007). Solubility in glassy polymers: correlations through the non-equilibrium lattice fluid model, Industrial and Engineering Chemistry Research, Vol. 40, 3027-3037. Minelli M., De Angelis M.G., Hofmann D. (2012). A novel multiscale method for the prediction of the volumetric and gas solubility behavior of high-Tg polyimides, Fluid Phase Equilibria, 333, pp. 87-96. Sarti G.C., Doghieri F. (1998). Prediction of the solubility of gases in glassy polymers based on the NELF Model, Chemical Engineering Science, 53, 3435-3447. Sarti G.C., De Angelis M.G. (2012). Calculation of the solubility of liquid solutes in glassy polymers, AIChE Journal, 58, pp. 292-301. Doghieri F., Sarti G.C. (1998). Predicting the Low-pressure solubility of gases and vapors in glassy polymers by the NELF model, Journal of Membrane Science, 147(1), 73-86. Minelli M., Campagnoli S., De Angelis M.G., Doghieri F., Sarti G.C. (2011). Predictive model for the solubility of fluid mixtures in glassy polymers, Macromolecules, 44, pp. 4852-4862. Doghieri F., Sarti G.C. (1996). Non-equilibrium lattice fluids - A predictive model for the solubility in glassy polymers, Macromolecules, 29, 78857896. De Angelis M.G., Sarti G.C. (2011). Solubility of gases and liquids in glassy polymers, Annual Review of Chemical and Biomolecular Engineering, 2, pp. 97-120. De Angelis M.G., Sarti G.C., Sanguineti A., Maccone P. (2004). Permeation, Diffusion, and Sorption of Dimethyl Ether in Fluoroelastomers, Journal of Polymer Science. Part B, Polymer Physics, Vol. 42, pp. 1987-2006. De Angelis M.G., Sarti G.C. (2008). Solubility and diffusivity of gases in Mixed Matrix Membranes containing hydrophobic fumed silica: correlations and predictions based on the NELF model, Industrial & Engineering Chemistry Research, 47, pp. 5214-5226. RESEARCH PROJECTS PRIN 08: Characterization and macroscopic modeling of the thermodynamic behavior of binary and ternary polymers/solvent mixtures for the fabrication of biomedical devices through thermally induced phase separation (TIPS). De Angelis M.G., Sarti G.C., Doghieri F. (2007). NELF model prediction of the infinite dilution gas solubility in glassy polymers, Journal of Membrane Science, 289, pp. 106-122. Vigoni 2009: Multiscale prediction of gas solubility in high performance polymers. Doghieri F., De Angelis M.G., Giacinti Baschetti M., Sarti G.C. (2006). Solubility of gases and vapors in glassy polymers modelled through non-equilibrium PHSC theory, Fluid Phase Equilibria, 241(1-2), pp. 300-307. FP6 Project: Multimat Design 2005-2008: Computer aided molecular design of multifunctional materials with controlled permeability properties. Giacinti Baschetti M., De Angelis M.G., Doghieri F., Sarti G.C. (2005). Solubility of gases in polymeric membranes, in: M. A. Galan E. Martin Del Valle, Chemical Engineering - Trends And Developments, Chichester, Wiley & Sons, pp. 41-62. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] Grassia F., Giacinti Baschetti M., Doghieri F., Sarti G.C. (2001). Solubility of gases and vapors 38 Geoengineering and Natural Resources Geoengineering and Natural Resources – Petroleum Engineering, Fluids Mechanic in Porous Media and Nuclear Magnetic Resonance MAGNETIC RESONANCE AND PETROPHYSICAL CHARACTERIZATION OF POROUS MEDIA RESEARCH GROUP: Villiam Bortolotti, Paolo Macini, Ezio Mesini, Marianna Vannini KEYWORDS: MRR, porous media, permeability, wettability, UPEN Nuclear Magnetic Resonance Relaxometry (MRR) is a universally accepted technique for the spatially non-resolved determination of structural and transport properties of porous media in a non-destructive and non-invasive way. It is based on parameters like longitudinal and transverse relaxations time (T1 and T2, respectively) and magnetization density (Mo) and, nowadays, is widely used both in core and log analysis to determine petrophysical properties of rocks, such as porosity, pore size distribution, permeability, wettability changes and irreducible water saturation. Natural rocks are usually heterogeneous and this generally leads to multiexponential relaxation, which we have usually inverted by UpenWin software, to obtain the distribution of local Surface/Volume ratios. UpenWin is a software for Windows internally developed that implements the UPEN (Uniform PENalty) algorithm and is distributed by the University of Bologna. UPEN is a robust algorithm for the inversion of multiexponential decay data, that allows appropriate smoothing of the distribution, allowing sharp peaks without breaking broad features into multiple peaks not required by the data. Magnetic Resonance Imaging (MRI) is a spatially resolved method to get information on the distribution of oil or/and water into the porous medium and to follow flow and absorption of the saturating fluids. A powerful extension of the previous techniques is the Quantitative Relaxation Tomography (QRT), based on the combination of MRR with MRI. QRT generates relaxation time maps, i.e. images where the signal of each voxel (elementary volume, corresponding to the elementary 2D pixel in the image) is proportional to T1 or T2 or Mo of the fluid in that voxel. The research activity of this group is focalized on the use of both MRR and MRI techniques to characterize the petrophysical properties of the porous media, to monitor the saturating fluids flow and to quantify the interaction of the fluids with the surfaces of the pores space. Particularly studied are the wettability and the permeability of rocks, that mainly affects oil recovery, and natural and amended soils. Fig. 1. Magnetic Resonance Tomograph (Esaote, Italy) at the LAGIRN Lab. Fig. 2. Creation of a T2 relaxation times map of a rock sample. Fig. 3. T1 relaxation distribution curve; time evolution of the wettability of a rock sample saturated with acid soltrol. 41 Research Projects and Activities 2015 MAIN PUBLICATIONS studied at pore and sample scale in porous media by portable single-sided and laboratory imaging devices. Journal of Magnetic Resonance, 181: 287-295, 2006. V. Bortolotti, P. Fantazzini, R. Mongiorgi, S. Sauro, S. Zanna. Hydration kinetics of cements by Time-Domain Nuclear Magnetic Resonance: Application to Portland-cement-derived endodontic pastes. Cement And Concrete Research, 42, 3, 577-582, 2012. V. Bortolotti, A. Campagnoli, M. Gombia, P. Fantazzini, G. Barile, C. Masciopinto. Quantitative relaxation tomography (QRT) and field test to estimate a porosity-transmissivity relationship in fractured aquifer. Proceedings of FEM-MODFLOW Conference, September 13-16, Karlovy Vary, Czech Republic, Edited by Karel Kovar, Zbynek Hrkal and Jiri Bruthans, pp 7-10, 2004. A. Bonoli, V. Bortolotti, P. Macini, E. Mesini, M. Vannini. Natural soil mixed with paper mill sludge characterization by 1h nuclear magnetic resonance longitudinal relaxation time. Proceedings of the CRETE 2012 - 3rd International Conference on Industrial and Hazardous Waste Management, Chania (Crete, GR), September 12-14th, 2012. G. C. Borgia, V. Bortolotti, P. Fantazzini. Changes of the local pore space structure quantified in heterogeneous porous media by 1H magnetic resonance relaxation tomography. Journal of Appl. Physics, 90: 1155-1163, 2001. V. Bortolotti, P. Fantazzini, M. Gombia, D. Greco, G. Rinaldin, S. Sykora. PERFIDI filters to suppress and/or quantify relaxation time components in multi-component systems: An example for fat-water systems. Journal of Magnetic Resonance, 206, 2: 219-226, 2010. G. C. Borgia, V. Bortolotti, P. Fantazzini. Magnetic Resonance Relaxation-Tomography to Assess Fractures Induced in Vugular Carbonate Cores. SPE paper 56787, Proceedings of the 74-th Annual Technical Conference and Exhibition of SPE, Houston, 3-6 Oct. 1999. M. Gombia, V. Bortolotti, RJS Brown, M. Camaiti, L. Cavallero and P. Fantazzini. Water Vapor Absorption in Porous Media Polluted by Calcium Nitrate Studied by Time Domain Nuclear Magnetic Resonance. Journal of Physical Chemistry B, 113, 31, 10580-10586, 2009. G. C. Borgia, V. Bortolotti, P. Dattilo, P. Fantazzini, G. Maddinelli. Quantitative determination of porosity: a local assessment by NMR Imaging techniques. Magn. Res. Imaging, 14: 919-921, 1996. M. Gombia, V. Bortolotti, R. J. S. Brown, M. Camaiti, and P. Fantazzini. Models of water imbibition in untreated and treated porous media validated by quantitative magnetic resonance imaging. Journal of Appl.Physics, 103, 9, pp 8. 2008. U. Bilardo, G. C. Borgia, V. Bortolotti, P. Fantazzini, E. Mesini. Magnetic resonance lifetimes as a bridge between transport and structural properties of natural porous media. J. Pet. Sc. and Eng., 5: 273-283, 1991. V. Bortolotti, M. Gombia, F. Cernich, E. Michelozzi, P. Fantazzini. A study to apply nuclear magnetic resonance porosity measurements to seabed sediments. Marine Geology, 230: 21 – 27, 2006. CONTACTS [email protected] [email protected] [email protected] [email protected] www.mrpm.org V. Bortolotti, M. Camaiti, C. Casieri, F. De Luca, P. Fantazzini, C. Terenzi. Water absorption kinetics in different wettability conditions 42 Geoengineering and Natural Resources – Mines and Quarries, Geothermal, Excavations ADVANCED METHODS FOR CHARACTERIZATION OF ROCK MATERIALS AND ROCK MASSES RESEARCH GROUP: Annalisa Bandini, Paolo Berry, Daniela Boldini, Stefano Bonduà, Villiam Bortolotti, Roberto Bruno, Marianna Vannini KEYWORDS: nanoindentation, bimrocks, rockburst, Magnetic Resonance, Rock Impact Hardness Number The research on the rock materials and rock masses characterization, in situ and in laboratory, covers a large number of themes and the main topics concern with: a) rock materials • study of the relationships between microstructure and mechanical response of rocks under static and dynamic loading conditions; • determination of the nano and micromechanical properties through instrumented indentation techniques and scratching; • characterization of the rocks internal structures through Nuclear Magnetic Resonance (MRI images and NMR curves); • measurement of the acoustic emissions (AE) during compression and tensile tests, to study rockburst phenomena; • development of innovative and non-conventional investigation techniques to determine the strength of irregular shaped specimens; • non destructive characterization techniques (ultrasounds, dye penetrant inspection, image analysis); b) rock masses • characterization of the mechanical strength of structurally complex rock masses (bimrocks). In the research activities, in addition to standard investigation techniques, non-conventional tests are specifically designed for particular applications and issues. With regard to non-conventional tests, a strength index (Rock Impact Hardness Number), a procedure for AE monitoring of rock samples under compression and instrumented indentation techniques, totally innovative in the Rock Mechanics field, have been developed. As concerns the rock masses, the research group has designed and performed non-conventional shear tests (Bim Test) for bimrocks. Moreover, the research team also utilizes a 3D camera probe for cored and drilled holes, to examine the rock masses structures, with continuous logging and a software for images processing. Fig. 1. Rock Impact Hardness Number: fracturing induced by stresses on a marble’s sample. Fig. 2. MRI: internal section of a rock of biocalcarenite saturated with water. Fig. 3. Schematic representation of a Bimtest. 43 Research Projects and Activities 2015 da2010. West Palm Beach (FL, USA) 20-24 February 2010. RESTON, VA 20191-4400 USA: ASCE - American Society of Civil Engineers, GSP n. 199, p. 1227-1236. ISBN/ISSN: 978-0-78441095-0. Gombia M., Bortolotti V., Brown R.J.S., Camaiti M., Cavallero L., Fantazzini P. (2009) Water Vapor Absorption in Porous Media Polluted by Calcium Nitrate Studied by Time Domain Nuclear Magnetic Resonance. J. Phys. Chem. B, 2 113, 1058010586. Coli N., Berry P., Boldini D., Bruno R. (2009) Investigation of block geometrical properties of the Shale-Limestone Chaotic Complex bimrock of The Santa Barbara open pit mine (Italy). Proc. 3rd Canada-US Rock Mechanics Symposium & 20th Canadian Rock Mechanics Symposium. Toronto (ON, Canada) 9-15 May 2009. Bonduà, S., Bruno, R., Muge, F. (2002) Geostatistical Simulation of Ornamental Stone Images: Results Analysis by Mathematical Morphology. Proc. IAMG 2002 Annual Conference of the International Association for Mathematical Geology. Berlin (Germany) 15-20 September 2002. RESEARCH PROJECTS PRIN 2007 Advanced techniques for monitoring and characterizing mine and quarry activities to preserve the safety and the environment during expoitation. National Coordinator: Prof. P. Berry. Joint Research Project between Dept. of Earth Sciences-University of Firenze and DICAM-University of Bologna on “Scientific support regarding the engineering aspects related to the Allori panel, in the framework of the 3rd Operative Agreement between the Dept. Earth Sciences and ENEL Production S.p.A. Gem/Business Unit Santa Barbara, related to the mining site of Santa Barbara (AR)”. Coordinator: Prof. P. Berry. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] MAIN PUBLICATIONS Bandini A., Berry P., Sebastiani M., Bemporad E. (2014) Nanomechanical characterization of brittle rocks. Nanomechanical Analysis of High Performance Materials. Springer Publication, Series: Solids Mechanics and its application Tiwari, Atul (Ed), vol. 203, cap. 11, pp. 209-229, ISBN: 97894-007-6918-2. Bandini A., Berry P. (2013) Influence of Marble’s Texture on its Mechanical Behavior. Rock Mechanics and Rock Engineering, 46: 785-799. Bandini A., Berry P., Bemporad E., Sebastiani M. (2012) Effects of intra-crystalline microcracks on the mechanical behavior under indentation of a marble. International Journal of Rock Mechanics and Mining Sciences 54: 47-55. Bandini A., Berry P. (2012) Multi-scale investigations on the mechanisms affecting the strength and deformability of a marble varying in texture. Proc. 46th US Rock Mechanics Geomechanics Symposium. ARMA 2012. Chicago (USA) 24-27 June 2012. Curran Associates, Inc.: vol. 2, pp. 957-965, ISBN: 978-162276514-0. Coli N., Berry P., Bruno R., Boldini D. (2012) The contribution of geostatistics to the characterisation of some bimrock properties. Engineering Geology 137-138: 53-63. Coli N., Berry P., Boldini D. (2011) In situ non-conventional shear tests for the mechanical characterisation of a bimrock. International Journal of Rock Mechanics and Mining Sciences 48: 95102. Coli N., Berry P., Bruno R., Boldini D. (2011) An integrated geostatistical-geomechanical approach for the characterization of a bimrock. Proc. 45th US Rock Mechanics Symposium. San Francisco (USA) June 26-29, 2011. Coli M., Livi E., Berry P., Bandini A., Jia X.N. (2010) Studies for rockburst prediction in the Carrara Marble (Italy). Proc. 5th International Symposium on In-situ Rock Stress (ISRSV). Beijing (China) 25-27 August 2010, London: CRC Press Taylor & Francis Group A Balkema Book, vol. 1, pp. 367-373, ISBN: 978-0-415-60165-8. Bandini A., Berry P. (2010) A suggested approach to study variability of impact hardness strength in heterogeneous rock materials. Proc. Geoflori44 Geoengineering and Natural Resources – Mines and Quarries, Geothermal, Excavations HIGH ENTHALPY – LOW ENTHALPY GEOTHERMAL RESERVOIR RESEARCH GROUP: Paolo Berry, Stefano Bonduà, Villiam Bortolotti, Roberto Bruno, Carlo Cormio, Sara Focaccia, Francesco Tinti, Ester Maria Vasini. KEYWORDS: geothermal numerical model, simulation, GIS, heating & cooling, heat pumps The best practice to exploit high enthalpy geothermal reservoirs also entails the design, development and use of numerical codes for simulation works. Usually, the geothermal reservoir is fractured and a non isothermal flow of multicomponent multiphase fluids, with in case mass exchange, is present. At present we use iTOUGH2 (a flexible and robust numerical geothermal simulator extensively used all over the world) for research and commercial activities. Nowadays, there are much commercial and non-commercial software that manage and display the input-output data of iTOUGH2, but in general there are severe limitations on the use of unstructured grids. The group has therefore developed an integrated software system to facilitate the mesh creation and population of irregular grids based on the customization of the open source GRASS GIS and an in-house 3D viewer written in JAVA. The use of the underground as geothermal reservoir where storing and retrieving thermal energy is the field of low-enthalpy geothermal energy, in which the research team has been engaged during last five years, nationally and internationally. The main applications deal with heating and cooling of residential and industrial buildings. The main contributions concern the modeling of petro-physical properties of the reservoir and its interaction with the geo-heat exchanger systems, by the use of geostatistics (GEO-MS) and numerical modelling (FEFLOW, COMSOL). Recently, methodologies of hydrocarbons to the characterization of shallow geothermal reservoir have been applied for the joint simulation of heating and cooling systems based on geothermal heat pumps. A top application regards Thermal Response Test (TRT); a new methodology of analysis based on a probabilistic modelling has been proposed at the international level. The team adheres to the Committee for Energy Conservation through Energy Storage of the International Energy Agency (IEA-ECES) and has collaborated in the drafting of the final document of Annex 21, Subcommittee for TRT. Fig. 1. Irregular grid, overlapped to a digital elevation model and a geothermal wells map (red dots) created with GRASS GIS. Fig. 2. Scheme of shallow geothermal system based on a vertical borehole heat exchanger. 45 Research Projects and Activities 2015 IAMG 2011 Salzburg, R. Marschallinger & F. Zobl eds., p.145-162, Peer-reviewed publication doi: 10.5242/iamg.2011.0305. S. Focaccia (2012). Characterization of geothermal reservoirs’ parameters by inverse problem resolution and geostatistical simulations. PhD Thesis, UNIBO. F. Tinti (2012). La caratterizzazione probabilistica del sottosuolo come strumento per l’ottimizzazione della progettazione integrata dei sistemi geotermici. PhD Thesis, UNIBO. R. Bruno, S. Mercuri, F. Tinti, H. Witte (2013). Probabilistic approach to TRT analysis: evaluation of groundwater flow effects and machine - borehole interaction. Proceeding of European Geothermal Congress 2013, Pisa, Italy, 3-7 June 2013 – 5 pp. R. Bruno, S. Focaccia, F. Tinti (2013). A software tool for Geostatistical Analysis of Thermal Response Test data: GA-TRT. Computers & Geosciences, in press; Elsevier. MAIN PUBLICATIONS P. Berry, S. Bonduà, V. Bortolotti, C. Cormio, A. Diolaiti (2010). Pre and post processing tools for tough2. European Geothermal PhD Day, Potsdam, Germany, 12 February 2010. P. Berry, S. Bonduà, V. Bortolotti, C. Cormio, A. Diolaiti, E. Lognoli (2010). GIS – based Pre – processing tools for TOUGH2. Risorse geotermiche di media e bassa temperatura in Italia. Potenziale, Prospettive di mercato, Azioni. Ferrara, Italy, 21-23 Settembre 2010. P. Berry, S. Bonduà, V. Bortolotti, C. Cormio, A. Diolaiti, E. Lognoli (2010). TOUGH2VIEWER: post processing tool for visualization of geothermic models. Risorse geotermiche di media e bassa temperatura in Italia. Potenziale, Prospettive di mercato, Azioni. Ferrara, Italy, 21-23 Sett. 2010. P. Berry, S. Bonduà, V. Bortolotti, A. Cassioli, C. Cormio, A. Diolaiti, E. Lognoli, F.Schoen (2010). A new global optimization external module for iTOUGH2. Risorse geotermiche di media e bassa temperatura in Italia. Potenziale, Prospettive di mercato, Azioni. GeoThermExpo 2010. Ferrara, Italy, 21-23 Settembre 2010. P Berry, S. Bonduà, V. Bortolotti, A. Diolaiti, C. Cormio, E. Lognoli (2011). GRASS GIS per il pre-processing di TOUGH2. Geomatics Workbooks n° 10 - “FOSS4G-it: Trento 2011”. S. Bonduá, P. Berry, V. Bortolotti, C. Cormio (2012). TOUGH2Viewer: A post-processing tool for interactive 3D visualization of locally refined unstructured grids for TOUGH2, Computers and Geosciences, 46 ,107-118. C. Cormio, P. Berry, S. Bonduà, V. Bortolotti (2012). Innovative tools for continuum discretization, better management of tough2 input data and analysis of the numerical simulation results. Proceedings of TOUGH Symposium 2012, Lawrence Berkeley National Laboratory, Berkeley, California, September 17-19, 2012. R. Bruno, F. Tinti (2009). Sistemi geotermici per il condizionamento. La Termotecnica, L’EDITRICE SAS Edizioni Tecnico Scientifiche, Milano, Anno LXIII, N.4, Maggio 2009, p.30-33. R. Bruno, S. Focaccia, F. Tinti (2011). Geostatistical modeling of a shallow geothermal reservoir for air conditioning of buildings. Proceedings of RESEARCH PROJECTS EuropeAid Project – Energy for Eastern Mayors (E4EM). DICAM Lead Partner. Characterization of underground thermal properties for geothermal applications in rural context. Collaboration with Agronomics School – UNIBO. Agreement DICAM – SAIPEM n°5000018160 for Studies and Research on Reservoir Engineering (2013 – 2014). MAC – GEO Project financed by Tuscany Region. “Modellazione matematica di sistemi geotermici per la definizione di strumenti di decisione da utilizzarsi nelle procedure di controllo di concessioni geotermiche”, in collaboration with University of Florence, CINIgeo and CNR. CONTACTS [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; [email protected] [email protected]; [email protected]. 46 Geoengineering and Natural Resources – Mines and Quarries, Geothermal, Excavations MODELING AND EXPLOITATION OF EARTH RESOURCES RESEARCH GROUP: Paolo Berry, Roberto Bruno, Stefano Bonduà, Annalisa Bandini, Sara Focaccia KEYWORDS: ore deposit, geostatistics, numerical model, mining and quarrying, reclamation The mineral raw materials are the basis of any process of economic development of man. The team deals with the characterization, modelling, selection and exploitation of mineral deposits and deposits of industrial materials. Specific topics are the spatial variability studies and modelling of useful substances and of petrophysical properties of the materials, the optimization of their sampling, the selection of the exploitable resources, technically and economically. Geostatistics is one of the major theoretical frameworks adopted; estimated and simulated models are typical tools used. The best international geostatistical software is available (ISATIS, …) besides its own library. In the sector of ornamental stone characterization, in the last 15 years the team coordinated or was partner of several international projects supported by the European Union (COSS; OSNET; FARO). In this field, an original technology was developed, and then patented, for the characterization of ornamental stone by image analysis. An advanced image processing of the surface of slabs and tiles can achieve goals related to aesthetics, such as quality certification, certification of origin, the automatic selection of different products and the degradation analysis. The research topics in the sector of exploitation of raw materials are mainly focused on: • planning and design of mining activities, at gional and local scale; • processes of selecting the most appropriate methods for mining; • environmental impact assessment and monitoring of surface and underground mining; • safety in underground, namely for methane emissions during stopes and excavations; • reclamation aspects in planning and design; • reclamation modelling and requalification projects; • rehabilitation of abandoned mines and quarries. Design software for ventilation networks, blasting, environmental control for open pit mining, was developed. In situ tests are done by advanced technologies (laser scanner, satellite images) and environmental controls are carried out (seismicity induced by blasting, overpressure). Fig. 1. Ornamental stone image analysis: variograms in 4 directions of grey tone image of “Crevola” marble tile. Fig. 2. DTM (Digital Terrain Model) with contour lines generated by laser detection. Construction of the model is the initial phase of the simulation for the determination of new forms of topographic landscape from the recovery projects studied. 47 Research Projects and Activities 2015 MAIN PUBLICATIONS Bonduà, S., Bruno, R. & Muge, F.“Geostatistical Simulation of Ornamental Stone Images: Results Analysis by Mathematical Morphology” - Proceedings of IAMG 2002 Annual Conference Berlin, Germany, 15-20/9/2002. Antonazzo, L., Badiali, E., Bruno, R. & Proverbio, M. “Certification Mark and Aesthetical Characterisation of Provincia VCO Ornamental Stones” - Proceedings of “2003 Con. Int, de la Piedra Natural” Lisboa, Portugal, 8-9 Maio, 2003, pp. 11. Bruno, R. and Pitavy, O. – Stone Characterisation by Image Analysis: Applications and Future Developments – in “Needs and Priorities in Stone Characterisation”, Chapter 4 OSNET Vol. 6 - Bruno R., Montoto M. & Paspaliaris I. Ed. - EUR 20637/6 – Athens, 2004, pp. 61-72. Bruno, R., Cuoghi, L. & Laurenge, P. – Quantitative identification of marbles aesthetical features – Proc. IBPRIA 2005, Estoril (Portugal).- Book Series: Lecture Notes in Computer Science, Vol. 3523 pp. 674-681; Marques, J.S.; Pérez de la Blanca, N.; Pina, P. (Eds.), 2005, Springer. Martoro, F., Bonduà, S. & Bruno, R. – Non Destructive Characterization of stone products: towards PDO like mark – in “F.A.R.O. Formazione Avanzata nel Settore delle Rocce Ornamentali e delle Geoelaborazioni” Chapter 1, Bruno R. & Focaccia, S. Eds –Bologna, Italy, 2009, pp. 25-42 Costa, A.G., Bruno, R. & Becerra Becerra, J.E. (2009) – Rochas ornamentais nos monumentos: Um guia para a caracterização e a valorização, in “Formação avançada no Sector das Rochas Ornamentais e do Geoprocessamento” Chapter 15 A.G. Costa & A.C.Moura Mourão Eds LABTECRochas / IGC-UFMG, Belo Horizonte, Brasil, 2009, pp. 185-194. Berry P., Squarci P. and Gambini G. - Subsidence Resulting from Solution Mining of the Buriano Salt Deposit, Italy - Proc. Of the 6th Int. Symp. On Land Subsidence, Ravenna, Italia, SISOLS, pp. 249 ÷ 264, sept. 2000. Berry P., Blengini G.A., Fabbri S., Tafaro V.A. Factors Affecting Safety in Diamond Wire Cutting Technology- Mine Planning and Equipment Selection 2001, Proc. Of the 10th Int. Symp on Mine Planning, New Delhi, Oxford & IBH Publishing, pp. 311-316, 2001. Berry P., Pistocchi A. - A Multicriterial Geographical Approach for the Environmental Impact Assessment of Open-Pit Quarries — Int. Journal of Surface Mining, Reclamation and Environment, Vol. 17, n° 4. pp. 213 – 226, Swets & Zeitlinger, 2003. Berry P., Capponi S., Fabbri A. – Seismicity Induced by Excavation Activities. In: Proceedings of ISMA 2006 – Noise and Vibration Engineering. Leuven, Belgium, 2006, LEUVEN: P. Sas, M. De Munek, pp. 1849-1860, 2006 Bandini A., Berry P., Dacquino C. – Implementation of a database for risk assessment of abandoned Italian mining sites. In: Mine Planning and Equipment Selection and Environmental Issues and Waste Management in Energy and Mineral Production. Banff, Alberta, Canada, 16-18 Nov. 2009, The Reading Matrix Inc., pp. 494-502. Coli M., Livi E., Berry P., Bandini A., Jia X.N. – Studies for rockburst prediction in the Carrara Marble (Italy). In: Rock Stress and Earthquakes. Beijing, China, 2010, London: CRC Press Taylor & Francis- A Balkema Book, vol. 1, p. 367 - 373. RESEARCH PROJECTS EC-DGIII - COSS “Characterisation of Ornamental Stone Standards by Image Analysis of Slab Surfaces”, 1995-1998. Lead Partner EC Competitive and Sustainable Growth Programme - OSNET “Ornamental and Dimensional Stone European Network”, 2000-2004. EC-EUROPEAID Alfa - FARO “Formaçao Avançada da no sector das Rochas Ornamentais”, 2005-2009. Lead partner. PA Terni - “Guidelines for the identification, characterization and quantification of mineral deposits of the second category” 2009-2010. ARPA PUGLIA, 2011, “Individuazione di modelli di gestione pubblico-privato e criteri di selezione per il recupero di paesaggi degradati a causa delle attività estrattive dismesse”. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] 48 Geoengineering and Natural Resources – Drilling Engineering and Environmental Issues of the Petroleum Indus-try DRILLING ENGINEERING AND ENVIRONMENTAL ISSUES OF THE OIL INDUSTRY RESEARCH GROUP: Paolo Macini, Ezio Mesini KEYWORDS: Drilling, Drill Bits, Drilling Fluids, No-Dig, Upstream industry & Environment Drilling engineering research concens the study of bit performance evaluation, the analysis of inhibitive drilling fluid and the optimization and testing of new formulations of fluids utilized in trenchless (or no-dig) drilling. Drill-bits are the most important tools utilized in oil and gas well drilling. Bit selection is vital from both the technical-economic standpoint, and for the optimization of the drilling process, since it can save drilling and roundtrip time. The research implemented a novel approach to bit performance evaluation, based on the analysis of large databases and the definition of a new drilling model, allowing the comparison of specific energy, cost per meter and a Bit Index, taking into account al large combination of drilling parameters, including a more precise lithological description of the well. Drilling fluid properties are the key element of any drilling operation. The principal studies concern the formulation and the rheological study of fluids utilized in trenchless drilling, whose purpose is the installation of a pipeline in the subsoil by limiting the excavation of open pits. Lab evaluation and characterization of new drilling fluids have been performed in laboratory and tested in the field. Another field of research is the evaluation of clay inhibitive effects of water based drilling fluids containing non toxic additives (polymers, glycols and inorganic electrolytes), formulated to reduce the mechanical instability of clay formation during drilling. The environmental research concerning exploration, production and utilization of hydrocarbons is twofold. On one side there are studies on environmental sustainability of the upstream industry, aimed to the implementation of strategies of sustainable management of hydrocarbon production in environmentally sensitive areas. On the other side, research is focused on anthropogenic soil subsidence caused by underground fluid withdrawals. The research activity of the Department concerns both regional subsidence studies (including modelling) and specific re- searches on measurement techniques, and in particular extensometric and in-situ Radioactive Marker Technique measurements. Fig. 1. A typical drilling rig operating in Italian oil fields. Fig. 2. Natural gas production, offshore gas field. 49 Research Projects and Activities 2015 MAIN PUBLICATIONS P. Macini, Drilling Engineering, in “Petroleum Engineering – Upstream”, edited by P. Macini & E. Mesini, in “Encyclopaedia of Life Support Systems (EOLSS)”, Developed under the Auspices of the UNESCO, Eolss Publishers, Oxford, UK, http://www.eolss.net. (2010) P. Macini, E. Mesini, The Petroleum Upstream Industry: Hydrocarbons Exploration and Production, in “Petroleum Engineering – Upstream”, in “Encyclopaedia of Life Support Systems (EOLSS)”, Eolss Publishers, Oxford, UK, http:// www.eolss.net. (2011). P. Macini, M. Magagni, G. Da Dalt, P. Valente, Bit Performance Evaluation Revisited by Means of Bit Index and Formation Drillability Catalogue, Paper SPE 107536, IADC/SPE Middle East Drilling Technology Conf. & Exhib., Cairo, Egypt, 22-24 Oct. 2007. P. Macini, M. Magagni, G. Da Dalt, P. Valente, Bit performance evaluation by means of bit index and formation drillability catalogue, OMC 2007, Offshore Mediterranean Conference, Ravenna, Italy, 28-30 Mar. 2007. P. Macini, M. Magagni, G. Da Dalt, P. Valente, How Minimum Interval Concept Can Improve Bit Performance Evaluation, Paper SPE 103590, IADC/SPE Asia Pacific Drilling Technology Conference & Exhibition, Bangkok, Thailand, 13-15 Nov. 2006. P. Macini, M. Magagni, P. Valente, Recent evolution of drill bits for hard and abrasive formations, Proc. 15th Intl. Symp. on Mine Planning & Equipment Selection (MPES 2006), Turin, Sept. 20-22, 2006, Vol 2, 1255-1260 (ISBN 88901342-4-0) P. Macini, M. Magagni, P. Valente, Bit Performance Evaluation in Southern Italy, Proc. 15th Intl. Symp. on Mine Planning & Equipment Selection (MPES 2006), Turin, Sept. 20-22, 2006, Vol. 2, 1261-1266 (ISBN 88-901342-4-0). P. Macini, M. Magagni, P. Valente, Drill-Bit Catalog and Bit Index: a New Method for Bit Performance Evaluation, Paper SPE 94798, 2005 SPE Latin American and Caribbean Petroleum Engineering Conference, Rio de Janeiro, Brazil, June 20-23, 2005. P. Macini, Drill bits for horizontal wells, Rudarsko-geolosko-naftni Zbornik (Zagreb University Bulletin), 8, 111-115, 1996. P. Macini, E. Mesini, Rock-Bit wear in ultra-hot holes, Paper SPE/ISRM 28055, Proc. Int. Conf. “Eurock ‘94”, 223-230, Delft, Aug. 29-31, 1994. D. Galazzo, P: Macini, R. Maestrello, E: Mesini, Fluidi di perforazione per HDD: dal laboratorio al cantiere, Quarry & Construction, 565 (2010), pp. 101-107 (ISSN 2036-9034). P. Macini, E. Mesini, Compaction of water/gas bearing formations: experiences in Northern Italy, Proc. IAH Intl. Symp. “Aquifer System Management”, Dijon, May 30-June 1, 2006. P. Macini, L’eredità dell’incidente nel Golfo del Messico e le tecnologie per la sicurezza nell’industria petrolifera, 1° Congresso dei Geologi di Basilicata; Ricerca sviluppo e utilizzo delle fonti fossili: il ruolo del geologo, Potenza, 30 Nov.-2 Dic. 2012. P. Macini, Offshore Drilling, Encyclopedia of Hydrocarbons, Istituto della Enciclopedia Italiana Treccani, Vol. I, Cap. 3.4, 373-384, 2005. P. Macini, Drilling Rigs and Technology, Encyclopedia of Hydrocarbons, Istituto della Enciclopedia Italiana Treccani, Vol. I, Cap. 3.1, 303-336, 2005. P. Macini, E. Mesini, G. Brighenti, Considerations on Strategies of Sustainable Management of Oil and Gas Fields in Italy. Land Subsidence, Associated Hazards and the Role of Natural Resources Development, IAHS Publication 339, Eds. D. Carreon-Freyre, M. Cerca, D.L. Galloway, IAHS Press, CEH Wallingford, Oxfordshire, UK, 2010 (ISBN 978-1-907161-12-4, ISSN 0144-7815). RESEARCH PROJECTS P. MACINI, Scientific coordination of several Research Contracts signed between the University of Bologna and Eni S.p.A., Div. E&P concerning research themes related to drill bit performance evaluation. CONTACTS [email protected] [email protected] 50 Geoengineering and Natural Resources – Petroleum Engineering and Reservoir Studies PETROLEUM RESERVOIR ENGINEERING, CARBON CAPTURE & STORAGE RESEARCH GROUP: Villiam Bortolotti, Paolo Macini, Ezio Mesini KEYWORDS: Reservoir Engineering, Petrophysics, Porous Media, Reservoir Fluids, Rock Mechanics distribution and porosity on hydraulic con-ductivity of soils or loose formations. The research activity of the group concerns the study, the development and the use of numerical codes for the simulation of hydrocarbons and other underground fluids reservoirs, including the study and the modelling of pollutant transport in ground water. Among other experimental research in the field of reservoir engineering, petrophysics and rock mechanics are the following: - Non-Darcy flow in porous media, observed in gas wells when the fluids converging to the wellbore attains the velocity peculiar of turbulent flow. In that case the use of Darcy law would lead to inaccurate production performances evaluation. - Measurement of rock compressibility at great depth, at confining pressure up to 150 MPa. The experimental apparatus has been designed to perform both static and dynamic measurements. - EOR and wettability reversal studies, including lab studies on reservoir rock and fluid properties (interfacial tension, wettability, etc.). Flooding efficiency curves are obtained and used as a criterion to evaluate the performance of wettability reversal, which seems to improve oil recovery in fractured carbonate reservoirs, where oil cannot be economically produced. - CCS application (reservoir assessment, site evaluation, injection modeling). The widespread application of CCS depends on technical maturity, costs, overall potential, diffusion and transfer of the technology to developing countries and their capacity to apply the technology, regulatory aspects, environmental issues and possible problems of public perception and acceptability. - Hydraulic conductivity of rocks and soils, featuring experimental studies on the physico-chemical interactions occurring between saturating fluids and permeability of natural porous media. These studies are aimed to aid the design of waste disposal sites (with potential release of bottom liquids), including safety criteria management. Other theoretical and lab studies concern the relationships between petro-physical properties of porous media, with particular reference to the effects of grain size Fig. 1. Some equipments of the Petroleum Engineering Lab at LAGIRN Lab, DICMA. Fig. 2. Permeability measurements. Fig. 3. Soxhlet extractor. 51 Research Projects and Activities 2015 “Groundwater in Fractured Rocks”, London, 2007, 189-202 (ISBN 978-0-415-41442-5, Krasny J. & Sharp J.M. Eds.). V. Bortolotti, P. Fantazzini, M. Gombia, P. Macini, E. Mesini, F. Srisuriyachai, Combined Spatially Resolved and Non-resolved 1H-NMR Relaxation Analysis to Assess and Monitor Wettability Reversal in Carbonate Rocks, Paper IPTC 13443, International Petroleum Technology Conference, Doha, Qatar, 7-9 December 2009. V. Bortolotti, P. Macini, F. Srisuriyachai, Laboratory Evaluation of Alkali and Alkali-Surfactant-Polymer Flooding Combined with Intermittent Flow in Carbonatic Rocks, Paper SPE 122499, SPE Asia Pacific Oil and Gas Conf. and Exhib., Jakarta, Indonesia, 4-6 Aug. 2009. V. Bortolotti, P. Macini, F. Srisuriyachai, Wettability Index of Carbonatic Reservoirs and EOR: Laboratory Study to Optimize Alkali and Surfactant Flooding, Paper SPE 131043, CPS/SPE International Oil & Gas Conf. and Exhib. in China., Beijing, 8-10 June 2010. V. Bortolotti, P. Fantazzini, M. Gombia, P. Macini, E. Mesini, F. Srisuriyachai, Probing Wettability Reversal in carbonatic rocks by Resolved and Non-resolved 1H-NMR Relaxation Analysis, Paper SPE 133937, SPE Annual Technical Conference and Exhibition, Florence, Italy, 19-22 Sept. 2010. P. Macini, E. Mesini, F. Moia, R. Guandalini, D. Savoca, Assessing the Underground CO2 Storage Potential in a Highly Populated and Industrialized Area: The Case of Lombardia Region (Italy), Paper SPE 133941, SPE Annual Technical Conference and Exhibition, Florence, Italy, 19-22 Sept. 2010. (ISBN 978-1-55563-300-4) G. Cau, G. Girardi, P. Macini, E. Mesini, S. Persoglia, The Italian Contribution to the European Initiative for the Capture, Transport, and Storage of CO2, Paper SPE 134083, SPE Annual Technical Conference and Exhibition, Florence, Italy, 19-22 Sept. 2010. (ISBN 978-1-55563-300-4) MAIN PUBLICATIONS P. Macini, E. Mesini, R. Viola, Laboratory measurements of non-Darcy flow coefficients in natural and artificial unconsolidated porous media, Journal of Petroleum Science and Engineering 77 (2011) 365-374. Elsevier. P. Macini, E. Mesini, G. Bitelli, L. Vituari, F. Bonsignore, A. Chahoud, B. Villani, P. Severi, Recent Extensometric Data for the Monitoring of Subsidence in Bologna (Italy), Proc. 8th Int. Symp. on Land Subsidence (EISOLS 2010), Queretaro, Mexico, Oct. 18-22, 2010. P. Macini, E. Mesini, Compaction of water/gas bearing formations: experiences in Northern Italy, Proc. IAH Intl. Symp. “Aquifer System Management”, Dijon, May 30- ìJune 1, 2006. P. Macini, E. Mesini, V. Salomoni, B. Schrefler, Casing influence while measuring in situ reservoir compaction. Journ. of Petroleum. Science & Engineering, 50, 2006, 40-54. P. Macini, E. Mesini, V. Salomoni, B. Schrefler, Effects of drilling-induced disturbance to estimate reservoir compaction through radioactive marker technique. Proc. 7th Int. Symp. On Land Subsidence (SISOLS 2005), Shanghai, R.P. China, Oct. 23-28, 2005. P. Macini, E. Mesini, Measuring reservoir compaction through radioactive marker technique, Jour. of Energy Resources Technology, 124, 2002, 269-275. P. Macini, E. Mesini, R. Viola, Aquifer protection: a combined study of microstructure and transport properties in clay-sand mixtures, IAHSP Vol. 10, London, 2007, 435-444 (ISBN 9780-415-44355-5, Chery, L. & de Marsily, G., Eds.). P. Macini, E. Mesini, Probing the effects on Hydraulic conductivity of grain size distribution and porosity of soils, Proc. 9th Congr. Int. Ass. of Eng. Geol., ISBN No. 0-620-28559-1, Durban, Sept. 16-20, 2002, 1566-1575. P. Macini, E. Mesini, R. Viola, Non-Darcy Flow: Laboratory Measurements in Unconsolidated Porous Media, Paper SPE 113772, SPE Europec/ EAGE Annual Conf. & Exhib., Rome, Italy, 9-12 Jun. 2008. G. Brighenti, P. Macini, Non-Darcy two-phase flow in fractured rocks, IAH-SP Series, Vol. 9, CONTACTS [email protected] [email protected] [email protected] 52 Geoengineering and Natural Resources – Mines and Quarries, Geothermal, Excavations ENGINEERING AND SAFETY OF EXCAVATIONS AND UNDERGROUND CONSTRUCTIONS RESEARCH GROUP: Annalisa Bandini, Paolo Berry, Daniela Boldini, Valentina Fargnoli KEYWORDS: tunnels, safety of excavations, seismicity, soil-structure interaction, numerical modelling The research related to underground constructions covers many different topics and aspects of tunnelling, the most important and recent being: - the tunnelling-induced subsidence and the interaction with surface structures - the seismic behaviour of tunnels - the soil-lining interaction in deep tunnels, especially in squeezing conditions - the influence of hydro-mechanical coupling on tunnel behaviour - the interaction between tunnelling and landslides - the air overpressures and seismicity induced by blasting and excavation activities to underground and surface structures - the excavation of tunnels in rock masses with methane - the analysis of the geomechanical and technological parameters affecting the TBM excavation rate The activity is developed using both numerical analysis and experimental investigations. As concerns the numerical modelling, special emphasis is dedicated to the implementation of advanced constitute models for soil, to the correct simulation of construction stages extending also the investigation to three-dimensional conditions and to the appropriate representation of the structural systems, those latter being the typical lining and support elements placed after the excavation or the buildings and monuments located at the ground surface. The results of the numerical simulations are most of the time validated against real case-histories and monitoring data. In situ new investigations approaches and technological innovations for tunnel excavations are under development. With reference to safety, the research group has been involved in the definition of 44 suggested methods of “best practice” for safe working in tunnelling, adopted by the regions Emilia Romagna and Tuscany. These recommendations have been applied so far in approximately 200 km of tunnels of TAV and VAV projects. Fig. 1. Methane monitoring in TBM-EPB. Fig. 2. Example of 3D Finite Element mesh for the analysis of soil-structure interaction during tunnelling in urban areas. Fig. 3. Distribution of curvature in the tunnel lining during a dynamic Finite Element analysis. 53 Research Projects and Activities 2015 No. 7, 886-897. Boldini D., Lackner R., Mang H.A. (2004). Influence of face reinforcement and shotcrete support on static conditions of deep tunnels: a thermo-chemo-mechanical study. Rivista Italiana di Geotecnica 4, 52-69. Boldini D., Graziani A., Ribacchi R. (2004). Raticosa tunnel, Italy: characterization of tectonized clay-shale and analysis of monitoring data and face stability. Soils and Foundations 44, No. 1, 59-71. Berry P., Squarci P., Gambini G. (2000) Subsidence Resulting from Solution Mining of the Buriano Salt Deposit, Italy. 6th Int. Symp. on Land Subsidence. Ravenna, SISOLS sept. 2000, p. 249-264. Berry P., Dantini E.M., Martelli F., Sciotti M. (2000) Emissioni di metano durante lo scavo di gallerie. Quarry and Construction, anno XXXVIII, n° 1, 37-64. Berry P. (2000) Lo scavo di gallerie con mezzi meccanici. 4a edizione Conf. Permanenti della SIG: Lo scavo, metodi, tecniche ed attrezzature nella progettazione e costruzione della tratta Bologna – Firenze. Scarperia (FI) marzo 2000, p. 19-43. Berry P., Dantini E.M., Lunardi P. (1999) Pressioni in aria e sismi indotti in opere sotterranee da volate in galleria. Strade & Autostrade, anno III, n° 5, 40-46. Berry P., Dantini E.M. (1986) Role of Blasting Control in Excavation Works near a Preexisting Tunnel. Int. Conf. on Rock Eng. and Excav. in an Urban Environment, IMM. Hong Kong, pp. 15-25. MAIN PUBLICATIONS Amorosi A., Boldini D., de Felice G., Malena M., Sebastianelli M. (2013). Tunnelling-induced deformation and damage on historical masonry structures. Geotechnique. In print. Fargnoli V., Boldini D., Amorosi A. (2013). TBM tunnelling-induced settlements in coarsegrained soils: the case of the new Milan underground line 5. Tunnelling and Underground Space Technology. In print. Graziani A., Boldini D. (2012). Influence of hydro-mechanical coupling on tunnel response in clays. Journal of Geotechnical and Geoenvironmental Engineering 138, No. 15, 415-418. Graziani A., Boldini D. (2012). Remarks on axisymmetric modeling of deep tunnels in argillaceous formations. I: Plastic clays. Tunnelling and Underground Space Technology, 28: 70-79. Boldini D., Graziani A. (2012). Remarks on axisymmetric modeling of deep tunnels in argillaceous formations. II: Fissured argillites. Tunnelling and Underground Space Technology 28, 80-89. Amorosi A., Boldini D., Elia G. (2010). Parametric study on seismic ground response by finite element modelling. Computers and Geotechnics 37, No. 4, 515-528. Amorosi A., Boldini D. (2009). Numerical modelling of the transverse dynamic behaviour of circular tunnels in clayey soils. Soil Dynamics and Earthquake Engineering 29, No. 6, 10591072. Berry P., Capponi S., Fabbri A. (2006) Seismicity Induced by Excavation Activities. ISMA 2006 – Noise and Vibration Engineering. Leuven (Belgium) September, 2006, LEUVEN: P. Sas, M. De Munek, p. 1849-1860. Graziani A. Boldini D., Ribacchi R. (2005): Practical estimate of deformations, loads and stress relief factors for deep tunnels supported by shotcrete. Rock Mechanics and Rock Engineering 38, No. 5, 345-372. Boldini D., Lackner R., Mang H.A. (2005). Ground-shotcrete interaction of NATM tunnels with high overburden. Journal of Geotechnical and Geoenvironmental Engineering 131, RESEARCH PROJECTS PRIN 2006. Effetti sismici sulle costruzioni in sotterraneo. PRIN 2008. Analisi progettuali di costruzioni sotterranee in condizioni sismiche. CONTACTS [email protected] [email protected] [email protected] [email protected] 54 Geoengineering and Natural Resources – Transition Engineering: Raw Material, Natural Resources and Solid Waste TRANSITION ENGINEERING AS NEW APPROACH FOR DESIGN AND MANAGEMENT IN AN ENVIRONMENTAL, SOCIAL AND ECONOMIC SUSTAINABILITY RESEARCH GROUP: Alessandra Bonoli, Luca Antonozzi, Francesca Cappellaro, Andrea Conte, Sara Rizzo, Anna Zanchetta e Sara Zanni KEY WORDS: LCA, ecological footprint, water, recycling, green technologies The team of Engineering of Transition is developing research activities oriented to building a sustainable world, from the point of view of environmental, social and economic, by saving and valorizing natural resources: raw materials, water and energy. Several themes of study and research to support design and management, in urban and industrial context, that can be summarized as follows: → treatment, valorization and recycling of raw materials and solid waste; → water supply, water and groundwater saving, wastewater recovery and recycling in relation with urban, industrial and agricultural uses; → energy recovery from solid waste and study of environmental impacts and waste production in relation with renewable energy sources; → research of unconventional or recycled materials for building and construction: recycled aggregates from demolition, utilization of straw, hemp, raw land, etc. for energy savings and to reduce climate-change emissions, for zero impact buildings, and in relation to greater simplicity in the process of rebuilding in areas affected by seismic events; → support to technological innovation in industrial R&D by recycling, savings and minimizing of environmental impacts: Ecodesign, Life Cycle Assessment and Life Cycle Cost Analysis, evaluation of Ecological Footprint, Carbon and Water footprint, multicriteria analysis and risk analysis in several production issues and in many environmental engineering activities (soil and polluted water reclamation, resources use and saving, waste management, etc.) → application of the concepts of resilience, green technologies and “site specific” design in rural and urban areas in order to reduce climate-change emissions and to save water, energy, soil and natural resources. A specific stream of research concerns the application of all these researches and studies in cooperation activities for emerging and developing countries. Fig. 1. Comparison of environmental performances (by LCA) for six different concretes realized with different recycled materials content. Fig. 2. The experimental DICAM urban green roof for the collection and regulation of the water and buildings energy saving determination. Fig. 3. Flotation treatment on the shredding residue of End of Life Vehicles for the recovery and recycling of different material fractions. 55 Research Projects and Activities 2015 Pantaleoni F., Bonoli A., Bergonzoni M. (2009). The life cycle assessment of the production of sound insulating panels. In: Sardinia 2009. vol. 1, p. 30-36, Cagliari, Ottobre 2009. MAIN PUBLICATIONS Bonoli A., Dall’Ara A. (2012). A bioremediation case of an ex-quarry area restored by paper sludge. JOURNAL OF BIOTECHNOLOGY, vol. 157, p. 499-504, ISSN: 0168-1656, doi: 10.1016/j.jbiotec.2011.08.010. Garfi M., Tondelli S., Bonoli A. (2009). Multi-criteria decision analysis for waste management in Saharawi refugee camps. Waste Management, vol. 29, p. 2729-2739, ISSN: 0956-053X. Bonoli A., Franchini M., Ventaglio E. (2011). A Procedure for Evaluating the Compatibility of Surface Water Resources with Environmental and Human Requirements. WATER RESOURCES MANAGEMENT, vol. 25, p. 3613-3634, ISSN: 0920-4741, doi: 10.1007/ s11269-011-9873. Bonoli A., Magelli F., Bi H., Boucherb K., Melinc S. (2008). An environmental impact assessment of exported wood pellets from Canada to Europe. BIOMASS & BIOENERGY, vol. 33, p. 434-441, ISSN: 0961-9534. Bonoli A., Garfi’ M. (2008). L’acqua piovana: un alleato per sopperire alla crisi idrica mondiale. Il Sole 24 Ore, vol. 1, p. 89-93, ISSN: 0391786X. Bonoli A., Chiavetta C., Tinti F. (2011). Comparative life cycle assessment of renewable energy systems for heating and cooling. PROCEDIA ENGINEERING, vol. 21, p. 591-597, ISSN: 1877-7058. Garfì M., Ferrer-Martí L., Bonoli A., Tondelli S. (2011). Multi-criteria analysis for improving strategic environmental assessment of water programmes. A case study in semi-arid region of Brazil. Journal Of Environmental Management, vol. 92(2011), p. 665-675, ISSN: 0301-4797. Bonoli A., Garfi’ M., Pantaleoni F. (2008). Appropriate Technologies For Plastic Recycling in Saharawi refugees camp, South Algeria. In: ACR. Waste and Climate Change conference proceedings. vol. pdf.413, LONDON:ACR, London., Thursday 31 January & Friday 1st February 2008. Bamonti S., Bonoli A., Tondelli S. (2011). Sustainable Waste Management Criteria for Local Urban Plans. Procedia Engineering, vol. 21, p. 221-228, ISSN: 1877-7058. Bonoli A., Nanni M. (2008). Efficiency of Energy Recovery from Municipal Solid Waste. In: IWWG. Venice 2008 Symposium proceedings. vol. 1, Elsevier, November 2008. Mancini M.L., Bonoli A., Chiavetta C. (2011). Construction and demolition waste (CDW): Recycling tecnologies and application of life cycle assessment (LCA) method in stabilized inert production. In: Proceedings of SARDINIA 2011- vol. 1, p. 133/1-133/7, ISBN: 9788862650007. RESEARCH PROJECTS Climate KIC - Pioneers into Practice. European Institute of Innovation and Technology. EU Minotaurus Project 7th Framework Programme under Grant Agreement no. 265946. Management and recycling activities of post-earthquake waste. Emilia Romagna Region. Mancini M.L., Bonoli A., Chiavetta C.. (2011). Life cycle application in industrial waste end of life tires use for thermo acoustic panels production. In: Proceedings of SARDINIA 2011. p. 134/1-134/7, ISBN: 9788862650007. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] Pantaleoni F., Bonoli A., Bergonzoni M. (2009). The life cycle analysis of end of life tyres for the production of asphalt. In: Sardinia 2009 vol. 1, p. 75-85, Cagliari, Ottobre 2009. 56 Geotechnical and Geological Engineering Geotechnical and Geological Engineering – Hydrogeological Risk ANALYSIS AND MITIGATION OF LANDSLIDE RISK RESEARCH GROUP: Lisa Borgatti, Federico Cervi, Guido Gottardi, Alberto Landuzzi, Marco Ranalli, Laura Tonni KEY WORDS: landslide, risk, slope stability, slope stabilization, Alps, Northern Apennines The deformed and displaced units which compose the fold-and-thrust belts of the Apennines and the Alps show a prominent predisposition to landslides. Research on large landslides from the recent past enables to better understand the geomorphological evolution of our territory, and in particular to evaluate the hazard related to dormant phenomena prone to reactivation. Our research methodology, taking advantage of modern technologies for data acquisition and representation, consists of the following stages: 1. detailed geological and geomorphological survey, to reconstruct stratigraphy and structure of the landslide sites; 2. archive research, to find any historical evidence of sliding events. 3. prehistorical landslides dating, by means of physical and incremental methods; 4. reconstruction of the slope geometry, also with reference to pre-landslide conditions, with photogrammetric and laser scanning techniques; 5. construction of longitudinal and transversal sets of geological cross-sections; 6. cross-section calibration by means of subsurface data; 7. 3D reconstruction of the sliding surfaces, by interpolation of altitude data drawn from outcrops and cross sections; 8. cross-section restoring and possible reconstruction of the pre-sliding slopes, taking into account any available historical evidence; 9. geotechnical modelling and slope stability assessment by back-analysis, also by means of probabilistic methods; 10. development of Bayesian analysis techniques as means of probabilistic calibration of the models and statistical update of the data; 11. monitoring of active movements by means of topographic, inclinometric and piezometric readings, also in real-time; 12. numerical modelling aimed at the design of structural mitigation countermeasures; 13. overall description of landslide evolution, from the precursors to the main event and the subsequent reactivations, including those expected for the next future; 14. analysis of the relationships between landslide occurrence and environmental factors at the Holocene temporal scale, with particular reference to climate and human interventions, also in archeological contexts. Fig. 1. Ca’ Lita (RE), April 2004 –3D model of the landslide after its total reactivation. Fig. 2. San Leo (RN). Northern sector of the slab, affected by rock falls and earth flows. Fig. 3. Baiso (RE). Ustable slopes in varicoulored clayshales. 59 Research Projects and Activities 2015 Gottardi G., Marchi G., Righi P.V. (1998). Learn-ing from a large landslide in Northern Italy. XI Danube-European Conf. SMGE, Porec, Croazia, 811-818. MAIN PUBLICATIONS Borgatti L., Soldati M. (2013). Hillslope Processes and Climate Change. In: J. Shroder (Ed.) Treatise on Geomorphology, 7, Mountain and Hillslope Geomorphology, 306-319. Academic Press San Diego, CA (USA). ISBN 9780080885223. Gottardi G., Marchi G., Landuzzi A., Benedetti G. (2004). Sui complessi fenomeni di instabilità presso le Gole di Scascoli (Appennino Settentrio-nale, Bologna). X Int. Conf. Interpraevent 2004, Riva del Garda, Italia, 2, V/25-V/36. Borgatti L., Soldati M. (2010). Landslides and climate change. In: I. Alcántara-Ayala, A. Goudie. Geomorphological Hazards and Disaster Prevention, 87-96. Cambridge University Press. ISBN 9780521. Meier J., Schaedler W., Borgatti L., Corsini A., Schanz T. (2008). Inverse Parameter Identification Technique using PSO Algorithm applied to Geotechnical Modelling. Journal of Artificial Evolution and Applications, 574613, 14 pp. doi:10.1155/2008/574613. Borgatti L., Soldati. M. (2010). Landslides as a geomorphological proxy for climate change: A record from the Dolomites (northern Italy). Geo-morphology, 120, 56-64. Marcato G., Mantovani M., Pasuto A., Zabuski L., Borgatti L. (2012). Monitoring, numerical modelling and hazard mitigation of the Moscardo landslide (Eastern Italian Alps). Engineering Geology, 128, 95-107. Borgatti L., Tosatti G. (2010). Slope instability processes affecting the Pietra di Bismantova ge-osite (Northern Apennines, Italy). Geoheritage, 2, 155-168. Piastra S., Landuzzi A., Cencini C. (2005). His-torical landslides (XVII-XIX centuries) from Romagna Apennines, Northern Italy. A cultural approach. 6th Int. Congress on Geomorphology, Zaragoza, Spain, 410. Borgatti L., Vittuari L., Zanutta A. (2010). Geo-matic methods for punctual and areal control of surface changes due to landslide phenomena. In Ernest D. Werner, Hugh P. Friedman. Landslides: Causes, Types and Effects, 133- 176. Hauppauge, NY: Nova Science Publishers Inc. Ranalli M., Gottardi G., Medina-Cetina Z., Nadim. F. (2010). Uncertainty quantification in the calibration of a dynamic viscoplastic model of slow slope movements. Landslides, 7, 31-41. Borgatti L., Corsini A., Barbieri M., Sartini G., Truffelli G., Caputo G., Puglisi C. (2006). Large reactivated landslides in weak rock masses: a case study from the Northern Apennines (Italy). Landslides, 3, 115-124. Ranalli, M., Medina-Cetina, Z., Gottardi, G., and Nadim, F. (2013). (2013). “Probabilistic Calibra-tion of a Dynamic Model for Predicting Rainfall Controlled Landslides.” J. Geotech. Geoenviron. Eng., 10.1061/(ASCE)GT.19435606.0000972. Corsini A., Borgatti L., Cervi F., Dahne A., Ron-chetti F., Sterzai. P. (2009). Estimating mass-wasting processes in active earth slides– earth flows with time-series of High-Resolution DEMs from photogrammetry and airborne LiDAR. NHESS, 9, 433-439. Tonni L., Gottardi G., Marchi G. (2001). Analisi di stabilità e modellazione numerica dei movimenti di versante nell’area di Corniglio (Appennino Parmense). Quaderni di Geologia Applicata, 8-2, 133-158. Gottardi G., Butterfield R. (2001). Modelling ten years of downhill creep data. XV ICSMGE, Is-tanbul, Turchia, 1, 99-102. CONTACTS Gottardi G., Tonni L. (2003). Interpretation of slope movements induced by adjacent large land-slide in Northern Italy. Natural Hazards Review, 4(2), 71-77. [email protected] [email protected] [email protected] 60 Geotechnical and Geological Engineering – Regional Geology TECTONICS AND SEDIMENTATION IN THE OUTER NORTHERN APENNINES RESEARCH GROUP: Alberto Landuzzi. KEYWORDS: Outer Northern Apennines, marker horizons, olistostromes, syndepositional tectonics, active tectonics. In the mountain range bounded to the S by the Mugello and Casentino basins, to the W by the Sillaro valley and to the E by the Conca valley, a study of the tectono-sedimentary relationships between the Umbria-Romagna foredeep and the Liguride nappe allows to define accurately chronology and style of the Apennine deformation. We recognise synsedimentary gentle folds and postdepositional thrusts in the foredeep succession, low angle normal faults confined within the nappe, and high angle normal faults offsetting the whole Apennine stack. The latter are connected to exumation and dismembering of the stack itself. Our research, carried out in collaboration with BiGeA – University of Bologna, focuses at the following subjects: (1) Age determination and physical correlation of the marker horizons in the foredeep successions of Mugello and Alta Romagna, along with detection of time-equivalent surfaces in the semi-allochthonous succession. (2) Characterisation of synsedimentary folding in the inner part of the Umbria-Romagna foredeep. (3) Structural and physiographic reconstruction of the Miocene Apennine front, by the study of olistostromes and their peculiar sedimentary covers. (4) Analysis of reactivations and displacements of the Liguride overthrust. (5) Mapping and interpretation of the low angle normal faults confined within the Liguride nappe. (6) Study of the relationships between recent uplift and the high angle normal faults which offset the whole Apennine stack. Our research is based upon the classical techniques of mapping and elaboration of stratigraphic and tectonic data. Seismic profiles and borehole data provided by hydrocarbon exploration companies are used for calibration at depth of geological cross-section (collaboration with public institutions and private enterprises). Fig. 1. Geologic map of the Liguride overthrust in the Western Tuscany-Romagna Apennines. Fig. 2. Regional geologic cross-section from the Mugello basin (Tuscany) to the Po Plain (Emilia). 61 Research Projects and Activities 2015 MAIN PUBLICATIONS CONTACTS Zattin M., Landuzzi A., Picotti V., Zuffa G.G. (2000). Discriminating between tectonic and sedimentary burial in a foredeep succession, Northern Apennines. J. Geol. Soc. London, 157, 629-633. [email protected] Barchi M., Landuzzi A., Pialli G.P., Minelli G. (2001). Outer Northern Apennines. In: Anatomy of an Orogen (Eds. G.B. Vai and I.P. Martini), Kluwer Academic Publishers, 215-254. Pini G.A., Lucente C.C., Cowan D.S., De Libero C.M., Dellisanti F., Landuzzi A., Negri A., Tateo F., Del Castello M., Morrone M., Cantelli L. (2004). The role of olistostromes and argille scagliose in the structural evolution of the Northern Apennines. Memorie Descrittive della Carta Geologica d’Italia, 63/1, B13, 1-40. Roveri M., Landuzzi A., Bassetti M.A., Lugli S., Manzi V., Ricci Lucchi F., Vai G.B. (2004). The record of Messinian events in the Northern Apennines foredeep basin. Memorie Descrittive della Carta Geologica D’Italia, 63/2, B19, 1-46. Landuzzi A. (2005). Sezione geologica dell’Appennino tra il Mugello e la Pianura Padana. In: Valli di Zena, Idice e Sillaro, Gruppo di studi Savena Setta Sambro. Bernagozzi G., Landuzzi A., Vai G.B. (2005). I percorsi nascosti. Il tracciato alta velocità Bologna-Firenze. In: Valli di Zena, Idice e Sillaro, Gruppo di studi Savena Setta Sambro, 324-342. Landuzzi A. (2005). Geologic Map of the Diaterna Area. In: Mapping Geology in Italy (Eds. C. Venturini, G. Pasquarè, G. Groppelli), APAT, ROME. Landuzzi A. (2005). Schematic geologic map of the Western Tuscany-Romagna Apennines. In: Mapping Geology in Italy (Eds. C. Venturini, G. Pasquarè, G. Groppelli), APAT, ROME. Landuzzi A. (2005). Sin-depositional advancement of the Liguride allochthon in the Miocene foredeep of the Western Romagna Apennines (Italy). In: Mapping Geology in Italy (Eds. C. Venturini, G. Pasquarè, G. Groppelli), APAT, ROME, 219-226. 62 Geotechnical and Geological Engineering – Hydrogeological Risk HYDROGEOLOGICAL CHARACTERIZATION OF MOUNTAINOUS AND PLAIN AREAS RESEARCH GROUP: Lisa Borgatti, Federico Cervi, Gilberto Bonaga KEYWORDS: hydrogeology, hydrochemistry, spring, clay-rich landslide, flood control reservoir The research is focused primarily on groundwater, on the one hand assessing and characterising water as reserve and resource, on the other hand in terms of hazard and risk, with reference to slope instability and flooding. Hydrogeological monitoring in mountainous areas is aimed at assessing rainfall infiltration and the amounts of groundwater stored inside the aquifers, together with their hydrodynamic properties. The study is carried out with a multidisciplinary approach, using also hydrochemistry and isotopic geochemistry. One of the most promising topic, is the study of the hydrological and geotechnical characteristics of complex landslides in clay-rich slopes (assessment of hydrogeological, chemical and isotopic variations following rainfall and infiltration processes, numerical modeling of infiltration processes and flow, deformation and slope stability). In plain areas, the main focus is on flood mitigation measures and their interactions with groundwater. This problem is worthy of research as during the last decades, a large number of flood control reservoirs were built in Emilia Romagna, in order to mitigate flood risk in urban areas. Besides this main purpose, the need for a multiple exploitation of the water stored in the reservoir is becoming of paramount importance, as a consequence of unusual drought periods and also as a source of alternative of energy production. In order to change what was the original designed destination, i.e., reservoirs that would have been filled for short periods and only in case of high return period flood events, a series of field and lab experimental data are needed, primarily to assure the stability of structures (dam, levees, eventual flood gates etc.) and also to check for possible negative effects, with particular reference to the risk of groundwater pollution and of base flow modifications. Therefore, a multidisciplinary research has to be undertaken, to collect hydrological, geological, hydrogeological and geochemical data, that are the basis of conceptual and numerical model that have to be developed in order to understand the interactions between the reservoir and the aquifer, in different scenarios. Fig. 1. Mulino delle Vene, Onfiano di Carpineti (RE). Springs area being monitored and sampled for hydrogeological characterization. Fig. 2. Macognano brackish spring (Val Dolo, MO). Fig. 2. Parma River flood control reservoir during the field operations in 2007. 63 Research Projects and Activities 2015 A case study in the northern Apennines (Reggio Emilia Province, Italy). Landslides, 7(4), 433-444. MAIN PUBLICATIONS Bonaga G., Mesini E., Pasquali C. (2004). Misure di conducibilità idraulica di sedimenti argillosi per la progettazione di una cassa di espansione, in: Problemi di Geoingegneria: Sondaggi e Perforazioni, SEGRATE (MI), Geo-Graph S.n.C., 2004, pp. 127-134. Cervi F., Bloschl G., Borgatti L., Ronchetti F., Corsini A. (2009). Predizione a scala regionale di indici di magra in bacini montani non strumentati e possibili implicazioni nella stima del Deflusso Minimo Vitale. Conferenza Interregionale Studi ed esperienze sull’uso sostenibile delle risorse idriche dell’Appennino mitigazione degli effetti del cambiamento climatico miglioramento dello stato ecologico dei corsi d’acqua ottimizzazione degli interventi per lo sfruttamento idropotabile ed idroelettrico. Pennabilli, Montefeltro. 26-27 Giugno 2009. (pp. 17 - 20). Borgatti L., Cervi F., Corsini A., Ronchetti F. & Pellegrini M. (2007). Hydro-mechanical mechanisms of landslide reactivation in heterogeneous rock masses of the northern Apennines (Italy). In: Proceedings of the First North American Landslide Conference, Landslides and Society: Integrated Science, Engineering; Management, and Mitigation, Vail, Colo., June 2007, American Society of Environmental and Engineering Geologists, AEG Special Publication n. 23, 749-758. Corsini, A., Cervi, F., Ronchetti, F. (2009). Weight of evidence and artificial neural networks for potential groundwater spring mapping: an application to the Mt. Modino area (northern Apennines, Italy). Geomorphology, 111(1-2), 79-87. Borgatti L., Corsini A., Chiapponi L., D’Oria M., Giuffredi F., Lancellotta R., Mignosa P., Moretti G., Orlandini S., Pellegrini M., Remitti F., Ronchetti F., Tanda M.G., Zanini A. Collecting a multi-disciplinary field dataset to model the interactions between a flood control reservoir and the underlying porous aquifer. AGU Fall Meeting, 2008. Ronchetti F., Borgatti L., Cervi F., Corsini A. (2010). Hydro-mechanical features of landslide reactivation in weak clayey rock masses. Bulletin of Engineering Geology and the Environment, 69, 267-274. Ronchetti F., Borgatti L., Cervi F., Gorgoni C., Piccinini L., Vincenzi V., Corsini A. (2009). Groundwater processes in a complex landslide, northern Apennines, Italy. Natural Hazards and Earth System Sciences, 9, 895 - 904. Cervi, F., Ronchetti, F., Martinelli, G., Bogaard, T.A., Corsini, A. (2012). Origin and assessment of deep groundwater inflow in the Ca’ Lita landslide using hydrochemistry and in situ monitoring. Hydrology and Earth System Sciences, 16, 4205–4221. Ronchetti F., Borgatti L., Cervi F., Corsini A., Gorgoni C., Piccinini L., Truffelli G., Vincenzi V. (2009). Hydrogeologic characterististics of roto-traslational slides in flysch. Landslide processes from geomorphologic mapping to dynamic modelling. A cura di Malet J.-P., Remaitre A., Bogaard T. Landslide processes from geomorphologic mapping to dynamic modelling. Landslide processes. Strasbourg, France. 6-7 February 2009. (pp. 183-189). ISBN: 2-95183317-1-4. Strasbourg: CERG. Cervi, F., Debieche, T-H., Marc, V., Krzeminska, D.M., Bogaard, T.A., Malet, J.P. (2011) Variable contributions of mixing end-members during small scale sprinkling experiments in partially weathered black marls Proceeding of the II italian workshop on landslides - (Picarelli L, Greco R, Urcioli G Eds) Large slow active slope movements and risk management, with a section on landslide hydrology - hillslope hydrological modelling for landslide prediction, Cues, Napoli, 135-140. ISBN 9788897821090. CONTACTS Cervi, F., Berti, M., Borgatti, L., Ronchetti, F., Manenti, F., Corsini, A. (2010). Comparing predictive capability of statistical and deterministic methods for landslide susceptibility mapping: [email protected] [email protected] 64 Geotechnical and Geological Engineering – Hydrogeological Risk PHYSICAL AND NUMERICAL MODELLING OF THE BEHAVIOUR OF FALLING ROCK PROTECTION BARRIERS RESEARCH GROUP: Guido Gottardi, Laura Govoni, Alessio Mentani, Francesco Ubertini, Cristina Gentilini, Stefano de Miranda KEYWORDS: rockfall, risk mitigation, passive systems, physical modelling, FEM Risk analysis and mitigation of very fast slope movements is the context of the research that addresses the physical and numerical modelling of passive systems against falling rocks and is especially focused on falling rock protection barriers, metallic structures designed to intercept and stop falling rocks along a slope. Such topic is currently of great interest, also following the recent publication of the “European Guideline for Technical Approval of falling rock protection kits” (ETAG 027). The research has involved the physical modelling of flexible falling rock protection barriers of high energy absorption capacity (from few hundreds to more than 5000 kJ) to investigate the highly non-linear mechanical response of these complex metallic structures in dynamic conditions. Tests were carried out in the fullscale test site located in Fonzaso, near Belluno in Italy, in collaboration with the Consorzio Triveneto Rocciatori and the Officine Maccaferri. Results of these tests, in which a free-falling concrete block (of velocity about 25 m/s and weight from 5 kN to 160 kN) impacts a prototype of barrier, have enabled the set-up of a reliable and consistent database and have provided a convenient starting point for the development of several non-linear and dynamic FE models. Such models have recently led to the development of a general and efficient strategy for the numerical modelling of these structures. In collaboration with the Autonomous Province of Bolzano, the numerical strategy has been also successfully applied to investigate the behaviour of other models of falling rock protection barriers with low energy absorption capacity (less than 200 kJ), widely used but not adequately studied. The research is currently developed along two main directions: 1) structural design optimization, with special emphasis on the foundations and 2) definition of a computational tool taking into full account the effect of these structures in typical procedures of rockfall risk analysis and mitigation, with particular interest on the barrier actual working conditions. 65 Fig. 1. Impact test on a falling rock protection barrier prototype. Fig. 2. FE model of a falling rock protection barrier under full-scale testing conditions. Research Projects and Activities 2015 In-ternational Journal of Physical Modelling in Geotechnics 11 (4), 126-137. MAIN PUBLICATIONS Gottardi G. and Govoni L. (2013). Modellazione e progetto di barriere paramassi, Hevelius Edizioni, Benevento. Gottardi G. and Govoni L. (2010). Full scale modelling of falling rock protection barriers. Rock Mechanics and Rock Engineering 43 (3), 261-274. Gentilini C., Govoni L., Gottardi G., Mentani A. and Ubertini F. (2013). Design of falling rock protection barriers using numerical models, Engineering Structures 50, 96-106. de Miranda S., Gentilini C., Gottardi G., Govoni L. and Ubertini F. (2010). A simple model to simulate the full-scale behaviour of falling rock protection barriers, 7th International Conference on Physical Modelling in Geotechnics (ICPMG 2010), Zurich, Switzerland, Vol. 2, 1247-1252. Gentilini C., Govoni L., de Miranda S., Gottardi G. and Ubertini F. (2012). Three-dimensional numerical modelling of falling rock protection barriers, Computers and Geotechnics 44, 58-72. Cantarelli G., Giani G.P., Gottardi G. and Govoni L. (2008). Modelling rockfall protection fences. Proc. First World Landslide Forum. Tokyo, Parallel Session Volume, 103-108. Gottardi G., Govoni L., Ranalli M., Mentani A., Strada C. (2012) The role of falling rock protection barriers in the context of landslide risk analysis and mitigation, 12th Congress INTERPRAEVENT 2012, Grenoble, France, Vol. 2, 699-706. RESEARCH PROJECTS Research and consulting contract with Consorzio Triveneto Rocciatori, Belluno, Italy (20062008). Investigation of the behaviour of falling rock protection barriers from the results of fullscale impact tests. Scientific Coordinator: Guido Gottardi. S. de Miranda, C. Gentilini, G. Gottardi, L. Govoni, A. Mentani, F. Ubertini (2011). On the structural response of falling rock protection barriers, XX Congress AIMETA - Associazione Italiana di Meccanica Teorica e Applicata, 12-15 September 2011, Bologna, 1-10. Research and consulting contract with Officine Maccaferri, Bologna (2008-2009). Numerical modelling of the behaviour of falling rock protec-tion barriers under full-scale impact tests. Scien-tific Coordinator: Guido Gottardi. Gottardi G. and Govoni L. (2011). Modellazione e progetto di barriere paramassi. XXIV Convegno Nazionale di Geotecnica. Innovazione tecnologica nell’ingegneria geotecnica, Napoli, Vol. 1, 73-84. Research and consulting contract with Autono-mous Province of Bolzano (2010-2012). Risk as-sessment and mitigation of the road network of the Provincia Autonoma of Bolzano. Scientific Coordinator: Guido Gottardi. Gottardi G., Govoni L., Ranalli M., Mentani A. and Strada C (2011). The effectiveness of protection systems toward rockfall risk mitigation, Proc. 3rd International Symposium on Geotechnical Safety and Risk (ISGSR 2011), Munich, 157-164. CONTACTS [email protected] [email protected] [email protected] [email protected] Govoni L., de Miranda S., Gentilini C., Gottardi G. and Ubertini F. (2011). Two-dimensional modelling of falling rock protection barriers, 66 Geotechnical and Geological Engineering – Soil Mechanics GEOTECHNICAL CHARACTERIZATION OF NATURAL SOILS BY IN SITU TESTING RESEARCH GROUP: Guido Gottardi, Laura Tonni, Michela Marchi, María Fernanda García Martínez KEYWORDS: piezocone, silty soils, soil compressibility, riverbank seismic stability, partial drainage In situ testing plays a crucial and effective role in subsoil geotechnical characterization. Since early ‘90s, the DICAM Geotechnical Engineering Lab has been equipped with a Delft Geotechnics piezocone device, installed on a suitably arranged and fully dedicated independent lorry, fitted for continuous and automated data acquisition. Significant efforts have been put on the refinement of testing procedures and on the improvement of measurement interpretation. In last years, research in this area has been mainly based on the extensive piezocone testing campaign performed at the Treporti Test Site (Venice, Italy) within a long-lasting and comprehensive research project funded by the Italian Ministry of Research and carried out in cooperation with the Italian Universities of Padova and L’Aquila. The project aimed at better understanding the stress-strain-time response of the heterogeneous, predominantly silty sediments of the Venetian lagoon and similar intermediate soils, for which little information can be generally found in the geotechnical literature. The large amount of piezocone data thus available has been interpreted with particular reference to the evaluation of compressibility characteristics of silts and silt mixtures, which have been found not to follow the framework published for other soils. In the context of intermediate soils, research has also focused on the issue of partial drainage detection during cone penetration. Indeed, in these soils, different degrees of drainage are very likely to occur under a standard rate of penetration and the preliminary evaluation of such condition turns out to be of crucial importance for the assessment of representative mechanical parameters. Accordingly, piezocone tests at non-standard penetration rates have been performed in the silty soils of the Venetian lagoon as well as in other sites of the Emilia-Romagna region. More recently, the research group has been involved in the geotechnical characterization, by in situ testing, of the sediments forming the banks of the Po river and the surrounding subsoil, within a research project aimed at verifying the seismic stability of the embankments. Fig. 1. Profiles of the corrected cone resistance qt, soil behaviour type index Icn and normalized cone resistance Qtn for a piezocone test performed at the Treporti Test Site. Fig. 2. Typical stratigraphic section of the Po river embankments. 67 Research Projects and Activities 2015 Proc. 4th Int. Conf. on Site Characterization, ISC-4, Vol. 1, 383-389. MAIN PUBLICATIONS Tonni L. and Gottardi G. (2009). Partial drainage effects in the interpretation of piezocone tests in Venetian silty soils. Proc. 17th ICSMGE, Alexandria, Egypt, Vol. 2, 1004-1007. Tonni L. and Simonini P. (2012). Evaluation of secondary compression of sands and silts from CPTU. Geomechanics and Geoengineering: An International Journal. Tonni L. and Gottardi, G. (2010). Interpretation of piezocone tests in Venetian silty soils and the issue of partial drainage. Proc. of the 2010 GeoShanghai International Conference, Deep Foundations and Geotechnical In Situ Testing, ASCE Geotechnical Special Publication (205 GSP), 367-374. DOI: 10.1080/17486025.2012.726748 Tonni L. and Simonini P. (2013). Shear wave velocity as function of cone penetration test measurements. Engineering Geology, 163, 55-67. Gottardi G., Madiai C., Marchi M., Tonni L. and Vannucchi G. (2013). Methodological approach for the static and seismic stability analysis of the Po riverbanks. Proc. 18th ICSMGE, Paris (France). In press. Tonni L., Gottardi G., Berengo V. and Simonini P. (2010). Classification, overconsolidation and stiffness of Venice lagoon soils from CPTU. Proc. CPT’10, 567-574. Omnipress. Tonni L. and Gottardi G. (2011). Analysis and interpretation of piezocone data on the silty soils of the Venetian lagoon (Treporti test site). Canadian Geotechnical Journal 48 (4), 616– 633. RESEARCH PROJECTS Tonni L., Gottardi G. and Simonini P. (2011). Piezocone data and state parameter interpretation for Venetian silty soils. Proc. 5th Int. Symp. Deformation Characteristics of Geomaterials, ISSeoul 2011, 1260-1267. Millpress, the Netherlands. Research and consulting contract with AUTORITÀ DI BACINO DEL FIUME PO. Evaluation of the seismic stability of the Po riverbanks in the Emilia-Romagna area. Bersan S., Cola S., Simonini P., Gottardi G. and Tonni L. (2012). Secondary compression of Venice Lagoon sands and silts from CPTU. [email protected] [email protected] [email protected] PRIN 2000. A geotechnical model of the soil for safeguarding Venice and its lagoon. Research project funded by the Italian Ministry of Research. CONTACTS 68 Geotechnical and Geological Engineering – Soil Mechanics MODELLING OF GRANULAR SOIL BEHAVIOUR IN STATIC AND SEISMIC CONDITIONS RESEARCH GROUP: Laura Tonni, Guido Gottardi KEYWORDS: constitutive models, Generalized Plasticity, sand, liquefaction, numerical modelling Due to the increasing complexity of geotechnical problems to be analysed, over the last years a considerable amount of research has been carried out on the constitutive modelling of soils. The attention of this research group has been mainly focused on the constitutive modelling of sands and sandy silts, within a rather versatile theoretical framework known as Generalized Plasticity. In this context, an existing Generalized Plasticity formulation for sands (Pastor, Zienkiewicz & Chan, 1990), specifically developed to describe many important features of granular soil behaviour in both monotonic and cyclic loading conditions, has been assumed as a base. The specific research activity of the team has mainly focused on the following two main areas: 1) A number of modifications and refinements, based on the state parameter concept in conjunction with the Critical State framework, have been introduced into the original constitutive equations, in order allow unified modelling of soil behaviour over a wide range of stress levels and void ratios. A significant application of such model has concerned the modelling of the complex mechanical behaviour of silty sediments of the Venetian lagoon basin. 2) A great amount of work has dealt with the implementation of Generalized Plasticity models into FE codes and especially on the development of robust and accurate integration schemes of the rate constitutive equations. Special emphasis has been given to the implementation of the Pastor-Zienkiewicz-Chan formulation. Typical applications of the model to general boundary value problem analyses have concerned the numerical modelling of initiation mechanisms of landslides, with special reference to catastrophic failures due to seismic-induced soil liquefaction or debonding phenomena in collapsible, weakly cemented soils. The whole research has been carried out in close cooperation with Spanish researchers of the Centro de Estudios y Experimentación de Obras Públicas (CEDEX, Madrid). (a) (b) (c) Fig. 1. (a) Soil layer problem and seismic input; (b) Evolution of mean effective stress p¢at different soil column points; (c) Evolution of excess pore pressure at different soil column points. 69 Research Projects and Activities 2015 Tonni L., Cola S. and Pastor M. (2006). A Generalized Plasticity approach for describing the behaviour of silty soils forming the Venetian Lagoon basin. Proc. Sixth European Conference on Numerical Methods in Geotechnical Engineering, 93-99. Taylor & Francis Group, London. MAIN PUBLICATIONS Mira P., Tonni L., Pastor M. and Fernández-Merodo J.A. (2009). A Generalized midpoint algorithm for the integration of a Generalized Plasticity model for sands. International Journal for Numerical Methods in Engineering 77, No. 9, pp. 1201-1223. Tonni L., Mira P., Pastor M. and Fernández Merodo J.A. (2005). Numerical modelling of granular soils using Generalized Plasticity. Proc. XI International Conference on Computer Methods and Advances in Geomechanics, IACMAG, Vol. 1, 199-206. Pàtron Editore. Fernández-Merodo J.A., Mira P., Pastor M. and Tonni L. (2008). Modélisation numérique des mécanismes de rupture. Micromécanique de la rupture dans les milieux granulaires, Cap. 10, 355-392. Lavoisier, Paris. Pastor M., Fernández Merodo J.A, Herreros I., Mira P., González E., Haddad B., Quecedo M., Tonni L. and Drempetic V. (2008). Mathematical, constitutive and numerical modelling of catastrophic landslides and related phenomena. Rock mechanics and rock engineering 41, No. 1, 85-132. Fernández Merodo J.A, Pastor M., Mira P., Tonni L., Herreros M.I., González E. and Tamagnini R. (2004). Modelling of diffuse failure mechanisms of catastrophic landslides. Computer methods in applied mechanics and engineering, 193, 2911-2939. RESEARCH PROJECTS Cola S., Tonni L., Pastor M. (2008). Mathematical Modelling of Venetian Sediment Behaviour Using Generalized Plasticity. Proc. IACMAG 2008, Vol. 2, 838-846. Red Hook, NY:Curran Associates, Inc. JOINT RESEARCH PROGRAMME ITALY-SPAIN, IT1895 (2004-2006). Supported by MIUR and the Spanish Ministerio de Ciencia y Tecnología. Code. “Finite Element Modelling of Seismic-Induced Landslides”. Italian Coordinator: Prof. Guido Gottardi, University of Bologna. Spanish Coordinator: Prof. Manuel Pastor, Universidad Politécnica de Madrid. Cola S. and Tonni L. (2007). Adapting a Generalized Plasticity model to reproduce the stressstrain response of silty soils forming the Venice lagoon basin. Soil stress-strain behavior: Measurement, Modeling and Analysis. A collection of papers of the Geotechnical Symposium in Rome, 16-17 March 2006, Series Solid Mechanics and its applications, Vol. 146, 743-758. Springer. CONTACTS [email protected] [email protected] 70 Geotechnical and Geological Engineering – Foundations MODELLING THE RESPONSE OF SHALLOW FOUNDATIONS UNDER GENERAL LOADING RESEARCH GROUP: Guido Gottardi, Laura Govoni, Michela Marchi KEYWORDS: soil-structure interaction, macroelement, stability of equilibrium, off-shore foundations, towers The response of shallow foundations subjected to combined loading has been intensively investigated for the last two decades. The understanding of their behaviour is crucial in many structural and geotechnical applications, not only off-shore like wind turbines, but also for other structures like gravity walls, chimneys, historical towers (Fig. 1). Among the most innovative and advanced analysis methods, the so-called Macro-element models enable to apply the external resultant forces (V, M/B, H) and displacements (w, θB, u) to the whole foundation and surrounding soil system, as generalised stress and strain variables (Fig. 2). This conceptual framework is simpler and more intuitive than the well-known finite element methods and, at the same time, it is more rational and consistent with the cultural background of the civil engineer. The research group has worked for many years on these topics, moving from extensive experimental campaigns involving several 1g and centrifuge tests carried out on shallow and embedded footings. These data have been interpreted through simple elastic, hardening-plastic models which are able to reproduce a footing response to general loading conditions with success. These models have been also modified to accommodate other important phenomena such as the soil creep and have been used to explore the stability of historical towers, whose soil-structure interaction is strongly time dependent. More recently the research group is exploring the use of more sophisticated constitutive models which can be model the footing response to other loading condition, such as cyclic or dynamic. The research group is currently planning further experimental tests to develop such models. The research has been carried out in collaboration with the University of Southampton, the Oxford University, The Centre for Offshore Foundation Systemsof Perth (WA), the Politecnico of Torino. Fig. 1. Two examples of structures with shallow foundations under combined loading: wind turbine and historical towers (in the picture a scheme of a wind turbine and the ‘Two Towers’ in Bologna). Fig. 2. Yield surface of a surface footing on sand in the 3D space of applied loading components. 71 Research Projects and Activities 2015 MAIN PUBLICATIONS ellazione del comportamento di fondazioni superficiali. Relazione Generale, V Convegno Nazionale dei Ricercatori di Ingegneria Geotecnica su “Fondazioni Superficiali e Profonde”, Politecnico di Bari, 15-16 Sept. 2006; Vol. 2, 85-119. Marchi M., Fabbi I., Gottardi G., Butterfield R., Lancellotta R. (2013). Analytical modelling of the creep-rotation rate for leaning towers. 2nd TC301 Int. Symp. on Geotech. Eng. for the Preservation of Monuments and Historic Sites, 30-31 May 2013, Napoli, Italy. ISBN: 9781138000551. Govoni L., Gourvenec S., Gottardi G., Cassidy M.J. (2006). Drum centrifuge tests of surface and embedded footings on sand, International Conference on Physical Modelling in Geotechnics, Hong Kong, China, 4-6 August 2006, 651-657. Marchi M. (2012). Effect of creep on the stability of leaning towers. 22nd European Young Geotechnical Engineers Conference. Gothenburg, Sweden, 26-29 August, 2012. ISBN: 978-91-637-1435-1. Gottardi G., Govoni L., Butterfield R. (2005). Yield loci for shallow foundations by `swipe’ testing, International Symposium on Frontiers in Offshore Geotechnics (ISFOG), Perth, Western Australia, 469-475. Govoni L., Gourvenec S., Gottardi G. (2011). A centrifuge study on the effect of embedment on the drained response of shallow foundations under combined loading, Géotechnique, Vol. 61(12), 1055-1068. ISSN: 0016-8505. Butterfield R., Gottardi G. (2003). Determination of the yield curves for shallow foundations by “swipe” testing, International Symposium on Shallow Foundations (FONDSUP 2003), Paris, France; Vol. 1, 111-118. Marchi M., Butterfield R., Gottardi G. Lancellotta, R. (2011). Stability and strength analysis of leaning towers. Géotechnique, Vol. 61(12), 1069-1079, ISSN: 0016-8505. Gottardi G., Houlsby G.T., Butterfield R. (1999). Plastic Response of circular footings on sand under general planar loading, Géotechnique, Vol. 49(4), 453-469. Govoni L., Gourvenec S., Gottardi G. (2010). Centrifuge modelling of circular shallow foundations on sand, International Journal of Physical Modelling in Geotechnics, Vol. 10(2), 35-46. ISSN: 1346-213X. Butterfield R., Gottardi G., Houlsby G.T. (1997). Standardised sign conventions and notation for generally loaded foundations, Géotechnique Vol. 47(4), 1051-1054. Gourvenec S., Govoni L., Gottardi G. (2008). The effect of embedment on the response of shallow foundations on sand under general loading, BGA International Conference on Foundations, Dundee, Scotland, 24-27 June 2008. 873-884. ISBN: 978-1-84806-044-9. Gottardi G., Butterfield R. (1995). The displacement of a model rigid surface footing on dense sand under general planar loading, Soils and Foundations, Vol. 35(3), 71-82. Gottardi G., Cavallari L., Marchi M. (2008). Soil fracturing of soft silty clays for the reinforcement of a bell tower foundation. Geotechnics of Soft Soils. University of Strathclyde, Glasgow, Scotland, 3-5 Sept. 2008. Vol. 1, 31 - 41, ISBN: 978-0-415-47591-4 Butterfield R., Gottardi G. (1994). A complete three-dimensional failure envelope for shallow footings on sand, Géotechnique Vol. 44(1), 181184. Gottardi G., Butterfield R. (1993). On the bearing capacity of surface footings on sand under general planar load, Soils and Foundations, Vol. 33(3), 68-79. Marchi M., Gottardi G., Butterfield R., Zervos A. (2008). On the stability of Santo Stefano bell tower in Venice. 2nd BGA International Conference on Foundations, ICOF 2008. Dundee, Scotland, UK, 24-27 June 2008. Vol. 2, 1581-1592, ISBN: 978-1-84806-044-9 CONTACTS [email protected] [email protected] [email protected] Gottardi G. (2007). Recenti sviluppi nella mod72 Industrial and Environmental Biotechnologies and Fluid-Dynamics Industrial and Environmental Biotechnologies and Fluid-Dynamics – Industrial Biotechnologies RECOVERY/PRODUCTION OF BIO-BASED COMPOUNDS AND BIOMATERIALS FROM AGRO-INDUSTRIAL RESIDUES OR MICROORGANISMS FROM NON-CONVENTIONAL HABITATS RESEARCH GROUP: Lorenzo Bertin, Fabio Fava, Lucia Giacomucci, Andrea Negroni, Noura Raddadi, Giulio Zanaroli KEYWORDS: agro-industrial residues, bioreactor, microbial characterization, non-conventional habitats The research is dedicated to the biotechnological production of bio-based compounds and biomaterials. To that aim, two main strategies are followed: (a) the exploitation of microorganisms collected from non-conventional environments, which could represent a ‘reservoir’ of microbial diversity and hence of new compounds and bioactive molecules; (b) the valorization of agro-industrial waste through the recovery and/or the transformation of their organic fraction. Bacteria adapted to the extreme environmental conditions could be a resource of new pigments that can be used as natural colorants, biosurfactants for the stimulation of the bioremediation of xenobiotics-contaminated marine sites, or extracellular enzymes that can be exploited in industrial processes. Microbiota actually taken into consideration are those from extreme environments including desert sand/ rocks, inland (‘Chott’) or coastal (‘Sebkha’) saline systems in the south of Tunisia, and several polluted sites in the Mediterranean Sea. Target residues to be valorized are: (i) wastewaters from the industrial production of olive oil, wine and cheese, and (ii) bran. If wastewaters contain high added-value compounds, they are pre-treated according to solid-phase extraction procedures for the recovery of such molecules (e.g., polyphenols occurring in olive mill wastewaters, which are natural antioxidants employed in several industrial fields). Wastewaters are employed as the feedstock for the biotechnological production of polyhydroxyalkanotes (PHAs), i.e., microbial biopolymers whose mechanical properties are similar to those of polypropilene. Wastewaters are previously digested under anaerobic acidogenic conditions for the production of volatile fatty acids, which represent a suitable substrate for PHA production. Bran is enzimatically hydrolyzed for the recovery of fe- rulic acid and its conversion into biovanillin via microbial conversion, after ferulic acid purification from carbohydrates (to be employed as the carbon source for the bioconversion process), and fructooligosaccharides (FOS) with prebiotic properties. Fig. 1. Pigmented bacteria from desert sand and saline systems. Fig. 2. Fermenter for bioconversion to biovanillin. 75 Research Projects and Activities 2015 symbiotic control of phytoplasmoses. In: Weintraub P.G, Jones P. Phytoplasmas: genomes, plant hosts and vectors. pp. 272-292, Wallingford. MAIN PUBLICATIONS Scoma A., Bertin L., Fava F. (2013). Effect of hydraulic retention time on biohydrogen and volatile fatty acids production during acidogenic di-gestion of dephenolized olive mill wastewaters. Biomass and Bioenergy 48, 51-58. Crotti E., Damiani C., Pajoro M., Gonella E., Rizzi A., Ricci I., Negri I., Scuppa P., Rossi P., Ballarini P., Raddadi N., Marzorati M., Sacchi L., Clementi E., Genchi M., Mandrioli M., Bandi C., Favia G., Alma A., Daffonchio D. (2009). Asaia, a versatile acetic acid bacterial symbiont, capable of cross-colonizing insects of phylogenetically distant genera and orders. Environmental Microbiology 11, 3252-3264. Puoci F., Scoma A., Cirillo G., Bertin L., Fava F., Picci N. (2012). Selective extraction and purifica-tion of gallic acid from actual site olive mill wastewaters by means of molecularly imprinted microparticles. Chem. Eng. J., Vol. 198-199, pp. 529-535. Di Gioia D., Sciubba L., Ruzzi M., Setti L., Fava F. (2009). Production of vanillin from wheat bran hydrolyzates via microbial bioconversion. Journal of Chemical Technology and Biotechnology, 84, 1441-1448. Scoma A., Pintucci C., Bertin L., Carlozzi P., Fava F. (2012). Increasing the large scale feasibility of a solid phase extraction procedure for the re-covery of natural antioxidants from olive mill wastewaters. Chemical Engineering Journal 198-199, 103-109. Sciubba L., Di Gioia D., Fava F., Gostoli C. (2009). Membrane-based solvent extraction of vanillin in hollow fiber contactors. Desalination, 241, 357-364. Scoma A., Bertin L., Zanaroli G., Fraraccio S., Fava F. (2011). A physicochemical–biotechnological approach for an integrated valorization of olive mill wastewater. Bioresource technology 102, 10273-10279. RESEARCH PROJECTS EU FP7-KBBE-2010-4 Project ID. 266473: ULIXES (Unravelling and exploiting Mediterra-nean Sea microbial diversity and ecology for xe-nobiotics’ and pollutants’ clean up). Bertin L., Ferri F., Scoma A., Marchetti L., Fava F. (2011). Recovery of high added value natu-ral polyphenols from actual olive mill wastewater through solid phase extraction. Chemical Engineering Journal 171, 1287-1293. EU FP7-KBBE-2009-3 ID 245267 Project: NA-MASTE (New Advances in the integrated Man-agement of food processing wAste in India and Europe: use of Sustainable Technologies for the Exploitation of byproducts into new foods and feeds). L. Bertin, S. Lampis, D. Todaro, A. Scoma, G. Vallini, L. Marchetti, M. Majone, F. Fava. (2010) Anaerobic acidogenic digestion of olive mill wastewaters in biofilm reactors packed with ce-ramic filters or granular activated carbon. Water Research 44, 4537- 49. EU FP7-KBBE-2010-4 ID. 265669 Project: ECOBIOCAP (Ecoefficient Biodegradable Com-posite Advanced Packaging). Raddadi N., Gonella E., Camerota C., Pizzinat A., Tedeschi R., Crotti E., Mandrioli M., Bianco P. A., Daffonchio D. Alma A. (2011). ‘Candidatus Liberibacter europaeus’ sp. nov that is associated with and transmitted by the psyllid Cacopsylla pyri apparently behaves as an endophyte rather than a pathogen. Environmental Mcrobiology 13, 14-26. EU FP7-2012-ID 311933 Project: WA-TER4CROPS (Integrating bio-treated wastewater with enhanced water use efficiency to support the Green Economy in EU and India). CONTACTS [email protected] [email protected] [email protected] [email protected] Alma A., Daffonchio D., Gonella E., Raddadi N. (2009). Microbial symbionts of auchenor-rhyncha transmitting phytoplasmas: a resource for 76 Industrial and Environmental Biotechnologies and Fluid-Dynamics – Industrial Biotechnologies BIOTECHNOLOGIES FOR THE SUSTAINABLE PRODUCTION OF BIOPOLYMERS AND THE DEGRADATION/VALORIZATION OF CONVENTIONAL PLASTICS AND MICROPLASTICS RESEARCH GROUP: Lorenzo Bertin, Fabio Fava, Lucia Giacomucci, Andrea Negroni, Noura Raddadi, Giulio Zanaroli KEYWORDS: plastiche di scarto, biopolimeri, valorizzazione, biodegradazione The research has the objective of finding solutions to the environmental problems linked to the production and consumption of plastics, which are obtained on the industrial scale from fossil sources and accumulate in the environments in which they are disposed, because of their scarce biodegradability. To this aim, the exploitation of renewable resources for the production of microbial biodegradable biopolymers, which could replace conventional plastics in defined applications, can represent a strategic approach. In particular, polyhydroxyalkanoates (PHAs) are polyesters, which are stored by several aerobic bacteria as a carbon and energy source under a metabolic stress due to the lack of one or more nutrients. To date, PHAs are industrially produces by employing sugars obtained from dedicated crops. The research objective is the substitution of such substrates with typical wastes of the Mediterranean basin, such as olive mill wastewaters and winery waste. The residue organic material has to be converted in volatile fatty acids (VFAs) within acidogenic anaerobic digestion processes. The biodegradation/valorization of waste plastics represents a further possible strategy to the aims describes above. The research activity deals with the development of experimental procedures for the selection of novel and robust microorganisms, both as pure cultures and mixed consortia, able to attack polyethylenes, polypropylenes, polystyrene and polyvinyl chloride. For this purpose, actual-site aged plastic wastes obtained from landfills, terrestrial and marine sites will be utilized as sources of microorganisms potentially able of biodegrading plastics. Such microorganisms will be isolated and their biodegradation activity will be compared with those of private pure bacterial strains purchased from public culture collections. The opportunity to have controlled depolymerization of some polymers by selected enzymes to get oligomers to be reused in new or hydrid polymer production is also being evaluated. Fig. 1. PHA film obtained by chemical extraction of the polymer from C. necator culture. Fig. 2. Anaerobic microcosms for the enrichment of microbial communities from waste plastics able to degrade synthetic polymers. 77 Research Projects and Activities 2015 MAIN PUBLICATIONS Lampis S., Majone M., Valentino F., Vallini G., Villano M. (2009). Exlopiting olive mill effluents as a renewable resource for production of biodegradable polymenrs through a combined anaerobic-aerobic process. J. Chem. Technol. Biotechnol. 84(17), 901-908. Scoma A., Bertin L., Fava F. (2013). Effect of hydraulic retention time on biohydrogen and volatile fatty acids production during acidogenic di-gestion of dephenolized olive mill wastewaters. Biomass and Bioenergy 48, 51-58. Raddadi N., Crotti E., Rolli E., Marasco R., Fava F., Daffonchio D. (2012). The most important Bacillus species in biotechnology. In ESTIBALIZ SANSINENEA. Bacillus thuringiensis Biotechnology. p. 329-345, Max Haring-Springer press, Netherlands. RESEARCH PROJECTS EU FP7-KBBE-2012.3.5-02 Project ID. 312100: BIOCLEAN (New BIOtechnologiCaL approaches for biodegrading and promoting the environmEntal biotrAnsformation of syNthetic polymeric materials) Giacomucci L., Toja F., Sanmartín P., Toniolo L., Prieto B., Villa F., Cappitelli F. (2012). Degradation of nitrocellulose-based paint by Desulfovibrio desulfuricans ATCC 13541. Biodegradation, 23, 705-716. EU FP7-KBBE-2010-4 Project ID. 266473: ULIXES (Unravelling and exploiting Mediterra-nean Sea microbial diversity and ecology for xe-nobiotics’ and pollutants’ clean up). EU FP7-KBBE-2010-4 ID. 265669 Project: ECOBIOCAP (Ecoefficient Biodegradable Com-posite Advanced Packaging). Scoma A., Bertin L., Zanaroli G., Fraraccio S., Fava F. (2011). A physicochemical–biotechnological approach for an integrated valorization of olive mill wastewater. Bioresource technology 102, 10273-10279. EU FP7-2012-ID 311933 Project: WA-TER4CROPS (Integrating bio-treated wastewater with enhanced water use efficiency to support the Green Economy in EU and India). Bertin L., Lampis S., Todaro D., Scoma A., Vallini G., Marchetti L., Majone M., Fava F. (2010) Anaerobic acidogenic digestion of olive mill wastewaters in biofilm reactors packed with ce-ramic filters or granular activated carbon. Water Research 44, 4537-49. CONTACTS [email protected] [email protected] [email protected] Beccari M., Bertin L., Dionisi D., Fava F., 78 Industrial and Environmental Biotechnologies and Fluid-Dynamics – Industrial Biotechnologies BIOREMEDIATION OF CONTAMINATED MATRICES RESEARCH GROUP: Lorenzo : Lorenzo Bertin, Fabio Fava, Dario Frascari, Maurizio Mancini, Andrea Negroni, Massimo Nocentini, Davide Pinelli, Noura Raddadi, Giulio Zanaroli KEYWORDS: biodegradation, biostimulation, bioreactors, microbial immobilization, modeling The aim of the research line is to develop innovative biotechnological processes for the decontamination of soils, sediments, groundwaters and wastewaters contaminated by chlorinated and non-chlorinated hydrocarbons and by polimeric compounds. The decontamination is attained either by stimulating the indigenous microbial population of the contaminated matrix (with the possible addition of a suitable growth substrate for cometabolic processes), or by introducting in the contaminated matrix microbial populations specialized in the degradation of the target pollutants (bioaugmentation). The main aspects of the research approach are: (1) the enrichment and selection of indigenous microbial cultures, capable to degrade the target pollutants; (2) the biochemical, physiological, kinetic and phylogenetic characterization, of the microbial cultures; (3) the design, development, optimization and scale-up of the biodegradation process; (4) the evaluation of the process through an integrated chemical, microbiological, molecular-biological and ecotoxicological monitoring; (5) the fluid-dynamic and kinetic modeling of the process, and its further optimization on the basis of the results obtained. The main goals of the research are: (a) to develop immobilized-biomass processes in packed bed reactors, for the decontamination of ground- and waste-waters contaminated by non-ionic synthetic surfactants, polychlorinated biphenyls (PCBs), chlorobenzoic acids, phenols and chlorinated solvents; (b) to develop innovative bioreactors and advanced biodegradation strategies (use of biogenous mobilizing agents to increase pollutant bioavailability; bioaugmentation; cometabolism with pulsed feed of growth substrate) for the decontamination of soils; (c) to detect, characterize and stimulate the microbial degradation of chlorinated and non-chlorinated organic pollutants in anaerobic sediments; d) to verify the applicability and the effectiveness of the proposed biodegradation approach to the treatment of rain waters collected from streets and industrial areas, by studying the pilot-scale application of the process in Sequencing Batch Reactors. Fig. 1. Attached-cell bioreactor for the treatment of groundwater. Fig. 2. Molecular analysis of the active microbial populations. 79 Research Projects and Activities 2015 (2010). Formal verification of wastewater treatment processes using events detected from continuous signals by means of artificial neural networks. Case study: SBR plant, International Review: Environmental Modelling & Software. Thematic issue on modelling and automation water and wastewater treatment processes 25, 648-660. Di Gioia D., Sciubba L., Bertin L., Barberio C., Salvatori L., Frassinetti S., Fava F. (2009). Nonylphenol polyethoxylate degradation in aqueous waste by the use of batch and continuous biofilm bioreactors. Water Research 43, 2977-2988. Occulti F., Camera Roda G., Berselli S., Fava F.. (2008). Sustainable decontamination of an actual site aged PCB polluted soil through a biosurfactant-based washing followed by a photocatalytic treatment. Biotechnology and Bioengineering 99, 1525 - 1534. RESEARCH PROJECTS EU Project FP7-KBBE-2012-3.5-02 ID 312100: BIOCLEAN (Novel biotechnological approaches for biodegrading and promoting the environmental biotransformation of synthetic polymeric materials). EU Project EU FP7-KBBE-2012-3.5-01 ID 312139: KILL SPILL (Integrated biotechnological solutions for combating oil spills). EU Project EU FP7-KBBE-2010-4 ID 265946: MINOTAURUS (Microorganism and enzyme Immobilization: novel techniques and approaches for upgraded remediation of underground-, wastewater and soil). EU Project EU Project FP7-KBBE-2010-4 ID 266473: ULIXES (Unravelling and exploiting Mediterranean Sea microbial diversity and ecology for xenobiotics’ and pollutants’ clean up). PRIN 2008: Novel processes for the sustainable remediation of groundwater contaminated by chlorinated compounds. MAIN PUBLICATIONS Frascari D., Fraraccio S., Nocentini M., Pinelli D. (2013). Aerobic / anaerobic / aerobic sequenced biodegradation of a mixture of chlorinated ethenes, ethanes and methanes in batch bioreactors. Bioresource Technology 128, 479-486. Zanaroli G., Balloi A., Negroni A., Borruso L., Daffonchio D., Fava F. (2012). A Chloroflexi bacterium dechlorinates polychlorinated biphenyls in marine sediments under in situ-like biogeochemical conditions. Journal of Hazardous Materials 209-210, 449-457. Zanaroli G., Negroni A., Vignola M., Nuzzo A., Shu H. – Y., Fava F. (2012). Enhancement of microbial reductive dechlorination of polychlorinated biphenyls (PCBs) in a marine sediment by nanoscale zerovalent iron (NZVI) particles. Journal of Chemical Technology and Biotechnology 87, 1246-1253. Ciavarelli R., Cappelletti M., Fedi S., Pinelli D., Frascari D. (2012). Chloroform aerobic cometabolism by butane-growing Rhodococcus aetherovorans BCP1 in continuous-flow biofilm reactors. Bioprocess Biosystems Engineering 35, 667-681. Frascari D., Cappelletti M., Fedi S., Verbaschi A., Ciavarelli R., Nocentini M., Pinelli D. (2012). Application of the growth substrate pulsed feeding technique to a process of chloroform aerobic cometabolism in a continuous-flow sand-filled reactor. Process Biochemistry 47, 1656-1664. Zanaroli G., Balloi A., Negroni A., Daffonchio D., Young L.Y., Fava F. (2010). Characterization of the microbial community from the marine sediment of the Venice lagoon capable of reductive dechlorination of coplanar polychlorinated biphenyls (PCBs). Journal of Hazardous Materials 178, 417-426. Zanaroli G., Di Toro S., Todaro D., Varese G.C., Bertolotto A., Fava F. (2010). Characterization of two diesel fuel degrading microbial consortia enriched from a non-acclimated, complex source of microorganisms. Microbial Cell Factories 9, 10. Luccarini L., Bragadin G.L., Colombini G., Mancini M., Mello P., Montali M., Sottara D. CONTACTS [email protected] [email protected] [email protected] [email protected] 80 Industrial and Environmental Biotechnologies and Fluid Dynamics – Environmental Biotechnologies WASTEWATER TREATMENT AND PLANT MANAGEMENT RESEARCH GROUP: Maurizio Mancini KEYWORDS: nitrogen removal, rainy conditions, finishing, monitoring, neural network, WWTP management The research activity about URBAN WASTEWATER TREATMENT is carried out by: • full scale investigation in Bologna WWTP about oxidization, foaming as effect filamentous biomasses and functioning during variations in dilution due to rainy weather conditions. Results concern: • efficiency in nitrogen removal in function of SRT and HDOC • efficiency in primary phases with increased flow during rainy weather conditions and in oxygen dissolving in presence of filamentous biomasses. Research activity about WASTEWATER PLANT MANAGEMENT is developed by: • monitoring and full scale investigations in Funo (BO) SBR WWTP and in Trebbo (BO) SSR WWTP, • continuous monitoring and laboratory scale investigations on a plant model realized in Bologna ENEA PROT laboratories. Obtained results permit: • identification of events and typical behaviors of signals useful in focusing variations in active biochemical processes, • description of transitory answer obtained by orders on control plant parameters pointed out by artificial neural network. Reserach activity about FINISHING, RECOVERY AND REUSE OF TREATED URBAN WASTEWATER is developed by: • full scale investigations about finishing effect of FWS phytotreatment systems and facultative lagoons, • laboratory experimentations about anionic/ cationic/non ionic surfactants removal by magnetic filtering, • full scale and pilot scale experiences about flow conditions and removal efficiency of O.S. and nutrients in H-SFS / V-SFS phytotreatment plants Results consist in discussions about: • efficiency in disinfection and nitrogen removal of floating macrophytes and microalgal biomass, • efficiency in surface-active substance removal, • efficiency of finishing systems and on site treatment in order to respect exysting law about wastewater recover and reuse. 81 Fig. 1. Bologna WWTP. Modelling of O.S. removal efficiency in primary and secondary treatment phases during rainy events. Fig. 2. Riccione (FC). Sea outlet of Marano river receiver of effluents from Riccione WWTP. Fig. 3. Cesenatico (FC). Allacciamento channel. Modelling of finishing effect on discharged treated wastewaters. Facultative lagoon scheme applied to varying conditions flow due to tidal oscillations. Research Projects and Activities 2015 head channel area at Ravenna: functions, design, environmental impact. Proc. of the 34th IABSE International Symposium on large structures and infrastructures for environmentally constrained and urbanized areas. IABSE 2010-Venice Italy. 22 - 24 September 2010. (vol. 1, pp. 790/1- 8). ISBN: 978-3-85748-122-2. Borghi C.C., Fabbri M., Fiorini M., Mancini M., Ribani P.L. (2011). Magnetic removal of surfactants from wastewater using micrometric iron oxide powders. International Review: SEPARATION AND PURIFICATION TECHNOLOGY 83, 180-188. Mancini M.L. (2012). Surfactants removal from industrial laundry wastewater using combined bio-oxidative and physical/chemical processes. Proceed. International Symposium of Sanitary and Environmental Engineering, 9th edition.-Milan (Italy). 26-29 june 2012. (vol. 1, pp. 895/1895/8). ISBN: 978-88-903557-2-1. Mancini M.L. (2012). Wastewater finishing by facultative lagoons open to tidal flow: field experiences in the internal system of channels at Cesenatico FC- Proceed. International Symposium of Sanitary and Environmental Engineering, 9th edition.-Milan (Italy). 26-29 june 2012. (vol. 1, pp. 890/1 - 890/8). ISBN: 978-88-903557-2-1. Luccarini L., Pulcini D., Marsilio F., Di Francia M., Mancini M., Sottara D. (2012). The use of modelling to implement strategies in automatic control of WWTPs Proc. Internat.Symposium of Sanitary and Environmental Engineering, 9th edition.-Milan (Italy). 26-29 june 2012. (vol. 1, pp. 1092/1 1092/4). ISBN: 978-88-903557-2-1. Archetti R., Mancini M.L. (2012). Freshwater Dispersion Plume in the Sea: Dynamic Description and Case Study. Hydrodynamics - Natural Water Bodies. INTECH Ed. Rijeka (pp.129152). ISBN: 978-95-330789-3-9. RESEARCH PROJECTS DISTART-DEIS-ENEA ACS Dept.-HERA BO. Project: Authomatic Management of Municipal Wastewater Treatment. CIRI - TECNOPOLI Project: Fluidodinamica per le applicazioni ambientali. MAIN PUBLICATIONS Bragadin G.L., Mancini M.L. (2008). Combined sewage-rain urban drainage system and active sludge WWTP design. Proceed. ANDIS-DICEA-IWA. International Symposium on Sanitary and Environmental Engineering-SIDISA 08 -Florence (Italy). 24-27 june 2008. (vol. 1, pp. 94/1 - 94/8). ISBN: 978-88-903557-0-7. Mancini M.L. (2008). Wastewater finishing by combined algal and bacterial biomass in a tidal flow channel. Modeling and field experiences in Cesenatico.Proceed.ANDIS-DICEA-IWA.Intern. Symp. on Sanitary & Environmental Engineering -SIDISA 08 -Florence (Italy). 24-27 june 2008. (vol. 1, pp. 50/1-50/8). ISBN: 978-88-903557-0-7. Luccarini L., Bragadin G.L., Mancini M.L., Mello P., Montali M., Sottara D. (2008) Process Quality Assessment in automatic management of wastewater treatment plants using Formal Verification. Proceed..International Symposium on Sanitary and Environmental Engineering-SIDISA08.Florence(Italy). 24-27 jun 2008. (vol.1, pp.152/1-152/8). ISBN: 978-88-903557-0-7. Giordano A., Aldrovandi A., Farina R., Mancini M.L., Stante L. (2008). Utilizzo di una MFC per la degradazione di sostanza organica e recupero di corrente elettrica. Primi risultati sperimentali. Proceed. International Symposium on Sanitary & Environmental Engineering-SIDISA08. Florence (Italy), 24-27 jun 2008 (vol.1/8, pp.111/1111/8). ISBN:978-88-903557-0-7. Bragadin G.L., Mancini M.L., Turchetto A. (2009). Wastewater discharge by estuarine transition flow and thermoaline conditioning in shore habitat near Cesenatico breakwaters. Proc. Fifth Internat. Conference on Coastal Structures. Coastal Structures 2007-Venice. July 2-4, 2007. (pp.1101-1112). World Scientific Publishing Company Pte Ltd (SINGAPORE). Luccarini L., Bragadin G.L., Colombini G., Mancini M.L., Mello P., Montali, M., Sottara D.(2010). Formal verification of wastewater treatment processes using events detected from continuous signals by means of artificial neural networks. Case study: SBR plant. Environmental Modelling & Software review 25, issue 5, 648-660. Bragadin G.L., Mancini M.L. (2010). Stormwater tanks option in remediation of Candiano CONTACTS [email protected] 82 Industrial and Environmental Biotechnologies and Fluid Dynamics – Environmental Biotechnologies SEA POLLUTION AND WASTEWATER OUTFALLS RESEARCH GROUP: Maurizio Mancini, Renata Archetti KEYWORDS: Oil spill, wastewater, thermoaline conditions, drifter, plume, sea currents, dispersion model • validation and calibration of a 3D dispersion model, applied to a plume dispersion in low depth sea areas characterized by along-shore submerged and emerged breakwaters. The research activity about WASTEWATER DISCHARGE IN COASTAL WATERS AND EFFECTS ON AQUATIC ECOSYSTEMS is carried out by: • coastal dispersion modelling of freshwater coming from mouth of harbour channels and carrying out monitoring campaigns of sea water quality data. Research field are the Marano estuary mouth receiving the outfall of Riccione WWTP and Rimini Nord along-shore area, characterized by presence of coastal breakwaters near sea outlet of Marecchia river, • monitoring campaigns of hydraulic parameters and water quality analysis executed in different tract of internal channels connected to Cesenatico port canal. Results concern • pointing out and calibration of a quality model describing aquatic ecosystem of transition waters in summer dry weather conditions, • evaluation of thermoaline profile role in maintaining nutrients and pollutants in surface layers of coastal sea, • model calibrations and prediction of freshwater dispersion plume area in summer dry weather conditions. The research activity about OIL SPILL OFF SHORE OUTFALLS AND COASTAL ZONE POLLUTANTS DISPERSION is developed by • testing drifter performances in tracing such offshore as coastal trajectory of floating discharged substances in different conditions of sea currents and winds, • monitoring of freshwater discharged from Cesenatico harbour channel mouth during tidal phases and varying thermoaline conditions, • measurements campaigns in coastal sea of vertical profiles of oxygen,temperature, salinity, pH, redox describing effects of breakwaters in conditioning freshwater alongshore distribution. Results consist in: • design of a proper oil spill drifter and tools to predict oil spill and validate numerical codes (GNOME, Medslik), Fig. 1. Sea trajectory monitoring described by oil spill drifters. Measurement campaigns carried out in the coastal area facing Cesenatico between june and september 2009. Fig. 2. Dispersion modelling of freshwater coming from Cesenatico Port Canal basin. Simulation of the plume dispersion during different wind and current conditions. 83 Research Projects and Activities 2015 merged breakwaters MED & Black Sea ICM08 INTER-NATIONAL CONFERENCE/ WORKSHOP. Akyaka (Turkey). 14-18 oct 2008.(vol.1,pp.1/1-1/12). MAIN PUBLICATIONS Archetti R.. (2009). Design of surface drifter for the oil spill monitoring. REVUE PARALIA. Coastal and Maritime Mediterranean Conference. HAMMAMET, TUNISIE (2009). 2-5 Dec 2009. vol. 1, pp. 231 – 234 Mancini M.L. (2008) - Wastewater finishing by combined algal and bacterial biomass in a tidal flow channel. Modeling and field experiences in Cesenatico. Proceedings ANDIS-DICEA-IWA. International Symposium on Sanitary & Environmental Engineering -SIDISA 08-Florence (Italy). 24-27 june 2008. (vol. 1, pp. 50/1-50/8). ISBN:978-88-903557-0-7. Archetti R., Mancini M. (2010). Model Calibration of a wastewater dispersion plume from a channel harbor by drifter and profilers. Coastlab2010 Archetti R., Mancini M.L. (2012). - Freshwater Dispersion Plume in the Sea: Dynamic Description and Case Study. Hydrodynamics - Natural Water Bodies. INTECH Ed. Rijeka (pp. 129152) ISBN: 978-95-330789-3-9 Mancini M.L. (2009). - Impatti dello smaltimento fanghi.- Atti del III Convegno Nazionale: Contributi operativi alla salvaguardia della balneazione 1988-1998-2008.1988. Riccione. 4 aprile 2008. (vol.1,pp.1/1- 1/14). ISBN: 97888-903945-0-8 Archetti R. Mancini M.L. (2013). - Freshwater discharge by estuarine transition flow near Cesenatico (Italy) . J. Coast. Res. 65. 13-15. Doi 10.2112/SI65.03.1 Mancini M.L. (2009). - Wastewater discharge and thermoaline conditioning in south Cesenatico (I) coastal area near breakwaters. Proceedings of the Ninth International Conference on the Mediterra-nean Coastal Environment. MEDCOAST 09 - Sochi-Russia 10-14 november 2009. (vol. 1, pp. 143/1 - 143/7). Bragadin G.L., Mancini M.L., Turchetto A. (2009) - Wastewater discharge by estuarine transition flow and thermoaline conditioning in shore habitat near Cesenatico breakwaters. Proc. Fifth Internat. Conference on Coastal Structures. Coastal Structures 2007-Venice. July 2-4, 2007. (pp.1101-1112). World Scientific Publishing Company Pte Ltd (SINGAPORE). Mancini M.L. (2012). Wastewater finishing by facultative lagoons open to tidal flow: field experiences in the internal system of channels at Cesenatico FC- Proceedings of the International Symposium of Sanitary and Environmental Engineering, 9th edition.- Milan (Italy). 26-29 june 2012. (vol. 1, pp. 890/1 - 890/8). ISBN: 978-88-903557-2-1 De Dominicis M. , Pinardi N., Zodiatis G., and Archetti R. (2013 ) - Lagrangian marine oil spill modeling for short-term forecasting. Part II: Numerical simulations and validations. Geoscientific Model Development discussion. 6 (1). pp. 1999-2043. RESEARCH PROJECTS Mancini M.L. (2005) - Estuarine Wastewater Draining into Riccione (I) Coast and Thermoaline Set due to Along-Shore Sand Bar. Proceedings of the Seventh International Conference on the Mediterranean Coastal Environment. MEDCOAST 05 - Kusadasi (Turkey) 25-29 oct 2005. (vol. 2, pp. 815-826). ISBN: 975-00526-0-9. ANKARA: MEDCOAST Secretariat (TURKEY). - PRIMI: Pilot project: marine hydrocarbon pollution. Financed by Agenzia Spaziale ItalianaCIRI - TECNOPOLI Project: Fluidodinamica per le applicazioni ambientali CONTACTS [email protected] [email protected] [email protected] Mancini M.L. (2008) Thermoaline conditioning in Cesenatico coastal seawater due to sub- 84 Industrial and Environmental Biotechnology and Fluid-Dynamics – Biofuels BIOFUEL PRODUCTION FROM BIOMASSES, MUNICIPAL SOLID WASTE AND SEWAGE SLUDGE RESEARCH GROUP: Lorenzo Bertin, Fabio Fava, Dario Frascari, Alessandro Paglianti, Davide Pinelli, Noura Raddadi, Giulio Zanaroli KEYWORDS: municipal solid waste, organic wastes, anaerobic digestion, biomethane, biohydrogen, biodiesel The aim of this research line is to study and optimize the production of biofuels through the anaerobic digestion (AD) of organic waste (biohydrogen and biomethane) and the exploitation of lipid-rich biomasses and waste matrices (biodiesel). The research on anaerobic digestion has the following goals: a) the study of the biomethanization of unconventional waste matrices, such as algae, municipal solid waste, activated sludge from the treatment of industrial waste, food industry waste; b) the development of chemical, physical and enzymatic pretreatments for the subsequent biomethanization of organic matrices with a high ligno-cellulosic content; c) the development of innovative bioreactors (biofilm reactors; non-conventional mixing techniques); d) the development of two-stage processes, with bioproduction of hydrogen in the 1st stage and methane in the 2nd; e) the development of prototype reactors aimed at the study and optimization of the process fluid-dynamics, using techniques such as Particle Image Velocimetry and Tomography; f ) the kinetic and fluid-dynamic modeling of the process, including the use of Computational Fluid Dynamics (CFD), and its subsequent optimization. The research approach includes the biochemical, physiological, phylogenetic and kinetic characterization of the microbial cultures. A second research line aims at the optimization of the process of biodiesel production from lipid-rich seeds, algae, bacteria and organic wastes. The specific research goals are: a) the energetic optimization of the process; b) the study of innovative mixing techniques (such as static mixers), also through CFD; c) the development of innovative processes with heterogeneous and/or enzyatic catalysis; d) the optimization of the separation of biodiesel from the polar phase (glycerin and process water) through the use of coalescers; e) the biotechnological exploitation of glycerol through its conversion to 1,3-propanediol; f ) the kinetic and fluid-dynamic modeling of the process. The available equipment includes several reactors, with pH and temperature control and mechanical agitation, in the 1-30 L volume range. Fig. 1. Bioreactor for the biological production of hydrogen. Fig. 2. Bioreactors for the biomethanization of organic wastes. 85 Research Projects and Activities 2015 with cattle manure in packed microcosms under batch conditions, Water Sci. Technol., 58, 17351742. MAIN PUBLICATIONS Bertin L., Grilli S., Spagni A., Fava F. (2013). Innovative two-stage anaerobic process for effective codigestion of cheese whey and cattle manure. Biores. Technol., 128, 779-783. Frascari D., Zuccaro M., Pinelli D., Paglianti A. (2008). A pilot-scale study of alkali-catalysed sunflower oil transesterification with static mixing and with mechanical agitation. Energy & Fuels, 22, 1493–1501. Cappelletti M., Bucchi G., De Sousa Mendes J., Alberini A., Fedi S., Bertin L., Frascari D. (2012). Biohydrogen production from glucose, molasses and cheese whey by suspended and attached cells of four hyperthermophilic Thermotoga strains. J. Chem. Technol. Biotechnol., 87, 1291-1301. Bertin L., Capodicasa S., Occulti F., Girotti S., Marchetti L., Fava F. (2007). Microbial processes associated to the decontamination and detoxification of a polluted activated sludge during its anaerobic stabilization, Water Res., 41, 2407-2416. Bertin L., Bettini C., Zanaroli G., Frascari D., Fava F. (2012). A continuous-flow approach for the development of an anaerobic consortium capable of an effective biomethanization of a mechanically sorted organic fraction of municipal solid waste as the sole substrate. Water Res., 46, 413-424. Dionisi D., Bertin L., Bornaroni L., Capodicasa S., Petrangeli Papini M., Fava F. (2006). Removal of organic xenobiotics in activated sludges under aerobic conditions and anaerobic digestion of the adsorbed species, J. Chem. Technol. Biotechnol., 81, 1496-1505. Bertin L., Bettini C., Zanaroli G., Fraraccio S., Negroni A., Fava F. (2012). Acclimation of an anaerobic consortium capable of an effective biomethanization of mechanically-sorted organic fraction of municipal solid waste through a semi-continuous enrichment procedure. J. Chem. Technol. Biotechnol., 87, No 9, 1312-1319. RESEARCH PROJECTS EU Project FP6-2004-ID 019829: BIOCARD (Global process to improve Cynara cardunculus exploitation for energy applications) (20052009). BIOHYDRO Project (Combined production of hydrogen and methane from agro-industrial wastes by biological processes) (2009-2013), financed by the Italian Ministry of Food and Agriculture (MIPAAF). Casali S., Gungormusler M., Bertin L., Fava F., Azbar N. (2012). Development of a biofilm technology for the production of 1,3-propanediol (1,3-PDO) from crude glycerol. Biochem. Eng. J., 64, 84-90. EXTRAVALORE Project (Valorization of the by-products of the biodiesel production process) (2010-2013), financed by the Italian Ministry of Food and Agriculture (MIPAAF). Bertin L., Capodicasa S., Fedi S., Zannoni D., Marchetti L., Fava F. (2011). Biotransformation of a highly-chlorinated PCB mixture in an activated sludge collected from a Membrane Biological Reactor (MBR) subjected to anaerobic digestion. J. Hazard. Mater., 186, 2060-2067. EU Project FP7-2012-ID 311933: WATER4CROPS (Integrating bio-treated wastewater with enhanced water use efficiency to support the Green Economy in EU and India). Frascari D., Zuccaro M., Paglianti A., Pinelli D. (2009). Optimization of mechanical agitation and evaluation of the mass-transfer resistance in the oil transesterification reaction for biodiesel production. Ind. Eng. Chem. Res., 48, 7540-7549. CONTACTS [email protected] [email protected] [email protected] [email protected] Bertin L., Todaro D., Bettini C., Fava F. (2008). Anaerobic codigestion of the mechanically sorted organic fraction of a municipal solid waste 86 Industrial and Environmental Biotechnologies and Fluid Dynamics – Applied Fluid Dynamics and Mixing APPLIED FLUID DYNAMICS AND MIXING RESEARCH GROUP: Alessandro Paglianti KEYWORDS: mixing, multi-phase flow, optical techniques, computational fluid dynamics, inertial separation The Applied Fluid Dynamics and Mixing Group is mainly concerned with the investigation of the behaviour of equipment typically employed in the chemical and process industries. Special focus has been given to fluid mixing problems, but over the past few years attention has also been extended to fluidised beds, static mixers, membrane modules for gas mixture separations, filter-press and inertial separators for oil and gas applications. Research efforts have been equally devoted to the development of experimental and computational techniques for the characterization and the prediction of single and multiphase flows in different process equipment. The studies in these areas are based on state-of-art experimental techniques and Computational Fluid Dynamics, on the development of mathematical and/or phenomenological models and on the application of these modelling techniques to the design, rating and optimisation of equipment. The experimental laboratory of the research group is fully equipped for the fluid dynamic characterization of the apparatuses through two complete Particle Image Velocimetry systems (2D-PIV and Stereo-PIV), that can be used in stereoscopic configuration for the detection of the three components of the velocity fields and that can be also adopted for mixing time measurements (PLIF technique). A PIV systems has been implemented for simultaneous two-phase flow measurements and the other for bubble size and BSD determination. Recently, the investigation of dense multiphase systems based on Electrical Resistance Tomography (ERT) has been started. For the computational activity, general purpose commercial CFD codes are usually adopted, implemented with in-house developed user functions for the introduction of specific models. As for the computer resources, several up-to-date computers are available, while on specific problems requiring particularly advanced computational resources, the supercomputing facilities of the High Perfor- mance Systems Department of CINECA have been used in the recent past. Fig. 1. Multiphase stirred tank: bubble size analysis. Fig. 2. CFD simulation of a stirred tank: the flow field. 87 Research Projects and Activities 2015 (2008). A pilot-scale study of alkali-catalysed sunflower oil transesterification with static mixing and with mechanical agitation. Energy & Fuels 22, 1493-1501. MAIN PUBLICATIONS Montante G., Paglianti A., Magelli F. (2012). Analysis of dilute solid-liquid suspensions in turbulent stirred tanks. Chemical Engineering Research and Design 90, 1448-1456. Laurenzi F., Coroneo M., Montante G., Paglianti A., Magelli F. (2009). Experimental and computational analysis of immiscible liquid-liquid dispersions in stirred vessels. Chemical Engineering Research and Design 87, 507-514. Montante G., Laurenzi F., Paglianti A., Magelli F. (2011). A study on some effects of a drag-reducing agent on the performance of a stirred vessel. Chemical Engineering Research and Design 89, 2262-2267. Coroneo M., Montante G., Giacinti Baschetti M., Paglianti A. (2009). CFD modelling of inorganic membrane modules for gas mixture separation. Chemical Engineering Science 64, 1085-1094. Coroneo M., Montante G., Paglianti A., Magelli F. (2011). CFD prediction of fluid flow and mixing in stirred tanks: Numerical issues about the RANS simulations. Computers and Chemical Engineering 35, 1959-1968. RESEARCH PROJECTS Coroneo M., Mazzei L., Lettieri P., Paglianti A., Montante G. (2011). CFD prediction of segregating fluidized bidisperse mixtures of particles differing in size and density in gas-solid fluidized beds. Chemical Engineering Science 66, 2317-27. PRIN 2006: Study of the fluid dynamics of mechanically stirred reactors and tubular reactors for the production of nanoparticles or microparticles. PRIITT 2008 (Regione Emilia Romagna): Analysis on the behavior of bi-phase fluids in filter presses. Coroneo M., Montante G., Paglianti A. (2010). Numerical and experimental fluid-dynamic analysis to improve the mass transfer performances of Pd-Ag membrane modules for hydrogen purification. Industrial and Engineering Chemistry Research 49, 9300-9309. Project EU FP6-2004-ID 019829: BIOCARD (Global Process to Improve Cynara cardunculus Exploitation for Energy Applications). BIOHYDRO Project (Combined production of hydrogen and methane from agro-industrial wastes by biological processes) (2009-2013), financed by the Italian Ministry of Food and Agriculture (MIPAAF). Montante G., Laurenzi F., Paglianti A., Magelli F. (2010). Two-phase flow and bubble size distribution in air-sparged and surface-aerated vessels stirred by a dual impeller. Industrial and Engineering Chemistry Research 49, 2613-2623. Industrial projects miscellanea: A2B- Development of a process for the recovery of waste oil (2011), Comart- Fluid-dynamic study of a slug catcher and of the cold finger process (2009), Costacurta- Fluid dynamic analysis of an inertial separator (2008), Pittaluga- Theoretical and experimental study of the fluid dynamic behavior of a static mixer (2008), Saddam Engineering- Pre-treatment and anaerobic digestion of stabilized marcs (2012). Frascari D., Zuccaro M., Paglianti A., Pinelli D. (2009). Optimization of mechanical agitation and evaluation of the mass-transfer resistance in the oil transesterification reaction for biodiesel production. Industrial & Engineering Chemistry Research 48, 7540-7549. Coroneo M., Montante G., Catalano J., Paglianti A. (2008). Modelling the effect of operating conditions on hydrodynamics and mass transfer in a Pd-Ag membrane module for H2 purification. Journal of Membrane Science 343, 34-41. CONTACTS Frascari D., Zuccaro M., Pinelli D., Paglianti A. [email protected] 88 Industrial Safety and Environmental Sustainability Industrial Safety and Environmental Sustainability – Industrial Safety METHODS AND MODELS FOR THE ANALYSIS OF DOMINO EFFECT IN THE PROCESS INDUSTRY RESEARCH GROUP: Alessandro Tugnoli, Giacomo Antonioni, Valerio Cozzani KEYWORDS: Industrial Safety, Major Accident Hazard, Quantitative Risk Assessment, Domino Effect, Escalation Domino effect was responsible of several catastrophic accidents. Escalation of primary accidental scenarios triggering domino effect have caused extremely severe accidental events in the chemical and process industry. As a matter of facts, severe accidents may arise from the escalation of primary events to trigger secondary scenarios. Hence, the identification of possible escalation events is required in the safety assessment of sites where relevant quantities of hazardous substances are stored or handled. In the European Union, the “Seveso-II” Directive (96/82/EC) requires the assessment of on-site and off-site possible escalation scenarios in sites falling under the obligations of the Directive. The present study aims to the development of a general methodology and of support tools for the quantitative assessment of risk due to domino effect. A set of models for the calculation of equipment damage probability is developed and combined to improved criteria for the calculation of threshold values for equipment damage. A specific effort is dedicated to the improvement of models for the calculation of equipment damage probability due to jet and pool fires. In this framework, experimental studies are carried out to assess the performance of fireproofing materials used to delay the heat-up of vessels involved by fire. Experimental results are coupled to finite element models to obtain a detailed model for the prediction of time to failure. These results will be coupled to a layer of protection assessment of mitigation systems, in order to calculate the expected probability of successful mitigation with respect to the escalation scenarios. The improved vulnerability models were applied to the calculation of the contribution of escalation scenarios to the overall industrial risk due to major accident hazard. The “domino package” of the Aripar-GIS software was upgraded to allow its use for risk recomposi- tion accounting for the contribution of domino effect. The set of tools developed allows the quantitative assessment of domino effect in complex lay-outs and extended industrial areas. Fig. 1. Large-scale test on a pressurized vessel involved in fire. Fig. 2. Finite Elements Modeling of a pressurized vessels involved in fire and increase in individual risk caused by domino accidents. 91 Research Projects and Activities 2015 simplified model for the assessment of the impact probability of fragments. J. Haz.Mat., vol. 116, p. 175. MAIN PUBBLICATIONS Antonioni, G., Spadoni, G., Cozzani, V. (2009). Application of Domino Effect Quantitative Risk Assessment to an Extended Industrial Area. Journal of Loss Prevention in the Process Industry vol.19, pp. 463-477. Gubinelli, G., & Cozzani, V. (2009). Assessment of Missile Hazard: Reference Fragmentation Patterns of Process Equipment. J. Haz. Mat., vol. 163 pp.1008-1018. Bonvicini, S., Ganapini, S., Spadoni, G., Cozzani, V. (2012). The description of population vulnerability in Quantitative Risk Analysis. Risk Analysis vol. 32, p. 1576 Gubinelli, G., & Cozzani, V. (2009b). Assessment of Missile Hazard: Evaluation of Fragment Number and Drag Factors. J. Haz.Mat., vol. 161, pp. 439-449. Cozzani, V., Gubinelli, G., Antonioni, G., Spadoni, G., Zanelli, S. (2005). The assessment of risk caused by domino effect in quantitative area risk analysis. J. Haz. Mat. vol. 127, p. 14. Landucci, G., Gubinelli, G., Antonioni, G., Cozzani, V. (2009). The assessment of the damage probability of storage tanks in domino events. Accident Analysis and Prevention vol. 41, pp. 1206-1215. Cozzani, V., Gubinelli, G., Salzano, E. (2006). Escalation thresholds in the assessment of domino accidental events. Journal of Hazardous Materials vol.129, pp. 1-21. Reniers, G.L.L., Cozzani, V. (2013). Domino effects in the process industries: Modeling, Prevention and Managing. Elsevier, London (UK). Cozzani, V., Antonioni, G., Spadoni, G., (2006). Quantitative assessment of domino scenarios by a GIS-based software tool. J. Loss Prev. Proc. Ind. vol. 19, p. 463. Spadoni, G., Egidi, D., Contini, S. (2000). Through ARIPAR-GIS the quantified area risk analysis supports land-use planning activities. J. Haz.Mat. vol. 71, p. 423. Cozzani, V., Salzano, E., (2004). The quantitative assessment of domino effect caused by overpressure. Part I: probit models. J. Haz.Mat. vol. 107, p. 67. Spadoni, G., Contini, S., Uguccioni, G. (2003). The New Version of ARIPAR and the Benefits Given in Assessing and Managing Major Risks in Industrialised Areas. Proc. Safety Env. Protection vol. 81, p. 19. Di Padova, A., Tugnoli, A., Cozzani, V., Barbaresi, T., Tallone, F. (2011). Identification of fireproofing zones in Oil&Gas facilities by a risk-based procedure. Journal of Hazardous Materials vol. 191, p. 83. RESEARCH PROJECTS ERGO Project - Value at risk of oil barrel - Convenzione Eni Exploration & Production - DICMA (2012-2014) Egidi, D., Foraboschi, F.P., Spadoni, G., Amendola, A., (1995). The ARIPAR project: an analysis of the major accident risks connected with industrial and trasnportation activities in the Ravenna area. Reliability Eng. System Safety vol.49, p. 75. TOSCA - Total Operation Management for Safety Critical Activities. European Commission, 7th Framework Programme - Nanoscience, Nanotechnologies, Materials and New Production Technologies (2013-2015). Gomez-Mares, M., Tugnoli, A., Landucci, G., Cozzani, V. (2012). Performance Assessment of Passive Fire Protection Materials. Industrial and Engineering Chemistry Research vol. 51, p. 7679. CONTACTS [email protected] [email protected] [email protected] Gubinelli, G., Zanelli, S., Cozzani, V., (2004). A 92 Industrial Safety and Environmental Sustainability – Industrial Safety ANALYSIS OF TECHNOLOGICAL ACCIDENTS TRIGGERED BY NATURAL DISASTERS (NATECH EVENTS) RESEARCH GROUP: Valerio Cozzani, Sarah Bonvicini, Giacomo Antonioni, Amos Necci, Alessandro Tugnoli, Gigliola Spadoni KEYWORDS: Industrial Safety, Major Accident Hazard, Natural Events, Technological Accidents, NaTech External hazard factors as natural events and intentional acts of interference are perceived as important threats affecting the safety of chemical and process plants. The increasing frequency of some natural events having a particularly high severity also raised a growing concern for the integrity of industrial assets and for the consequences of major accident scenarios that may be triggered by intense natural events and that may lead to the release of huge quantities of hazardous substances. The specific features of technological accidents triggered by natural events were recently recognized, and these scenarios are now indicated as NaTech (Natural-Technological) accidents. The analysis of past accident databases points out that NaTech accidents frequently impacted industrial facilities. However, these scenarios are seldom considered in major accident hazard assessment, as well as in safety assessment of industrial facilities. Methodologies and tools for the specific assessment of the potential consequences of NaTech accidents were only recently developed, and are still missing for a number of specific NaTech scenarios. The present activity aims at the development of a framework for the analysis of NaTech accidents and to the advancement of tools aimed at the assessment of NaTech events. A first aim of the activity is the development of screening criteria to apply on a regional scale, to identify hot-spots and critical sites for NaTech scenarios. A second issue is the development of models for the probability of failure of equipment items when involved in natural events. A third activity is the development of a specific methodology supported by a software tool aimed at the calculation of the individual and societal risk due to NaTech scenarios. Results obtained for case-studies evidenced that technological accidents triggered by natural events may stronly affect the overall risk due to an industrial activity. Fig. 1. Effects of an earthquake on a process plant. Fig. 2. Individual risk calculated including NaTech accident scenarios caused by seismic events. 93 Research Projects and Activities 2015 Renni, E., Cozzani, V., Antonioni, G., Krausmann, E., Cruz A.M. (2009). Assessment of major accidents triggered by lightning. Proc. Eur. Safety and reliability conf., Taylor & Francis: London; pp. 959-965. MAIN PUBBLICATIONS Antonioni, G., Spadoni G., Cozzani, V. (2007). A methodology for the quantitative risk assessment of major accidents triggered by seismic events. J. Hazardous materials 147, 48. Renni, E., Krausmann, E., Cozzani, V. (2010). Industrial accidents triggered by lightning. J. Hazardous Materials 184, 42. Antonioni, G., Bonvicini, S., Spadoni, G., Cozzani, V. (2009). Development of a general framework for the risk assessment of NaTech accidents. Reliability engineering system safety 94, 1442. Sabatini, M., Ganapini, S., Bonvicini, S., Cozzani, V., Zanelli, S., Spadoni, Gigliola (2008). Ranking the attractiveness of industrial plants to external acts of interference. Proc. Eur. Safety and reliability conf., Taylor & Francis: London; pp. 1199-205. Campedel, M., Cozzani, V., Garcia-Agreda, A., Salzano, E. (2008). Extending the quantitative assessment of industrial risks to earthquake effects. Risk analysis, 28,1231. Salzano, E., Basco, A., Busini, V., Renni, E., Rota, R., Cozzani, V. (2010). Acceptability parameters for industrial risk with respect to natural-technological interactions. Proc. 13th international symposium on loss prevention and safety promotion, Ti-Kviv, Antwerpen (B); pp. 81-88. Cozzani, V., Salzano, E., Campedel, M., Sabatini, M., Spadoni, G. (2007). The assessment of major accidents caused by external events. Proc. 12th int. Symp. On loss prevention and safety promotion, Icheme, Rugby (UK), pp.331-336. Cozzani, V., Campedel, M., Renni, E., Krausmann, E. (2010). Industrial accidents triggered by flood events: analysis of past accidents. J. Hazardous Materials 175, 501. RESEARCH PROJECTS iNTeg-Risk - Early Recognition, Monitoring, and Integrated Management of Emerging, New Technology related, Risks. European Commission, 7th Framework Programme - Nanoscience, Nanotechnologies, Materials and New Production Technologies. Large scale integrating project, 2008-2013 Krausmann, E., Cozzani, V., Salzano, E., Renni, E. (2011). Industrial accidents triggered by natural hazards: an emerging risk issue. Natural hazards and earth system sciences 11, 921. Krausmann, E., Renni, E., Campedel, M., Cozzani, V. (2011). Industrial accidents triggered by earthquakes, floods and lightning: lessons learned from a database analysis. Natural hazards 59, 285. Framework agreement DICMA - EC JRC IPSC 2011-2014 Convenzione quinquennale DICMA - Agenzia Regionale di Protezione Civile Emilia-Romagna (2010-2015) Landucci, G., Antonioni, G., Tugnoli, A., Cozzani, V. (2012). Release of hazardous substances in flood events: damage model for atmospheric storage tanks. Reliability engineering and system safety. CONTACTS valerio. [email protected] [email protected] [email protected] [email protected] [email protected] Necci, A., Antonioni, G., Renni, E., Cozzani, V., Borghetti, A., Nucci, C.A., Krausmann, E. (2012). Equipment failure probability due to the impact of lightning. Chem.eng.trans. 26, 129. 94 Industrial Safety and Environmental Sustainability – Industrial Safety TOOLS AND METHODS FOR QUANTITATIVE RISK ASSESSMENT IN PROCESS FACILITIES AND IN HAZMAT TRANSPORTATION MATERIALS RESEARCH GROUP: Sarah Bonvicini, Gigliola Spadoni, Giacomo Antonioni, Alessandro Tugnoli, Valerio Cozzani KEYWORDS: fireproofing; hazardous materials; passive fire protection; pipelines; process facilities; quantitative risk assessment; risk reduction; road and railway transport; routing The concentration of industrial activities close to residential areas and the related supply of hazardous materials requires operating companies and control authorities to implement adequate measures in control of major accident hazard, in appropriate land use planning, and in integrated emergency planning. The decision-making process requires the analysis of a large amount of information on risk sources, accident modeling, population distribution, etc. The treatment of such information needs the support of software tools. ARIPAR and TRAT are two software packages that implement a probabilistic methodology to the assessment of the risks of complex industrial areas, including transport of dangerous substances, producing a number of different risk indexes. The research activities in this area mainly addressed the development of new methods, tools and models for the identification of accident scenario and their quantitative assessment. Improved methods for the identification of atypical accident scenarios are addressed within the activities of two FP7 research projects (iNTeg-Risk and TOSCA). Specific models for the assessment of risk to the environment caused by spills of oil and/or of hazardous chemicals from pipelines were developed. More specifically, innovative risk indexes are defined for soil and groundwater and for superficial water bodies, and a well-defined procedure for their evaluation was established. In the field of risk mitigation, operative strategies of “hazmat routing” were addressed for the transportation of hazardous substances. Hazmat routing consists in the determination of alternative paths, less risky than those usually taken by the drivers. proofing materials were explored by experimental tests. Risk-based criteria for application to different plant areas were explored. Detailed models for the assessment of fireproofing performance were developed. Fig. 1. Individual risk contours for fixed plants calculated using the ARIPAR software. Fig. 2. Transportation risk analysis: example of data and results. A further important research topic concerned fireproofing. Basic performance data for fire95 Research Projects and Activities 2015 N.Paltrinieri, S.Bonvicini, G.Spadoni, V.Cozzani, 2012, Cost-Benefit Analysis of Passive Fire Protections in Road LPG Transportation, Risk Analysis, 32, 200-219. ities of Civil Protection in the Emilia Romagna region for the control and reduction of the risks posed by industrial installations and hazmat transport”. Project leader: Gigliola Spadoni (2008-2012) G.Landucci, A.Tugnoli, V.Busini, M.Derudi, R.Rota, V.Cozzani, 2011, The Viareggio LPG accident: Lessons learnt, Journ. Loss Prev., 24(4), 466-476. Convention with the Municipality of Ferrara about: “Investigation on the risks caused by pipelines transport of flammable and toxic substances”. Project leader: Gigliola Spadoni (2007) N.Paltrinieri, G.Landucci, M.Molag, S.Bonvicini, G.Spadoni, V.Cozzani, 2009, Risk reduction in road and rail LPG transportation by passive fire protection, Journ. Haz. Mat., 167, 332-344. Convention with Trenitalia about: “Risk analysis in the railroad transport of propylene from Brindisi to Terni”. Project leader: Gigliola Spadoni (2004) D.Monaci, S Bonvicini, G Antonioni, V. Cozzani, G.Uguccioni, 2008, Quantitative assessment of the risk associated to the transport of hazardous substances by pipeline, Proceedings of CISAP3, 3rd International Conference on Safety & Environment in Process Industry (Rome (I), 11-14 May 2008), Chemical Engineering Transactions. Convention with RFI – Rete Ferroviaria Italiana about: “Operational Plan Dangerous Goods”. Project leader: Gigliola Spadoni (2002) S.Bonvicini, G.Spadoni, 2008, A hazmat multi-commodity routing model satisfying risk criteria: a case study, Journ. Loss Prev., 21(4), 345-358. Young Researchers’ Project of the University of Bologna about: “Evaluation of the environmental risk posed by pipeline transport of hazardous materials”. Project leader: Sarah Bonvicini (2000) MAIN PUBLICATIONS Convention with ITALFERR s.p.a. about: “Risk reduction in the railway transport of dangerous goods”. Project leader: Gigliola Spadoni (2000) V.Cozzani, S.Bonvicini, G.Spadoni, S.Zanelli, 2007, Hazmat transport: A methodological framework for the risk analysis of marshalling yards, Journ. Haz. Mat., 147(1-2), 412-423. M.F.Milazzo, R.Lisi, G.Maschio, G.Antonioni, S.Bonvicini, G.Spadoni, 2002, HazMat transport through Messina town: from risk analysis suggestions for improving territorial safety, Journ. Loss Prev., 15(5) 347-356. Research Contract of the National Research Council CNR / G.N.D.R.C.I.E. – National Group for the Defense from chemical, industrial and natural risks about: “Procedures, tools and guidelines for the risk analysis of road and railway transport of hazardous materials”. Project leaders: Paolo Leonelli, Sarah Bonvicini (2000-2002) P.Leonelli, S.Bonvicini, G.Spadoni, 1999, New detailed numerical procedures for calculating risk measures in hazardous materials transportation, Journ. Loss Prev., 12(6), 507-515. Research Contract of the National Research Council CNR “Routing of vehicles shipping hazardous materials”. Project leader: Gigliola Spadoni (1996-1998) RESEARCH PROJECTS CONTACTS Convention with the Civil Protection Agency of the Region Emilia Romagna about: “Activ- [email protected] [email protected] 96 Industrial Safety and Environmental Sustainability – Industrial Safety OCCUPATIONAL SAFETY RESEARCH GROUP: Gigliola Spadoni, Ada Saracino KEYWORDS: hazards in workplace, dangerous substances, check lists, key safety indicators, industrial safety performance From long time the occupational health and safety on work-place is matter of significant importance and evidence is given by laws that Europe has enacted. Recent developments introduced, inside laws too, risk assessment procedure and safety management systems whose specific contents were established extracting basic points by similar contexts. Necessarily the aim was and is to guarantee safe work conditions and to provide a health-observant workplace. At the same time research efforts have studied and promoted innovative methods able to evaluate models of organization for companies of any size. One of these methods was produced by using the results of a collaboration among academic and company members of different cultural background (organizational-economic, legal and medical-psychological and engineering). This method tried to achieve the balance between two important features which are: the evaluation of systems and/or patterns of health and safety organization and management in workplace, and the ability to measure effectiveness in exempting the administrative liability (as included in Legislative Decree n. 231/2001, Italian Health and Safety laws). The introduced measures of quantification consist of two different types of tools: check-lists and indicators. These tools are based on the tree structure of the model, represented in Fig. 2. In summary values given to check-lists and indicators allow to quantify themes and key-elements and to lay the foundation of a complete score, that means obtaining the index of global performance of the examined company (IPESHE index). A detailed evaluation of the equation representing IPESHE requires to test consistent but theoretical considerations on actual workplaces of industries. Once the procedure is well established, its use allows to define the priority of interventions for improvements, so that the management process becomes more effective and efficient. Fig. 1. Workers in a evident non-safe condition. Fig. 2. Tree-structure of the methodology that evaluates occupational management system. 97 Research Projects and Activities 2015 MAIN PUBLICATIONS RESEARCH PROJECTS Saracino A., Spadoni G., Curcuruto M., Guglielmi D., Bocci V., Cimarelli V., Dottori E., Violante F. (2012), A New Model for Evaluating Occupational Health and Safety Management Systems (OHSMS), CHEMICAL ENGINEERING TRANSACTIONS, VOL. 26, pp 519-524, ISBN 978-88-95608-17-4, ISSN 1974-9791. Sicurezza nell’ambiente di lavoro, Convenzione di ricerca tra la Fondazione Alma Mater dell’Università di Bologna e il Dipartimento di Ingegneria chimica, mineraria e delle tecnologie ambientali (DICMA), responsabile scientifico del DICMA: Gigliola Spadoni, 2011 CONTACTS [email protected] Saracino A., Curcuruto M., Pacini V., Spadoni G., Guglielmi D., Saccani C., Bocci V., Cimarelli M. (2012), IPESHE: an Index for Quantifying the Performance for Safety and Health in a Workplace, CHEMICAL ENGINEERING TRANSACTIONS VOL. 26, 2012, p 489-494, ISBN 978-88-95608-17-4, ISSN 1974-9791. Saracino A., Curcuruto M., Guglielmi D., Spadoni G. (2012), Salute e sicurezza negli ambienti di lavoro: un nuovo sistema di valutazione quantitativa, Convegno Nazionale GRICU 2012: Ingegneria chimica dalla macroscala alla nanoscala. Montesilvano (PE), 16-19 Settembre 2012. Saracino A., Bocci V., Cimarelli M., Curcuruto M., Dottori E., Guglielmi D., Spadoni G., Vella F., Violante F.(2012) M.I.M.O.SA. una metodologia per incrementare salute e sicurezza nei luoghi di lavoro, Atti del VII Convegno sulla Valutazione e Gestione del Rischio negli Insediamenti Civili ed Industriali. VII Convegno Nazionale Valutazione e Gestione del Rischio negli Insediamenti Civili ed Industriali (VGR 2012). Pisa. 3-5 Ottobre. MIMOSA: Metodo per implementare, misurare e organizzare la sicurezza in azienda (2012), Testo a cura della Fondazione Alma Mater dell’Università di Bologna, Società editrice Il Mulino. In stampa. 98 Industrial Safety and Environmental Sustainability – Environmental Technologies ENHANCED BIOMASS TO ENERGY CONVERSION RESEARCH GROUP: Carlo Stramigioli, Francesco Santarelli, Lucia Basile, Alessandro Tugnoli, Valerio Cozzani KEYWORDS: Biomass, Energy, Thermochemical processes, Supply chain analysis, Sustainability assessment Biomass has the potential to play a significant role in the world energy scenarios due to its abundance and to the neutral contribution to the CO2 balance when it is used as fuel. Biomass energy content can be exploited through the direct combustion of the biomass or through the preliminary conversion of the biomass into solid, liquid and gaseous fuels followed by the combustion process. Different thermo-chemical processes can be used to produce fuels from biomass, e.g. pyrolysis, gasification, Fischer-Tropsch synthesis. Pyrolysis is a thermo-chemical process in which organic material is decomposed in absence of oxygen in a solid residue (i.e. char), in a liquid product (i.e. pyro-oil) and in a gaseous phase. Due to the higher density of solid and liquid products, pyrolysis can be considered a densification process, which is supposed to decrease the transport burdens from the field to the final use of the bio-fuels. In particular slow pyrolysis allows for the production of similar amounts of liquid, solid and gaseous fractions. Light gases could supply the heat needed in the process. The present activity is oriented to the analysis of biomass to energy routes based on pyrolysis processes. The experimental characterization of the pyrolysis process is carried out for different biomass species, in order to understand the yield and composition of the different product fractions, and in particular of bio-oil. Specific aspect as the thermal requirements of the pyrolysis process are also investigated. In the perspective of bio-oil recovery, manipulation and upgrading, a further aim of the activity is the exploration of the hazard footprint of bio-oils. Finally, the sustainability of bio-energy systems based on the pyrolysis process and their compatibility with the territory still is assessed based both on reference and experimental data produced in the activity. Conventional Life Cycle Assessment (LCA) methodology as well as advanced methodologies for sustainability assessment are further developed and applied to the assessment of the biomass to energy supply and conversion chain. Fig. 1. Fixed bed reactor for experimental characterization of feedstock. Fig. 2. Example of pyrolysis products from different biomass types. Fig. 3. Example of sustainability indexes applied to supply chains. 99 Research Projects and Activities 2015 MAIN PUBLICATIONS RESEARCH PROJECTS Cordella, M., Torri, C., Adamiano, A., Fabbri, D., Barontini, F., Cozzani, V. (2012). Bio-oils from biomass slow pyrolysis: a chemical and toxicological screening. Journal of Hazardous Materials 231-232: 26-35. Asse 1 PON-FESR 2007-2013. Attività I.1.1 Creazione di Tecnopoli - CIRI Energia ed Ambiente - UO Bioenergia Cordella, M., Cozzani, V., Santarelli, F. (2010). Life cycle modeling and environmental impact assessment of energy production supply chains based on a biomass pyrolysis densification process. Proc. 7th European Congress on Chemical Engineering (ECCE-7), CSCHI ed., Prague (CZ). [email protected] [email protected] [email protected] [email protected] CONTACTS Cordella, M., Barontini, F., Santarelli, F., Cozzani, V. (2008). Valutazione del rischio associato alla produzione ed allo stoccaggio di combustibili derivanti da biomasse. Atti del VI Convegno Nazionale Valutazione e Gestione del Rischio negli Insediamenti Civili ed Industriali, DIMNP, Pisa, p. 93: 1-12. Gomez, C., Velo, E., Barontini, F., Cozzani, V. (2009). Influence of Secondary Reactions on the Heat of Pyrolysis of Biomass. Industrial & Engineering Chemistry Research 48: 1022210233. Rath, J., Wolfinger, M.G., Steiner, G., Krammer, G., Barontini, F., Cozzani, V. (2003). Heat of wood pyrolysis. Fuel 82: 81-91. Sanchirico, R., Pinto, G., Pollio, A., Cordella, M., Cozzani, V. (2011). Toxicological Characterization of the Thermal Decomposition Products of Chemicals: a New Approach to an old Problem. Proc. 10th International Conference on Chemical and Process Engineering, Chem. Eng.Trans. 24: 1123-1128, AIDIC: Milano. Tugnoli, A., Santarelli, F., Cozzani, V. (2011). Implementation of Sustainability Drivers in the Design of Industrial Chemical Processes. A.I.Ch.E. Journal 57: 3063-3084. Tugnoli, A., Cozzani, V., Santarelli, F. (2007). A quantitative framework for sustainability assessment in the process industry. Proc. 6th European Congress of Chemical Engineering, EFCE Event n.669, Norhaven Book: Lyngby (DK); p. 975-976. 100 Industrial Safety and Environmental Sustainability – Environmental Technologies TECHNOLOGIES FOR FLUE-GAS TREATMENT RESEARCH GROUP: Carlo Stramigioli, Giacomo Antonioni, Valerio Cozzani, Daniele Guglielmi KEYWORDS: MSWI, flue-gas treatment, acid gases, gas-solid reactions, process simulation Power generation from municipal solid waste incineration is widespread used as a technology for solid waste treatment and energy recovery. However one of the main sources of environmental impact for these plants is the continuous emission of pollutants into the atmosphere (emissions of airborne pollutants are regulated by European Union Directive 2008/1/EC on IPPC). Another issue to be addressed is the generation of solid or liquid residues from flue-gas cleaning, depending on the flue-gas treatment process. For these reasons two-stage processes are becoming more and more popular for the treatment of the flue-gas from Municipal Solid Waste Incinerators (MSWI). Even if there are some plants that are already running this process, showing high levels of effectiveness in terms of exhaust gas concentrations, there is still lack of knowledge about reaction efficiency and reactant consumption. Thus a great amount of solid products are produced by and should be disposed of, usually by landfilling. Among the substances produced during waste combustion, acid gases are of particular interest because of their environmental impact (long term exposure, acid rains, etc.), and a feasible solution is to remove them by means of dry processes. The two-stage dry treatment of flue gas with solid reactants is one of the Best Available Technologies for acid gas cleaning. Each stage is composed of a reactor (where the solid reactants are mixed with the flue gas) followed by a filter (where the solid products are separated). An operational model based on literature data was proposed to describe the removal efficiency of acid gases (HCl, HF and SO2) in an incineration power plant. The model was developed considering the ratio of solid reactants (calcium hydroxide and sodium bicarbonate) to stoichiometric values, initially on the basis of plant design data. Then model parameters have been calibrated using the design data of an existing MSWI. The implementation within Aspen Hysys® allowed an economic optimization of the treatment process taking into account both reactant and disposal costs (Fig. 2). Fig. 1. The emission stack of the MSWI running the two-stage process. Fig. 2. Economic process optimization of the flue-gas treatment section of a MSWI. 101 Research Projects and Activities 2015 MAIN PUBLICATIONS RESEARCH PROJECT Antonioni, G., Modeling and simulation of an existing MSWI flue gas two-stage dry treatment (2013) Process Safety and Environmental Protection, ISSN 0957-5820. Research agreement between Hera S.p.A., Alma Mater Foundation and University of Modena and Reggio e Emilia Guglielmi, D., Antonioni, G., Stramigioli, C. Cozzani V. Ottimizzazione di un processo di abbattimento a secco per l’abbattimento dei gas acidi prodotti nella termovalorizzazione di RSU. Atti Convegno GRICU 2012 CONTACTS [email protected] [email protected] Antonioni, G., Guglielmi, D., Stramigioli, C., Cozzani, V MSWI flue gas two-stage dry treatment: Modeling and simulation (2012) Chemical Engineering Transactions, 26, pp. 213-218. Antonioni, G., Sarno, F., Guglielmi, D., Morra, P., Cozzani, V. Simulation of a two-stage dry process for the removal of acid gases in a MSWI (2011) Chemical Engineering Transactions, 24, pp. 1063-1068. 102 Industrial Safety and Environmental Sustainability – Environmental Technologies METHODS AND TOOLS FOR HEALTH RISK ASSESSMENT RESEARCH GROUP: Gigliola Spadoni, Sarah Bonvicini, Giacomo Antonioni KEYWORDS: dangerous substances effects, environmental modeling, human health, health risk evaluation, industrial and anthropic activities The assessment of human health risk due to the use of dangerous substances in anthropic activities is a topic of growing interest for both citizens and public authorities. As a matter of fact, the former want to know the influence that such substances have on changing life conditions and the latter must establish rules and regulations to guarantee a safe exposure to them, if there is. Human health risk is assessed through a procedure based on identification, evaluation and management. As given in Fig. 1, the global evaluation procedure can be profitably conducted by using the capabilities of Geographycal Information Systems able to describe the spatial distribution of sources of Chemicals of Concern (CoC), of their dispersion in air, water and soil established through fate and transport models and finally able to draw maps of cancer risk or of hazard quotient, if dangerous substances are involved, being carcinogenic or not. The research activities of the group were and are focused on all the aspects of the procedure: methodological contents, simple or complex environmental models, dose – response models of dangerous substances, uncertainties evaluation and tolerability criteria; all these topics have to be deepened if we want to give an actual and credible picture of health risks of human beings living in a territory. The software code EHHRA-GIS includes all the models previously cited; it has been built by research group step by step following innovations in fields involved, especially in modeling, and technical regulations established by national authorities. At present this tool can manipulate several sources due to industrial and civil activities or to transport, being both continuous or accidental ones (see, as an example, Fig. 2). Maps of individual risk produced by one or several substances, histograms on risk importance of substances and on the most relevant ways of intakes (by ingestion of foods, by drinking of water or different beverage…) are some of the several results which can be obtained by the code. It has to be outlined that all values are useful and important in order to support the job of territorial authorities in a correct management of risk. Fig. 1. Architecture block diagram of the methodology in EHHRA-GIS. Fig. 2. Map of terrain elevation showing different sources of contamination. 103 Research Projects and Activities 2015 MAIN PUBLICATIONS Morra P.,Bagli S., Spadoni G. (2006). The Analysis Of Human Health Risk With A Detailed Procedure Operating In A Gis Environment, Environment International, Elsevier,Vol. 32 (4), pp 444-454, ISSN: 0160-4120. Morra P., Spadoni G., Lisi R., Maschio G. (2006). The application of the Ehhra-Gis tool for the assessment of human health risk in the Pace valley of Messina, in C. Guedes Soares, E. Zio. Safety and Reliability for Managing Risk. European Safety and Reliability Conference 2006 (ESREL 2006). Estoril, Portugal. 18-22 September. (vol. 3, pp. 2239 - 2245). ISBN: 978-0-415-42315-1. LONDON: Taylor & Francis / Balkema. Lisi R., Milazzo M.F., Morra P., Antonioni G., Spadoni G., Maschio G. (2007). Environmental Impact Assessment Of A MSW Incinerator, Proceedings of SARDINIA 2007, XI International Waste Management and Landfill Symposium, 1 – 5 October 2007, S. Margherita di Pula (Cagliari), pp. 575-584, CISA-Environmental Sanitary Engineering Centre, ISBN 978-886265-003-8. Morra P., Lisi R., Spadoni G., Maschio G. (2009). The assessment of human health impact caused by industrial and civil activities in the Pace valley of Messina, Science of The Total Environment, Elsevier (2009), Vol. 407 (12), pp. 3712-3720, ISSN: 0048-9697. G. Antonioni, S. Burkhart, J. Burman, A. Dejoan, A. Fusco, R. Gaasbeek, T. Gjesdal, A. Jäppinen, K. Riikonen, P. Morra, O. Parmhed, J.L. Santiago. (2012). Comparison of CFD and operational dispersion models in an urban-like environment, Atmospheric Environment (Elsevier), Vol.47, 2012 pp.365-372. Morra P., Spadoni G. (2011). The Environmental And Human Health Risk Assessment: Methodology And Decision Support Systems, in the book Advances in Environmental Research vol.20, Nova Publishers Editors: Justin A. Daniels , ISBN: 978-1-61324-869-0. Morra P., Leonardelli L., Spadoni G. (2011). The Volatilization of Pollutants from Soil and Groundwater: Its Importance in Assessing Risk for Human Health for a Real Contaminated Site, Journal of Environmental Protection, Vol.2 No.9, pp. 1192-1206, DOI: 10.4236/ jep.2011.29137. F. Bacci, S. Bonvicini, G. Antonioni, P. Morra, V. Cozzani, Analisi del rischio di contaminazione di corsi d’acqua dovuti a rilasci accidentali di liquidi idrocarburici, Atti del VII Convegno sulla Valutazione e Gestione del Rischio negli Insediamenti Civili ed Industriali. VII Convegno Nazionale Valutazione e Gestione del Rischio negli Insediamenti Civili ed Industriali (VGR 2012). Pisa. 3-5 Ottobre. P. Morra, C. Campri, G. Antonioni, G. Spadoni, Inquinamento atmosferico e valutazione dei rischi per la salute, Atti del VII Convegno sulla Valutazione e Gestione del Rischio negli Insediamenti Civili ed Industriali. VII Convegno Nazionale Valutazione e Gestione del Rischio negli Insediamenti Civili ed Industriali (VGR 2012). Pisa. 3-5 Ottobre 2012 Antonioni, G., Sarno, F., Guglielmi, D., Morra, P., Cozzani, V. Simulation of a two-stage dry process for the removal of acid gases in a MSWI (2011) Chemical Engineering Transactions, 24, pp. 1063-1068. RESEARCH PROJECT Attività di Protezione Civile di competenza regionale in materia di rischi connessi con le attività’ industriali e i trasporti di sostanze pericolose. Research contract between Regione Emilia-Romagna and Department of Chemical, Mining and Environmental Engineering (DICMA), DICMA person responsible: Gigliola Spadoni, (2004-2008). CONTACTS [email protected] [email protected] [email protected] 104 Industrial Safety and Environmental Sustainability – Sustainability SAFETY AND SUSTANABILITY DRIVERS FOR PROCESS DESIGN AND OPTIMIZATION OF SUPPLY CHAINS RESEARCH GROUP: Alessandro Tugnoli, Valerio Cozzani, Carlo Stramigioli, Francesco Santarelli KEYWORDS: sustainability assessment, inherent safety, life cycle assessment, optimization, key performance indicators, process & plant design, supply chain, environmental impact The main determinants of the impact and safety of process plants are defined in the design stage, in particular in the early phases where a higher number of degrees of freedom is present. Furthermore, the production of goods causes impacts that extend beyond the actual production facility and involve up-stream and downstream processes: a holistic perspective is required in the technological optimization of such life-cycle. The research activity on this topic focused on the development of Key Performance Indicators (KPIs), applicable as sustainability drivers in the design activities and in the supply chain optimization. The use of quantitative indicators provides auditable support in design choices and allows for selection of the production and treatment technologies which more effectively reduce environmental burdens, maximize yields and minimize costs. The main outcomes of the research activity included: 1. Tools for the identification of sustainability KPIs through a structured approach accounting for the specific factors and constraints of design activities (e.g. limited availability of data). System analysis ranged from Life Cycle Assessment (LCA), to detailed process simulation. Experimental activity supported the collection of relevant performance data for emerging processes (e.g. biomass densification). 2. Advanced approaches for the interpretation, normalization and aggregation of indicators. The use of site-specific factors introduces a sound reference for the interpretation of the indicator values. 3. Indicators for inherent safety assessment. The methodology was developed to provide both a flexible procedure for the identification of the hazards, and a sound consequence-based quantification of the safety performance of a process scheme. 4. Specific optimization studies. Examples of studies include: alternative fuel supply chains based on biomass, production of bulk and fine chemicals, envisaged hydrogen chain for automotive applications, hazardous wastes. 105 Fig. 1. Sustainability study of alternative design options for a process plant. Fig. 2. A product chain study: alternative fuels from biomass pyrolysis. Research Projects and Activities 2015 MAIN PUBLICATIONS Tugnoli A., Landucci G., Salzano E., Cozzani V. (2012). Supporting the selection of process and plant design options by Inherent Safety KPIs. Journal of Loss Prevention in the Process Industries. Vol. 25 (5), pp. 830-842. Cordella M., Torri C., Adamiano A., Fabbri D., Barontini F. & Cozzani V. (2012). Bio-oils from biomass slow pyrolysis: a chemical and toxicological screening. Journal of Hazardous Materials. vol. 231-232, pp. 26-35. Tugnoli A., Santarelli F. & Cozzani V. (2011). Implementation of Sustainability Drivers in the Design of Industrial Chemical Processes” AIChE Journal, 57 (11), Vol. 57 (11), pp. 3063-3084. Righi S., Morfino A., Galletti P., Samorì C., Tugnoli A. & Stramigioli C. (2011). Comparative cradle-to-gate life cycle assessments of cellulose dissolution with 1-butyl-3-methylimidazolium chloride and N-methyl-morpholine-N-oxide, Green Chemistry, 13, pp. 367-375. Landucci G., Tugnoli A. & Cozzani V. (2010). Safety assessment of envisaged systems for automotive hydrogen supply and utilisation, International Journal of Hydrogen Energy, Volume 35, Issue 3, pp. 1493-505. Cozzani V., Tugnoli A. & Salzano E. (2009). The Development of an Inherent Safety Approach to the Prevention of Domino Accidents, Accident Analysis & Prevention, Vol. 41 (6), pp. 1216-1227. Cordella M., Tugnoli A., Barontini F., Spadoni G. & Cozzani V. (2009). Inherent Safety of Substances: Identification of accidental scenarios due to decomposition products, J. Loss Prev. Proc. Ind., Vol. 22 (4), pp. 455-462. Tugnoli A., Khan F., Amyotte P. & Cozzani V. (2008). Safety Assessment in Plant Layout Design using Indexing Approach: Implementing Inherent Safety Perspective; Part 1 & Part 2, Journal of Hazardous Materials, Vol. 160 (1), pp. 100–121. Tugnoli A., Santarelli F. & Cozzani V. (2008). An Approach to Quantitative Sustainability Assessment in Early stages of Process Design, Environmental Science & Technology, Vol. 42(12), pp. 4555-4562. Tugnoli A., Landucci G. & Cozzani V. (2008). Sustainability Assessment of Schemes for Hydrogen Production by Steam Reforming, International Journal of Hydrogen Energy, Vol. 33 (16), pp. 4345-4357. Tugnoli A., Khan F. & Amyotte P. (2008). Inherent Safety Implementation Throughout the Process Design Lifecycle, Book of abstracts of PSAM9, 18-23 May; Hong Kong, pp. 24 (paper on attached CD). Cordella M., Tugnoli A., Spadoni G., Santarelli F. & Zangrando T. (2008). LCA of an Italian Lager beer, International Journal of Life Cycle Assessment, 13 (2), pp. 133-139. Tugnoli A., Cozzani V. & Landucci G. (2007). A Consequence Based Approach to the Quantitative Assessment of Inherent Safety, AIChE Journal, Vol. 53 (12), pp. 3171-3182. Cozzani V., Tugnoli A. & Salzano E. (2007). Prevention of domino effect: From active and passive strategies to inherently safer design, Journal of Hazardous Materials, Vol. 139 (2), pp. 209-219. RESEARCH PROJECTS Sviluppo di un approccio integrato alla valutazione della sostenibilità della sicurezza e dell’impatto ambientale di materiali contenenti ritardanti di fiamma bromurati. MIUR, Progetto di Ricerca di Rilevante Interesse Nazionale, PRIN. Unità di Ricerca. (2004-05). Indicatori di prestazione nella progettazione di processo. MIUR, Progetto di Ricerca di Rilevante Interesse Nazionale, PRIN. Unità di Ricerca. (2007-08). iNTeg-Risk - Early Recognition, Monitoring, and Integrated Management of Emerging, New Technology related, Risks. European Commission, 7th Framework Programme - Nanoscience, Nanotechnologies, Materials and New Production Technologies. Large scale integrating project (63 partners), (2008-2013). CONTACTS [email protected] [email protected] [email protected] [email protected] 106 Industrial Safety and Environmental Sustainability – Sustainability PROCESS INTENSIFICATION IN INTEGRATED PROCESSES RESEARCH GROUP: Giovanni Camera Roda, Francesco Santarelli, Antonio Gaetano Cardillo KEYWORDS: Process intensification, Membrane reactors, Photocatalyisis, Green chemistry, Water detoxification In the chemical industry, a process intensification is needed to meet important goals such as sustainable and eco-friendly processes. The “produce more with less” objective can be achieved by coupling reaction and separation in a so called “integrated process”. Our research group has developed in the recent years important knowledge on the synergetic mechanisms that act in the integration of photocatalysis with membrane separation processes or other oxidative reactions. Photocatalysis is the most studied among the Advanced Oxidation Technologies (AOTs), due to many positive features: mild conditions, no chemical additives, possibility to use solar radiation to activate the reaction, modularity, simplicity for the operation and the control etc. The coupling of photocatalysis with pervaporation is simple and straightforward, even operating the two processes in separate equipments. This “membrane reactor” shows important benefits in the green synthesis of aromatic aldehydes and in water detoxification. In the first case the selectivity of the reaction is highly enhanced by the recovery by the membrane of the aldehyde while it is produced, avoiding its further oxidation in the photocatalytic reactor. The result are very satisfactory and the “AROMA” process (Advanced Recovery and Oxidation Method for Aldehydes) has been therefore patented and has been applied to the production of many aromatic aldehydes, such as vanillin and benzaldehyde. In water detoxification the membrane reactor has been used to remove recalcitrant pollutants from water streams. The rate of detoxification more than double with respect to the one obtainable without integration, thanks to a synergy between the two process, The optimization showed that a relatively low membrane area is sufficient to maximize the “intensification” index. It has been shown that also the coupling of photocatalysis with ozonization increases synergistically the rate of oxidation and the capability to control the formation of unwanted compounds. In our laboratories, many apparatuses are available for the experiments and the tests both for aqueous and gaseous effluents. Fig. 1. Scheme of an integrated process in our lab. Fig. 2. One of the experimental apparatuses. Fig. 3. Optimization of the yield of a membrane reactor. 107 Research Projects and Activities 2015 MAIN PUBLICATIONS Camera-Roda G., Santarelli F. (2012), Design of a Pervaporation Photocatalytic Reactor for Process Intensification, Chemical Engineering and Technology 35 (7) , pp. 1221-1228. Camera-Roda, G., Augugliaro, V., Cardillo A., Loddo, V., Palmisano,G.,Palmisano,L.(2013). A pervaporation photocatalytic reactor for the green synthesis of vanillin, Chem. Eng. J. 224 , pp. 136-143. Camera-Roda, G., Santarelli, F., Augugliaro, V., Loddo, V., Palmisano, G., Palmisano, L., Yurdakal, S.(2011). Photocatalytic process intensification by coupling with pervaporation, Catalysis Today 161 (1) , pp. 209-213. Camera-Roda, G., Santarelli, F., Panico, M. (2009). Study and optimization of an annular photocatalytic slurry reactor, Photochemical and Photobiological Sciences 8 (5) , pp. 712-718. Camera-Roda, G., Santarelli, F. (2007). Optimization of the thickness of a photocatalytic film on the basis of the effectiveness factor, Catalysis Today 129 (1-2 SPEC. ISS.) , pp. 161-168. Camera-Roda G., Santarelli F. (2007), Intensification of water detoxification by integrating photocatalysis and pervaporation, J. Solar En. Eng. 129, pp. 68-73. Camera-Roda et al., the “AROMA process” Patent Camera-Roda G., Augugliaro V., Loddo V., Palmisano L., Pervaporation Membrane Reactors, in: A. Basile, Handbook of membrane reactors: Reactor types and industrial applications (Volume 2), Chap.3, Woodhead Publishing Series in Energy No. 56, 2013. F. Occulti, G. Camera Roda, S. Berselli, F. Fava, Sustainable decontamination of an actual site aged PCB polluted soil through a biosurfactant-based washing followed by a photocatalytic treatment, Biotech. Bioeng., 2008, 99, pp. 1525 – 1534. F. Parrino, V. Augugliaro, G. Camera-Roda, V. Loddo, M.J. López-Muñoz, C. Márquez-Álvarez, G. Palmisano, L. Palmisano, Visible-light-induced oxidation of trans-ferulic acid by TiO2 photocatalysis, J. Catal. 295, (2012), Pages 254-260. CONTACTS [email protected] 108 Geomatics Geomatics – Geodetic Activities in Antarctica GEODETIC ACTIVITIES IN ANTARCTICA FOR THE STUDY OF PRESENT-DAY GEODYNAMICS AND FOR THE MONITORING OF GLACIAL BODIES RESEARCH GROUP: Luca Vittuari, Stefano Gandolfi, Antonio Zanutta, Gabriele Bitelli, Luca Poluzzi, Luca Tavaci KEYWORDS: VLNDEF, EPICA, DOME C, TALDICE, ITASE The geodetic activities conducted by DICAM in Antarctica within the National Program of Research in Antarctica (PNRA) concern two main areas of research: the study of current geodynamics of Northern Victoria Land and the monitoring applications of glacial bodies for studies related to paleo-climate. The network VLNDEF (Victoria Land Network for Deformation control) consists of 28 stations located (Figure 1). Within the experiments conducted to study the geodynamics of the Northern Victoria Land were tested different GNSS analysis techniques based on the use of carrier phases (differenced and un-differenced), particularly interesting for the remote areas of the Earth. Concerning the applications devoted to Glaciology, the research group is involved in the study of the velocity field of the ice surface for a radius of 25 km around the site of perforation depth of the Antarctic ice sheet at Dome Concordia (European Project for Ice Core in Antarctica, EPICA) through the establishment of a control network properly designed and established in situ. The whole EPICA project involved researchers of ten European nations, and it allowed to realize a deep coring in ice of about 3270 m. The extracted cores highlighted the paleo-climatic history of the last eight climatic cycles of the planet occurred in lasts 820 000 years. The scientific excellence of the whole project EPICA was rewarded by the committee of the European Science Foundation in 2007 with the prestigious Cartesio - Descartes Prize for Transnational Collaborative Research. The group of research took part, starting from 1988, to several international projects, such as the study of the ice surface dynamics at Talos Dome, (place of a further deep ice-coring project named TALDICE) and to the International Trans-Antarctic Scientific Expedition (ITASE). ITASE is a research program promoted by the SCAR and the IGBP (International Geosphere Biosphere Programme) which involves the execution of long scientific routes realized with tracked vehicles on the Antarctic plateau. Fig. 1. Position of the control points of the network VLNDEF, superimposed to the tectonic scheme investigated for the entire region. Fig. 2. Tracked vehicles of ITASE project on the Antarctic plateau during the overnight stop. 111 Research Projects and Activities 2015 MAIN PUBLICATIONS Bitelli G., Gusella L., Mancini F., Pino I., Vittuari L. (2008). Analysis of multispectral satellite images for ice-streams velocity evaluation. Terra Antartica Reports, 14, 7-10, ISBN 978-88-88395-10-4. A. Capra, M. Dubbini, A. Galeandro, L. Gusella, A. Zanutta, G. Casula, M. Negusini, L. Vittuari, P. Sarti, F. Mancini, S. Gandolfi, M. Montaguti, G. Bitelli, VLNDEF Project for Geodetic Infrastructure Definition of Northern Victoria Land, Antarctica, in: Geodetic and Geophysical Observations in Antarctica, An Overview in the IPY Perspective, BERLIN HEIDELBERG, Springer-Verlag, 2008, pp. 37-72. Danesi S., Dubbini M., Morelli A., Vittuari L., Bannister S., Joint Geophysical Observations of Ice Stream Dynamics, in: Geodetic and Geophysical Observations in Antarctica, BERLIN HEIDELBERG, Springer-Verlag, 2008, pp. 281-298. Frezzotti M., Urbini S., Proposito M., Scarchilli C., Gandolfi S. (2007). Spatial and temporal variability of surface mass balance near Talos Dome, East Antarctica. Journal of Geophysical Research vol. 112 ISSN: 0148-0227. Frezzotti M., Pourchet M., Flora O., Gandolfi S., Gay M., Urbini S., Vincent C., Becagli S., Gragnani R., Proposito M., Severi M., Traversi R., Udisti R., Fily M. (2004). New estimations of precipitation and surface sublimation in East Antarctica from snow accumulation measurements. Climate Dynamics. vol. 23, pp. 803 - 813 ISSN: 0930-7575. Frezzotti M., Pourchet M., Flora O., Gandolfi S., Gay M., Urbini S., Vincent C., Becagli S., Gragnani R., Proposito M., Severi M., Traversi R., Udisti R., Fily M. (2005). Spatial and temporal variability of snow accumulation in East Antarctica from traverse data. The Journal of Glaciology. vol. 51(172), pp. 113-124 ISSN: 0022-1430. King M.A., Z. Altamimi, J. Boehm, M. Bos, R. Dach, P. Elosegui, F. Fund, M. Hernández-Pajares, D. Lavallée, P.J. Mendes Cerveira, N. Penna, R.E.M. Riva, P. Steigenberger, T. van Dam, L. Vittuari, S. Williams, P. Willis, Improved Constraints to Models of Glacial Isostatic Adjustment: A Review of the Contribution of Ground-based Geodetic Ob- servations, «SURVEYS IN GEOPHYSICS», 2010, 31, pp. 465- 507 K.G. Strassmeier, K. Agabi, L. Agnoletto, A. Allan, M. I. Andersen, W. Ansorge, F. Bortoletto, R. Briguglio, J.-T. Buey, S. Castellini, V. Coud´e du Foresto, L. Dam´e, H. J. Deeg, C. Eiroa, G. Durand, D. Fappani, M. Frezzotti, T. Granzer, A. Gr¨oschke, H. J. K¨archer, R. Lenzen, A. Mancini, C. Montanari, A. Mora, A. Pierre, O. Pirnay, F. Roncella, F.-X. Schmider, I. Steele, J.W. V. Storey, N. F. H. Tothill, T. Travouillon, L. Vittuari, and M. Weber, Telescope and instrument robotization at Dome C, «ASTRONOMISCHE NACHRICHTEN», 2007, AN 328, No. 6, pp. 451-474. Urbini S., Frezzotti M., Gandolfi S., Vincent C., Scarchilli C., Vittuari L., Fily M. (2008). Historical behaviour of Dome C and Talos Dome (East Antarctica) as investigated by snow accumulation and ice velocity measurements. Global and Planetary Change. vol. 60 (2008), pp. 576 - 588 ISSN: 09218181. doi:10.1016/j.gloplacha.2007.08.002. Vittuari L., Vincent C., Frezzotti M., Mancini F., Gandolfi S., Bitelli G. & Capra A. (2004) - Space Geodesy as a tool for measuring ice surface velocity in the Dome C region and along the ITASE traverse. Ann. of Glaciol., 39, 402-408. Zanutta A., Vittuari L., Gandolfi S., Geodetic GPSbased analysis of recent crustal motions in Victoria Land (Antarctica), «GLOBAL AND PLANETARY CHANGE», 2008, 62, pp. 115- 131. RESEARCH PROJECTS PNRA - RU “Geodesia e osservazioni mareografiche”. (PI G. Bitelli) PNRA - Project: Paleoclimatic Records from Icecore Data Elaboration (PRIDE). RU of Geodesy (PI L. Vittuari) CONTACTS Observatory activities: [email protected] [email protected] Geodetic application in Glaciology: [email protected] [email protected] 112 Geomatics – Geomatics for Cultural Heritage Surveying and Carthographic Heritage GEOMATICS FOR CULTURAL HERITAGE SURVEYING AND CARTOGRAPHIC HERITAGE RESEARCH GROUP: Gabriele Bitelli, Giorgia Gatta, Fabrizio Girardi, Valentina Alena Girelli, Emanuele Mandanici, Maria Alessandra Tini, Paolo Conte, Luca Vittuari, Antonio Zanutta KEYWORDS: Beni Culturali, archeologia, modellazione 3D, cartografia storica The applications of Geomatics in the field of Cultural Heritage have several purposes: study and documentation of movable or immovable objects, structural monitoring in support of restoration, integration with noninvasive diagnostic techniques (e.g. multispectral/thermal surveys), high-precision replica of works of art, creating databases for the visualization and exploration in virtual reality, new products for museums. The contextualization in the territory is done by low altitude photogrammetric surveys, large scale numerical cartography, terrestrial or aerial laser scanning, high-resolution satellite imagery. The research of the team is oriented to the data acquisition stage, making use of integrated instrumentation (topography, digital photogrammetry, scanning systems of various types, GNSS, satellite remote sensing, GIS), and to the development and application of algorithms and techniques for optimal processing and high-fidelity 3D modeling. Examples of activities: multi-scale and multi-technical surveys of archaeological sites, from the territory to the single object; surveying and 3D modeling of architectural complexes, painted surfaces, sculptures; high-precision topographic control of deformation for ancient buildings and infrastructures; 3D survey of small findings, high precision monitoring of decay evolution on historic outdoor brick masonry. The group has worked in major multi-disciplinary projects in a variety of interventions: Italy, Egypt, Turkey, Albania, Syria, Malta, Uzbekistan, Tajikistan. A particular topic, with a number of significant realizations, is the use of digital methods for the management and enhancement of historical cartography (XVI-XIX century): analysis of the genesis of the ancient map, metrical acquisition by dedicated scanners, accuracy evaluation, special methods of georeferencing, innovative visual techniques, multidisciplinary study of the map content. The group participates in Alma HeritageScience, The Integrated Research Team of the University of Bologna on Science & Technology for Cultural Heritage: http://www.heritage.unibo.it. Fig. 1. Image from balloon of an archaeological site; vector plotting and raster orthophoto; laser scanning and photogrammetry in the model of a dome; scanning with 3D structured light; digital processing of one eighteenth-century historical map of Bologna. 113 Research Projects and Activities 2015 MAIN PUBLICATIONS Bitelli G., Mandanici E., Vittuari L. (2013). A land in its setting: Remote Sensing satellite imagery for the characterization of the Eblaite Chora. In Matthiae P. and Marchetti N. (Eds.): “Ebla and its Landscape”, 295-301, Left Coast Press Inc., Walnut Creek, USA. Bitelli G., Colla C., Gabrielli E., Girardi F., Ubertini F. (2013). Salt effects in plastered and unplastered outdoor brick masonry: quantitative laser monitoring of surface decay evolution. International Journal of Architectural Heritage (in print) Bitelli G. (2012). Remote Sensing and Integration with Other Geomatic Techniques in Archaeology. In Lasaponara R. and Masini N. (Eds.): “Satellite Remote Sensing. A New Tool for Archaeology”, 113-127, Springer Verlag Bitelli G., Gatta G. (2011). Experiences on georeferencing of maps from the XIX century Gregorian Cadastre of Bologna (Italy). e-Perimetron, Vol. 6, No. 4, 270-275 Bitelli G., Gatta G., Girelli V.A., Vittuari L., Zanutta A. (2011). Integrated Methodologies for the 3D Survey and the Structural Monitoring of Industrial Archaeology: The Case of the Casalecchio di Reno Sluice, Italy”, Int. J. of Geophysics, Vol.2011, ID 874347, 8 pp Bitelli G., Gatta G. (2011). Digital Processing and 3D Modelling of an 18th Century Scenographic Map of Bologna. In A. Ruas (Ed.) “Advances in Cartography and GIScience”, Vol.2, 129-146, Springer-Verlag Bitelli G., Girelli V.A. (2009). Metrical use of declassified satellite imagery for an area of archaeological interest in Turkey. Journal of Cultural Heritage, vol. 10S, 35-40 Zanutta A., Bitelli G. (2008). Some aspects of close-range photogrammetric surveys for Cultural Heritage documentation. ARCHAIA: Case Studies on Research Planning, Characterization, Conservation and Management of Archaeological Sites, Archaeopress, Oxford, 77-90 Bitelli G., Girelli V.A., Remondino F., Vittuari L. (2007). The potential of 3D techniques for Cul- tural Heritage object documentation. Proc. Videometrics-IX, Vol. 6491, S1-S10, San Jose, USA Bitelli G., Girelli V.A., Marziali M., Zanutta A. (2007). Use of historical images for the documentation and the metrical study of Cultural Heritage by means of digital photogrammetric techniques. The Int Arch Photogram Rem Sens, Vol. XXXVI-5/C53, 141-146. RESEARCH PROJECTS PRIN2002 “Strumenti, metodologie operative e innovatrici per il rilievo e la gestione dei Beni Culturali a supporto della redazione della Carta del Rischio”. Resp. Scient. G. Bitelli PRIN2004 “Integrazione di tecniche di rilevamento terrestre, fotogrammetriche e satellitari al fine del monitoraggio di strutture ed aree di interesse architettonico ed archeologico”. Resp. Scient. L. Vittuari PRIN2007 “Approccio multiscala per la salvaguardia di strutture archeologiche murarie in Ercolano: dal rilievo e modellazione alla diagnostica e analisi strutturale”. Resp. Scient. A. Zanutta EU FP7-ENV-2008-1 GA_226995: EU-CHIC European Cultural Heritage Identity Card. PI: R. Zarnic, UniBO: R. Mazzeo, Resp. Scient. Loc.: G. Bitelli (2009-2012) http://eu-chic.eu/index.php EU FP7-Ideas ERC-2009-AdG 20090415: EBLA CHORA - The early state and its chora. Towns, villages and landscape at Ebla in Syria during the 3rd Millennium BC. Royal archives, visual and material culture, remote sensing and artificial neural networks. PI: P. Matthiae, Local Sc. Resp. G. Bitelli (2010-2014) http://www.eblachora.eu Progetto di Ricerca Fondazione Cariplo: “Ritratti di città in un interno. Consolidare la memoria collettiva della città attraverso l’informatizzazione e la divulgazione della cartografia storica”. Resp. Sc.: G. Bitelli (2008-2014) CONTACTS [email protected] [email protected] [email protected] 114 Geomatics – Monitoring of Structures and Environment MONITORING OF STRUCTURES AND ENVIRONMENT RESEARCH GROUP: Maurizio Barbarella, Stefano Gandolfi, Luca Poluzzi, Luca Tavasci, Andrea Lugli KEYWORDS: Monitoring, GPS, TLS The needs of monitoring structures and territory stabilities is recently often required. If the monitoring interest few isolated points the GNSS systems can be a powerful technique for their characteristics that combine high performances (at centimeter level for real time and millimeter level for long periods observation) with flexibility and costs. A first experimentation conduced by the DISTART researcher has been performed on buildings over a landslide located in the Appenines mountains. This experimentation has demonstrate the possibility to reach real time centimetre level of accuracy using low cost receiver and monitoring the position of sensors from a remote location. Now the experimentation is moving to the optimization of devices, instrumentation and software procedure in order to improve the accuracy maintaining the low cost aspect that is fundamental for a large diffusion of this method. The final aim is to realise a monitoring system that can monitor, from remote, many structures at the same time in real time and control any movements of them. A central aspect consist in the definition of some procedure able to alert population or public authorities in case of danger. In figure 1 is reported an example of the first experimentation with the monitored buildings and obtained results. Is almost ready the realization of a real-time monitoring system for one of the most important towers of the City of Bologna both for early warning system and for the study of their low movements. Concerning the monitoring of the territory (and in particular of landslides), Terrestrial Laser Scanner can be employed. As example a landslide in an area located over a railway has been surveyed using TLS from 2010 to 2012. All the derived products DSM and DTM obtained removing vegetation has been referred to the ETRF00 assumed as enough stable in the surveyed area. The comparison of the different surveys has evidenced the areas with movements respect the stable ones. Particularly interesting the information relative to the kinematic of landslide respect to the stable area. Fig. 1. Example of GNSS time series for buildings monitoring. Fig. 2. Lower part of the landslide in proximity of the railway and chromatic representation of block movements. Fig. 3. Lower part of the landslide: 2012 TLS cloud and representation of the movements respect 2010. 115 Research Projects and Activities 2015 PUBBLICATIONS RESEARCH PROJECTS Ashkenazi V., Barbarella M., Manzoni G., Graglia G., Musmeci M., Roberts W. (2006) – The MONITOR Project: Galileo for Land and civil engineering surveyors – CIVIL ENGINEERING SURVEYOR – ICES May 2006, pp 1619, ISSN: 0266-139X. MONITOR Project. 6th Framework Program (2006-2007) Founded by EU, Galileo Joint Undertacking. Graglia G., Muscinelli R., Manzoni G., Barbarella M., Roberts W. (2006). The MONITOR Project a GNSS based platform for Land Monitoring and Civil Engineering applications Tyrrhenian International Workshop on Digital Communications. Island of Ponza, september 6-8. Barbarella M., Bedin A., Gandolfi S., 2006, The transmission of GNSS Data in the DISTART Network for Real Time Kinematic Positioning, Report on Geodesy (ISSN: 0867-3179) – Wroclaw - Poland, No. 2 (77) 2006, 241-247. Barbarella M., Bedin A., Gandolfi S., Vittuari L., 2004, La trasmissione dei dati nelle reti di stazioni permanenti GNSS per il posizionamento REAL TIME, Atti 8a Conferenza Nazionale ASITA, Roma, 14-17 dicembre 2004, 259-264. M. Barbarella, S. Gandolfi, (2008), Monitoraggio GPS in Real Time di edifici con strumenti a basso costo., Bollettino SIFET (ISSN 1721971X), 2008, 2, 69-86 PRIN2005 (2006-2007) - National Coordination. Reti di stazioni permanenti GPS per il rilievo in tempo reale in impieghi di controllo e emergenza. –Operative Unit: Reti di stazioni permanenti GNSS per il rilievo real time : configurazione in situazioni di emergenza, trasmissione dati e protocolli, inquadramento PRIN2007 (2008-2009) –National Coordination. La Geomatica a supporto delle azioni di Governo del Territorio. – Operative Unit: Monitoraggio in ambito regionale: di Strutture con sistemi GNSS di alta precisione e di caratteristiche del terreno con dati telerilevati e uso di GIS. PRIN2010-11 (2012-2014) Operative Unit: Tecniche innovative ed emergenti di telerilevamento (da aereo, satellite , UAV) e WEBGIS per la mappatura del rischio in tempo reale e la prevenzione del danno ambientale. CONTACTS [email protected] [email protected] Barbarella M., Casali F., Gandolfi S., Ricucci L., (2010): Rete GPS di monitoraggio in continuo di edifici e suo inquadramento., Atti 14a Conferenza Nazionale ASITA, (ISBN 978-88903132-5-7), Brescia, 9-12 novembre 2010, pp.171-180 Gandolfi S., Gusella L., Milano M., 2005, Precise Point Positioning: studio sulle accuratezze e precisioni ottenibili, Bollettino di Geodesia e Scienze Affini (ISSN 0006-6710), 4, 2005, 227253. Gandolfi S., La Via L., 2011, SKYPLOT_ DEM: a tool for GNSS planning and simulations Applied Geomatics, Springer, Doy 10.1007/s12518-011-0045-1 [SCOPUS ref. 2-s2.0-84867345123] 116 Geomatics – Satellite Remote Sensing for Environmental Sustainability and Disaster SATELLITE REMOTE SENSING FOR ENVIRONMENTAL SUSTAINABILITY AND DISASTERS MAPPING RESEARCH GROUP: Gabriele Bitelli, Paolo Conte, Francesca Franci, Alessandro Lambertini, Emanuele Mandanici, Maria Alessandra Tini, Luca Vittuari, Rossella Casciere, Maurizio Barbarella, Michaela de Giglio KEYWORDS: Remote Sensing, Sustainability, Energy losses mapping, Environmental monitoring, Disasters The European project EnergyCity concerns the use of airborne thermal imagery for the mapping of energy losses of buildings in seven urban areas, in the implementation of practices for energy efficiency and reduction of CO2 emissions in European cities. The final data, derived from a complex image processing workflow, are used in energy models to flow into a Decision Support WebGIS. Urban Heat Island (UHI) phenomenon is also addressed by using satellite imagery. Environmental monitoring of a protected area in Egypt is conducted by multi- and iper-spectral satellite images, comprising analysis of the water for Qarun Lake (salinity, chlorophyll) and lithological mapping of the area by multispectral image classification; the research furthermore covers the analysis of change detection in the region over decades, using also declassified Corona satellite imagery. Another satellite multispectral data application is a study of the effects of salt water intrusion in the pine forests near Ravenna. The aim is to create a procedure to assess the vegetation health in areas potentially damaged analyzing NDVI. In fact, the salinization of aquifer influences the plants inducing a photosynthetic properties and coverage changes, observable by spectral measurements. From the comparison between responses in the red and infrared channels of vegetation, and its statistical validation, the most stressed areas could be identified. Subsequently, related field monitoring at detailed scale can be planned and actions carried out accordingly. In the event of a disaster, the availability of high-resolution multispectral satellite images, along with radar data, allows to realize in a short time and with a good level of precision the mapping of large areas, for emergency management and for damage assessment in a GIS environment. Significant experiences that have been carried by the research team on various areas of the world are floods, fires, tsunamis and earthquakes, in the latter case with the possibility of obtaining a first evaluation of the level of buildings damage. Fig. 1. Energy losses of buildings in urban areas: from original nocturnal thermal image to the use of processed data in a Decision Support WebGIS. 117 Fig. 2. Chlorophyll-a concentration map in lacustrine water (Qarun Lake) obtained from hyperspectral imagery; effects of atmospheric correction. Fig. 3. Pine forests near Ravenna: NDVI spatial distribution with sample areas; average NDVI trend of sample areas. Fig. 4. Bam earthquake (2003): buildings damage mapping through object-based classification of high resolution imagery. Research Projects and Activities 2015 MAIN PUBLICATIONS XXXVI, 5/C55, pp. 150-158, ISSN: 1682-1777. Bitelli G., Franci F., Mandanici E. (2013). Monitoring the urban growth of Dhaka (Bangladesh) by satellite imagery in flooding risk management perspective. Proc. Workshop “The Role of Geomatics in Hydrogeological Risk”, 6 pp., Padova. Bitelli G., Gusella L. (2008). Remote sensing satellite imagery and risk management: image based information extraction. In C.A. Brebbia & E. Beriatos (Eds.) Risk Analysis VI, pp. 149-158, WIT Press, Southampton. Africani P., Bitelli G., Lambertini A., Minghetti A., Paselli E. (2013). Integration of LIDAR data into a municipal GIS to study solar radiation. Int. Archives of the Photogrammetry, Remote Sensing and Spatial Information Sciences, Volume XL-1/ W1, 6 pp., Hannover, Germany. Gusella L., Adams B.J., Bitelli G., Huyck C.K., Mognol A. (2005). Object Oriented Image Understanding and Post-Earthquake Damage Assessment for the 2003 Bam, Iran, Earthquake. Earthquake Spectra, 21, S1, pp. 225-238. Bitelli G., Conte P. (2011). Techniques, tools and workflow for remote sensed roof temperature mapping in some cities across Central Europe. In: Proc. 17th Int. Conference “Building Services, Mechanical and Building Industry Days” – Urban Energy Conference, Debrecen, ISBN: 978-963313-039-1, 49-56, BME Budapest. RESEARCH PROJECTS COFIN2003: Tecnologie innovative per la previsione, il controllo e la mitigazione dell’impatto delle emergenze ambientali. Resp. Scient.: G. Bitelli PRIN2005: Analisi, comparazione e integrazione di immagini digitali acquisite da piattaforma aerea e satellitare. Resp. Scient.: G. Bitelli Bitelli G., Curzi P.V., Dinelli E., Mandanici E. (2011). Empirical model for salinity assessment on lacustrine and coastal waters by remote sensing. In U. Michel and D.L. Civco (Eds.) Proc. SPIE Remote Sensing - Earth Resources and Environmental Remote Sensing/GIS Applications, vol. 8181, pp. 818119-1 - 818119-8. PRIN2007: La Geomatica a supporto delle azioni di Governo del Territorio. Resp. Scient.: M. Barbarella. Bitelli G., Mandanici E. (2010). Atmospheric correction issues for water quality assessment from Remote Sensing: the case of Lake Qarun (Egypt). In U. Michel and D.L. Civco (Eds.), Proc. SPIE Remote Sensing - Earth Resources and Environmental Remote Sensing/GIS Applications, Vol. 7831, pp. 78311Z1-78311Z8. ASI (Agenzia Spaziale Italiana). Cosmo-SkyMed AO n. 2248: RAPID RApid Processing for Information on Damage. Contract L/104/09/0. PI: G. Bitelli (2010-2012). Conte P., Bitelli G. (2009). Burned areas mapping by multispectral imagery: a case study in Sicily, Summer 2007. Proc. VII Int. EARSeL Workshop “Advances in Remote Sensing and GIS applications in Forest Fire Management”, Matera, ISBN 978-88-904367-0-3, 277-284. Gusella L., Adams B.J., Bitelli G. (2008). Mobile Mapping technology and integration with Remote Sensing imagery for post-disaster damage evaluation. Int. Arch. of the Photogrammetry, Remote Sensing and Spatial Information Sciences, PRIN2008: Mapper - Procedure di acquisizione ed elaborazione di dati multisorgente per il supporto alle emergenze. Resp. Scient.: G. Bitelli PRIN 2010-11: Tecniche geomatiche innovative ed emergenti di rilievo, telerilevamento (da aereo, satellite, uav) e webgis per la mappatura del rischio in tempo reale e la prevenzione del danno ambientale. Resp. Scient.: M. Barbarella. EU Central Europe Contract 2CE126P3. ENERGYCITY - Reducing energy consumption and CO2 emissions in cities across Central Europe. PI: T. Csoknyai, Resp. Scient. G. Bitelli (2010-2013) http://www.enercity2013.eu. CONTACTS [email protected] [email protected] 118 Geomatics – Monitoring of Structures and Environment GEOMATICS FOR THE CONTROL OF GROUND SUBSIDENCE AND LONG-TERM PHENOMENA RESEARCH GROUP: (Subsidence) Gabriele Bitelli, Luca Vittuari, Maria Alessandra Tini, Francesca Franci, Alessandro Lambertini; (Archival Photogrammetry) Antonio Zanutta, Gabriele Bitelli, Luca Vittuari, Valentina Alena Girelli, Giorgia Gatta, Andrea Lugli KEYWORDS: Subsidence, Deformation Control, Archival Photogrammetry, Landslides, Glaciers, LaserScanning, Ground subsidence (of natural type or man-induced, e.g. by fluid withdrawal) can be a critical aspect in territory management. Geometrical surveying and monitoring are the first essential steps for the knowledge and understanding of the phenomenon, to detect entity, trend and spatial arrangement of the movements. Different techniques have been applied and integrated over the years by the team: from spirit leveling (‘70s) to space geodesy (the ‘90s), and finally to the recent use of interferometric analysis of satellite radar images (PSInSAR). The research was carried out in national and international projects or with public authorities (Regions, Provinces, Municipalities, ARPA) and large private companies. The primary area of study is the Po Valley, with researches at regional, provincial or basin scale; a specific interest is furthermore towards coastal zones (EU FP7 project). The activity is also carried out at urban scale, monitoring single buildings and structures in city centers (e.g. Bologna) by high precision topographic techniques. The work involves the production of technical specifications, design and realization of networks, monitoring through repeated measurement campaigns, quality verification, realization of GIS databases, production of maps of subsidence rate and other related products. Other long-term phenomena can be studied using historical data, among them old aerial photograms. The so-called Archival Photogrammetry is made today through advanced digital techniques that complement the traditional photointerpretation for: Multi-temporal landslide studies; Evolution of glaciers; Change detection in urban centers; Changes in the coastline; Changes in forest cover. For this purpose it is frequently necessary to realize Digital Terrain Models (DTM) or surface models (DSM) that allow for a metric definition of the 3D form; image matching techniques are applied on old photogrammetric images or satellite stereo-couples, and airborne or terrestrial laserscanning is an effective solution for current situations. Fig. 1. Integration of different techniques (levelling, GNSS, radar satellite interferometry) for subsidence monitoring at different scales; map of subsidence rate for the regional Emilia-Romagna plain area, derived from radar intereferometric analysis (period 1992-2000). Fig. 2. Photogrammetric analysis of landslide movements; analysis of glacier evolution. 119 Research Projects and Activities 2015 MAIN PUBLICATIONS construction aspects, Secon Hdgk, 147-156. van der Krogt R., Bitelli G., Bremmer C., Capes R., Crosetto M., Cyziene J., Granizcki M., Hansen R., van Leijen F., Marsh S., Novali F., Schach Pedersen S., Westerhoff R. (2013). Monitoring subsidence of coastal lowland areas by satellite radar interferometry. Proc. 6th EARSeL Workshop on Remote Sensing of the Coastal Zone Bitelli G., Gatta G., Giorgini G., Minghetti A., Mognol A., Paselli E. (2006). Recupero a fini metrici di fotogrammi aerei storici per lo studio delle dinamiche territoriali in ambito urbano: un caso di studio. Atti X Conferenza Naz. ASITA, 355-360. Bissoli R., Bitelli G., Bonsignore F., Rapino A., Vittuari L. (2010). Land subsidence in Emilia-Romagna Region, northern Italy: recent results. Land Subsidence, Associated Hazards and the Role of Natural Resources Development, IAHS Publ. 339, 307-311, Wallingford. Bitelli G., Bonsignore F., Carbognin L., Ferretti A., Strozzi T., Teatini P., Tosi L., Vittuari L. (2010). Radar interferometry-based mapping of the present land subsidence along the low-lying northern Adriatic coast of Italy. Land Subsidence, Associated Hazards and the Role of Natural Resources Development, IAHS Publ. 339, 279-286 Bitelli G., Gatta G., Landuzzi A., Vittuari L., Zanutta A. (2009). La fotogrammetria digitale d’archivio per lo studio multitemporale di un’area in frana nelle Prealpi vicentine, Atti 13a Conferenza Nazionale ASITA, 415-420. P. Baldi, N. Cenni, M. Fabris, A. Zanutta (2008). Kinematics of a landslide derived from archival photogrammetry and GPS data. Geomorphology, 102, 435-444. D’Agata C., Zanutta A. (2007). Reconstruction by indirect source of the recent changes of a debris covered glacier (Brenva, Mont Blanc Massif, Italy). Methods, results and validation. Global and Planetary Change, 56, Issues 1-2, 57-68. Zanutta A., Baldi P., Bitelli G., Cardinali M., Carrara A. (2006). Qualitative and quantitative photogrammetric techniques for multi-temporal landslide analysis”. Annals of Geophysics, vol.49, 1121-1134. Bitelli G., Vittuari L. (2006). Integrated methodologies for monitoring of subsidence effects on urban areas and buildings. Heritage Protection: Bitelli G., Dubbini M., Zanutta A. (2004). Terrestrial laser scanning and digital photogrammetry techniques to monitor landslide bodies”. The Int Arch Photogram Rem Sens Spatial Inform Sci, Vol. XXXV, Part B, 246-251. Strozzi T., Wegmüller U., Tosi L., Bitelli G., Spreckels V. (2001). Land Subsidence Monitoring with Differential SAR Interferometry. Photogrammetric Engineering and Remote Sensing, vol. 67, 2, 1261-1270. Bitelli G., Bonsignore F., Unguendoli M. (2000). Leveling and GPS networks for ground subsidence monitoring in the Southern Po Valley. Journal of Geodynamics, 30, 355-369. RESEARCH PROJECTS ARPA Emilia-Romagna, su incarico della Regione Emilia-Romagna: Rilievo della subsidenza nella pianura emiliano-romagnola, Rete Regionale di monitoraggio della subsidenza (dal 1997) ASI (Agenzia Spaziale Italiana). Cosmo-SkyMed AO n. 2283: Integration of classical and space geodetic techniques for the study of vertical ground motions. Contract L/129/09/0 PI: Luca Vittuari (2010-2012). EU FP7-SPACE-2009-1 ID: 242332 SUBCOAST - Assessing and Monitoring Subsidence Hazards in Coastal Lowland around Europe. A collaborative project aiming at developing a GMES-service for monitoring and forecasting subsidence hazards in coastal areas around Europe. Resp. Scient.: G. Bitelli (2010-2013). CONTACTS [email protected] [email protected] [email protected] 120 Geomatics – International Reference Frames and Network Infrastructures GEOMATICS FOR THE MAINTENANCE OF THE INTERNATIONL TERRESTRIAL REFERENCE FRAMES (ITRF) AND FOR THE ANALYSIS OF NATIONAL GEODETIC NETWORKS RESEARCH GROUP: (ITRF-Tie vectors) Luca Vittuari, Pierguido Sarti, Claudio Abbondanza, Monia Negusini, Maria Alessandra Tini (Network analysis) Maurizio Barbarella, Stefano Gandolfi, Antonio Zanutta, Luca Poluzzi, Luca Tavasci KEYWORDS: ITRF, IERS, Tie vectors, ETRF, RND, NRTK The realization of precise and reliable global geodetic reference frames is one of the innovations that have most contributed to the efficiency of positioning techniques, i.e. for monitoring surveys, land surveying and cadastral procedures, the stacking-out of large infrastructures, or for maritime, terrestrial and aerial navigation. Starting from the initial applications exclusively conducted by research institutions, we can now observe a wide dissemination of the techniques of space geodesy for consumer applications, and it is sufficient to cite satellite car navigation systems or applications based on global positioning installed in smartphones or tablets PC. The reference frame more accurate is the International Terrestrial Reference Frame (ITRF) maintained by the International Earth Rotation and Reference Systems Service (IERS). The update of ITRF, entirely depends on the voluntary effort of a large number of agencies and research infrastructures, this creates a fundamental relationship between public and private, national and global technical services. This reference frame is now the backbone also for the realization of national reference frames. As example in Italy the Presidency of the Council of Ministers established by the Decree of 10 November 2011, the institution of the Rete Dinamica Nazionale (RDN) as official national reference frame, composed by 99 GNSS permanent stations. A team of DICAM studied in collaboration with the Institute of Radio Astronomy (IRA-INAF) the ensemble of high-accuracy survey methodologies and geometrical/statistical procedures necessary for the measure of eccentricity vectors between the reference points (RP) of co-located geodetic instruments and a WG was established in 2003 within the IERS - IAG Sub-Commission 1.2. Moreover DICAM is involved both in real time GNSS network for NRTK positioning and for the RDN analysis by means of the most advanced scientific GNSS data processing packages. Fig. 1. Topographical measurements for the estimation of the tie-vectors GPS-VLBI at the IRA-INAF observatories of Medicina (BO) and Noto (SR). Fig. 2. Residual velocities in ETRF of GNSS permanent stations belonging the Rete Dinamica Nazionale (RDN). 121 Research Projects and Activities 2015 MAIN PUBLICATIONS Abbondanza C., Negusini M., Sarti P., Vittuari L.. (2006). An investigation on a GPS-based approach to local tie computation. International VLBI Service for Geodesy and Astrometry 2006 General Meeting Proceedings. Fourth IVS General Meeting. Concepción, Chile. January 9-13, 2006. (vol. NASA/CP-2006-214140, pp. 162 166). -: NASA Conference Publication (US). Abbondanza C., Vittuari L., Sarti P., Negusini M.. (2007). An Analysis of Local Tie Vectors’ Temporal Evolution and Site Stability at Medicina Observatory through Terrestrial and GPS-based Observations. GEOWISSENSCHAFTLICHE MITTEILUNGEN. 18th European VLBI for Geodesy and Astrometry Working Meeting. Vienna. 12-13 April 2007. (vol. 79, pp. 188 - 183). ISSN 1811-8380. VIENNA: edited by J. Boehm, A. Pany, and H. Schuh (Austria). Barbarella M., Cenni N., Gandolfi S., Ricucci L., Zanutta A., (2009), Technical and scientific aspects derived by the processing of GNSS networks using different approaches and software, ION GNSS 22th International Technical Meeting of the Satellite Division, 23-25 September 2009, Savannah, GA, USA, 2677-2688. Barbarella M., Gandolfi G., Ricucci L, Zanutta A., (2009) The new Italian geodetic reference network (RDN): a comparison of solutions using different software packages; http://www.euref.eu/ symposia/2009Florence/06-03-p-gandolfi.pdf Barbarella M., Gandolfi S., Ricucci L., 2010, Esperienze di calcolo della Rete Dinamica Nazionale, Bollettino SIFET (ISSN 1721-971X), 2010, 2, 27-43. Bolli P., Montaguti S., Negusini M., Sarti P., Vittuari L., Deiana GL. (2006). Photogrammetry, laser scanning, holography and terrestrial surveying of the Noto VLBI dish. International VLBI Service for Geodesy and Astrometry 2006 General Meeting Proceedings. Fourth IVS General Meeting. Concepción, Chile. January 9-13, 2006. (vol. NASA/CP-2006-214140, pp. 172-176).-: NASA Conference Publication (US). Dawson J., Sarti P., Johnston G. M., Vittuari L.. (2007). Indirect approach to invariant point determination for SLR and VLBI systems: an assessment. Journal of Geodesy. vol. 81(6-8), pp. 433- 441 ISSN: 0949-7714. DOI 10.1007/s00190006-0125-x. Montaguti S., Vittuari L., Sarti P., Negusini M. (2007). Medicina and Noto VLBI Radiotelescopes: gravitational deformations evaluated with terrestrial laser scanning. GEOWISSENSCHAFTLICHE MITTEILUNGEN. Proceedings of the 18th European VLBI for Geodesy and Astrometry Working Meeting. Vienna. 12-13 April 2007. (vol. 79, pp. 4-9). VIENNA: edited by J. Boehm, A. Pany, and H. Schuh (Austria). Sarti, P., Abbondanza, C., Legrand, J., Bruyninx, C., Vittuari, L., Ray, J., 2013, Intra-site motions and monument instabilities at Medicina ITRF co-location site, Geoph. J. Int., vol. 192, p. 10421051, ISSN: 0956-540X, doi: 10.1093/gji/ ggs092. pp. 1042-1051. Sarti P., Sillard P., Vittuari L. (2004) - Surveying co-located Space Geodesy techniques for ITRF computation, Journal of Geodesy, vol.78, n. 3, Springer, 210-222. DOI 10.1007/s00190-0040387-0. Vittuari L., Sarti P., Sillard P., Tomasi P., Negusini M.. (2005). Surveying the GPS-VLBI Eccentricity at Medicina: Methodological Aspects and Practicalities. IERS Technical Note. Proceedings of the IERS Workshop on site co-location. Matera. Italy, 23 - 24 October 2003. (vol. 33, pp. 38 - 48). ISBN: 3-89888-793. RESEARCH PROJECTS PRIN 2007: “Uso degli osservatori geodetici co-locati VLBI-GPS per l’omogeneizzazione ed il confronto di serie storiche derivate da PS INSAR e livellazione geometrica, nello studio dei movimenti del suolo a scala regionale” (National PI A. Capra). FARB 2012 – Linea 1 Studi di fattibilità. Titolo della ricerca: “Metodi matematici per l’esplorazione ambientale sostenibile”. PI: V. Simoncini. CISIS 2011 e 2012: Monitoraggio della Rete Dinamica Nazionale Italiana (RDN) CONTACTS ITRF tie-vectors: [email protected] [email protected] National reference networks: [email protected] [email protected] 122 Materials Chemistry Materials Chemistry – Chemical Physics and Quantum Mechanics of Materials and Electronic Devices QUANTUM MECHANICAL STUDY AND MODELLING OF STRUCTURAL ELECTRONIC OPTICAL AND TRANSPORT PROPERTIES OF ORGANIC SEMICONDUCTORS FOR ELECTRONIC DEVICES RESEARCH GROUP: Renato Colle KEYWORDS: quantum mechanics, organic semiconductors, polymers, thermoelectric materials, organic-inorganic interfaces, organic solar cells, organic field effect transistors The aim of the research is the quantum-mechanical study, interpretation and prediction of structural, electronic, optical and transport properties of crystalline organic semiconductors, used or proposed for photovoltaic cells (OPV) and organic electronic devices, eg OFET. This research aims also to use the knowledge acquired on these materials to work out models useful to simulate or predict and interpret the functioning of electronic devices such as OPV and OFET. The materials considered are those of major interest for organic electronics: (1) single crystal organic semiconductors, such as perfluorobutil dicyanoperylene diimide (PDI-FCN2) and Rubrene, that are the prototype and most efficient n-channel and p-channel materials for OFET; (2) prototype pairs of e-donor /e-acceptor crystalline organic materials for “Bulk HeteroJunction” (BHJ) solar cells, such as P3HT(polymer) / PCBM (fullerene derivative); (3) ionic liquid crystalline materials, such as dicationic thienoviologen salts of different alkyl-chain lengths, that self-assemble into either calamitic or columnar mesophases and are used in the new interdigitated BHJ OPV. In the study of these materials, large attention is also devoted to the structure and properties of interfaces, such as e-donor/e-acceptor, organic semiconductor/ metallic electrode or insulating substrate. Finally, (4) we study also organic materials, such as semiconduting conjugated polymers, e.g. polyanilines, polypirroles, polythiophenes, that seem to be the best candidates, alternative to inorganics, for the realization of economic and efficient thermoelectric materials, being characterized by poor thermal conductivity, but good electronic conductivity if suitably doped. Some of the indicated activities are carried out in collaboration with research groups of the Department of Physics, University of Pisa (activities 1, 2, 4) and of the Department of Chemistry, University of Calabria (activity 3). 125 Fig. 1. Primitive cell of crystalline PCBM with diclorobenzene molecules from QM calculations. Fig. 2. Conjugated molecule between two Au electrodes; prototype molecular electronic device. Research Projects and Activities 2015 MAIN PUBLICATIONS R.Colle, G.Grosso, A.Ronzani, M.Gazzano, V.Palermo: “Anisotropic molecular packing of soluble C60 fullerenes in hexagonal nanocrystals obtained by solvent vapor annealing”. Carbon 50, 1332-1337 (2012). R.Colle, G.Grosso, A.Ronzani, C.M.Zicovich-Wilson: “Structure and X-ray spectrum of crystalline poly(3-hexylthiophene) from DFTVan der Waals calculations”. Phys. Status Solidi B 248, No.6, 1360-1368 (2011). R.Colle: “A variational density matrix approach with nonlocal effective potential”. Theoret.Chem. Acc. 123, 183-187 (2009). L.Argenti and R.Colle: “On the B-spline effective completeness”. Computer Physics Communications 180, 1442-1447 (2009) G.Cinacchi, R.Colle, P.Parruccini, A.Tani: “Structural, electronic and optical properties of a prototype columnar discotic liquid crystal”. J.Chem.Phys. 129, 174708-1,8 (2008). C.Cavazzoni, R.Colle, R.Farchioni, and G. Grosso: “Acidification of three-dimensional Emeraldine polymers: search for minimum energy paths from base to salt”. J.Chem.Phys. 128, 234903-1,5 (2008). E.Gnani, S.Reggiani, A. Gnudi, R. Colle, G. Baccarani: “OH dangling-bond saturation and dielectric function effects in ultra-scaled SNWFETs”. Proc. of the Device Research Conference. Device Research Conference (DRC-2008). Santa Barbara, CA 23-25 June, 2008 (pp. 9596). SANTA BARBARA, CA:IEEE Press. E.Gnani, S.Reggiani, A.Gnudi, P.Parruccini, R.Colle, M.Rudan, G.Baccarani: “Band-Structure Effects in Ultrascaled Silicon Nanowires”. IEEE Transactions on Electron Devices 54, no.9, 2243-2254 (2007). R.Colle, P.Parruccini, A.Benassi, and C.Cavaz- zoni: “Optical properties of emeraldine salt polymers from ab initio calculations: comparison with recent experimental data”. J.Phys.Chem.B 111, 2800-2805 (2007). C.Cavazzoni, R.Colle, R.Farchioni, and G. Grosso: “HCl doped conducting Emeraldine polymer by ab-initio Car-Parrinello molecular dynamics”. Phys.Rev.B 74, 033103-1,4 (2006). C.Cavazzoni, R.Colle, R.Farchioni, and G. Grosso: “Base and salt 3D forms of emeraldine II polymers by Car-Parrinello molecular dynamics”. Comput.Phys.Comm. 169, 135-138 (2005). G.Cinacchi, R.Colle, and A.Tani: “Atomistic Molecular dynamics simulation of hexa-pentyloxy-triphenylene: structure and translational dynamics of its columnar state”. J.Phys.Chem.B 108, 7969-7977 (2004). C.Cavazzoni, R.Colle, R.Farchioni, and G. Grosso: “Ab-Initio Molecular Dynamics Study of the Structure of Emeraldine Base Polymers”. Phys. Rev. B 69, 115213-1,6 (2004). C.Cavazzoni, R.Colle, R.Farchioni, and G. Grosso: “Car-Parrinello Molecular Dynamics study of electronic and structural properties of neutral polyanilines”. Phys. Rev. B 66, 1651101,10 (2002). RESEARCH PROJECTS CINECA ISCRA 2010 Project: HP10CEC8DR. DFT-van der Waals structural, electronic and optical properties of crystalline PCBM. CINECA ISCRA 2011 Project: HP10BAPZTX. Small-molecule organic single crystal for field effect transistors: the case of Rubrene/PDI-FCN2 interface. CINECA ISCRA 2012 Project: HP10BTREQQ. Polymeric thermoelectric materials. CONTACTS [email protected] 126 Materials Chemistry – Macromolecular Chemistry POLYMERIC COMPOSITES AND NANOCOMPOSITES FOR ADVANCED APPLICATIONS RESEARCH GROUP: Andrea Munari, Maurizio Fiorini, Nadia Lotti, Annamaria Celli, Martino Colonna, Lara Finelli, Laura Sisti, Paola Marchese, Francesco Di Credico, Matteo Gigli, Matteo Moncalero, Marco Nicotra, Grazia Totaro, Micaela Vannini KEYWORDS: layered silicates, layered double hydroxide, carbon nanotubes, fullerenes, biofibres The skills developed by the research group in the field of polymeric composites and nanocomposites arise from the specific needs for high-performance materials, characterized by low environmental impact. The applications of these materials are wide: in fact, depending on the type of nanofiller employed, they are characterized by high mechanical performance, heat resistance, reduced gas permeability and flammability and by specificic properties, such as conduction, optical, antibacterial and photo-catalytic properties. In all cases, in order to obtain the best possible performances of the final material, physicochemical properties of the inorganic phase, such as surface area, morphology, particle size, interaction with the polymer chains and their functional groups, are developed. Moreover, the degree of dispersion and adhesion at the interface with the matrix, which play a crucial role and can be controlled by acting on the chemical modification of fillers and on the techniques used for their mixing with the matrix, are also improved. The research group is able to synthesize, for the specific needs, inorganic fillers compatible with polymer matrices and to disperse them by direct polymerization or by melt mixing using Brabender or co-rotating twin-screw extruders. Moreover, in the field of composite, research has been focused on the preparation of materials based on poly (butylene succinate) (PBS), which constitutes one of the emerging biopolymers. Currently the application of this polyester is limited due to the high production costs and reduced mechanical and gas barrier properties. To solve these issues composites with lignocellulosic fibers, such as those derived from coconut, sugarcane bagasse, curauá and sisal, have been prepared through the technique of thermoforming. Excellent results in terms of adhesion at the interface and mechanical properties were obtained without chemically altering the fibers and then developing a final material completely “bio”. Fig. 1. Materials for composites and nanocomposites preparation. Fig. 2. a) Polybutylene succinate (PBS) composites with lignocellulosic fibers and b) a thermoplastic with a nanodispersed layered silicate. 127 Research Projects and Activities 2015 MAIN PUBLICATIONS Sisti L., Totaro G., Fiorini M., Celli A., Coelho C., Hennous M., Verney V. and Leroux F. (2013). Poly(butylene succinate)/Layered Double Hydroxide Bionanocomposites: Relationships between Chemical Structure of LDH Anion, Delamination Strategy, and Final Properties. Journal of Applied Polymer Science DOI: 10.1002/APP.39387. Frollini E., Bartolucci N., Celli A. and Sisti L. (2013). Poly(butylene succinate) reinforced with different lignocellulosic fibers Industrial Crops and Products 45, 160-169. Kango S., Kalia S., Celli A, Njugunad J., Habibie Y., Kumara R. (2013). Surface modification of inorganic nanoparticles for development of organic-inorganic nanocomposites – A review. Progress in Polymer Science 38, 1232-1261. Sisti L., Cruciani L., Totaro G., Vannini M., Berti C., Tobaldi D.M., Tucci A., Aloisio I., Di Gioia D. and Commereuc S. (2012). TiO2 deposition on the surface of activated fluoropolymer substrate, Thin Solid Films 520, 2824-2828. Celli A., Marchese P., Vannini M., Berti C., Fortunati I., Signorini R., Bozio R. (2011). Synthesis of novel fullerene-functionalized polysulfones for optical limiting applications. Reactive & Functional Polymers 71, 641-647. Colonna M., Berti C., Binassi E., Fiorini M., Karanam S. and Brunelle D.J. (2010). Nanocomposite of montmorillonite with telechelic sulfonated poly(butylene terephthalate): Effect of ionic groups on clay dispersion, mechanical and thermal properties. European Polymer Journal 46, 918-927. Berti C., Fiorini M. and Sisti L. (2009). Synthesis of poly(butylene terephthalate) nanocomposites using anionic clays. European Polymer Journal 45, 70-78. Colonna M., Berti C., Binassi E., Fiorini M., Acquasanta F. and Celli A. (2009). Improved dispersion of multi-wall carbon nanotubes in poly(butylene terephthalate) using benzimidazolium surfactants. e-Polymers, no. 051. Berti C., Binassi E., Colonna M., Fiorini M., Zuccheri T., Karanam S., and Brunelle D.J. (2009). Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring-opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation. Journal of Applied Polymer Science 114, 3211-3217. PATENTS Karanam S., Berti C., Binassi E., Brunelle D.J., Colonna M. and Fiorini M. (2010). Process for synthesis of imidazolium and benzimidazolium surfactants and their use in clays and nanocomposites. US 2010056693. Karanam S., Berti C., Binassi E., Brunelle D.J., Colonna M. and Fiorini M. (2010). Preparation of imidazolium and benzimidazolium surfactants for organically-modified clays used in thermoplastic matrix nanocomposites. WO 2010028032. Brunelle D.J., Colonna M., Fiorini M., Berti C. and Binassi E. (2009). Polycarbonate nanocomposites and processes for production of polycarbonate nanocomposites. WO 2009020968. Brunelle D.J., Colonna M., Berti C. and Fiorini M. (2006). Nanocomposite polymer composition with improved physical and mechanical properties useful for automotive parts. US 200611646. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] 128 Materials Chemistry – Macromolecular Chemistry ADVANCED POLYMERIC MATERIALS FOR SPORT EQUIPMENT APPLICATIONS RESEARCH GROUP: Martino Colonna, Maurizio Fiorini, Matteo Moncalero, Marco Nicotra KEYWORDS: sport equipment, polymeric materials, dynamical-mechanical behavior, coloration, composites In the last years the polymer group of the DICAM has focused his attention towards the study of advanced polymeric materials for sport equipment, in particular for winter sports, e.g. ski boots. Hitherto, both in academia and in industry, the research in this field has been minor. Our method is based on a scientific approach to choose and develop new materials with specific characteristics such as low weight, good visco-elastic properties, high impact resistance at low temperatures and gliding on snow. Thanks to our knowledge in the characterization and synthesis of polymeric materials we are able to use a new technique to evaluate and select appropriate materials for the different applications. For example, through DMTA analysis we can evaluate the optimal parameters of the visco-elastic material’s behavior. By analyzing the variation of the elastic modulus with temperature is possible to evaluate the stiffening of the material in the different conditions of use. From the loss modulus (E’’) is possible to deduce the vibration’s damping of the material and the speed of elastic return once the stress is finished. These parameters have a fundamental effect on the final performance of the sports equipment. The correct choice of material also helps in product design, providing higher performance and less weight. Moreover, the DMTA analysis allows to calculate the temperature at which the material softens. This fact may be used to modify the equipment’s geometry through a thermoforming process that allows the customization of the product on the needs of the final user. Using our expertise in materials obtained from renewable sources, we can define the most appropriate materials, reducing the carbon footprint of the product. We are also able to study new systems for the material’s coloring and their photo-degradation during use. We are also equipped with wireless sensors that can measure on field the thermal comfort and moisture transport during the use of materials, equipment and technical sports clothing. Fig. 1. Dynamical-mechanical analysis of materials used for skiboots. Fig. 2. Flexural behavior of skiboot. 129 Research Projects and Activities 2015 MAIN PUBLICATIONS CONTACTS Colonna M., Fiorini M., Nicotra M. and Moncalero M. Viscoelastic properties of thermoplastic materials used for ski boots. ISEA 2012 International Meeting, Lowell USA. [email protected] [email protected] 130 Materials Chemistry – Macromolecular Chemistry POLYMERIC MATERIALS FOR BIOMEDICAL APPLICATIONS RESEARCH GROUP: Andrea Munari, Maurizio Fiorini, Nadia Lotti, Annamaria Celli, Martino Colonna, Lara Finelli, Laura Sisti, Paola Marchese, Francesco Di Credico, Matteo Gigli, Grazia Totaro, Micaela Vannini KEYWORDS: tissue engineering, controlled drug release, antibacterial properties, biodegradability/biocompatibility, structure-properties relationships As it is well known, polymers are the most versatile class of materials, thus can be favorably designed to fulfill the needs related to the variety of tissues and diseases involved in the human body. The research group has recently focused its activities on three main aspects of biomedical engineering: tissue engineering, controlled drug release and polymers with antibacterial properties. Tissue engineering The control of molecular structure and tridimensional architecture of synthetic polymeric constructs (scaffolds) – designed to reproduce the typical properties of the damage tissue –is a key element for controlling cell adhesion, proliferation, migration and differentiation. In the field of tissue engineering the possibility to employ scaffolds mimicking native tissue is limited by the scarce availability of biocompatible and biodegradable polymers with proper mechanical properties, especially in terms of stiffness. Controlled drug release Classical methods of drug delivery exhibit specific problems that scientists are attempting to address. The goal of new drug delivery systems, therefore, is to deliver medications intact to specifically targeted parts of the body and to release them in a controlled way depending on the required treatment regime. The design of the drug carrier is fundamental in order to achieve the correct tissutal and cellular localization of drug molecules and perform an adequate release. In this framework, polymers and copolymers are the most promising tool to obtain materials showing specifically designed properties to be employed as drug carriers. Polymers with antibacterial properties Antibacterial properties can be introduced into a polymer by following different strategies: chemical modifications carried out in bulk, surface modification, blending with chemically modified nanofillers. a) b) Fig. 1. SEM micrographs of PBS scaffolds: a) 1000x, b) 10000x. Fig. 2. Drug release profile from biodegradable polymeric microparticles. 131 Research Projects and Activities 2015 MAIN PUBLICATIONS Gualandi C., Soccio M., Saino E., Focarete M. L., Lotti N., Munari A., Moroni L., Visai L. (2012). Easily synthesized novel biodegradable copolyesters with adjustable properties for biomedical applications. Soft Matter 8, 5466-5476. Sisti L., Cruciani L., Totaro G., Vannini M., Berti C., Aloisio I., Di Gioia D. (2012). Antibacterial coatings on poly(fluoroethylenepropylene) films via grafting of 3-hexadecyl-1-vinylimidazolium bromide. Progress in organic coatings 73, 257– 263. Gualandi C., Soccio M., Govoni M., Valente S., Lotti N., Munari A., Giordano E., Pasquinelli G., Focarete M. L.. (2012). Poly(butylene/diethylene glycol succinate) multiblock copolyesters as a candidate biomaterial for soft tissue engineering: solid-state properties, degradability and biocompatibility. Bioactive and Compatible Polymers 27(3) 244-264. Colonna M., Berti C., Binassi E., Fiorini M., Sullalti S., Acquasanta F., Vannini M., Di Gioia D., Aloisio I. (2012). Imidazolium poly(butylene terephthalate) ionomers with long-term antimicrobial activity. Polymer 53, 1823-1830. Soccio M., Lotti N., Gazzano M., Govoni M., Giordano E., Munari A. (2012). Molecular architecture and solid-state properties of novel biocompatibile PBS-based copolyesters containing sulphur atoms. Reactive & Functional Polymers 72, 856-867. Colonna M., Berti C., Binassi E., Fiorini M., Sullalti S., Acquasanta F., Vannini M., Di Gioia D., Aloisio I., Karanam S., Brunelle D.J. (2012) Synthesis and characterization of imidazolium telechelic poly(butylene terephthalate) for antimicrobial applications. Reactive & Functional Polymers 72, 133-141 Gigli M., Lotti N., Gazzano M., Finelli L., Munari A. (2012). Macromolecular design of novel sulphur-containing copolyesters with promising mechanical properties. Journal of Applied Polymer Science 126, 686-696. RESEARCH PROJECTS PRIN NANOMED. Molecular Nanotecnologies for controlled drug release. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] 132 Materials Chemistry – Macromolecular Chemistry MONOMERS AND POLYMERS FROM BIOMASS AND FROM WASTE OF AGROFOOD INDUSTRIES RESEARCH GROUP: Andrea Munari, Maurizio Fiorini, Nadia Lotti, Annamaria Celli, Martino Colonna, Lara Finelli, Laura Sisti, Paola Marchese, Claudio Gioia, Grazia Totaro, Micaela Vannini KEYWORDS: bio-based monomers, biopolymers, bio-PET There is today a clearly detectable increasing interest in exploitation of non-food biomass and industrial wastes. Moreover, academic and industrial research is interested in the preparation of bio-based polymers, i.e. polymers obtained from renewable resources, in order to substitute the traditional petro-based polymers. By the combination of these two necessities, we have developed some research activities which are focused on the exploitation of biomass and agro-food wastes to prepare bifunctional monomers, mainly for the polyester synthesis. An example of such activity is the development of a chemical route which starts from terpenes (in particular, from limonene, which is a raw material of juice industry) to prepare terephthalic acid (TPA) and derivatives (see Fig. 1). TPA is an important monomer, from which poly(ehtylene terephthalate) (PET) and poly(butylene terephthalate) (PBT), some of the most important commercial polymers, are produced. For the first time, it was possible to prepare fully biobased PET and PBT. Moreover, other polymers, prepared starting from TPA derivatives, are now potentially fully biobased materials. This is the case of aliphatic polymers containing 1,4-cyclohexylene units, for example poly(1,4-cyclohexylenedimethylene-1,4-cyclohexanedicarboxylate) (PCCD) polymers, which are used for outdoor applications, due to their high UV resistance. Our reaserch group is developing analogous approaches to obtain other bio-based dicarboxylic acids, diesters, diols starting from non-food biomass and wastes. 133 Fig. 1. Synthesis of bio-PET and bio-PBT. Research Projects and Activities 2015 MAIN PUBLICATIONS Celli A., Marchese P., Sullalti S., Cai J., Gross R.A. (2013) Aliphatic/aromatic copolyesters containing biobased w-hydroxyfatty acids: synthesis and structure–property relationships. Polymer 54, 3774-3783. Colonna M., Berti C., Fiorini M., Binassi E., Mazzacurati M., Vannini M., Karanam S. (2012) Synthesis and radiocarbon evidence of terephthalate polyesters completely prepared from renewable resources. Green Chemistry 13, 2543-2548. Berti C., Celli A., Marchese P., Marianucci E., Sullalti S., Barbiroli G. (2010). Environmental-friendly copolyesters containing 1,4-cyclohexane dicarboxylate units: 1. Relationships between chemical structure and thermal properties. Macromolecular Chemistry and Physics 211, 1559-1571. Berti C., Celli A., Marchese P., Barbiroli G., Di Credico F., Verney V., Commereuc S. (2009). Novel copolyesters based on poly(alkylene dicarboxylate)s: 2. Thermal behavior and biodegradation of fully aliphatic random copolymers containing 1,4-cyclohexylene rings. European Polymer Journal 45, 2402-2412. PATENTS I., Vannini M. (2010). Bio-based terephthalate polyesters. US 2010168371. Berti C., Binassi E., Colonna M., Fiorini M., Kannan G., Karanam S., Mazzacurati M., Odeh I. (2010). Preparation of bio-based terephthalic acid used to produce terephthalate polyesters. U.S. Pat. Appl. Publ., US 2010016846. Berti C., Binassi E., Colonna M., Fiorini M., Kannan G., Karanam S., Mazzacurati M., Odeh I., Vannini M. (2010). Preparation of bio-based 1,4-cyclohexane dimethanol used to produce terephthalate polyesters. U.S. Pat. Appl. Publ., US 20100168373. Berti C., Binassi E., Colonna M., Fiorini M., Kannan G., Karanam S., Mazzacurati M., Odeh I., Vannini M. (2010). Preparation of bio-based terephthalic acid used to produce terephthalate polyesters. PCT Int. Appl. WO 2010078328. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] Berti C., Binassi E., Colonna M., Fiorini M., Kannan G., Karanam S., Mazzacurati M., Odeh 134 Materials Chemistry – Macromolecular Chemistry ECO-FRIENDLY POLYMER FOR FOOD PACKAGING, GREEN BUILDING AND COATING APPLICATIONS RESEARCH GROUP: Andrea Munari, Maurizio Fiorini, Nadia Lotti, Annamaria Celli, Martino Colonna, Lara Finelli, Laura Sisti, Paola Marchese, Claudio Gioia, Francesco Di Credico, Matteo Gigli, Grazia Totaro, Micaela Vannini KEYWORDS: biodegradability, mechanical properties, barrier properties, structure-properties relationships This research field is mainly focused on the synthesis and characterization of novel biodegradable polymers and copolymers which offer physicochemical properties suitable for the desired application. An alternative approach consists in the chemical modification of commercially available polymers to make them attractive for different uses. Regardless of the synthetic approach adopted, the main goal is to find out structure-properties relationships of main interest for designing a material which completely fits the requested specifications. As an example, green food packaging materials must accomplish basic requirements to be an ideal candidate for food, which includes barrier properties (water vapor, gases, light and aroma), optical properties (transparency), strength, welding and molding properties, disposal requirements, antistatic properties and, above all, strictly follow food safety. Copolymerization as well as physical and/or reactive blending approach are an effective way of achieving a deliverable combination of properties, which are often absent in single component polymers. Moreover, the final properties of the material can be favorably modified, depending on the kind, relative amount, distribution and architecture of the comonomeric units or, in the case of mixture, by properly varying the homopolymers and blend composition. The choice of the monomers to be used in the polymerization process as well as of the comonomeric unit to be introduced along the polymeric chain of the parent homopolymer will be made on the basis of the requirements that the materials have to satisfy. The so synthesized polymers are fully and deeply characterized both using the technology available in the DICAM labs and through collaborations with other research groups. Fig. 1. Examples of biopolimers obtained from renewable resources. a 135 b c Fig. 2. SEM micrographs of partially biodegraded PBS-based copolymers a) 0h, b) 7h, c) 22h of incubation in the presence of a lipase. Research Projects and Activities 2015 MAIN PUBLICATIONS Celli A., Marchese P., Sullalti S., Cai J., Gross R.A. (2013). Aliphatic/aromatic copolyesters containing biobased w-hydroxyfatty acids: synthesis and structure–property relationships. Polymer 54, 3774 - 3783. Gigli M., Negroni A., Soccio M., Zanaroli G., Lotti N., Fava F., Munari A. (2013). Enzymatic hydrolysis studies on novel eco-friendly aliphatic thiocopolyesters, Polymer Degradation & Stability 98, 934-942. Soccio M., Lotti N., Gigli M., Finelli L., Gazzano M., Munari A. (2012). Reactive blending of poly(butylene succinate) and poly(triethylenesuccinate): characterization of the copolymers obtained. Polymer International 61, 11631169. Gigli M., Lotti N., Gazzano M., Finelli L., Munari A. (2012). Novel eco-friendly random copolyesters of poly(butylene succinate) containing ether-linkages. Reactive & Functional Polymers 72, 303-310. Gigli M., Negroni A., Soccio M., Zanaroli G., Lotti N., Fava F., Munari A. (2012). Influence of chemical and architectural modifications on the enzymatic hydrolysis of poly(butylene succinate) Green Chemistry 14, 2885-2893. Berti C., Celli A., Marchese P., Barbiroli G., Di Credico F., Verney V., Commereuc S., (2009). Novel copolyesters based on poly(alkylene dicarboxylate)s: 2. Thermal behavior and biodegradation of fully aliphatic random copolymers containing 1,4-cyclohexylene rings. European Polymer Journal 45, 2402-2412. Soccio M., Lotti N., Finelli L., Gazzano M., Munari A. (2008). Influence of transeterification reactions on the miscibility and thermal properties of poly(butylene/diethylene succinate) copolymers. European Polymer Journal 44, 1722-1732. Berti C., Celli A., Marchese P., Barbiroli G., Di Credico F., Verney V., Commereuc S. (2008). Novel copolyesters based on poly(alkylene dicarboxylate)s: 1. Thermal behavior and biodegradation of aliphatic-aromatic random copolymers. European Polymer Journal 44, 3650-3661. Berti C., Celli A., Marchese P., Marianucci E., Barbiroli G., Di Credico F. (2008). Influence of molecular structure and stereochemistry of the 1,4-cyclohexylene ring on thermal and mechanical behaviour of Poly(butylene 1,4-cyclohexanedicarboxylate). Macromoelcular Chemistry and Physics 209, 1333-1344. RESEARCH PROJECTS Soccio M., Lotti N., Finelli L., Gazzano M., Munari A. (2010). (2-Hydroxy isobutyric) acid containing poly(glycolic acid): structure-properties relationship. Journal of Polymer Science Part B: Polymer Physics 48, 1901-1910. EU FP7-KBBE-2012.3.5-02 Project: BIOCLEAN. New biotechnological approaches for biodegrading and promoting the environmental biotransformation of synthetic polymeric materials. Berti C., Celli A., Marchese P., Marianucci E., Sullalti S., Barbiroli G. (2010). Environmental-friendly copolyesters containing 1,4-cyclohexane dicarboxylate units: 1. Relationships between chemical structure and thermal properties. Macromolecular Chemistry and Physics 211, 1559-1571. PON NAMASTE. Nanomaterials for sustainable building. Commereuc S., Askanian H., Verney V., Celli A., P. Marchese (2010). About durability of biodegradable polymers: Structure/Degradability relationships. Macromolecular Symposia 296, 378-387. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] 136 Materials Chemistry – Macromolecular Chemistry INVESTIGATION OF POLYMER CRYSTALLIZATION PROCESS RESEARCH GROUP: Andrea Munari, Maurizio Fiorini, Nadia Lotti, Annamaria Celli, Martino Colonna, Lara Finelli, Laura Sisti, Paola Marchese, Matteo Gigli, Grazia Totaro, Micaela Vannini KEYWORDS: crystallization kinetics, melting behavior, morphology, structure-property relationship It is well known that crystallization is a phase transition that plays an important role in determining the morphology of a polymer for a wide range of technological processes. Therefore, studies of the isothermal crystallization of polymers commonly have been used to investigate the specific mechanisms of the crystallization process and from a technical standpoint are relevant to optimizing process conditions. In fact, the morphological structure (size, shape, perfection, orientation of crystallites), which is formed by crystallization from the molten state, influences strongly most of the physical and mechanical properties of polymeric products. Moreover, because the crystal structure and morphology (the crystal habit and organization of crystals into aggregates of a higher order) are responsible for many properties of the final products, knowledge of the crystallization mechanism is crucial for designing materials with the required properties. The crystallization kinetics are investigated by DSC and hot-stage optical microscopy (MO), both available at the laboratories of the Department. MO technique, beside measuring spherulitic growth rate, allows to obtain information on crystal phase morphology, which changes with undercooling degree and therefore with Tc. Both melt isothermal and non-isothermal crystallization kinetics studies are carried out. Melt isothermal crystallization kinetics is investigated by DSC technique and the data analyzed according to the Avrami’s treatment. The data obtained from measurements carried out under non-isothermal conditions are analyzed according Tobin and Ozawa equations. The crystallization process is also investigated employing equipments located at other research laboratories, such as: XRD, AFM and DETA. Lastly, structure-property relationships, which are fundamental to design a new material with “ad hoc” properties, are found. For copolymers, crystallization parameters are correlated with copolymer composition (random copolymers) and with molecular architecture, i.e. crystallisable block length (block copolymers). Fig. 1. Crystallization rate of homopolymers and copolymers, determined in isothermal conditions, as a function of the undercooling degree. Fig. 2. Optical micrographs of PGA homopolymer, isothermally crystallized at 145°C. 137 Research Projects and Activities 2015 MAIN PUBLICATIONS Celli A., Marchese P., Sullalti S., Berti C., Barbiroli G. (2011). Eco-Friendly Poly(butylene 1,4-cyclohexanedicarboxylate): Relationships Between Stereochemistry and Crystallization Behavior. Macromolecular Chemistry and Physics 212, 1524-1534. Sanz A., Nogales A., Ezquerra T.A., Soccio M., Munari A., Lotti N. (2010). Cold Crystallization of Poly(trimethylene terephthalate) as revealed by simultaneous WAXS, SAXS and Dielectric Spectroscopy. Macromolecules 43(2), 671-679. Soccio M., Lotti N., Finelli L., Munari A. (2009). Effect of transesterification reactions on the crystallization behaviour and morphology of poly(butylene/diethylene succinate) block copolymers. European Polymer Journal 45, 171-181. Soccio M., Nogales A., Lotti N., Munari A., Ezquerra T.A. (2007). The b-relaxation as a probe to follow real-time polymer crystallization in model aliphatic polyesters. Polymer 48, 4742-4750. Soccio M., Finelli L, Lotti N, Gazzano M., Munari A. (2007). Aliphatic poly(propylene dicarboxylate)s: effect of chain length on thermal properties and crystallization kinetics. Polymer 48, 3125-3136. Soccio M., Nogales A., Lotti N., Munari A., Ezquerra T.A. (2007). Evidence of early stage precursors of polymer crystals by dielectric spectroscopy. Physical Review Letters 98(3), 037801/1-037801/4 Berti C., Celli A., Marchese P., Marianucci E., Barbiroli G., Di Credico F. (2007) The effect of aliphatic chain length on thermal properties of poly(alkylene dicarboxylate)s. e-Polymers no. 057. Berti C., Celli A., Marchese P., Marianucci E., Marega C., Causin V., Marigo A. (2007). Aliphatic poly(alkylene dithiocarbonate)s: thermal properties and structural characteristics of poly(hexamethylene dithiocarbonate). Polymer 48, 174-182. Celli A., Barbiroli G., Berti C., Di Credico F., Lorenzetti C., Marchese P., Marianucci E., (2007) Thermal properties of poly(alkylene dicarboxylate)s derived from 1,12-dodecanedioic acid and even aliphatic diols, Journal of Polymer Science, Part B: Polymer Physics 45, 1053-1067. Marchese P., Celli A., Fiorini M., (2006) Influence of the molecular architecture on the crystallizability and phase behavior of Poly(ethylene terephthalate)/bisphenol A Polycarbonate block copolymers, In “Leading Edge Polymer Research”, R.K. Editor, Nova Science Publishers, Inc., NY. CONTACTS [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] [email protected] 138 Materials Science and Technology Materials Science and Technology – Materials for Civil Engineering and Architecture Restoration SUSTAINABLE CONCRETE, RECYCLING AND ENVIRONMENT RESEARCH GROUP: Maria Chiara Bignozzi, Elisa Franzoni, Stefania Manzi, Andrea Saccani KEYWORDS: industrial waste, waste, eco-cements, durability With the aim to obtain materials with high dura-bility and good performances for civil engineer-ing, the research is focused on the mix-design and characterization of sustainable concrete (i.e. concrete with eco-cements, sulphur concrete, concrete where natural aggregates are replaced with construction and demolition waste and/or end-use tyre rubber, etc.). Innovative and sus-tainable conglomerates are designed combining high durability features with the introduction of waste materials in the mix design. Mix-design, physical and mechanical properties, microstruc-ture, alkali-silica reaction (ASR), durability in aggressive environment, and protection against corrosion are studied to design conglomerates with tailored properties. Porosity and its distri-bution are deeply investigated by means of mer-cury intrusion porosimetry and microscopy techniques. Tailoring the porosity through the optimization of conglomerate mix-design, al-lows tuning the mechanical properties and the density of the final product. The research on recycling of waste and by-products for the development of new building materials is often supported by different indus-trial partners. Recycling contributes to the valor-isation of waste and reduction of environmental impact, thus avoiding waste landfill disposal and use of non-renewable resources. The treatment and use of waste from construction and demoli-tion, the recycling of waste wash water coming from ready-mix concrete plants, of ceramic in-dustry by-products, of end-used tyre, of glass waste from separate collection, of ashes from incineration of municipal solid waste, of poly-meric and agricultural waste, etc. are studied. These by-products are successfully used as new constituents for ecocements, fiber reinforce-ment, aggregates and filler for ordinary and self-compacting concrete. In the field of materials for architecture, new methodologies have been set up. They concern the evaluation of construc-tion materials sustainability and new systems of integrated design for the reduction of environ-mental impact related to the construction and building service life (energy saving, renewable energy sources available on-site, etc.). Fig. 1. Construction and demolition waste and agricultural waste. Fig. 2. Test on self-compacting concrete. Fig. 3. Concrete samples with innovative mix-design. 141 Research Projects and Activities 2015 MAIN PUBLICATIONS Manzi S., Mazzotti C. and Bignozzi M.C. (2013). Short and long-term behavior of structural concrete with recycled concrete aggregate. Cement and Concrete Composites 37, 312-318. Bignozzi M.C. and Saccani A. (2012). Ceramic waste as aggregate and supplementary cementing material: A combined action to contrast alkali silica reaction (ASR). Cement and Concrete Composites 34, No.10, 1141-1148. Ferretti E. and Bignozzi M.C. (2012). Stress and Strain Profiles along the Cross-Section of Waste Tire Rubberized Concrete Plates for Airport Pavements. Computers, Materials & Continua 27, 231-274. Manzi S. (2011). An investigation on sulfur based composite materials containing C&D waste. Proceedings of XIII International Congress on Chemistry of Cement, XIII ICCC, Cementing a sustainable future, Madrid, 3-8 July 2011. Editors: Á. Palomo, A. Zaragoza, J. C. López Agüí, Editado por el Instituto de Ciencias de la Construcción “Eduardo Torroja”. CSIC, Madrid, Diseño gáfico de portada: Advertising Label 3 (Acubo). Maquetación: SIASA CONGRESOS S.A., 1-7. Manzi S., C. Mazzotti C. and Bignozzi M.C. (2011). Concrete demolition waste: sustainable source for structural concrete. 2nd Workshop on The new boundaries of structural concrete, Università Politecnica delle Marche – ACI Italy Chapter, Ancona, Italy, September 15-16, 2011. Editors: L. Dezi, G. Moriconi, R. Realfonso, Published by Imready, Galazzano, Printed by Imready srl, 39-46. Bignozzi M.C. (2011). Sustainable cements for green buildings construction. Procedia Engineering 21, 915-921. Saccani A. and Bignozzi M.C. (2010). ASR expansion behavior of recycled glass fine aggregates in concrete. Cement and Concrete Research 40, 531-536. Bignozzi M.C., Saccani A. and Sandrolini F. (2010). Chemical-Physical behavoiur of matt waste in cement mixture. Construction and Building Materials 24, 2194-2199. Andreola F., Barbieri L., Bignozzi M.C., Lancellotti I. and Sandrolini F. (2010). New Blended Cement from Polishing and Glazing Ceramic Sludge. International Journal of Applied Ceramic Technology 7, No. 4, 546-555. Bignozzi M.C., Saccani A. and Sandrolini F. (2009). Matt waste from glass separated collection: an ecosustainable addition for new building materials. Waste Management 29, 329-334. Franzoni E. (2011). Materials selection for green buildings: which tools for engineers and architects? Procedia Engineering 21, 883-890. Sandrolini F. and Franzoni E. (2009). Embodied energy of building materials: a new parameter for sustainable architectural design. Heat & Technology 27, No. 1, 163-167. Bignozzi M.C. and Sandrolini F. (2008). Effects of different glasses composition on ecosustainable blended cements. Proceeding of the Conference on Concrete Construction “Excellence in Concrete Construction – Through Innovation” Kingston University, London, UK. 9-10 September, 2008, CRC press, Taylor & Francis Group, 511-515. Sandrolini F., Manzi S. and Andrucci A. (2006). Sulfur-polymer matrix composites from particulate wastes: a sustainable route to advanced materials. Composites, Part A: Applied Science and Manufacturing 37, 695-702. Bignozzi M.C. and Sandrolini F. (2006). Tyre rubber waste recycling in self compacting concrete. Cement and Concrete Research 36, No. 4, 735-739. Sandrolini F. and Franzoni E. (2001). Waste wash water recycling in ready-mixed concrete plants. Cement and Concrete Research 31, 485489. CONTACTS [email protected] [email protected] [email protected] 142 Materials Science and Technology – Materials for Civil Engineering and Architecture Restoration ALKALI ACTIVATED MATERIALS (GEOPOLYMERS) FOR CONSTRUCTIONS RESEARCH GROUP: Maria Chiara Bignozzi, Stefania Manzi KEYWORDS: inorganic polymers, physical-mechanical properties, microstructure, durability Alkali activated materials (AAM) are a new class of inorganic materials obtained by calcium-alumino-silicates precursors. Such precursors are able to consolidate when treated with strong alkaline solutions at temperatures between 20°C and 100°C. If the nature of the starting materials is mainly alumino-silicate (i.e. metakaolin coming from calcined caolin), then the relevant activated materials are known as ‘geopolymers’. The interest for this new class of materials is based on several factors: (i) industrial waste can be used as precursors thus saving natural raw materials; (ii) alkali activation is a productive process with a low environmental impact if compared with the industrial processes of traditional building materials; (iii) alkali activated materials can be used as binders (similarly to cement) to produce composites and conglomerates or as one-phase materials to obtain blocks and tiles also suitable for high temperature applications. The research activity is mainly focused on innovative precursors in order to: (i) set up their mix design and process parameters (time, temperature, types and concentration of alkaline solutions, molar ratios, etc.); (ii) provide fresh state characterizations and optimize moulding technology; (iii) provide physical-mechanical characterization of the final products at the hardened state (with special focus on porosity and its control); (iv) study their physical and mechanical behaviour after high temperature treatments; (v) investigate final products durability by means of climate chambers with temperature, humidity and ultraviolet controls. The research activity is carried out in collaboration with the Department of Engineering “Enzo Ferrari”, University of Modena (Prof. Cristina Leonelli) and the Centre for Materials Research, Curtin University, Perth, Australia (Prof. A. van Riessen). Fig. 1. Fiber reinforced composites and onephase samples obtained by alkali activation process of different industrial waste. Fig. 2. Geopolymer mortar and concrete samples. Fig. 3. Fiber reinforced composite with alkali-activated matrix. 143 Research Projects and Activities 2015 MAIN PUBLICATIONS Analysis and Calorimetry 108, No. 3, 1189-1199. Bignozzi M.C., Manzi S., Natali M.E., van Riessen A. and Rickard W.D.A. (2013). Thermal stability and microstructural analysis of inorganic polymer binders based on Italian and Australian fly ash. SCMT3 – 3rd International Conference on Sustainable Construction Materials & Technologies, August 18-21, 2013. Kyoto, 1-9. Kamseu E., Nait-Ali B., Bignozzi M.C., Leonelli C., Rossignol S. and Smith D.S. (2012). Bulk composition and microstructure dependence of effective thermal conductivity of porous inorganic polymer cements. Journal of the European Ceramic Society 32, No. 8, 1593-1603. Bignozzi M.C., Manzi S., Lancellotti I., Kamseu E., Barbieri L. and Leonelli C. (2013) Mix-design and characterization of alkali activated materials based on metakaolin and ladle slag. Applied Clay Science 73, 78-85. Natali Murri A., Rickard W.D.A, Bignozzi M.C. and van Riessen A. (2013). High temperature behaviour of ambient cured alkali-activated materials based on ladle slag. Cement and Concrete Research 43, 51-61. Kamseu E., Bignozzi M.C., Melo U.C., Leonelli C. and Sglavo V.M. (2013). Design of inorganic polymer cements: Effects of matrix strengthening on mi-crostructure. Construction and Building Materials 38, 1135-1145. Kamseu E., Ceron B., Tobias H., Leonelli C., Bignozzi M.C., Muscio A. and Libbra A. (2012). Insulating behaviour of Metakaolin-based Geopolymer Materials assess with Heat Flux Meter and Laser Flash Techniques. Journal of Thermal Bignozzi M.C. (2011). Geopolimeri e cementi: due leganti a confronto. Geopolimeri: polimeri inorganici chimicamente attivati, a cura di Marcello Romagnoli e Cristina Leonelli. Editore I.Cer.S, Casa Editrice Lulu, 83-101. Natali A., Manzi S. and Bignozzi M.C. (2011). Novel fiber-reinforced composite materials based on sustainable geopolymer matrix. Procedia Engineering 21, 1124-1131. Bignozzi M.C., Sandrolini F., Barbieri L. and Lancellotti I. (2010). New Geopolymers Based on Electric Arc Furnace Slag. 12th International Ceramics Congress, CIMTEC 2010, June 6-11, 2010, Montecatini Terme, Tuscany, Italy, Trans Tech Publications Ltd, Laubisrutistr. 24, CH8712 Stafa-Zurich, Switzerland. Advances in Science and Technology 69, 117-122. CONTACTS [email protected] [email protected] 144 Materials Science and Technology – Materials for Civil Engineering and Architecture Restoration MATERIALS AND TECHNOLOGIES FOR ARCHITECTURE RESTORATION AND BUILDING REHABILITATION RESEARCH GROUP: Elisa Franzoni, Alberto Fregni, Stefania Manzi KEYWORDS: Ancient building materials, decay, diagnostics, restoration, rising damp, consolidating materials The research activities in this field range from diagnostic investigations on ancient buildings, to the evaluation of compatibility and durability of conservation materials, to the design and set-up of new restoration materials (with their application techniques). New diagnostic techniques and protocols based on a holistic approach have been developed, as a tool for the restoration of ancient building materials. The Research Unit has been involved in the diagnostic investigations on several Italian and European historic buildings, e.g. Tiberius bridge in Rimini (I cent.), St. Mark basilica in Venice (XI cent.), Montetiffi abbey, RN (XI cent.), Pio Palace at Carpi (XV cent.), St. Francis church at Correggio (XV cent.), Ducal Palace in Mantua (XVI cent.), S. Caterina degli Italiani and Sarria churches in Malta (XVII cent.), Vizzani Palace in Bologna (XVI cent.), St. Luca porticoes in Bologna (XVII cent.), Isolani Palace in Bologna (XV-VII cent.), Casa Major Pessoa in Aveiro, Portugal (XX cent.) and other Art Nouveau buildings in Italy. An important research line concerns the problem of measurement and reclaim of rising damp in ancient brick and stone masonries (by means of on-site and laboratory experimental campaigns), as well as the relevant electrokinetic effects and the decay effects. Research on materials involves several key aspects for the architectural restoration design, also in collaboration with foreign colleagues (e.g. EMPA, Princeton University, Universidade de Aveiro) and industrial partners: materials durability in aggressive environments, historic building materials, set-up of innovative and compatible conservation materials. The development of innovative materials includes: new consolidants based on hydroxyapatite, silicate consolidants, nanoconsolidants, self-cleaning photocatalytic finishing for façades. The Unit is member of the “Integrated Research Team - Alma HeritageScience ” (University of Bologna) in the field of heritage conservation. Collaborations are currently running with several Italian Superintendences, Municipalities and local Administrations. 145 Fig. 1. Lab fixture for investigating rising damp. Fig. 2. Ancient materials and atmospheric decay. Fig. 3. Lab tests on new consolidating materials. Research Projects and Activities 2015 MAIN PUBLICATIONS Sassoni E., Franzoni E., Pigino B., Scherer G.W. and Naidu S. (2013). Consolidation of calcareous and siliceous sandstones by hydroxyapatite: Comparison with a TEOS-based consolidant. Journal of Cultural Heritage 14 (3 SUPPL), e103-e108. Franzoni E., Sassoni E., Scherer G.W. and Naidu S. (2013). Artificial weathering of stone by heating. Journal of Cultural Heritage 14 (3 SUPPL), e85-e93. Franzoni E., Pigino B. and Pistolesi C. (2013). Ethyl silicate for surface protection of concrete: performance in comparison with other inorganic surface treatments. Cement and Concrete Composites, in press (doi: 10.1016/j.cemconcomp.2013. 05.008). Franzoni E., Bandini S. and Graziani G. (2013). Rising moisture, salts and electrokinetic effects in ancient masonries: From laboratory testing to on-site monitoring. Journal of Cultural Heritage, in press (doi: 10.1016/j.culher.2013.03.003). Franzoni E. and Bandini S. (2012). Spontaneous electrical effects in masonry affected by capillary water rise: The role of salts. Construction and Building Materials 35, 642-646. Sandrolini F. and Franzoni E. (2010). Characterization procedure for ancient mortars’ restoration: the plasters of the Cavallerizza courtyard in the Ducal Palace in Mantua (Italy). Materials Characterization 61, 97-104. Pigino B., Leemann A., Franzoni E. and Lura P. (2012). Ethyl silicate for surface treatment of concrete - Part II: Characteristics and performance. Cement and Concrete Composites 34 (3), 313-321. Sandrolini F., Franzoni E. and Pigino B. (2012). Ethyl silicate for surface treatment of concrete Part I: Pozzolanic effect of ethyl silicate. Cement and Concrete Composites 34 (3), 306-312. Franzoni E. and Sassoni E. (2011). Correlation between microstructural characteristics and weight loss of natural stones exposed to simulated acid rain. Science of the Total Environment 412-413, 278-285. Sandrolini F., Franzoni E., Varum H. and Nakonieczny R. (2011). Materials and technologies in Art Nouveau architecture: Façade decoration cases in Italy, Portugal and Poland for a consistent restoration. Informes de la Construccion 63 (524), 5-11. Sandrolini F., Franzoni E., Sassoni E. and Diotallevi P.P. (2011). The contribution of urban-scale environmental monitoring to materials diagnostics: A study on the Cathedral of Modena (Italy). Journal of Cultural Heritage 12 (4), 441-450. Franzoni E., Sandrolini F. and Bandini S. (2011). An experimental fixture for continuous monitoring of electrical effects in moist masonry walls. Construction and Building Materials 25 (4), 2023-2029. Sandrolini F., Franzoni E., Cuppini G. and Caggiati L. (2007). Materials decay and environmental attack in the Pio Palace at Carpi: a holistic approach for historical architectural surfaces conservation. Building and Environment 42, 1966-1974. Sandrolini F. and Franzoni E. (2007). Repair Systems for the restoration of ancient buildings – Dampness Rise Problem. Restoration of Buildings and Monuments 13, No. 3, 161-171. Sandrolini F. and Franzoni E. (2006). An operative protocol for reliable measurements of moisture in porous materials of ancient buildings. Building and Environment 41, 1372-1380. Sandrolini F., Franzoni E., Vio E. and Lonardoni S. (2005). Challenging transient flooding effects on dampness in brick masonry in Venice by a new technique: the narthex in St. Marco Basilica. Flooding and Environmental Challenges for Venice and its Lagoon: State of Knowledge. C. A. Fletcher, T. Spencer eds., Cambridge University Press, 181 - 188. CONTACTS [email protected] [email protected] [email protected] 146 Materials Science and Technology – Materials for Industrial Engineering INDUSTRIAL AND ADVANCED CERAMIC MATERIALS RESEARCH GROUP: Alberto Fregni, Giorgio Timellini KEYWORDS: innovative ceramic materials, functionalized ceramic surfaces, environment, ceramic industry The aim of the research activities is design and development of innovative ceramic materials, characterization and verification of performance characteristics, optimization of production processes, solving of environmental and process problems in the ceramic industry. In the field of traditional and advanced ceramic materials, research activity concerns mainly: • qualification and testing of the performance characteristics of traditional ceramic materials, according to operating conditions and target environment and application techniques; • optimization of production processes of traditional ceramic materials, experimenting with innovative technologies that improve the quality of the product; • environmental problems in the ceramics industry (pollution, energy consumption, waste disposal/recycling of products, etc.); • design of innovative construction materials with high thermal and acoustic performances; • functionalization of ceramic materials: high solar reflectance, photovoltaic, photocatalytic, antibacterial, antiwear surfaces; • study of shaping techniques to obtain innovative ceramics (bioceramics and piezoelectrics). Fig. 1. EM-EDS mapping of titania particles on ceramic substrate: dip coated sample (20x60mm) after firing. Fig. 2. 3D image of a screen printed Ag layer. 147 Research Projects and Activities 2015 MAIN PUBLICATIONS Bordignon F., Kaminski P.C. and Timellini G. (2012) Guidelines for the brazilian ceramic sector strategic development, based on a comparison with the Italian market. Cfi/Ber. DKG 89, 8-9. Timellini G., Nassetti G. and Fazio S. (2011) Energy saving and use of renewable energies in the building ceramic sector. XII International Conference & Exhibition of the European Ceramic Society, Stockholm (S), 19-23 June. Rambaldi E., Salomoni A., Timellini G. and Lindeman A. (2011) Thermal and mechanical performances of porous porcelain stoneware tiles. XII International Conference & Exhibition of the European Ceramic Society, Stockholm (S), 19-23 June. Timellini G. (2011) International standards on ceramic tiles, toward quality, sustainability, competitiveness. Invited Lecture at SERES ’11 – II International Ceramic, Glass, Porcelain Enamel, Glaze and Pigment Congress, Eskisehir (TR), 10-12 October. Timellini G. (2011) Process and product innovation for ceramics. Centro Ceramico and DICAM – University of Bologna The First China and Italy Bilateral Forum on Materials Science, Shanghai (CN) 21-23 November. Rambaldi E., Tucci A., Esposito L., Naldi D. and Timellini G. (2010). Nano-oxides to improve the surface properties of ceramic tiles. Boletin de la Sociedad Española de Cerámica y Vidrio, 49, 4, 253-258. Rastelli E., Jazayeri S.H., Salem A. and Timellini G. (2009). Dilatometric study of shrinkage during sintering process for porcelain stoneware body in presence of nepheline syenite. Journal of materials processing technology. 209, 1240-1246. Rastelli E., Salomoni A., Fregni A. and Stamenkovic I. (2008). Influence of calcium phosphate on rheological properties of the sanytaryware slip – Part 1. Advances in Applied Ceramics, 107, 2, 76-82. Esposito L., Rambaldi E., Tucci A., Bonvicini G., Albertazzi A. and Timellini G.. (2008). Chemical aging and microstructural changes of glazed ceramic tile surfaces. Cfi-Ber. DKG 85 (6), 64-67. Gombia M., Fantazzini P., Rambaldi E., Tucci A., Esposito L. and Timellini G. (2008). Water 1H NMR technique to analyze the porous structure of ceramics. Advanced Engineering Materials, 10 (3), 235-240. Breedveld L., Timellini G., Casoni G., Fregni A. and Busani G. (2007). Eco-efficiency of fabric filters in the Italian ceramic tile industry. Journal of Cleaner Production, 15, 86-93. Rambaldi E., Esposito L., Tucci A. and Timellini G. (2007). Recycling of polishing porcelain stoneware residues in ceramic tiles. Journal of the European Ceramic Society. 27, 3509-3515. Tucci A., Nanetti A., Malmusi L. and Timellini G. (2007) Ceramic surfaces with microbiological action for healthcare buildings. Cfi/Ber. DKG 84 (3), E47-E50. Rastelli E., Jazayeri S.H., Salem A. and Timellini G.. (2007). A kinetic study on the development of porosity in porcelain stoneware tile sintering. Boletin de la Sociedad Española de Cerámica y Vidrio. 46, 1, 1-6. RESEARCH PROJECTS Progetto RFO (EX 60%) E.F. 2009 – Comitato 09 – Ingegneria Industriale e dell’Informazione; Coordinatore del gruppo di ricerca Prof. Ing. Giorgio Timellini. CONTACTS [email protected] [email protected] 148 Materials Science and Technology – Materials for Industrial Engineering POLYMERS AND ADVANCED COMPOSITE MATERIALS RESEARCH GROUP: Maria Chiara Bignozzi, Stefania Manzi, Antonio Motori, Andrea Saccani KEYWORDS: particle and fibre reinforced composites, polymer and ceramic matrices Research activity is mainly focused on poly-meric materials, micro or nano-sized composite materials, fiber reinforced composites with ceramic or polymeric matrix, toughened materials. As reinforcement natural fibers as straw and hemp are also investigated. Mechanical, microstructural and thermal charac-terization of traditional and innovative polymer-ic materials is performed. Special focus is addressed to investigate the relationship occurring between microstructure and macroscopical properties of the polymer. Laboratory techniques allow to investigate the cristallinity, the orientation and distribution as well as the relative amount of the different phases. An important aspect is related to the study of polymer degradation in specific and tailored environmental conditions (oxygen, temperature, UV radiation, relative humidity, body fluids). The life-time of the polymer is evaluated through the choice of suitable diagnostic properties. The effect of organic-inorganic coatings on the durability of substrates is also studied. Particular interest is addressed to polymers used as high voltage electrical insulating materials, for automotive, biomedical and civil engineering applications. As to what concerns composite materials, we investigate: the toughening of ceramic or polymer matrix respectively by fibers and by a second elastomeric phase or graphene platelets, the use of natural fibers (hemp or straw) in hybrid organic-inorganic matrixes. Fig. 1. Fibre reinforced composite material. Fig. 2. Toughened ceramic material. 149 Research Projects and Activities 2015 MAIN PUBLICATIONS Motori A., Manzi S., Montecchi M. and Canti M. (2012). A preliminary study of physical and mechanical properties of sustainable hemp fibers based composite materials for building insulated walls. ECCM15 - 15th European Conference On Composite Materials. Venice - Italy. June 24-28, 2012, 1-7. Manzi S., Canti M., Montecchi M. and Motori A. (2012). Caratterizzazione preliminare di pannelli contenenti fibre naturali per l’edilizia ecosostenibile. Atti XI Convegno Nazionale AIMAT. XI Convegno Nazionale AIMAT. Gaeta (LT). 16-19 settembre 2012, 331-334. Saccani A., Toselli M. and Pilati F. (2011). Improvement of the thermo-oxidative stability of LDPE films by organic-inorganic hybrid coatings Poly-mer Degradation and Stability 96, 212-219. Fabiani D., Montanari G.C., Cavallini A., Sac-cani A. and Toselli M. (2011). Nanostructured-coated XLPE showing improved electrical properties: partial discharge resistance and space charge ac-cumulation Proceedings of ISEIM, September 2011, Kyoto, Japan, paper A5, 14-18. Sandrolini F., Manzi S. and Natali A. (2010). Cement-polymer prepreg carbon fabrics in concrete strengthening. Restoration of Buildings and Monuments 16, No. 4/5, 377-386. Sandrolini F. and Manzi S. (2010). Self-compacting high performance cement/polymer composite materials. Restoration of Buildings and Monuments 16, No. 4/5, 283-290. Sandrolini F. and Manzi S. (2009). High performance self-compacting mortar with multifunctional filler. Special Topics on Materials Science and Technology – The Italian Panorama. Brill, Leiden, Boston, 345-350. Prete F., Esposito L., Tucci A. and Motori A. (2008). Materiali ceramici nanostrutturati: stato dell’arte. C+CA (Ceramurgia+Ceramica Acta), XXXVIII, 1, 33-42. Montanari G.C., Fabiani D., Ciani F., Motori A., Paajanen M., Gerhard-Mulhaupt R. and Wagener W. (2007). Charging Properties and time-temperature stability of innovative polymeric cellular ferroelectrets. IEEE Trans. on Dielectr. and Electr. Insul. 14, No. 1, 238-248. Motori A., Patuelli F., Saccani A., Cannillo V., Manfredini T. and Sola A. (2007). Technological properties of celsian-reinforced glass matrix composites. Ceramics International. 33, No. 8, 15971601. Erani P., Cristofolini L., Baleani M., Bignozzi M.C., Cotifava M., Ihaddedene N., Tomei F. and Viceconti M. (2007). Quantitative crack surface morphology of bone cements in relation to propagation rate. Fatigue and fracture of engineering materials and structures 30, 783-795. Motori A., Montanari G.C., Saccani A. and Patuelli F. (2007). Electrical conductivity and polarization processes in nanocomposites based on isotactic polypropylene and modified synthetic clay. J. Polym. Sci. Part B: Polym. Phys. 45, 705-713. Motori A., Patuelli F., Saccani A., Andreola F., Bondioli F., Siligardi C. and Ferrari A.M. (2006). Electrical behaviour of monoclinic celsian derived from cation-exchanged commercial zeolites. J. Mater. Sci. 41, 4327-4333. Sandrolini F. and Manzi S. (2006). Particulate composite materials with modulated mechanical properties. Proceedings of International Symposium Polimers in Concrete – ISPIC 2006, 2-4 Aprile 2006, Guimaraes, Portugal, J. Barroso de Aguiar, S. Jalali, A. Camoes, R. Miguel Ferreira Eds., Oficinas Gràficas de Barbosa &Xavier, Lda, Braga, Portugal. 61-68. Saccani A., Sandrolini F., Andreola F., Lancellotti I., Barbieri L. and Corradi A. (2005). Influence of the pozzolanic fraction obtained from vitrified bottom ashes from MSWI on the properties of cementitiuos composite. Materials and Structures 38, No. 277, 367-371. Montanari G.C., Motori A., Saccani A., Di Lorenzo del Casale M., Schifani R., Testa L., Guastavino F. and Camino G. (2005). Dielectric spectroscopy analysis of EVA-silicate nanocomposite insulating materials. Int. IEEE-ISEIM Conf., Kitakyushu, Japan, 2005. Conf. Proc., 247-250. CONTACTS [email protected] [email protected] [email protected] [email protected] 150 Materials Science and Technology – Materials for Industrial Engineering CORROSION AND PROTECTION OF METALS RESEARCH GROUP: Maria Chiara Bignozzi, Stefania Manzi, Antonio Motori KEYWORDS: corrosion, accelerating ageing, electrochemical measurements, surface characterization The aim of the research is the development of guidelines for the prevention and protection from corrosion of ferrous and not-ferrous alloys exposed to different environments. Research projects concern the study of corrosion mecha-nisms and protection of metal alloys used in the industrial sector (i.e. “Corrosion of 316L in Ul-trahigh-Purity Water for Pharmaceutical Indus-tries” and “Corrosion of different steels in Chemical Plants”), in Cultural Heritage (i.e. “Corrosion behaviour and protection of outdoor bronzes”) and in architecture/building construc-tion (i.e. “Atmospheric corrosion of COR-TEN steel with different surface finish” and “Corrosion of steel bar reinforcement in geopolymer or ce-ment matrix”). In particular, the evaluation of the corrosion behaviour and the protective effi-ciency of coatings is performed through acceler-ated ageing, surface analyses, thermal analyses, electrochemical measurements. Research activi-ties are carried out in collaboration with re-search groups of the Interdepartmental Center for Industrial Research of the University of Bo-logna for Advanced Applications in Mechanical Engineering and Materials Technology CIRI-MAM (Corrosion Unit: Dr. Cristina Chiavari), of the Industrial Engineering (Dr. Carla Martini) and Industrial Chemistry «Toso Montanari» (Dr. Elena Bernardi) Departments of the University of Bologna, of the Corrosion Center “Daccò”, University of Ferrara (Prof. Cecilia Monticelli). Moreover, research projects supported by na-tional and international companies are devel-oped in order to solve technological problems due to unexpected corrosion phenomena. Fig. 1. Electrochemical cell with thermostat. Fig. 2 Polarisation curves. Fig. 3 Corten structure in Cemetery of Certosa (Bologna, Italy). 151 Research Projects and Activities 2015 MAIN PUBLICATIONS Chiavari C., Bernardi E., Cauzzi D., Volta S., Bignozzi M.C., Lenza B., Montalbani S., Rob-biola L. and Martini C. (2013). Influence of natural patinas of outdoor quaternary bronzes on conservation treatment. METAL 2013: Proceedings of the Interim Meeting of the ICOMCC Metal Working Group. Edimburgh, United Kingdom, 16-20/9/2013. Chiavari C., Bernardi E., Lenza B., Martini C., Vassura I., Motori A., Balbo A. and Monticelli C. (2013). Organosilane coatings applied on bronze: natural exposure and exposure to temperature/UV cy-cles. Proceedings of Eurocorr 2013 (EFC Event n.343), 01-5/09/2013, Estoril, Portugal (EFC, London, UK, CD-ROM). Mattei A., Chiavari C., Bernardi E., Martini C., Gandolfi N., Sessa S. and Bignozzi M.C. (2013). Stainless steel corrosion in Ultrahigh-Purity Water: Surface analyses and metal release. Proceedings of Eurocorr 2013 (EFC Event n.343), 01-5/09/2013, Estoril, Portugal (EFC, London, UK, CD-ROM). Chiavari C., Balbo A., Bernardi E., Martini C., Bignozzi M.C., Abbottoni M. and Monticelli C. (2013). Protective silane treatment for patinated bronze exposed to simulated natural environments. Materials Chemistry and Physics 141, No. 1, 502-511. Chiavari C., Bernardi E., Martini C., Vassura I., Motori A. and Bignozzi M.C. (2012). CORTEN steel: atmospheric corrosion behavior by accelerated ageing”, Proceedings of Eurocorr 2012 (EFC Event n.330), 09-13/09/2012, Istanbul, Turkey (EFC, London, UK, CD-ROM), 1-14. Chiavari C., Bernardi E., Balbo A., Monticelli C., Passarini F., Bignozzi M.C. and Martini C. (2012). Influence of nanoparticles on the inhibiting efficiency of organosilane coatings on bronze. Part 2: metal release in accelerated ageing tests. Proceedings of Eurocorr 2012 (EFC Event n.330), 09-13/09/2012, Istanbul, Turkey (EFC, London, UK, CD-ROM), 1-11. Chiavari C., Bernardi E., Martini C., Passarini F., Motori A. and Bignozzi M.C (2012). Atmospheric corrosion of Cor-Ten steel with different surface finish: Accelerated ageing and metal release. Materials Chemistry and Physics 136, 477-486. Bignozzi M.C., Manzi S. and Tattini E. (2012). Corrosion behaviour of steel reinforced mortars based on alkali activated materials. Proceedings of Eurocorr 2012 (EFC Event n.330), CD-ROM. Istanbul, Turkey, 09-13/09/2012, LONDON: European Federation of Corrosion (EFC), 1-9. Bignozzi M.C., Manzi S., Natali A., Tattini E. and Van Riessen A. (2012). Comportamento a corrosione di barre d’armatura in materiali a base di scarti industriali chimicamente attivati. Atti XI Convegno Nazionale AIMAT. Gaeta (LT). 16-19 settembre 2012, 45-48. Bignozzi M.C. and Bonduà S. (2011). Alternative blended cement with ceramic residues: Corrosion resi-stance. Cement and Concrete Research 41, 947-954. Bignozzi M.C. (2011). Sustainable inorganic binders with corrosion resistance properties. Proceedings of European Coatings Conference “Construction Chemicals” – Berlin 13-14th December 2011, Edited by Vincentz Network, 65-75. CONTACTS [email protected] 152 Materials Science and Technology – Durability and Protection of Materials ELECTRICAL BEHAVIOUR, AGING AND RELIABILITY OF POLYMER-BASED INSULATING MATERIALS RESEARCH GROUP: Antonio Motori, Andrea Saccani KEYWORDS: polymeric insulating materials, nanocomposites, aging, dielectric losses The investigation of the electrical properties studies allow to make correlations with the physical, mechanical, structural and microstructural characteristics of materials. In the laboratory, the electrical bulk and surface conductivity are investigated in the temperature range from -80 to 250 °C, as well as the permittivity and the loss factor from10-2 to 106 Hz. Main research topics are insulating materials and polymeric systems, including nanacomposites. The more relevant aims are: 1. the investigation of the aging mechanisms of insulating materials and the evaluation of the time behaviour and reliability through accelerated test methods that simulate the on-service conditions; 2. the investigation of the conduction mechanisms and of the dielectric relaxation processes in the bulk and at the interfaces. 3. the deposition of organic-inorganic coatings with peculiar properties (antistatic, charge injection barrier). Some of the indicated activities are carried out in collaboration with research groups of the University in particular with the Department of Electrical Engineering “G. Marconi” of the University of Bologna. Fig. 1. Laboratory of electrical measurements. Fig. 2. Cell for accelerated aging. 153 Research Projects and Activities 2015 MAIN PUBLICATIONS Mancinelli P., Fabiani D., Saccani A., Toselli M., Heid T. and Frechette M. (2013). Preparation and dielectrical behaviour of epoxy resin containing graphene oxide. Proceedings of the IEEEICSD June 2013, Bologna, 30 June 2013. Saccani A., Toselli M. and Pilati F. (2011). Improvement of the thermo-oxidative stability of LDPE films by organic-inorganic hybrid coatings. Polymer Degradation and Stability. 96, 212-219. Fabiani D., Montanari G.C., Cavallini A., Saccani A. and Toselli M. (2011). Nanostructured-coated XLPE showing improved electrical properties: partial discharge resistance and space charge accumulation Proceedings of ISEIM, September 2011, Kyoto, Japan, paper A5, 14-18. Marini M., Pilati F., Saccani A. and. Toselli M. (2008). Thermo-oxidative stability of electrically insulating polymeric materials coated by organic-inorganic hybrid nanocomposite. Polymer Degradation and Stability 93, 1170-1175. Saccani A., Patuelli F., Motori A. and Montanari G.C. (2007). Electrical conductivity and polarization processes in nanocomposites based on isotactic poly(propylene) and modified synthetic clay. Journal of Polymer Science: part B Polymer Physics 45, 705-713. Montanari G.C., Fabiani D., Ciani F., Motori A., Paajanen M., Gerhard-Mulhaupt R and Wagener W. (2007). Charging Properties and time-temperature stability of innovative polymeric cellular ferroelectrets. IEEE Trans. on Dielectr. and Electr. Insul. 14, No. 1, 238-248. Motori A., Saccani A., Patuelli F. and Montanari G.C. (2007). Thermal endurance evaluation of isotactic poly(propylene) based nanocomposites by short-term analytical methods. IEEE: Trans. Diel. Electr. Ins. 14, No. 3, 689-695. Saccani A, Toselli M., Messori M., Fabbri P. and Pilati F. (2006). Electrical behavior of PET films coated with Nanostructured Organic-Inorganic Hybrids. Journal of Applied Polymer Science 102, No.5, 4870-4877. Montanari G.C., Palmieri F., Testa L., Motori A., Saccani A. and Patuelli F. (2006). Polarization processes of nanocomposite silicate-EVA and PP materials. IEEE Trans FM 126, No. 11, 1-7. Montanari G.C., Motori A., Saccani A., Lorenzo del Casale M., Schifani R., Testa L., Guastavino F. and Camino G. (2005). Dielectric spectroscopy analysis of EVA-silicate nanocomposite insulating materials. Proc.of the IEEE-IEEJ ISEIM, Kytakyushu, Japan, June 5-9th 2005, 247-250 Saccani A., Motori A. and Montanari G.C. (2005). Short-term thermal endurance evaluation of thermoplastic polyesters by isothermal and non-isothermal thermogravimetric analysis. Journal of Applied Polymer Science 98, No. 3, 968-973. Saccani A., Motori A., Patuelli F., Montanari G.C. and Mulhaupt R. (2005). Improving thermal endurance properties of polypropylene by nanostructuration. IEEE Int. Conference on Conduction and Breakdown in Solid Dielectrics, Nashville, October 16-19th 2005, Paper 2C-13, 195-198. CONTACTS [email protected] [email protected] 154 Structures Structures – Structural Reliability and Probabilistic Methods DEFINITION OF INPUT GROUND-MOTIONS FOR NONLINEAR DYNAMIC ANALYSIS RESEARCH GROUP: Nicola Buratti, Giada Gasparini, Marco Savoia, Stefano Silvestri, Tomaso Trombetti KEYWORDS: earthquake engineering, accelerograms, intensity measures, nonlinear dynamic analysis, seismic hazard In the framework of performance based earthquake engineering, the assessment of the seismic structural demands is extremely important. This latter, is usually defined through a sequence of nonlinear dynamic analyses that require to define some sets of accelerograms as input. The choice of the accelerograms is crucial for the correct prediction of the structural response. The research carried out covered different aspects of this issue. The research group developed a new probabilistic seismic hazard analysis (PSHA) procedure that leads to the definition of the probability function (PDF and CDF) of the various intensities of the ground-motion. Using this results the group developed a new vector ground-motion intensity measure based on the combination of PGA and PGV. Finally the research group studied the features (in terms of spectral acceleration) that a set of accelerograms must present in order to be associated to a given probability of occurrence, and hence proposed a new procedure for defining sets of design ground motions. The research group also developed a procedure for simulating non-stationary stochastic accelerograms, using ground-motion prediction equations to obtain realistic estimates of some important ground motion intensity measures: duration, Arias intensity, and frequency content. The so generated accelerograms were used as input for nonlinear dynamic analyses of various RC structures and gave results that compared very well with those obtained from recorded accelerograms. Finally, as a results of a collaboration with Imperial College, London, we developed a new criterion to select and scale recorded accelerograms starting from the definition of a scenario in terms of magnitude and source-to-site distance. The procedure is based on the definition of a target response spectra, using the data provided by spectral-acceleration attenuation relationships. This method has given good results both in terms of estimates of the mean structural response and in terms of its distribution. 157 Fig. 1. CDF curve of the spectral acceleration for Bologna. Fig. 2. Selection of recorded accelerograms. Fig. 3. Error given by different ground motion selection procedures in terms of maximum drift. Research Projects and Activities 2015 MAIN PUBLICATIONS Buratti N. (2012) A comparison of the performances of various ground–motion intensity measures. 15th World Conference on Earthquake Engineering. Lisbon, 24-28 September. Ligabue V., Buratti N. (2012) Analysis of codebased ground-motion selection procedures in terms of inelastic interstorey drift demands. 15th World Conference on Earthquake Engineering. Lisbon, 24-28 September. Buratti N., Stafford P.J., Bommer J.J. (2011) Earthquake accelerogram selection and scaling procedures for estimating the distribution of structural response. Journal of Structural engineering 137, 345-157. Buratti N., Savoia M. (2010). Artificial Nonstationary Accelerograms with Natural Variability. Proceedings of the Fourteenth European Conference on Earthquake Engineering. Ohrid, Republic of Macedonia. 30 Agosto - 3 September. Buratti N., Savoia M. (2010). Non-stationary Artificial Accelerograms for Nonlinear Analysis of R.C. Frame Structures. Proceedings of the Fourteenth European Conference on Earthquake Engineering. Ohrid, Republic of Macedonia. 30 Agosto - 3 September. Buratti N. (2009). Generation of artificial nonstationary accelerograms with natural variability. XIII Convegno ANIDIS 2009- L’Ingegneria Sismica in Italia. Bologna. 28 June-2 July. Buratti N.,Savoia M. (2009). Using non-stationary artificial accelerograms for estimating maximum drift demands on R.C. frame structures. XIII Convegno ANIDIS 2009 - L’Ingegneria Sismica in Italia. Bologna. 28 June-2 July. Trombetti T., Ceccoli C., Silvestri S., Gasparini G. (2003). Probability Density Function of the Peak Ground Acceleration due to the Seismic Action. Proceedings of the 9th International Conference on Applications of Statistics and Probability in Civil Engineering - ICASP 9. San Francisco. California, 6-9 July. Trombetti T., Gasparini G., Silvestri S. (2004) Statistical characterisation of the seismic action (PGA and PGV) for Performance Based Seismic Design, Proceedings of the 13th World Conference on Earthquake Engineering. Vancouver, B.C., Canada, 1-6 August. Trombetti T., Silvestri S., Gasparini G., Malavolta D. (2006), “Identification of efficient groups of design earthquake inputs”, Proceedings of the First European Conference on Earthquake Engineering and Seismology. Geneva, Switzerland, 3-8 September. Trombetti T., Silvestri S., Malavolta D., Gasparini G. (2007). A methodology for determination of efficient earthquake bins for Performance Based Seismic Design. Proceedings of the “Tenth International Conference on Applications of Statistics and Probability in Civil Engineering - ICASP10. Tokyo, Japan, 31 July – 3 August. Trombetti T., Silvestri S., Gasparini G., Righi M., Ceccoli C. (2008). Correlations between the displacement response spectra and the parameters characterising the magnitude of the ground motion. Proceedings of the 14th World Conference on Earthquake Engineering. Beijing, China, 12-17 October. Silvestri S., Trombetti T., Gasparini G. (2009) A Procedure For Probabilistic Seismic Hazard Analysis Which Allows To Account For Poisson Or Non-Poissonian Models. Proceedings of 10th International Conference on Structural Safety and Reliability. Osaka, Japan, 13-17 September. Trombetti T., Silvestri S., Gasparini G. (2009). The Role Of Epsilon For The Identification Of Groups Of Earthquake Inputs Of Given Hazard. Proceedings of 10th International Conference on Structural Safety and Reliability. Osaka, Japan, 13-17 September. CONTACTS [email protected] [email protected] 158 Structures – Structural Reliability and Probabilistic Methods ADVANCED PROCEDURES FOR THE ASSESSMENT OF SEISMIC RELIABILITY RESEARCH GROUP: Nicola Buratti, Pier Paolo Diotallevi, Barbara Ferracuti, Luca Landi, Marco Savoia KEYWORDS: seismic risk, seismic fragility, reliability, probabilistic methods, earthquake engineering, SAC/ FEMA In the framework of Performance-Based Earthquake Engineering the actual research trend is to develop rigorous probabilistic approaches. These latter involve complex nonlinear problems with many random and non-random variables. For this reason many practical reliability methods have been recently developed for assessing seismic safety. The main purpose of this research concerns two of these approaches: the “2000 SAC/FEMA Method” and response-surface based methods. As for the 2000 SAC/FEMA Methods, used for the reliability analysis of different R.C. frames, also equipped with dampers, on a first stage, probabilistic hazard analyses were performed for several sites in Italy, and then the Probabilistic Seismic Demand was defined through Incremental Dynamic Analyses (IDA), considering both flexure and shear failure modes. Particular care was put into the study of the sensitivity of the results to the ground-motion intensity measure used. This issue was further investigated during a collaboration with the “Blume Earthquake Engineering Center” at Stanford University, that lead to the proposal to a new intensity measure. The second procedure investigated is based on the response-surfaces with random factors. These statistical models are used for approximating the structural capacity, in terms of spectral acceleration, through a polynomial function of the variables considered. The coefficients of the polynomial are fitted using data gathered from a set of non-linear incremental dynamic analysis. The number of simulations required increases as the number of variables increases, therefore in order to keep the model computationally efficient the aleatory variables involved can be split in two groups: one in taken into account explicitly in the polynomial while the second is considered only implicitly, by dividing the numerical simulations in blocks and introducing random factors in the polynomial model. Recently the research group has also started to investigate the seismic vulnerability of cylindrical tanks containing liquids. Fig. 1. IDA curves calibrated for a given seismic intensity measure. Fig. 2. Fragility curves obtained from response surface models. 159 Fig. 3. Fragility curves for cylindrical tanks. Research Projects and Activities 2015 MAIN PUBLICATIONS Buratti N., Tavano M. (2013). Dynamic buckling and seismic fragility of anchored steel tanks by the added mass method. Earthquake Engineering and Structural Dynamics. DOI: 10.1002/eqe.2326. Bianchini M., Diotallevi P.P., Landi L. (2007). Full probabilistic approach for seismic reliability assessment of RC frames structures. X International Conference on Applications of Statistics and Probability in Civil Engineering (ICASP). Tokyo, Japan, July 31-August 3. Landi L., Fabbri O. and Diotallevi PP (2013). Simplified method for the assessment of the nonlinear seismic response of structures equipped with viscous dampers. Proceedings of the 11th International Conference on Structural Safety & Reliability, Columbia University, NY, USA. Buratti N., Ferracuti B., Savoia M.. (2007). Response surface with random factors for seismic fragility of RC frames. Proceedings of ICASP 10. 10th International conference on applications of statistics and probability in civil engineering. Tokyo, JP. July 31- August 3. Buratti N., Ferracuti B., Savoia M., Antonioni G., Cozzani V. (2012). A Fuzzy-Sets Based Approach for Modelling Uncertainties in Quantitative Risk Assessment of Industrial Plants Under Seismic Actions. Chemical Engineering Transactions. Vol. 26, Part 1, 105-110. Buratti N., Ferracuti B., Savoia M.. (2007). Seismic fragility of RC frame structures using response surfaces with random block effects. Proceedings of the XVIII Convegno Associazione Italiana di Meccanica Teorica ed Applicata ( AIMETA). Brescia. 11-14 September. Bianchini M., Diotallevi P.P., Landi L (2010). Seismic reliability assessment of RC structures based on different ground motion prediction models. XIV European Conference on Earthquake Engineering (ECEE). Ohrid, Republic of Macedonia, August 30-September 3. Buratti N., Ferracuti B., Savoia M. (2006). Seismic fragility of existing RC structures by Response Surface Method. First European Conference on Earthquake Engineering and Seismology (ECEES). Geneva, Switzerland, 3-8 September. Buratti N., Ferracuti B., Savoia M. (2010). Response Surface with random factors for seismic fragility of reinforced concrete frames. Structural Safety. vol. 32, pp. 42 - 51 ISSN: 0167-4730. Buratti N., Ferracuti B., Savoia M. (2006). Seismic Risk Assessment of R/C Structures Through Response Surface Method. Proceedings of III European Conference on Computational Mechanics. Lisbon, Portugal. 5-9 June. Bianchini M., Diotallevi P.P., Landi L. (2009). Influenza della legge di attenuazione sull’analisi probabilistica della risposta sismica di strutture in c.a. XVIII Convegno dell’Associazione Nazionale Italiana di Ingegneria Sismica (ANIDIS). Bologna, Italy, June 28-July 2. Bianchini M., Diotallevi P.P., Baker J.W. (2009). Prediction of inelastic structural response using an average of spectral accelerations. X International Conference on Structural Safety and Reliability (ICOSSAR). Osaka, Japan, September 13-17. Bianchini M., Diotallevi P.P., Landi L.. (2008). Influence of earthquake intensity measure on the probabilistic evaluation of RC buildings. XVI World Conference on Earthquake Engineering (WCEE). Beijing, China, October 12-17. Buratti N., Ferracuti B., Savoia M. (2006). Reliability of r.c. structures against seismic action: response surface approach. GIMC 2006: XVI Convegno italiano di meccanica computazionale. Bologna, Italy. 26-28 June. Diotallevi P.P., Landi L., Bianchini M. (2006). Analisi di affidabilità per la valutazione probabilistica di strutture in c.a. in zona sismica. Mensile di Tecnica e Informazione dell’Associazione Ingegneri, Architetti e Costruttori della Provincia di Bologna (INARCOS), Vol. 672, pp.535-542. CONTACTS [email protected] [email protected] 160 Structures – Structural Reliability and Probabilistic Methods PROBABILISTIC APPROACHES IN STRUCTURAL ENGINEERING RESEARCH GROUP: Stefano de Miranda, Cristina Gentilini, Lucio Nobile, Francesco Ubertini, Erasmo Viola KEYWORDS: probabilistic analysis, identification techniques, Bayesian approach, uncertainty, random fields This research topic encompasses the development of numerical simulations for the probabilistic analysis of structures and components. In particular, the research focuses on: (1) probabilistic analysis of structures with uncertain damage. Crack depth and location are modeled as random variables in order to take into account the unavoidable uncertainty that always affects damaged structures. A simple and accurate method for the probabilistic characterization of the linear elastic response of cracked structures with uncertain damage is employed. According to this method, the uncertainties are transformed into superimposed deformations depending on the distribution of internal forces and an iterative procedure is established to solve the resultant equations; (2) dynamic identification of elastic constants of thick laminated composite plates. The plate response is modeled by finite elements based on Reddy’s third-order theory. The elastic constants are estimated within a Bayesian framework, using two estimators available in the literature. The estimators differ in the way they account for a priori information on the elastic constants to be identified. A modified strategy is proposed that overcomes the drawbacks of the literature estimators; (3) identification of damaged elements by means of Genetic Algorithms. The objective is to evaluate the mechanical characteristics of constituent bars in existing truss structures. In particular, the proposed procedure locates bars with reduced mechanical properties and quantifies the loss of stiffness. The procedure is based on genetic algorithms to overcome lack of information; Fig. 1. Cracked element – displacement distribution. Fig. 2. Cracked frame structure with uncertain damage. Fig. 3. Thick composite laminated plate. (4) numerical procedures for random field simulation in mechanics. 161 Research Projects and Activities 2015 MAIN PUBLICATIONS L. Nobile, C. Gentilini. (2009). Probabilistic analysis of cracked frame structures taking into account the crack trajectory. Procedia Engineering. Vol. 1, pp. 83-86. L. Nobile, C. Gentilini. (2008). Three dimensional frame structures with edge-cracks of uncertain depth and location. Recent Patents on Mechanical Engineering. Vol. 1, pp. 12-21. C. Gentilini, L. Nobile. (2007). Probabilistic analysis of three-dimensional beams with uncertain damage. Key Engineering Materials. Vols. 348-349, pp. 97-100. P. Bocchini, G. Deodatis, E. Viola. (2008). Simulation of multi-dimensional, strongly non-Gaussian random fields in mechanics. Proceedings Meccanica Stocastica. Cefalù, Italy. June 11-12, 2008. structures. Structural Durability and Health Monitoring. Vol. 2, No. 2, pp. 109–122. C. Gentilini, F. Ubertini, E. Viola. (2005). Uncertain edge-cracked frame structures. Proceedings IV International Conference on Fracture and Damage Mechanics - FDM (eds. M.H. Aliabadi, F.-G. Buchholz, J. Alfaiate, J. Planas, B. Abersek, S.-i. Nishida), pp. 371-376. Mallorca (Spain). July 12-14, 2005. P. Bocchini, F. Ubertini, E. Viola. (2005). An iterative fitting method based on a three-parameter distribution. Proceedings IX International Conference on Structural Safety and Reliability – ICOSSAR. Rome, Italy. June 19-22, 2005. C. Gentilini, F. Ubertini, E. Viola. (2005). Probabilistic analysis of linear elastic cracked structures with uncertain damage. Probabilistic Engineering Mechanics. Vol. 20, pp. 307-323. F. Daghia, S. de Miranda, F. Ubertini, E. Viola. (2007). Estimation of elastic constants of thick laminated plates within a Bayesian framework. Composite Structures. Vol. 80, pp. 461-473. C. Gentilini, E. Viola, F. Ubertini. (2003). Probabilistic characterization of linear truss structures with cracked members. Key Engineering Materials. Vols. 251-252, pp. 141-146. F. Daghia, S. de Miranda, F. Ubertini, E. Viola. (2007). On the Bayesian identification of the elastic parameters of laminated structures. Proceedings International Symposium on Recent Advances in Mechanics, Dynamical Systems and Probability Theory – MDP. Palermo, Italy. June 3–6, 2007. RESEARCH PROJECTS E. Viola, P. Bocchini. (2007). Identification of damaged bars in three-dimensional redundant truss structures by means of genetic algorithms. Key Engineering Materials. Vols. 348-349, pp. 229-232. P. Bocchini, C. Gentilini, F. Ubertini, E. Viola. (2006). Advanced analysis of uncertain cracked Dynamic identification of elastic constants in fiber-reinforced plates by means of Bayesian methods and optimization techniques, PRIN2003 – Bologna Research Unit. Coordinator: Prof. E. Viola. Dynamic identification of elastic constants in plates of orthotropic material, PRIN2000 – Bologna Research Unit. Coordinator: Prof. E. Viola. CONTACTS [email protected] [email protected] 162 Structures – Computational Structural Mechanics MULTIPHYSICS AND COUPLED PROBLEMS RESEARCH GROUP: Giovanni Castellazzi, Stefano de Miranda, Luisa Molari, Francesco Ubertini, Erasmo Viola KEYWORDS: fluid-structure interaction, coupled deformation-diffusion, phase transitions, salt attack, piezoelectricity This research line encompasses the development of ad-hoc numerical formulations for the analysis of several coupled problems. In particular, tools are developed for: - CFD simulation of high Reynolds number flows around stationary and moving bluff bodies aimed at predicting aerodynamic and aeroelastic forces. The flutter critical speed is evaluated before wind tunnel tests allowing optimal deck design; Fig. 1. Unsteady RANS simulation around Gibraltar bridge deck section: vorticity contours. - simulation of phase transition in metals provoked by heat treatments, largely employed in the industrial applications, which involves a microstructural transformation; - simulation of fluid-structure interaction problems by coupling the lattice Boltzmann fluid solver and the finite element solid solver. A proper coupling strategy has been developed. A wide range of applications has been investigated, spanning mechanics, industry/defence, biology and biomimetics; Fig. 2. Simulation of diffusive and displacive phase transitions. - simulation of the mechanically driven mass diffusion in deformable solids, aimed at predicting the so-called hydrogen embrittlement, which may occur in metals containing an initially uniform dilute concentration of hydrogen; - simulation of the masonry degradation due to the salt attack. - modelling of crack growth in piezoelectric materials. 163 Fig. 3. Simulation of the take-off of two butterflies: velocity field. Research Projects and Activities 2015 MAIN PUBLICATIONS Brusiani F., de Miranda S., Patruno L., Ubertini F., Vaona, P. (2013). On the evaluation of bridge deck flutter derivatives using RANS turbulence models. Journal of Wind Engineering and Industrial Aerodynamics 119, 39-47. Brusiani F., Cazzoli G., de Miranda S., Ubertini F., Vaona P. (2011). Application of the k-ω turbulence model to assess the flutter derivatives of a long span bridge. WIT Transactions on the Built Environment 115, 231-242. roscale phase-field model for shape memory alloys with non-isothermal effects: Influence of strain rate and environmental conditions on the mechanical response. Acta Materialia 60, 179-191. Maraldi M., Molari L., Grandi D. (2012) A unified thermodynamic framework for the modelling of diffusive and displacive phase transitions. International Journal of Engineering Science 50, 31-45. Maraldi M., Molari L., Molari P.G. (2012). Towards modelling diffusive and displacive phase transitions. Metallurgia Italiana 104, 29-33. De Rosis A., Falcucci G., Ubertini S., Ubertini F., Succi, S. (2013). Lattice Boltzmann analysis of fluid-structure interaction with moving boundaries. Communications in Computational Physics 13, 823-834. Maraldi M., Wells G.N., Molari L. (2011) Phase field model for coupled displacive and diffusive microstructural processes under thermal loading. Journal of the Mechanics and Physics of Solids 59, 1596-1612. Castellazzi G., Colla C., de Miranda S., Formica G., Gabrielli E., Molari L., Ubertini, F. (2013). A coupled multiphase model for hygrothermal analysis of masonry structures and prediction of stress induced by salt crystallization. Construction and Building Materials 41, 717-731. Auricchio F., Bonetti E., Scalet G., Ubertini F. (2012). Refined shape memory alloys model taking into account martensite reorientation. ECCOMAS 2012 - European Congress on Computational Methods in Applied Sciences and Engineering, e-Book Full Papers, 3349-3362. Colla C., Baldracchi P., Troi A., Ubertini F., Carli R. (2012). Simulation and test procedures to correlate structural damage with moisture and salts migration in masonry. RILEM Bookseries 6, 1157-1163. Daghia F., Inman D.J., Ubertini F., Viola E. (2010). Active shape change of an SMA hybrid composite plate. Smart Structures and Systems 6, 91-100. de Miranda S., Garikipati K., Molari L., Ubertini F. (2009). A simple solution strategy for coupled piezo-diffusion in elastic solids. Computational Mechanics 44, 191-203. de Miranda S., Molari L., Ubertini F. (2009). On analytical and numerical modeling of mechanically driven mass diffusion in elastic solids. Part B –International Journal of Advances in Mechanics and Applications of Industrial Materials 1, 51–63. Maraldi M., Molari L., Grandi D.(2012). A non-isothermal phase-field model for shape memory alloys: Numerical simulations of superelasticity and shape memory effect under stress-controlled conditions. Journal of Intelligent Material Systems and Structures 23, 1083-1092. Grandi D., Maraldi M., Molari L. (2012). A mac- Viola E., Belmonte C., Viola G. (2009). A non-conventional approach for crack problems in piezoelectric media under electromechanical loading. International Journal of Fracture 157, 175-192. Viola E., Boldrini C., Tornabene F. (2008). Non-singular term effect on the Fracture Quantities of a Crack in a Piezoelectric Medium. Engineering Fracture Mechanics 75, 4542-4567. RESEARCH PROJECTS Mathematical models for phase transitions of complex systems. Progetto Strategico d’Ateneo. Coordinator: Prof. M. Fabrizio. CONTACTS [email protected] [email protected] 164 Structures – Computational Structural Mechanics NUMERICAL METHODS FOR STRUCTURAL ANALYSIS RESEARCH GROUP: Giovanni Castellazzi, Stefano de Miranda, Elena Ferretti, Cristina Gentilini, Alessandro Marzani, Luisa Molari, Lucio Nobile, Francesco Tornabene, Francesco Ubertini, Erasmo Viola KEYWORDS: finite element method, time integration methods, structural dynamics, meshless method, error estimation This research line encompasses the development and application of new and effective numerical methods and computational techniques for the solution of structural engineering problems. The current research activities address a wide range of structural issues, including: • finite element formulations for arches, plates and shells, • stress recovery techniques in finite element analysis, • a posteriori error estimation in finite element analysis, • time integration methods for transient analyses, • finite element approaches for structural dynamics, • discontinuous Galerkin methods, • flexible multi-body systems, • finite element formulations for the dynamic analysis of damaged structures, • meshless methods for the analysis of vibrations of spherical and parabolic shells, • nonconservative stability problems, • finite element and boundary element formulations for modeling bulk, guided and leaky guided waves in solids, • cell method formulations for crack paths analysis in brittle materials, • special finite elements for stress concentration problems, • image-based finite element modelling. Fig. 1. RCP stress recovery and adaptive mesh refinement. Fig. 2. From magnetic resonance to finite element modelling. Fig. 3. Mode shapes of different shell structures. 165 Research Projects and Activities 2015 MAIN PUBLICATIONS Daghia F., de Miranda S., Ubertini F. (2013). Patch based recovery in finite element elastoplastic analysis. Computational Mechanics (in press). Castellazzi G., de Miranda S., Ubertini F. (2011). Patch based stress recovery for plate structures. Computational Mechanics 47, 379-394. Castellazzi G., de Miranda S., Ubertini F. (2010). Adaptivity based on the recovery by compatibility in patches. Finite Elements in Analysis and Design 46, 379-390. Castellazzi G., Gentilini C., Krysl P., Elishakoff I. (2013). Static analysis of functionally graded plates using a nodal integrated finite element approach. Composite Structures 103, 197-200. Castellazzi G., Krysl P., Bartoli I. (2013). A displacement-based finite element formulation for the analysis of laminated composite plates. Composite Structures 95, 518-527. Castellazzi G., Krysl P. (2012). A nine-node displacement-based finite element for Reissner-Mindlin plates based on an improved formulation of the NIPE approach. Finite Elements in Analysis and Design 58, 31-43. Tornabene F. (2009). Free Vibration Analysis of Functionally Graded Conical, Cylindrical and Annular Shell Structures with a Four-parameter Power-law Distribution. Computer Methods in Applied Mechanics and Engineering 198, 2911-2935. Viola E., Tornabene F., Fantuzzi N. (2013). General Higher-Order Shear Deformation Theories for the Free Vibration Analysis of Completely Doubly-Curved Laminated Shells and Panels. Composite Structures 95, 639-666. Viola E., Tornabene F., Fantuzzi N. (2013). Static Analysis of Completely Doubly-Curved Laminated Shells and Panels Using General Higher-Order Shear Deformation Theories. Composite Structures 101, 59-93. Cannarozzi M., Molari L. (2013). Stress-based formulation for non-linear analysis of planar elastic curved beams. International Journal of Non-Linear Mechanics 55, 35-47. Mazzotti M, Bartoli I., Marzani A. and Viola E. (2013). A 2.5D Boundary Element formulation for modelling damped wave in arbitrary cross-section waveguides and cavities, Journal of Computational Physics, 248, 363-382. Mazzotti M., Bartoli I., Marzani A and Viola E. (2013). A coupled SAFE-2.5D BEM approach for the dispersion analysis of damped leaky guided waves in embedded waveguides of arbitrary cross-section, Ultrasonics, 53, 1227-1241. Castellazzi G., De Marchi L., Krysl P. and Marzani A. (2013). Quantitative simulation of wave propagation in human bones to support the ultrasonic non-invasive assessment of human bones, Proc. of SPIE, Vol. 8695, 86952G-1 86952G-10. Mazzotti M., Marzani A., Bartoli I., Viola E. (2012). Guided Waves dispersion analysis for prestressed viscoelastic waveguides by means of the SAFE method, International Journal of Solids and Structures 49, 2359-2372. de Miranda S., Mancuso M., Ubertini F. (2010). Time discontinuous galerkin methods with energy decaying correction for non-linear elastodynamics. International Journal for Numerical Methods in Engineering 83, 323-346. Ferretti E. (2009). Cell method analysis of crack propagation in tensioned concrete plates. Computer Modeling in Engineering and Sciences 54, 253-281. Ferretti E., Casadio E., Di Leo A. (2008). Masonry walls under shear test: A CM modeling. Computer Modeling in Engineering and Sciences 30, 163-189. C. Gentilini, L. Nobile, K.A. Seffen. (2009). Numerical analysis of morphing corrugated plates. Procedia Engineering 1, 79–82. RESEARCH PROJECTS EU FP7-AAT-2011-RTD-1 ID. 284562 Project: SARISTU. Smart Intelligent Aircraft Structures. Verification in computational structural mechanics, PRIN2007 – Research Unit of Bologna, coordinator: Prof. F. Ubertini. CONTACTS [email protected] [email protected] 166 Structures – Computational Structural Mechanics ADVANCED COMPUTATIONAL TOOLS FOR ANALYSIS AND DESIGN OF REAL STRUCTURES RESEARCH GROUP: Giovanni Castellazzi, Stefano de Miranda, Cristina Gentilini, Alessandro Marzani, Luisa Molari, Francesco Ubertini KEYWORDS: steel structures, falling rock protection barriers, leakage in cracked pipes, ceramic sanitary ware, guided waves This research line encompasses the application of advanced computational tools for the analysis and design of real structures. The current research activities address a wide range of issues, including: - linear and nonlinear structural analysis of thin walled beams, with emphasis for cold-formed steel members, in which local phenomena such as section distortion require the use of beam models with enriched kinematics or three-dimensional shell models, - numerical strategies for the design and verification of flexible falling rock barriers: passive protection measures for risk mitigation of potentially unstable rock slopes. The key point of the proposed approaches is that notwithstanding the complexity of the simulated phenomenon, the resulting highly non-linear, dynamic models are simple and produce an accurate prediction of all the relevant parameters for barrier design, such as anchorage forces, net panel elongations and residual heights, - modelling of ceramic sanitary ware deformations during the production process, - analysis of the effects of permanent ground deformation on undergound and above ground pipe networks, - analysis of waveguides dispersive properties, - models to evaluate the influence of the deformability of a cracked pressurized pipe on leakage, with a focus on losses because of longitudinal splits. The purpose is to evaluate the opening area (leak area), while keeping the model as simple as possible, - nonlinear analysis of masonry structures, - modelling of tiles debonding due to shrinkage: substrate shrinkage or temperature variations can produce differential elongation/shortening between tiles and substrate. Consequently the tiling failure like mode I mechanism can occur. These issues have advanced broad applications in the engineering practice of modern structural analysis, design and construction of buildings and other structures. Fig. 1. Global, distortional and local buckling of a thin-walled beam. Fig. 2. Numerical simulation of the concrete block impact on a rockfall barrier. Fig. 3. Modelling of ceramic sanitary wares. 167 Research Projects and Activities 2015 MAIN PUBLICATIONS de Miranda S., Gutiérrez A., Miletta R., Ubertini F. (2013). A generalized beam theory with shear deformation. Thin-Walled Structures 67, 88-100. Zagari G., Madeo A., Casciaro R., de Miranda S., Ubertini F. (2013). Koiter analysis of folded structures using a corotational approach. International Journal of Solids and Structures 50, 755-765. Braham M., Ruggerini A., Ubertini F. (2008). A numerical model for roof detailing of cold-formed purlin-sheeting systems. Stahlbau 77, 238-246. de Miranda S., Miletta R., Ruggerini A., Ubertini F. (2011). Progettazione e calcolo di sistemi di copertura formati a freddo. Costruzioni Metalliche 3, 43-53. Castellazzi G. (2012). Analysis of second-order shear-deformable beams with semi-rigid connections. Journal of Constructional Steel Research 79, 183-194. Castellazzi G., de Miranda S., Mazzotti C. (2012). Finite element modelling tuned on experimental testing for the structural health assessment of an ancient masonry arch bridge. Mathematical Problems in Engineering, art. no. 495019. Mazzotti C., de Miranda, S., Castellazzi G., Carrea F. (2012). Structural assessment of the railway masonry arch bridge crossing the reno river in Bologna. 6th International Conference on Bridge Maintenance, Safety and Management, 1078-1085. Gentilini C., Govoni L., de Miranda S., Gottardi G., Ubertini F. (2012). Three-dimensional numerical modelling of falling rock protection barriers. Computers and Geotechnics 44, 58-72. Govoni L., de Miranda S., Gentilini C., Gottardi G., Ubertini F. (2011). Modelling of falling rock protection barriers. International Journal of Physical Modelling in Geotechnics 11, 126-137. de Miranda S., Gentilini C., Gottardi G., Govoni L., Ubertini F. (2010). A simple model to simulate the full-scale behaviour of falling rock protection barriers. Physical Modelling in Geotechnics - Proceedings of the 7th International Conference on Physical Modelling in Geotechnics 2010, ICPMG 2010, pp. 1247-1252. Gentilini C., Gottardi G., Govoni L., Mentani A., Ubertini F. (2013). Design of falling rock protection barriers using numerical models. Engineering Structures 50, 96-106. Bocchini P., Marzani A. and Viola E. (2010), A Graphical User Interface for guided acoustic waves, Journal of Computing in Civil Engineering 25, 202-210. Pavlovic A., Fragassa C., de Miranda S. (2012). Mini city cars need a crash test. International CAE Conference, October 22-23, Pacengo-Lazise. de Miranda S., Molari L., Scalet G., Ubertini F. (2012). Simple beam model to estimate leakage in longitudinally cracked pressurized pipes. ASCE Journal of Structural Engineering 138, 1065-1074. de Miranda S., Molari L., Scalet G., Ubertini F. (2010). Leakage evaluation in longitudinally cracked pressurized pipes. 4th International Conference on Structural Engineering, Mechanics and Computation - SEMC, September 6-8, Cape Town. de Miranda S., De Rosis A., Fantuzzi N., Patruno L., Ubertini F. (2011). Progettazione integrata di stampi per sanitari ceramici. XX Congresso dell’Associazione Italiana di Meccanica Teorica e Applicata - AIMETA2011, September 12-15, Bologna. RESEARCH PROJECTS Models and algorithms for the nonlinear analysis of structures and performance-based design, PRIN2010 – Research Unit of Bologna, coordinator: Prof. F. Ubertini. CONTACTS [email protected] [email protected] 168 Structures – Experimental Testing, Diagnosis and Monitoring of Structures MATERIALS CHARACTERIZATION RESEARCH GROUP: Camilla Colla, Elena Ferretti, Alessandro Marzani, Giovanni Pascale, Francesco Ubertini, Erasmo Viola KEYWORDS: NDT, monitoring, effective stress, effective strain, Poisson ratio The research topics concern the development of innovative and unconventional procedures and testing techniques to be performed in the laboratory and on site for studying building materials, e.g. mortars, bricks, wood, … with the aim of determining their mechanical and physical properties, such as compression, shear or tensile strength, the elastic modulus, the capillary rise velocity, etc. Moreover, special procedures for testing single materials samples which may have irregular shapes or portions of structural elements taken on-site, also on historic and/or earthquakes damaged structures. A further innovative development in the procedures for the mechanical characterization of materials and assessment of the structure - environment interaction, is represented by the coupling of mechanical tests with non-destructive diagnostic techniques (sonic tests, IR thermography, digital correlation of images, acoustic emission…) or monitoring systems, also wireless (e.g. potential embedded sensors for salt content monitoring in masonry materials). Among the laboratory procedures, to identify the constitutive law in uniaxial compression, it has been proposed the procedure of the effective law for brittle heterogeneous materials, which produces evidence against the existence of strain-softening and identifies a monotone strictly non decreasing material law for concrete specimens in uniaxial compression, whose average stress versus average strain diagrams, σ-ε, are softening. The basic idea is that the actual failure mechanism develops internally, with macro-cracks propagating through the specimens from the very beginning of the compression test. In cylindrical specimens, these cracks isolate a resistant inner core of bi-conic shape, which remains intact, while the outer part is expelled along the radial direction and splits into several portions. The actual failure mechanism gradually modifies the resistant structure and, consequently, the resistant area of the specimen. On-site, minimally invasive testing equipment (e.g. penetrometers for mortars and wood, hammers…) and combined procedures are used to characterize the materials and assess the healthstate of the structures. Fig. 1. View of the LISG laboratory. Fig. 2. Monitoring of physical-mechanical tests using acoustic emission sensors or DIC. Fig. 3. Monotonically increasing constitutive law for concrete specimens in uniaxial compression. Fig. 4. On-site mechanical characterization of historic mortars by micro-destructive testing. 169 Research Projects and Activities 2015 MAIN PUBLICATIONS Ferretti E. and Bignozzi M.C. (2012). Stress and Strain Profiles along the Cross-Section of Waste Tire Rubberized Concrete Plates for Airport Pavements, Computers, Materials, & Continua (CMC) 27(3), 231-274. Ferretti E. (2012). Shape-effect in the effective laws of Plain and Rubberized Concrete. Computers, Materials, & Continua (CMC), 30(3), 237-284. Ferretti E. (2012). Waste Tire Rubberized Concrete Plates for Airport Pavements: Stress and Strain Profiles in Time and Space Domains. Computers, Materials, & Continua (CMC) 31(2), 87-112. Colla C., Gabrielli E., Krueger M. and Lehmann, F., (2012). Experience of acoustic emissions of masonry. Proc. of EWCHP 2012, Cultural Heritage Preservation, Kjeller, Norway, September 24th -26th, ed. E. Dahlin, NILU –Norwegian Institute for Air Research, ISBN 978-82-425-2525-3, 207-215. Gabrielli E., Marani F. and Colla C. (2012). Ir thermography to compare the evaporation fluxes in brick masonry. Proc. of EWCHP 2012, Cultural Heritage Preservation, Kjeller, Norway, September 24th -26th, ed. E. Dahlin, NILU – Norwegian Institute for Air Research, ISBN 978-82-425-2525-3, 216-223. Rajcic V. and Colla C. (2011). Correlations between destructive and four NDT techniques tests on historic timber elements. Proc. of EWCHP 2011, Cultural Heritage Preservation, Berlin, Germany, September 26-28, ed. M. Krüger, Fraunhofer IRB Verlag, ISBN 978-3-81678560, 148-155. Colla C. and Pascale G. (2010). Prove non distruttive e semidistruttive per la caratterizzazione delle murature della torre Ghirlandina di Modena. In La torre Ghirlandina – storia e restauro, R. Cadignani (a cura di), Roma, 218-227. Ferretti E. and Di Leo A. (2008). Cracking and Creep Role in Displacements at Constant Load: Concrete Solids in Compression. Computers, Materials & Continua. vol. 7, pp. 59 - 80 ISSN: 1546-2218. E. Ferretti (2004). On Strain-Softening in Dynamics. International Journal of Fracture. vol. 126, pp. L75 - L82 ISSN: 0376-9429. Ferretti E. (2004). On Poisson’s Ratio and Volumetric Strain in Concrete. International Journal of Fracture. vol. 126, pp. L49 - L55 ISSN: 03769429. Ferretti E. (2004). Experimental Procedure for Verifying Strain-Softening in Concrete. International Journal of Fracture. vol. 126, pp. L27 - L34 ISSN: 0376-9429. Ferretti E. (2004). A Discussion of Strain-Softening in Concrete. International Journal of Fracture. vol. 126, pp. L3 - L10 ISSN: 03769429. Ferretti E., Di Leo A. and Viola E. (2003). A Novel Approach for the Identification of Material Elastic Constants. CISM Courses and Lectures N. 471: Problems in Structural Identification and Diagnostic: General Aspects and Applications, Springer, Wien-New York, pp. 117-131. RESEARCH PROJECTS SMooHS – Smart Monitoring of Historical Structures, Unità di Bologna, European Research project ENV.2007.3.2.1.1. CONTACTS [email protected] [email protected] 170 Structures – Experimental Testing, Diagnosis and Monitoring of Structures MODELING AND DESIGN OF SHAKING TABLE TEST FACILITIES RESEARCH GROUP: Giada Gasparini, Stefano Silvestri, Tomaso Trombetti KEYWORDS: shaking table, dynamic tests, modelling, design Shaking tables represent the main test tool for the evaluation of the dynamic and seismic behaviour of structures. The first tables were realised at the end of the 60’s and at the beginning of the 70’s and were often used for tests of scale models with linear elastic behaviour. Since the first 90’s, they became the object of an extensive research activity for the development of a next generation of such tools capable of offering new and better possibilities. This next generation of shaking tables (Rice University at Houston, University of Firenze, LHPOST shaking table at San Diego, Eucentre in Pavia, …) is characterised by: (a) high accuracy in the displacements reproduction, (b) large dimensions (in order to allow dynamic tests upon small-scale structures, to better capture the post-yielding behaviour), (c) capability of well reproducing near-fault seismic input (characterised by very large values of peak ground velocity and displacements). The scientific activity mainly lies in the development of an analytical/numerical model of the dynamic functioning of the shaking table capable of effectively capturing its actual behaviour (creation of a virtual model of the table). This model has revealed to be very useful for: (a) the design project of new shaking tables, (b) for their adjustments, and (c) for the study devoted to the minimisation of the interactions between the table itself and the testes structures. Recently (2010-2013), the research group planned, designed and directed two experimental shaking-table test campaigns: 1. Tests on a full-scale 3-storey building structure realized with sandwich r.c. panels, at the EUCENTRE Lab in Pavia. 2. Tests on scaled models of flat-bottom silos containing grain –like materials, at the EQUALS Lab in Bristol (UK). Fig. 1. Tests on a full-scale 3-storey building structure realized with sandwich r.c. panels, at the EUCENTRE Lab in Pavia. Total publications: 20. 171 Fig. 2. Tests on scaled models of flat-bottom silos containing grain –like materials, at the EQUALS Lab in Bristol (UK). Research Projects and Activities 2015 MAIN PUBLICATIONS T. Trombetti, S. Silvestri, G. Gasparini, I. Ricci, S. Ivorra, D. Foti (2013). Preliminary results of a shaking table tests on a 3-story building realized with cast in place sandwich squat concrete walls, ISEC-7, Honolulu, June 18 –23, 2013. D. Foti, S. Ivorra, T. Trombetti, S. Silvestri, G. Gasparini, L. Di Chiacchio, Final Report – ASESEGRAM project, “Assessment of the SEismic behaviour of flat-bottom Silos containing GRAin-like Materials”, February 2013. T. Trombetti, S. Silvestri, G. Gasparini, I. Ricci, S. Ivorra, D. Foti (2011). Progettazione di una prova su tavola vibrante di un edificio a tre piani in scala reale costituito da pareti sandwich in c.a. gettato in opera, XIV Convegno Nazionale “L’Ingegneria Sismica in Italia” ANIDIS 2011, Bari, 19 - 22 Settembre 2011. Ozcelik O., Luco E., Conte J.P., Trombetti T. and Restrepo J. (2008). Experimental characterization, modeling and identification of the NEESUCSD shake table mechanical system. EARTH. ENG. & STR. DYN. vol. 37-2, 243-264. Conte J.P. and Trombetti T. (2000). Dynamic modeling of a uni-axial shaking table system. Earthquake Engineering & Structural Dynamics 29, 1375-1404. Trombetti T. and Conte J.P. (2002). Shaking Table Dynamics: results form a test-analysis comparison study. Journal of Earthquake Engineering 6(4), 513–551. Trombetti T., Conte J.P. and Durrani A.J. (1998). Actuator-foundation-specimen interaction in a small shaking table. Proceedings of the 12th ASCE Engineering Mechanics Specialty Conference, San Diego, California, 770-773. Trombetti T., Barrasso P., Crewe A., De Stefano M., Gasparini G., Nudo R., Rutenberg A., Silvestri S. and Taylor C. (2004). Shaking table testing of symmetric and asymmetric three-storey steel frame structures. Atti del 13th World Conference on Earthquake Engineering - 13WCEE, Vancouver, B.C., Canada, August 1-6, Paper No. 1248. Trombetti T., Conte J.P. and Durrani A.J. (1999). Correlation Studies between Analytical and Experimental Dynamic Behavior of the Rice University Shaking Table. Structural Research at Rice Report N°. 49. Rice University, Houston, Texas. Trombetti T., Conte J.P. and Durrani A.J. (1999). Analytical Modeling of a Shaking Table System. Structural Research at Rice Report N°. 48. Rice University, Houston, Texas. Aprile A., Benedetti A. and Trombetti T. (1994). On Non Linear Dynamic Analysis in the Frequency Domain. Earthquake Engineering & Structural Dynamics 23, 363–388. RESEARCH PROJECTS Progettazione e realizzazione di una tavola vibrante (2000-2001): Università di California a Los Angeles. Sperimentazione dinamica su tavola vibrante (2000-2001): Bristol (UK). Shake down test for a large shaking table facility (responsabile delle prove di caratterizzazione e messa a punto per una tavola vibrante di ampie dimensioni) 2004: Università di California San Diego (finanz. NISEE – prog. Marco Polo). Progetto Giovani Ricercatori: Analisi e controllo del funzionamento dinamico delle tavole vibranti”, Univ. di Bologna 2000/2001, T. Trombetti. Prove di messa a punto ed accettazione di tavola vibrante monoassiale a movimento idraulico (2005): Eucentre – Pavia. Progetto di ricerca SERIES (2010-2011): “Seismic behavior of structural systems composed of cast in situ concrete walls”, EUCENTRE TREES Lab facility (Pavia, Italy), Lead User: Prof. Salvador Ivorra Chorro, University of Alicante, Resp. Unità di Bologna: Prof. Tomaso Trombetti. Progetto di ricerca SERIES (2010-2011): “Assessment of the seismic behaviour of flat-bottom silos containing grain-like materials”, EQUALS Laboratories (Bristol, UK), Lead User: Prof. Dora Foti, Politecnico di Bari, Resp. Unità di Bologna: Prof. Tomaso Trombetti. CONTACTS [email protected] 172 Structures – Experimental Testing, Diagnosis and Monitoring of Structures DYNAMIC IDENTIFICATION AND TESTING RESEARCH GROUP: Pier Paolo Diotallevi, Claudio Mazzotti, Marco Savoia KEYWORDS: identification, optimization, dynamics test, Wavelet wave, bridge The research group is involved in the experimental study of the dynamic behavior of civil structures. The problem is particularly relevant because from the dynamic characterization of the system (modes, natural frequencies, damping), the most plausible values of the main parameters governing the numerical models able to simulate the behavior of the structure can be defined by identification techniques. The study can be split in three main topics: setup of experimental tests, determination of the dynamic characteristics of the structure and processing of data to estimate unknown parameters of models such as stiffness and mass of the system (model updating). Within the first topic, different types of structures such as hospitals, schools, bridges, railway bridges and pedestrian bridges were considered. The tests were carried out either using a forced excitation or environmental excitation (wind, traffic). Both conventional instrumentation and low-cost accelerometers (MEMS) were used. Frequencies, modal deformation and damping were then identified by using methods defined in the frequency domain and in the time domain, such as circle fit, ARMA, ARMAV, Lissajous diagrams and coupled time-frequency methods such as wavelet transforms. The estimate of the actual values of the parameters of the mechanical properties (material assumptions, constraints, and structural and nonstructural masses), finally, was obtained by solving an optimization process. The research focuses on the study and application of genetic and evolutionary algorithms and their variants, whereas frequencies and mode shapes were assigned. The shape of the error function for different choices of the number of natural frequencies and mode shapes were investigated. In addition, pseudo-experimental or experimental input data were considered. Finally, it was implemented a modified version of an evolutionary algorithm to improve accuracy and speed of convergence. Fig. 1. Identification of natural frequencies for a building. Fig. 2. Test of environmental vibration for a flyover. Fig. 3. Forced vibration test on a pedestrian bridge. 173 Research Projects and Activities 2015 MAIN PUBLICATIONS Vincenzi L., De Roeck G., Savoia M. (2013- in press) Comparison between Differential Evolution Algorithm and Coupled local Minimizer Method. Advances in Engineering Software. Guidorzi R., Diversi R., Vincenzi L., Mazzotti C., Simioli V. (2013 – in press) Structural monitoring of a tower by means of MEMS–based sensing and enhanced autoregressive models. European Journal of Control. Vincenzi L., Savoia M., Salvatore W. (2012) Experimental modal analysis and fatigue assessment on the Lagoscuro viaduct. 6th International Conference on Bridge Maintenance, Safety and Management, 8-12/07/2012, Stresa, Lago Maggiore. Pantoli E., Vincenzi L., Savoia M., Testa R. (2011) The effect of local vibrations on fatigue in old steel riveted bridges. A case study: the Manhattan Bridge. 8th International Conference on Structural Dynamics, EURODYN 2011, 4-6/7/2011, Leuven, Belgio Vincenzi L., Mazzotti C., Guidorzi R. (2011) Monitoraggio strutturale della torre della facoltà di Ingegneria di Bologna. XIV convegno ANIDIS, 18-22/09/2011, Bari. Vincenzi L., Savoia M. (2010) Improving the speed performance of an Evolutionary Algorithm by a second-order cost function approximation. 2nd International Conference on Engineering Optimization, 6-9/09/2010, Lisbona, Portogallo Vincenzi L., Mazzotti C., Guidorzi R. (2010). Utilizzo di MEMS per il monitoraggio strutturale. XVIII Convegno CTE, Brescia. C. Belmonte, P.P. Diotallevi, O. Manfroni. (2010). “Comparison Between Two Methods In Frequency Domain for Dynamic Identification”. Proceedings of the 14th European Conference on Earthquake Engineering, 30/08-3/09/2010, Ohrid, Republic of Macedonia C. Belmonte, P. P. Diotallevi, O. Manfroni. (2009). “Metodi nel dominio delle frequenze per l’identificazione dinamica di una passerella pedonale”. XIII Convegno Nazionale L’Ingegneria Sismica in Italia, ANIDIS. 28/06-2/07, Bologna. C. Belmonte, E. Caetano, A. Cunha, P.P. Diotallevi. (2009). “Extraction of modal parame- ters through Wavelet Transform”. Proceedings of the “IV ECCOMAS Thematic Conference SMART’09”. 13-15 July 2009, Porto, Portugal. Vincenzi L., Mazzotti C. (2009). Identificazione dinamica di una passerella pedonale strallata mediante algoritmi nel dominio delle frequenze, XIII Convegno Nazionale di Ingegneria Sismica ANIDIS, 28 giugno-2 luglio, Bologna. Vincenzi L. Savoia M., (2009). Coupling of differential evolution algorithm and quadratic approximation for dynamic identification, ICOSSAR - International conference of structural safety and reliability 2009, Osaka, Japan. P.P. Diotallevi, O. Manfroni, C. Belmonte. (2008). “Dynamic identification of a timber footbridge subject to vibration tests”. Proceedings of the 14th World Conference on Earthquake Engineering, Beijing, China, October 12-17, 2008. Savoia M., Vincenzi L. (2008). Differential Evolution Algorithm for Dynamic Structural Identification. Journal of Earthquake Engineering. Vol. 12, pp. 800-821. Vincenzi L., Mazzotti C., Savoia M. (2006). Modal identification of a TAV viaduct using subspace models. 2nd International FIB Congress. 5-8 giugno, Napoli. Vincenzi L., Savoia M. (2005), Identificazione dei parametri modali autoregressivi di un modello ARMA Vettoriale attraverso algoritmi evolutivi, AIMeTA di Meccanica Teorica e Applicata, 11-15 settembre, Firenze. RESEARCH PROJECTS 2009-2012: Research Project FADLESS (Fatigue damage control and assessment for railway bridges), sponsored by European Commission within program RFCS (Research Fund for Coal and Steel-FP7); partners of the projects are: PISA ricerche, Riva Acciaio, VCE Holding, K. U. Leuven, LMS International NV, Bauhaus Universitat Weimar, Facultade De Engenharia Da Universitade Do Porto, University of Bologna. CONTACTS [email protected] [email protected] [email protected] 174 Structures – Historical/Monumental Cultural Heritage EXPERIMENTAL TECHNIQUES FOR THE STUDY OF HISTORICAL MASONRY STRUCTURES RESEARCH GROUP: Andrea Benedetti, Nicola Buratti, Pier Paolo Diotallevi, Giada Gasparini, Cristina Gentilini, Luca Landi, Claudio Mazzotti, Marco Savoia, Stefano Silvestri, Tomaso Trombetti, Francesco Ubertini KEYWORDS: masonry, consolidation, monuments, seismic vulnerability The research focus on the development of consolidation techniques that combine the conservation of monuments with the seismic protection of users. The activity includes: (1) The development of experimental techniques for non-destructive characterization of the masonry walls. In particular, advanced diagnostic and monitoring techniques are implemented and used in laboratory and on-site, to allow the non-destructive evaluation of the quality, the ‘homogeneity, the degradation and the state of health of structural elements in masonry, wood and concrete buildings. The development of new procedures for data acquisition, post-processing of the data and data fusion is pursued in order to maximize the potential of these techniques. (2) The analysis of seismic vulnerability of buildings and masonry bridges. In this context, a simplified methodology for the assessment of the vulnerability of existing RC structures and masonry has been developed (RESISTO). Fig. 1. Diagnosis on Ghirlandina tower, Modena: sonic results and velocity classes. Fig. 2. Evaluation of homogeneity of mansonry by thermography and wireless monitoring. (3) The definition of consolidation techniques. Various solutions to repair structures have been studied. In particular composite materials with metal or carbon fibers, in a matrix of epoxy or cement-based have been studied. Numerous applications to real cases have been carried out. The results of the analysis were included in the guidelines document developed by CNR for the repair of composite materials CD 200/2004. (4) assessment of the structural damage induced by salts on masonry. The shear behaviour of artificially damaged masonry specimens is investigated by means of an ad hoc experimental test. As well known, the shear behaviour of masonry buildings plays a crucial role for structures located in areas prone to seismic hazard. Fig. 3. Shear test on masonry triplet. Precompression apparatus. 175 Research Projects and Activities 2015 MAIN PUBLICATIONS Sassoni E., Mazzotti C. (2013) The use of small diameter cores for assessing the compressive strength of clay brick masonries. Journal of Cultural Heritage 14S, 95-101. Bitelli G., Colla C., Gabrielli E., Girardi F., Ubertini F. Quantitative monitoring of superficial decay evolution in plastered and unplastered outdoors masonry, Journal of Architectural Heritage (in print). Gentilini C., Franzoni E., Bandini S., Nobile L. (2012) Effect of salt crystallisation on the shear behaviour of masonry walls: An experimental study. Construction and Building Materials, 37, 181-189. Gasparini G., Silvestri S., Palermo M., Trombetti T., Dallavalle G. (2012) The monitoring system of the “Due Torri” in Bologna, Italy: preliminary results, Proceedings of MEMSCON Workshop 2012 (7th European Framework Programme): Towards Intelligent Civil Infrastructure, Athens, Greece. Frick, J., Colla, C., Gabrielli, E., Gruener, F., (2012), “Seasonal Monitoring of Salt Movement in Masonry Materials”, In Cultural Heritage Preservation, Proc. of EWCHP 2012, Kjeller, Norway, September 24th -26th, ed. E. Dahlin, NILU – Norwegian Institute for Air Research, ISBN 97882-425-2525-3, pp. 27-34. Strojecki, M., Łukomski, M., Colla, C., Gabrielli, E., (2012), “Acoustic emission as a non-destructive method for tracing damage: from laboratory testing to monitoring historic structures”, RILEM Bookseries, vol. 6, Proc. of NDTMS-2011 Int. Symp. on Nondestructive Testing of Materials and Structures, Istanbul Technical University, Turkey, May 15-18, Springer, ISBN: 978-94-007-0722-1, pp. 1131-1136. F. Sandrolini, E. Franzoni, E. Sassoni, P.P. Diotallevi. (2011). The contribution of urban-scale environmental monitoring to materials diagnostics: a study on the Cathedral of Modena (Italy). Journal of Cultural Heritage, 12, 441-450. Colla C., Pascale G. (2010) Prove non distruttive e semidistruttive per la caratterizzazione delle murature della torre Ghirlandina di Modena, in La torre Ghirlandina – storia e restauro, R. Cadignani (a cura di), Luca Sossella editore s.r.l., Roma, pp. 218-227. L. Landi, P.P. Diotallevi, R. Gabellieri (2010). Outof-plane dynamic behaviour of unreinforced masonry walls in buildings with flexible diaphragms. 14th European Conference on Earthquake Engineering. Ohrid, Republic of Macedonia. Colla, C., Benedetti, A., (2009), “Applicazioni di tomografia acustica e prove di resistenza alla penetrazione per la valutazione del degrado di elementi strutturali lignei antichi”, in Consolidamento delle strutture di legno, M. Piazza (Ed.), Benevento, Hevelius Edizioni, Ottobre, pp. 79-98. L. Pelà, A. Aprile, A. Benedetti, (2009), “Seismic assessment of masonry arch bridges”, Engineering Structures, 31(8), August 2009, p. 1777-1788. A. Benedetti and E. Mangoni (2008), NDT evaluation of ancient masonry properties by means of splitting tests on cores with diametric mortar layer, First International RILEM Symposium SACoMaTiS 2008, 1-2 September 2008, Varenna, Italy, p. 431-441. RESEARCH PROJECTS ReLUIS 2005–2008: N. 8 Task 7: Criteri di progetto per l’adeguamento sismico di strutture in muratura. ReLUIS 2009-2012: Area Tematica 2, Linea di Ricerca 3, Task 1: Sviluppo ed analisi di nuovi materiali per l’adeguamento sismico di volte e cupole in muratura. SMooHS – Smart Monitoring of Historical Structures, FP7-2008, Collaborative EU project. Project Ref.: 212939. 3ENCULT – Efficient Energy for EU Cultural Heritage, FP7-2010, Collaborative EU project. Project Ref.: 260162. CONTACTS [email protected] [email protected] 176 Structures – Historical/Monumental Cultural Heritage NUMERICAL TECHNIQUES FOR THE STUDY OF HISTORICAL MASONRY STRUCTURES RESEARCH GROUP: Andrea Benedetti, Giovanni Castellazzi, Camilla Colla, Alberto Custodi, Stefano de Miranda, Pier Paolo Diotallevi, Elena Ferretti, Cristina Gentilini, Luca Landi, Luisa Molari, Lucio Nobile, Giovanni Pascale, Lino Sciortino, Francesco Ubertini KEYWORDS: FEM simulations, masonry structures, coupled models, seismic vulnerability, salt attack The focus of the research is the development and application of theoretical models and numerical methods for the structural analysis of historic structures. The actual research activity encompasses a large number of structural issues involving historical buildings, in particular: - development of coupled multiphase models for the hygrothermal analysis of masonry structures aimed at the evaluation of the stress induced by crystallization of salts; - development of advanced constitutive models of the mechanical behavior of masonry; - analysis of the seismic vulnerability of masonry structures, considering both in-plane and outof-plane mechanisms; - assessment of the carrying capacity of masonry structures and reserves of security against the stresses might be required as a result of the execution of works of consolidation and restoration; - development, investigation and evaluation of new methodologies for the integrated, multyphisics modelling of built cultural heritage with the target to support the development of energy efficiency interventions which minimize the primary energy consumption in historic buildings, taking into full account the preservation tasks. Further research topic concerns the development of multiscale approaches for the structural analysis of masonry buildings in the presence of degradation due to environmental actions, such as capillary suction and crystallization of salts. The multiscale approach allows to accurately capture most of the degradation process – often accompanied by localization of damage in narrow zones, which ultimately leads to failure – still remaining computationally efficient for large-scale structural computations. Fig. 1. Rising moisture: numerical model and experimental evidence. Fig. 2. Linear dynamic analysis: modal identification of an historical bridge. Fig. 3. Linear dynamic analysis of an historical church. Longitudinal section of a main eigenmode. 177 Research Projects and Activities 2015 MAIN PUBLICATIONS Bovo M., Mazzotti C., Savoia M. (2013). Structural behaviour of historical stone arches and vaults: experimental tests and numerical interpretation. Studi e Ricerche 32. Castellazzi G., Gentilini C., Nobile L. (2013). Seismic vulnerability assessment of an historical church: limit analysis and non-linear Finite Element analysis. Advances in Civil Engineering (in press). Gabellieri R., Landi L., Diotallevi P.P. (2013) A 2-dof model for the dynamic analysis of unreinforced masonry walls in out-of-plane bending. 4th ECCOMAS Thematic Conference on Computational Methods in Structural Dynamics and Earthquake Engineering, Kos Island, Greece. Colla C., Molari L., Gabrielli E., de Miranda S. (2012). Damp and salt rising in damaged masonry structures: numerical modelling and NDT monitoring. RILEM Bookseries 6, 11511156. Colla C., de Miranda S., Ubertini F. (2011). Indagini in sito per la diagnostica strutturale dell’elevato: la Casa del Tramezzo di Legno ad Ercolano. In: DHER, Domus Herculanensis Rationes, Sito Archivio Museo – A. Coralini (a cura di), Vesuviana, AnteQuem- Studi e Scavi 30, Bologna, 145-161. Ferretti E., Casadio E., Di Leo A. (2008). Masonry Walls under Shear Test: a CM Modeling, Computer Modeling in Engineering & Science 30, 163-190. Castellazzi G., de Miranda S., Mazzotti C. (2012). Finite Element Modelling Tuned on Experimental Testing for the Structural Health Assessment of an Ancient Masonry Arch Bridge. Mathematical Problems in Engineering art. no. 495019. Castellazzi G., Custodi A., Sciortino L., Vagnetti A., Colla C., de Miranda S., Ubertini F. (2008). Modellazione e simulazione di strutture archeologiche in area vesuviana, Convegno Internazionale VESUVIANA, Bologna, January 14-16. Mazzotti C., de Miranda S., Castellazzi G., Carrea F. (2012). Structural assessment of the railway masonry arch bridge crossing the Reno river in Bologna. 6th International Conference on Bridge Maintenance, Safety, Management, Resilience and Sustainability, Stresa, 1078-1085. RESEARCH PROJECTS Castellazzi G., Colla C., de Miranda S., Formica G., Gabrielli E., Molari L., Ubertini F. (2013). A coupled multiphase model for hygrothermal analysis of masonry structures and prediction of stress induced by salt crystallization. Construction and Building Materials 41, 717-731. Castellazzi G., de Miranda S., Formica G., Ubertini F. (2010). Fully coupled diffusion-damage analysis in historical masonry walls. XVIII Convegno Italiano di Meccanica Computazionale GIMC 2010, Siracusa, Italy. Savoia M., Carli R., D’Amato L. (2010) L’utilizzo di tecniche di indagine soniche per la valutazione dell’efficacia dei consolidamenti nelle murature storiche. XVIII Congresso C.T.E. Atti. s.n, pp. 1163-1172. 2, Brescia. 3ENCULT – Efficient Energy for EU Cultural Heritage, FP7-2010, Collaborative EU project. Project Ref.: 260162. SMooHS – Smart Monitoring of Historical Structures, FP7-2008, Collaborative EU project. Project Ref.: 212939. Homogenization of elementary cells of masonry by means of the Cell Method, PRIN2006 - Research Unit of Bologna, coordinator: Prof. A. Di Leo. From survey to structural analysis of Roman constructions in the Vesuvio area, PRIN2005 Unit of Bologna, coordinator: Prof. F. Ubertini. Pompei, Insula IX 8: experimentation and modeling of materials and structures, PRIN2003, Unit of Bologna, coordinator: Ing. Custodi. CONTACTS [email protected] 178 Structures – Historical/Monumental Cultural Heritage STRUCTURAL DIAGNOSTICS AND MONITORING OF CULTURAL HERITAGE RESEARCH GROUP: Roberto Carli, Camilla Colla, Alessandro Marzani, Giovanni Pascale, Francesco Ubertini KEYWORDS: historic structures, marble statues, NDT, cracks, sensors, monitoring The Cultural Heritage evaluation requires a multiphase and integrated diagnostic approach with extended and deepened experimental campaigns, not harmful to the good. The research group works on the advanced development and use of non-destructive and minimally invasive survey techniques and test procedures aimed at determining the health-state of historic structures and their materials (brick and stone masonry, timber). Among these, sonic tests, radar, IR thermography, tomography, penetrometric tests on mortar and timber, micro-coring, lab determinations on historic samples. In addition, structural monitoring, both traditional and wireless, has been carried out. The experience gained has resulted in prestigious projects in the field of Cultural Heritage, such as the 7FP EU Project SMooHS, the agreements with regional architectonic and archaeological Superintendents and with the Galleria dell’Accademia in Florence, for monitoring large marble statues including two Michelangelo Buonarroti works: the famous David and the “Prigione Barbuto”. In big marble statues, the large masses and shapes often cause high stresses in the material, especially in case of earthquakes or other vibrations. This can result in dangerous situations. Thus, non-destructive diagnostic investigations and continuous monitoring by means of minimally invasive, high sensitive and stable systems, able to give early warnings, become necessary. The David presents a severe crack pattern in the lower part of the legs. The cracks’ depths estimation, important for the structural analyses, has been carried out by means of ultrasonic tests, using properly developed and optimized procedures. A wide crack in the “Prigione Barbuto” has been monitored over two years with laser triangulation sensors. The crack pattern of the David is monitored by a fiber optic sensors FBG network, providing remotely recorded and processed information. The system is controlled by a “Smartbrick ®” device, which also measure vibration, inclination and changes in the environmental parameters. Fig. 1. Some structures recently surveyed: Ghirlandina tower and Modena Cathedral (UNESCO sites), Palazzina della Viola, Palazzo D’Accursio, San Barbaziano church (top); Palazzo Malvezzi, load tests on a ceiling, with details of traditional and wireless monitoring systems, and on a timber beam (bottom). Fig. 2. David and Prigione Barbuto at the Galleria dell’Accademia in Florence. Fig. 3. Ultrasound tests at the David and wireless monitoring of salt content in masonry. 179 Research Projects and Activities 2015 MAIN PUBLICATIONS Grosse C.U., Pascale G., Simon S., Krüger M., Troi A., Colla C., Rajčić V., Lukomski M., “Smart monitoring of historic structures - overview about a medium-scale research project in the EU 7th research Framework Programme”, International Workshop - SMW08, In Situ Monitoring of Monumental Surfaces, Florence, 27-29 October 2008, ISBN 978-88-7970-390-1. Ubertini F., Pascale G., de Miranda S., Colla C. “Monitoraggio intelligente di strutture storiche”. Atti del XIII Congresso dell’Associazione Italiana Prove non Distruttive Monitoraggio Diagnostica – AIPnD. Roma. 15-17 ott. 2009, IDN 83. Colla, C., Pascale, G., (2010), “Prove non distruttive e semidistruttive per la caratterizzazione delle murature della torre Ghirlandina di Modena”, in La torre Ghirlandina – storia e restauro, R. Cadignani (a cura di), Roma, pp. 218-227. Pascale G., Bastianini F., Carli R., “Monitoring marble cracking in the David by Michelangelo”, Proc. Art’11, 10th Int. Conf. on Non-Destructive Investigations and microanalysis for the diagnostics and conservation of cultural and environmental heritage, Florence, April 13th-15th, 2011, NDT44. Pascale G., Bastianini F., Colla C., Gabrielli E. “Diagnostica e monitoraggio dei beni culturali”, relazione su invito, XCVII Cong. Naz. SIF, Società Italiana di Fisica, L’Aquila, 26-30 sett.2011. Bastianini F., Sedigh S., Pascale G., Perri G., “Cost-Effective Dynamic Structural Health Monitoring with a Compact and Autonomous Wireless Sensor System”, Proc. of NDTMS-2011 Int. Symp. Nondestructive Testing of Mat. and Struct., Istanbul Tech. Univ., Turkey, May 15-18, RILEM Bookseries, 6, Springer 2012, ISBN: 978-94-0070722-1, pp. 1065-1070. Pascale G., Bastianini F., Lolli A., Carli R., Peddis F., Grossi S.. “Monitoraggio di stati fessurativi nelle grandi statue marmoree”, Conf. Naz. prove non distruttive monitoraggio diagnostica, 14° Congresso AIPnD, Firenze, 26-28 ottobre 2011. Colla C., Gabrielli E., Pascale G., Di Tommaso A., Ubertini F., “Masonry assessment for the seismic risk evaluation of historic structures”, 15th IB- 2MaC, 15th Int. Brick and Block Masonry Conf., Florianópolis, Brazil, June 3th-6th, 2012. Strojecki, M., Łukomski, M., Colla, C., Gabrielli, E., “Acoustic emission as a non-destructive method for tracing damage: from laboratory testing to monitoring historic structures”, Proc. of NDTMS-2011 Int. Symp. Nondestructive Testing of Mat. and Struct., Istanbul Tech. Univ., Turkey, May 15-18, RILEM Bookseries, 6, Springer, 2012, ISBN: 978-94-007-0722-1, pp. 1131-1136. Colla, C., et al., “Integrated approach for on-site assessment of conservation state of a historical masonry building: Malvezzi Palace, Italy”, Proc. of SAHC 2012, Structural analysis of historical constructions, Wroclaw, Poland, Oct. 15th -17th, 2012, ISBN 978-83-7125-216-7, pp. 2367-2375. Colla, C., Gabrielli, E., Krueger, M., Lehmann, F., Bastianini, F., “On-site loading test in the historic building of Malvezzi Palace, Bologna, Italy: experience integrating traditional measurements tools with wireless sensor systems”, Proc. of EWCHP 2012, Kjeller, Sept.24th-26th, 2012, ISBN 97882-425-2525-3, pp. 198-206. Pascale G., Lolli A., “Cracking assessment in the David by Michelangelo”, 5th Int. Conf. on NDT of HSNT - IC MINDT 2013, Athens, Greece, May 20-22, 2013. RESEARCH PROJECTS SMooHS – Smart Monitoring of Historical Structures, FP7-2008, Collaborative EU project. Project Ref.: 212939. Convenzione con la Fondazione “Friends of Florence” per il monitoraggio dello stato fessurativo presente nel Prigione Barbuto di Michelangelo presso la Galleria dell’Accademia di Firenze, 2007-2009. Convenzione con la Fondazione “Friends of Florence” per il monitoraggio dello stato fessurativo presente nel David di Michelangelo presso la Galleria dell’Accademia di Firenze, delle vibrazioni alla base e di altri parametri correlabili alla situazione statica dell’opera d’arte, 2009-2011. CONTACTS [email protected] [email protected] 180 Structures – New Materials and Special Structures EXPERIMENTAL INVESTIGATION AND MODELING OF PRECAST SYSTEMS RESEARCH GROUP: Andrea Benedetti, Claudio Mazzotti, Marco Savoia KEYWORDS: precast structure, experimental study, node panel, creep, bar anchorage In the last few years, precast construction systems for multi-storey buildings which include in-situ completion are becoming more and more common. They provide a certain degree of hyperstaticity and an adequate resistance to seismic actions to the structure. The research group is interested in the characterization of precast reinforced concrete structural elements such as beams, single- or multi-storey columns, columns anchored to the foundation, beam-column joints and sandwich panels, with regard to the serviceability and ultimate limit states. The research was carried out conducting lab tests on full-scale specimens and numerical models for the interpretation of the experimental results. The long-term behaviour and the evolution of the strain distribution in the various construction stages of precast reinforced concrete beams constructed by stages have been observed and a fibre model have been proposed to describe the long-term redistribution of stresses in the section. Tests on multi-storey precast columns with only longitudinal reinforcement in the node panel were conducted and a numerical model to predict the critical load was validated. Tests on the behavior of bars anchored in the foundation inside metal box, filled with high-performance mortar have been carried out considering monotonic and cyclic loads (pull-out tests on individual bars with different anchorage lengths and tests on RC columns, anchored in foundation, under cyclic bending and axial force) as well as tests for the evaluation of the cyclic behaviour of full-scale three and four way beam-column nodes. Currently the research group is also working on innovative wall systems made of concrete and weak reinforcement and on walls made of wooden blocks. Monotonic and cyclic tests have been conducted on full scale specimens in order to characterize the seismic behaviour also, as well as tests for the evaluation of the performance of thermal and acoustic insulation. The group is also working in collaboration with companies for the development of a dissipative beam-column connection for precast reinforced concrete structures designed without seismic criteria. 181 Fig. 1. Experimental set-up for creep test on precast beams. Fig. 2. Cyclic loading test on beam-column node in full-scale. Fig. 3. Dissipative beam-column connection for precast structures. Research Projects and Activities 2015 MAIN PUBLICATIONS Pollini A. V., Mazzotti C., Savoia M. (2013) Comportamento sperimentale e numerico di un sistema dissipativo per le connessioni di strutture prefabbricate. 15° Convegno ANIDIS,30/06-04/07/2013, Padova. Savoia M., Mazzotti C., Buratti N., Ferracuti B., Bovo M., Ligabue V., Vincenzi L. (2012) Damages and collapses in industrial precast buildings after the Emilia earthquake. Ingegneria Sismica 3-3, 120-131. Mazzotti C., Bacci L. (2012) Prove di pull-out su un sistema di ancoraggio per strutture prefabbricate. 19° Congresso C.T.E. 8-10/11/2012, Bologna. Bovo M., Mazzotti C. (2012) Indagini numeriche su nodi trave-colonna a tre vie per sistemi prefabbricati completati in opera. 19° Congresso C.T.E. 8-10/11/2012, Bologna. Bottoni M., Mazzotti C., Savoia M. (2008). Prove sperimentali a lungo termine su una trave prefabbricata realizzata in due fasi. 17° Congresso C.T.E. Roma. 5-8/11/2008 pp. 223-232. Benedetti A., Finotto E., Montesi M. (2007). Modellazione ad Elementi Finiti di Edifici a Struttura Prefabbricata in Zona Sismica, Atti del XII Convegno Nazionale L’Ingegneria Sismica in Italia, 1014/06/2007. Pisa, Italy. Vincenzi L., Mazzotti C., Savoia M., Ceccoli C., Ferrari M. (2007). Investigation of ultimate capacity of beam-column joints of precast system. Studies and Researches Vol. 27, pp. 93-116. Ceccoli C., Mazzotti C., Savoia M., Vincenzi L. e Ferrari M. (2007). Comportamento dei nodi del sistema di prefabbricazione APE, Industria della prefabbricazione, Vol. 13/2007, pp. 14-26. Vincenzi L., Mazzotti C., Ferrari M. (2011) Studio sperimentale-numerico di nodi trave-pilastro di sistemi a telaio prefabbricati. 24° Convegno ANIDIS, 18-22/09/2011, Bari. Ceccoli C., Mazzotti C., Savoia M., Vincenzi L., Ferrari M. (2006). Comportamento dei nodi del sistema di prefabbricazione Ape, 16° Congresso C.T.E., 9-11/11/2006, Parma. Mazzotti C., Vincenzi L. (2010) Experimental Investigation on a Beam-Column Node of a Multi-Story Precast RC System. 14th European Conference on Earthquake Engineering, 30/08/2010 - 3/09/2010, Ohrid, Republic of Macedonia. RESEARCH PROJECTS Mazzotti C., Savoia M., Ferrari M. (2010), Comportamento ciclico degli ancoraggi in fondazione di pilastri prefabbricati. 18° Congresso C.T.E. Brescia. 11-13/11/2010 pp. 1-10. Research Project with REGLASS (Minerbio - Bo) for the development of dissipative beam-column connections in precast reinforced concrete structures. Mazzotti C., Vincenzi L., Savoia M., Ferrari M. (2010), Comportamento di nodi trave-colonna di strutture parzialmente prefabbricate. 18° Congresso C.T.E. Brescia. 11-13/11/2010 pp. 1-10. Bottoni M., Mazzotti C. e Savoia M. (2009), Longterm experimental tests on precast beams completed with cast in situ concrete, European Journal of Environmental and Civil Engineering, 13(6), pp. 727744. Mazzotti C., Savoia M. (2008). A fiber model for the long-term behavior of reinforced concrete sections. Proceedings of the 8th international conference on Creep, Shrinkage and Durability Mechanics of Concrete and Concrete Structures. Ise-Shima, Japan. 30 September - 2 October, pp. 615-621. Research Project with APE (Montecchio Emilia RE) for the study of the mechanical behaviour of precast elements completed on site. Coordinator: Prof. Marco Savoia. Research Project with TERZER (Besenello - TN) for the characterization of the mechanical behavior and thermo-acoustic properties of walls made of wooden blocks. Research Project with ISOBLOC (Soragna - Pr) for the study of innovative block-formwork systems. 2010-2013: Research project funded by the Department of Civil Protection – Reluis, Task 2.1.1: Aspects on the seismic design of new buildings “Reinforced Concrete Structures” Coordinator: Prof. Spacone CONTACTS [email protected] [email protected] [email protected] 182 Structures – New Materials and Special Structures NUMERICAL AND EXPERIMENTAL CHARACTERIZATION OF THE INSTANTANEOUS AND LONG-TERM BEHAVIOR OF INNOVATIVE AND SUSTAINABLE CONCRETES RESEARCH GROUP: Nicola Buratti, Barbara Ferracuti, Claudio Mazzotti, Marco Savoia KEYWORDS: Fibres, FRC, SCC, cracking, long-term behaviour Fibre reinforced concretes are standard or high strength concretes to which steel, synthetic or natural fibres are added. The properties of this composite materials depend on the characteristics of the different components and on their dosages; in particular for a given percentage volume of fibres the most important parameters are the mechanical and geometrical properties of the fibres, and the fibre-concrete bond. As part of this research, experimental tests have been carried out in order to evaluate the flexural tensile strength of FRC prisms, the long-term behaviour of plain and self-compacting concrete reinforced with either steel or synthetic fibres, the effects of temperature and the durability in aggressive environments of FRC beams. The results of the experimental tests allowed to compare the behaviour, for ultimate and serviceability loads, of elements reinforced with different types of fibres. Using the experimental data gathered, different hinge-based and sectional models were developed to describe the short-term mechanical behaviour of the FRCs as well as constitutive inverse analysis procedures to define the constitutive relationships for the FRCs.The issue of evaluating the long-term behaviour of self-compacting concrete was also addressed as the higher amount of fines suggests the possibility of developing a greater deformation. Several experimental campaigns aiming at the study of both viscosity and shrinkage of SCC have been conducted. The development over time of both longitudinal and transverse deformation as well as other mechanical properties were measured and different stress levels were also considered. Based on the results obtained, a prediction model based on the Model Code 1990 was developed, modified by including the dependence on certain mix parameters and the development of resistance over time. SCC mixes were also used to cast beams in order to observe the development of deflection, the cracking behaviour with time and the residual strength at the end of the long-term loading. Current studies are mainly focused on the mechanical behaviour of SCC made with various types of fibres and recycling aggregates. Fig. 1. Long-term tests on cracked FRC beams. Fig. 2. Force-crack opening curves from threepoint bending tests. 183 Fig. 3. Development with time of viscosity for different SCCs. Research Projects and Activities 2015 MAIN PUBLICATIONS Manzi S., Bignozzi M. C., Mazzotti C. (2013) Short and long-term behavior of structural concrete with recycled concrete aggregate. Cement & Concrete Composites 37, 312-318. Buratti N., Ferracuti B., Savoia M. (2013) Concrete crack reduction in tunnel linings by steel fibre-reinforced concretes. Construction and Building Materials 44, 249-259. Mazzotti C., Savoia M. (2012) An Experimental Campaign on the Long-Term Properties of Self Compacting Concrete. Advances in Structural Engineering 15, No.7, 1155-1166. Buratti N., Mazzotti C. (2012) Effects of different types and dosages of fibres on the long–term be-haviour of fibre–reinforced self–compacting con-crete. 8th RILEM International Symposium of Fibre Reinforced Concrete, 19-21/09/2012, Guimaraes, Portugal. Buratti N., Mazzotti C. (2012) Temperature effect on the long term behaviour of macro–synthetic– and steel–fibre reinforced concrete. 8th RILEM International Symposium of Fibre Reinforced Concrete, 19-21/09/2012, Guimaraes, Portugal. Mazzotti C. (2011) Long term behavior of self-compacting concrete: comparison between exper-imental results and predicting models. 2nd Work-shop on The new boundaries of structural con-crete. 15-16/09/2011, Ancona, Italy. Buratti N., Mazzotti C., Savoia M. (2011). Post-cracking behaviour of steel and macro-synthetic fibre-reinforced concretes. Construction and Building Materials 25, 2713-2722. Buratti N., Mazzotti C., Savoia M. (2011). Long– term behavior of cracked SFRC elements exposed to chloride solutions. Advances in FRC Durability and Field Applications, 72-85. Buratti N., Mazzotti C., Savoia M. (2010). Longterm behaviour of cracked SFRC beams exposed to aggressive environment. 7th International Con-ference on Fracture Mechanics of Concrete and Concrete Structures (FRAMCOS), 23-28 May, Jeju, Corea del sud. Bottoni M., Mazzotti C., Savoia M. (2009) Long-term experimental tests on precast beams com-pleted with cast in situ concrete. European Journal of Environmental and Civil Engineering, 13(6), 727-744. Mazzotti C., Savoia M. (2009) “Long-term de-flection of reinforced Self Compacting Concrete beams”, ACI Structural J., 106(6), 772-781. Buratti N., Ferracuti B., Savoia M. (2009). Steel fibre reinforced concrete for crack control of tunnel linings. Advances in Reinforced Concrete and Precast Constructions, 103 - 112. Mazzotti C., Ceccoli C. (2008) Comparison between long term properties of self compacting concretes with different strength. SCC 2008, Oc-tober 2008, Chicago, USA. Mazzotti C., Ceccoli C. (2008) “Creep and shrinkage of self compacting concrete: Experi-mental behavior and numerical model. 8th Inter-national Conference on Creep, Shrinkage and Du-rability of Concrete and Concrete Structures, Sep-tember 2008, Ise-Shima, Japan. Mazzotti C., Savoia M. (2003) Non linear creep damage model for concrete under uniaxial compression, J. Eng. Mech. ASCE, 129(9), 1065-1075. Mazzotti C., Savoia M. (2002) Non-linear creep, Poisson’s ratio and creep-damage interaction of concrete in compression, ACI Material Journal, 99(5), 450-457, 2002. RESEARCH PROJECTS Research agreement with Consorzio Tecnico Produttori Fibre in Acciaio (Technical Consortium of Steel Fibre Producers) “Instantaneous and long-term behaviour of cracked FRC specimens: comparison between steel and macro-syntetic fibres”. Coordinator: Prof. Marco Savoia 2010-2013: Research project funded by the Department of Civil Protection - Reluis tasks 1 and 3: “Reinforced Concrete Structures”; “Development and analysis of new materials for seismic retrofit (including new concretes)”. Coordinators: Proff. G. Manfredi, L. Ascione CONTACTS [email protected] [email protected] [email protected] [email protected] 184 Structures – New Materials and Special Structures NUMERICAL MODELING AND EXPERIMENTAL TESTS FOR THE CHARACTERIZATION OF COMPOSITE MATERIALS RESEARCH GROUP: Andrea Benedetti, Barbara Ferracuti, Claudio Mazzotti, Marco Savoia KEYWORDS: FRP, FRCM, bond slip, fire, pultruded materials The research group conducts several experimental tests concerning the FRP-concrete bond behaviour and currently is also interested in the FRP-masonry bond behaviour (carrying out tests on bricks and walls). FRP plates and sheets, in various number of layers, of several widths and lengths and with different substrate surface preparation techniques have been considered, together with different test set-ups using traditional instrumentation as well as innovative optical techniques (Digital Image Correlation). The effects of aggressive agents and long-term loads have been considered investigating the FRP-concrete interface creep behaviour. The problem of fire resistance of the strengthening intervention has also been addressed, by testing the effectiveness of different methods of protection. Within the ReLUIS research project, the effect of cyclic loads was studied in order to verify the effectiveness of the strengthening of RC elements subjected to seismic loadings. As for the FRCMs, the group works on the definition of test standards and on the identification of failure mechanisms (for various types of fibers and matrices). The research group was involved in two national and international Round Robin Tests on bond and Proff. Savoia and Benedetti are part of the Committee which drafted the Guidelines CNR DT200/2004 “Istruzioni per la Progettazione, l’Esecuzione ed il Controllo di Interventi di Consolidamento Statico mediante l’utilizzo di Compositi Fibrorinforzati”. The group deals also with pultruded elements, addressing issues related to the development of computational models for the descriptions of the behavior of cellular and thin wall beam sections and has been investigating both experimentally and numerically the long-term behavior of pultruded elements under long-term loadings. Professor Savoia was part of the Committee which drafted the DT205/2007 “Istruzioni per la Progettazione, l’Esecuzione ed il Controllo di Strutture realizzate con Profili Pultrusi di Materiale Composito Fibrorinforzato (FRP)”, of National Research Council (CNR). Fig. 1. Experimental set-up for bond slip tests on FRP-concrete systems. Fig. 2. Numerical calibration of interface law with experimental test. Fig. 3. Experimental set-up for viscosity tests on pultruded materials. 185 Research Projects and Activities 2015 MAIN PUBLICATIONS Iovinella I., Prota A., Mazzotti C. (2013). Influence of surface roughness on the bond of FRP laminates to concrete. Construction and Building Materials 40, 533-542. Carloni C., Subramaniam K. V., Savoia M., Mazzotti C. (2012). Experimental determination of FRP– concrete cohesive interface properties under fatigue loading. Composite Structures 94, 1288-1296. M. Guadagnini, A. Serbescu, A. Palmieri, S. Matthys, A. Bilotta, E. Nigro, F. Ceroni, C. Czaderski, S. Olia, Z. Szabo, G. Balazs, C. Mazzotti (2012) Round Robin Test on the bond behaviour of externally bonded frp systems to concrete. Proceedings of CICE International Conference, 13-15 June 2012, Rome. Mazzotti C. (2011). The effect of the number of strengthening layers on the FRP-concrete bond behavior. European Journal Of Environmental And Civil Engineering 15, No. 9/2011, 1277-1296. Palmieri, S. Matthys, A. Seberscu, M. Guadagnini, J. Barros, I. Costa, A. Bilotta, F. Ceroni, E. Nigro, C. Czaderski, S. Olia, Z. Szabo, G. Balazs, G. Sas, B. Taljsten, C. Mazzotti, N. Taranu, V. Munteanu, V. Tamuzs (2011) Round Robin Testing Initiative for Fiber Reinforced Polymer (FRP) Reinforcement. FIB Symposium PRAGUE 2011, pages 1129-1132, 8-10 June, Prague single-shear set-up for stable delamination tests on FRP-concrete joints. Construction and Building Materials, Volume 23, Issue 4, April 2009: 1529-1537. Mazzotti C., Savoia M., Ferracuti B. (2008) An Experimental Study on Delamination of FRP Plates Bonded to Concrete. Construction and Building Materials, Volume 22, Issue 7, July 2008, Pages 1409-1421. Ferracuti B., Savoia M., Mazzotti C. (2007). Interface law for FRP-concrete delamination. Composite Structures, Volume 80, Issue 4: 523-531. Ferracuti B., Savoia M., Mazzotti C. (2006) A numerical model for FRP–concrete delamination. Composites Part B: Engineering, Vol. 37, Issues 4-5, June-July 2006: 356-364. Savoia M., Ferracuti B., Mazzotti C. (2005) Creep deformation of FRP- plated R/C tensile members. Journal of Composites for Construction, ASCE, Vol. 9, Issue 1: 63-72. Aprile A., Benedetti A. (2004) Coupled flexural-shear design of R/C beams strengthened with FRP. Composites Part B: Engineering, 35(1), 1-25. RESEARCH PROJECTS RILEM TC 234-DUC Committee “Design procedures for the use of composites in strengthening of reinforced concrete structures”: members Proff. Savoia and Mazzotti. Mazzotti C., Savoia M. 2009. FRP-concrete bond behaviour under cyclic debonding force. Advances in Structural Engineering, 12(6), 771-780. RILEM TC 223-MSC Committee “Masonry Strengthening with Composite materials”: member Prof. Mazzotti Mazzotti C., Savoia M. 2009, Stress redistribution along the interface between concrete and FRP subject to long-term loading, Advances in Structural Engineering, 12(5), 648-658. Research project with ARDEA and BASF for the study of crisis mechanisms of fiber-reinforced systems. Mazzotti C., Savoia M. 2009, Experimental tests on intermediate crack debonding failure in FRP-strengthened RC beams, Advances in Structural Engineering, 12(5), 625-637. Bottoni M., Mazzotti C., Savoia M. (2008) A finite element model for linear viscoelastic behaviour of pultruded thin-walled beams under general loadings. International Journal of Solids and Structures, 45(3-4), 770-793. Mazzotti C., Savoia M., Ferracuti B. (2008) A new 186 2010-2013: Research project funded by the Department of Civil Protection - Reluis tasks 1 and 3: “Reinforced Concrete Structures”; “Development and analysis of new materials for seismic retrofit (including new concretes)”. Coordinators: Proff. G. Manfredi, L. Ascione CONTACTS [email protected] [email protected] [email protected] [email protected] Structures – Damage and Fracture Mechanics ADVANCES MATERIALS AND SMART STRUCTURES RESEARCH GROUP: Giovanni Castellazzi, Stefano de Miranda, Elena Ferretti, Cristina Gentilini, Lucio Nobile, Giovanni Pascale, Francesco Tornabene, Francesco Ubertini, Erasmo Viola KEYWORDS: shape memory alloy, functionally graded material, FRP, multistable structure The research focuses on advanced ad-hoc developed formulations and numerical analysis for modeling the behavior of structural components constituted by innovative materials. Recently, a research line on morphing/bistable structures has been started in collaboration with the Department of Engineering at the University of Cambridge. Morphing structures can undergo large changes of shape without plastic deformations giving the potential for large improvement in cost, weight and reliability. Fig. 1. Piastra corrugata multistabile. The research touches numerical simulations for the analysis of shape and stiffness control of slender structures using shape memory alloys components. The following topics are under study: (1) functionally graded materials (FGM) plates; (2) interface behaviour in FRP reinforced structures; Fig. 2. Tronco-conical shell. (3) enhanced strength in FRP wrapped concrete columns. The flexural behaviour of concrete beams cracked and strengthened with fiber reinforced polymers has been studied based on fracture mechanics concepts. The dynamic behaviour has been investigated too, for estimating the variations due to cracking and subsequent strengthening on vibration modes, frequencies and damping; (4) multistable structures (corrugated plates); (5) finite element approaches for electroelasticity problems; Fig. 3. Variation through the thickness of the mechanical properties of a FGM plate. (6) finite element approaches for laminated composites. 187 Research Projects and Activities 2015 MAIN PUBLICATIONS G. Castellazzi, C. Gentilini, P. Krysl, I. Elishakoff. (2013) Static analysis of functionally graded plates using a nodal integrated finite element approach. Composite Structures, Vol. 103, pp. 197-200. F. Tornabene, E. Viola. (2013) Static Analysis of Functionally Graded Doubly-Curved Shells and Panels of Revolution. Meccanica, 48(4), 901-930. de Miranda S., Patruno L., Ubertini F. (2012). Transverse stress profiles reconstruction for finite element analysis of laminated plates. Composite Structures 94, 2706-2715. F. Tornabene, N. Fantuzzi, E. Viola, J.N. Reddy. (2013) Winkler-Pasternak Foundation Effect on the Static and Dynamic Analyses of Laminated Doubly-Curved and Degenerate Shells and Panels. Composites: Part B Engineering, doi: http://dx.doi.org/10.1016/j.compositesb.2013.06.020, In Press. F. Tornabene, E. Viola, N. Fantuzzi. (2013) General Higher-order Equivalent Single Layer Theory for Free Vibrations of Doubly-Curved Laminated Composite Shells and Panels. Composite Structures. Vol. 104(1), 94-117. F. Daghia, D.J. Inman, F. Ubertini, E. Viola. (2010) Active shape change of an SMA hybrid composite plate. Smart Structures and Systems, An International Journal. Vol. 6 (2), pp. 91-100. C. Gentilini, L. Nobile, K.A. Seffen. (2009) Numerical analysis of morphing corrugated plates. Procedia Engineering, Vol. 1 (1), pp. 79-82. C. Gentilini, K.A. Seffen, S.D. Guest, L. Nobile. (2008) On the effect of prestress on the bistable behaviour of tape-springs. Proceedings II AES-ATEMA International Conference on Advances and Trends in Engineering Materials and their Applications. Cesena, Italy, 1-5 September 2008. C. Gentilini, K.A. Seffen, S.D. Guest, L. Nobile. (2008) On the behaviour of corrugated plates in bending. Proceedings II AES-ATEMA Inter- national Conference on Advances and Trends in Engineering Materials and their Applications. Cesena, Italy, 1-5 September 2008. F. Daghia, S. de Miranda, F. Ubertini, E. Viola. (2008) A hybrid stress approach for laminated composite plates within the First-order Shear Deformation Theory. International Journal of Solids and Structures. Vol. 45, pp. 1766-1787. B. Bonfiglioli, A. Strauss, G. Pascale, K. Bergmeister. (2005) Basic study of monitoring on fibre reinforced polymers: theoretical and experimental study. Smart Materials and Structures. Vol. 14, pp. S12-S23. I. Elishakoff, C. Gentilini, E. Viola. (2005) Forced vibrations of functionally graded plates in three-dimensional setting. American Institute of Aeronautics and Astronautics Journal. Vol. 43, pp. 2000-2007. I. Elishakoff, C. Gentilini. (2005) Three-dimensional flexure of rectangular plates made of functionally graded. Journal of Applied Mechanics, Transactions ASME Vol. 72, pp. 788-791. I. Elishakoff, C. Gentilini, E. Viola. (2005) Three-dimensional analysis of an all-round clamped plate made of functionally graded materials. Acta Mechanica. Vol. 180, pp. 21-36. S. de Miranda, F. Ubertini. (2004) Consistency and recovery in electroelasticity. Part II: Equilibrium and mixed finite elements. Computer Methods in Applied Mechanics and Engineering. Vol. 193, pp. 2155-2168. RESEARCH PROJECTS Active and passive reinforcements by means of composites for the technologic innovation of the civil structures., PRIN2002 – Bologna Research Unit. Coordinator: Prof. G. Pascale. CONTACTS [email protected] [email protected] 188 Structures – Damage and Fracture Mechanics FRACTURE MECHANICS RESEARCH GROUP: Elena Ferretti, Cristina Gentilini, Lucio Nobile, Erasmo Viola KEYWORDS: stress intensity factors, piezoelectric materials This research line encompasses the development of numerical simulations for the analysis of cracked structural components. In particular, the research focuses on advanced ad-hoc developed formulations for modelling the behaviour of: • Cracked piezoelectric media. • Stress intensity factors. • Investigation on the behaviour of cracked beams within the stability framework. In particular, beams with one or more non-interacting edge-cracks are considered. The cracks are modelled as massless rotational springs. The spring constant is determined on the basis of the energy released due to the crack and by means of Castigliano’s theorem. This method has been employed to compute exact critical loads for a single cracked column with various end conditions and crack locations. Enforcing displacements, slope, moment continuity and additional conditions related to the presence of the cracks, analytical expressions for the characteristic equations are derived for different crackto-beam depth ratios, geometry and location of the cracks. • A new fatigue sensor called smart stress-memory patch, which can estimate the cyclic number, the stress amplitude and the maximum stress from the measurement of crack length and acoustic emission (AE), is proposed to evaluate the fatigue damage of such infrastructure as bridges and ships. Fig. 1. Specimen dimensions and loading arrangement. Fig. 2. Edge-cracked T beams. 189 Research Projects and Activities 2015 MAIN PUBLICATIONS Nobile L., Gentilini, C. (2011). On the evaluation of the energy release rate in edge cracked beams. Recent Patents on Mechanical Engineering 4, No. 3, 220-225. Boldrini C., Viola E. (2008). Crack energy density of a piezoelectric material under general electromechanical loading. Theoretical and Applied Fracture Mechanics 49, No. 3, 321-333. Viola E., Boldrini C., Tornabene F. (2008). Non-singular term effect on the fracture quantities of a crack in a piezoelectric medium. Engineering Fracture Mechanics 75, No. 15, 45424567. Carloni C., Nobile L., Gentilini C. (2007). Stability of multi-cracked beams. AES Technical Reviews, Part B: International Journal of Advances in Mechanics and Applications of Industrial Materials 1, 69-78. Piva A., Tornabene F., Viola E. (2007). Subsonic Griffith crack propagation in piezoelectric media. European Journal of Mechanics - A/Solids 26, No. 3, 440-457. Subramaniam K.V., Carloni C., Nobile L. (2007). Width effect in the interface fracture during shear debonding of FRP sheets from concrete. Engineering Fracture Mechanics 74, No. 4, 578-594. Viola, E. Belmonte C., Viola G. (2007). Lateral stress effect on fracture quantities in a piezoelectric medium. Key Engineering Materials 348349, 957-960. Carloni C., Gentilini C., Nobile L. (2006). Buckling of thin-walled cracked columns. Key Engineering Materials 324-325, 1127-1130. Carloni C., Gentilini C., Nobile L. (2006). Buckling of multicracked columns. Proc. XVI European Conference of Fracture. Alexandropuolus (Greece). 3-7 July. Piva A., Tornabene F., Viola E. (2006). Crack propagation in a four-parameter piezoelectric medium. European Journal of Mechanics - A/ Solids 25, No. 2, 230-249. Ricci P., Viola E., Di Leo A., Ferretti, E. (2006). Modelling and Analysis of Timoshenko Beams Weakened by Multiple Transverse Open Cracks. Proc. GIMC XVI, Bologna (Italy), 26-28 June. Nobile L., Carloni C. (2005). Fracture analysis for orthotropic cracked plates. Composite Structures 68, No. 3, 285-293. Piva A., Carloni C., Viola E., Ferretti E. (2002). Analysis of Mixed Mode Crack Initiation Angles for Orthotropic Material under Biaxial Loading. Proc. WCCM V. Vienna (Austria), 7-12 July. RESEARCH PROJECTS SMooHS – Smart Monitoring of Historical Structures, University of Bologna, European Research project ENV.2007.3.2.1.1. CONTACTS www.dicam.unibo.it/Centro-laboratori/lamc www.dicam.unibo.it/Ricerca/Centri/CIMEST [email protected] [email protected] 190 Structures – Damage and Fracture Mechanics DAMAGE MECHANICS RESEARCH GROUP: Elena Ferretti, Luisa Molari, Francesco Ubertini, Erasmo Viola KEYWORDS: effective stress-strain, SHM, fatigue damage, Smart Stress-Memory Patch Sensor The nucleation and growth of cracks can be described by continuum damage mechanics. An internal variable is included in the constitutive law to represent the evolution of microstructural damage. Damage degradation can manifest itself in progressive material softening, for which reason numerical results based upon classical continuum mechanics are characterised by a pathological mesh dependence: to avoid this regularised continuum models have been introduced. Among these are the strain gradient models. We address numerical issues associated with some strain gradient models. Numerical complication arises from the higher order character of the governing differential equations. A discontinuous Galerkin method has been developed. An alternative approach shows that nonlocal constitutive laws between stresses and strains are not strictly needed to construct a material model. They are required only if we use a differential formulation, in which the length scale is absent since the metric notions have been lost in performing the limit process. Also the effective law, which is a local constitutive law, is suitable for modelling nonlocal effects if used with a formulation which is nonlocal in itself, such as the Cell Method (CM) is. The research group has focused his attention both on static and dynamic analysis of damaged slender structures. A new fatigue sensor called Smart Stress-Memory Patch, which can estimate the cyclic number, the stress amplitude and the maximum stress from the measurement of crack length and acoustic emission (AE), is proposed for Structural Health Monitoring (SHM), to evaluate the fatigue damage of such infrastructure as bridges and ships. The fatigue crack growth behaviour of thin electrodeposited (ED) Cu specimen for this sensor is investigated. The modified stress intensity factor is proposed to introduce the master curve of fatigue crack growth, because the fatigue growth behaviour of this patch is affected by the maximum stress and the stress ratio. Fig. 1. FEM analysis of damage in three-point bending. Fig. 2. The CM compared to the differential formulation. 191 Research Projects and Activities 2015 MAIN PUBLICATIONS Ferretti E. (2013). A Cell Method Stress Analysis in Thin Floor Tiles Subjected to Temperature Variation. Proc. ICCES’13, International Conference on Computational & Experimental Engineering and Sciences. Seattle, USA. 24-28 May. Ferretti E. (2009). Ability of the Cell Method of modelling nonlocality. Invited lecture for the “ICCES / S. Ramanujan Young Investigator Award: Computation”. ICCES’09. Phuket (Thailand). 8-13 April. 30, 163-190. Ferretti E. (2009). Cell Method Analysis of Crack Propagation in Tensioned Concrete Plates. Computer Modeling in Engineering & Sciences 54, 253-282. Viola E., Marzani A., Hasan W. (2008). Stability maps of a cracked Timoshenko beam resting on elastic soils under sub-tangential forces. Key Engineering Materials 385-387, 465-468. Viola E., Ricci P., Aliabadi M.H. (2007). Free vibration analysis of axially loaded cracked Timoshenko beam structures using the dynamic stiffness method. Journal of Sound and Vibration 304, 124-153. Molari L., Wells G. N., Garikipati K., Ubertini F. (2006). A discontinuous Galerkin method for strain gradient-dependent damage: Study of interpolations and convergence. Computer Methods in Applied Mechanics and Engineering 195, 1480-1498. Ferretti E. (2005). A Local Strictly Nondecreasing Material Law for Modeling Softening and Size-Effect: a Discrete Approach. Computer Modeling in Engineering & Sciences 9, 19-48. Ferretti E. (2005). On Nonlocality and Locality: Differential and Discrete Formulations. ICF XI, 11th International Conference on Fracture. Turin (Italy). 20-25 March. Tornabene F., Viola E. (2005). The Effect of Cracks on the Dynamic Response of Circular Arches with Varying Cross-section by G.D.Q.E. Technique. Advances in Fracture and Damage Mechanics 4, 295-300. Viola E., Tornabene F. (2005). Vibration Analysis of Damaged Circular Arches with Varying Cross-section. Structural Integrity & Durability. 1, No. 2, 155-169. Ferretti E. (2004). A Discrete Nonlocal Formulation Using Local Constitutive Laws. International Journal of Fracture 130, L175-L182. Wells, G. N. Garikipati K., Molari L. (2004). A discontinuous Galerkin formulation for a strain gradient-dependent continuum model. Computer Methods in Applied Mechanics and Engineering 193, 3633-3645. Wells G.N., Garikipati K., Molari L. (2004). A continuous/discontinuous Galerkin formulation for strain gradient-dependent continuum models. Proc. of Symposium on Instabilities across the scales. Cairns, Queensland, Australia. 14-17 September. Wells G. N., Garikipati K., Molari L. (2004). A continuous/discontinuous Galerkin formulation for strain gradient-dependent damage model. Proc. 4th European Congress on Computational Methods in Applied Sciences and Engineering - ECCOMAS. Jyvaskyla, Finland. 24-28 July. RESEARCH PROJECTS SMooHS – Smart Monitoring of Historical Structures, Unità di Bologna, European Research project ENV.2007.3.2.1.1. A. Di Leo. (2006). Homogenization of elementary cells of masonry by means of the Cell Method, PRIN. Di Leo. (2004). Historical-monumental heritage: modelling and stochastic identification of damage and risk, PRIN. CONTACTS [email protected] [email protected] 192 Structures – Damage and Fracture Mechanics MONITORING AND MODELLING OF PROPAGATION PATHS IN CRACKED BRITTLE SOLIDS RESEARCH GROUP: Camilla Colla, Elena Ferretti, Giovanni Pascale, Erasmo Viola KEYWORDS: diagnostics, fracture mechanics, fracture propagation, FRP The monitoring of existing cracks can be performed by means of several non-destructive techniques. A part of the research activity has been dedicated to new techniques for SHM (structural health monitoring), with particular regard to the assessment of externally bonded FRP (fiber reinforced polymer) strengthening systems. The use of FOS (fiber optic sensors) has been taken into account, and some new applications have been developed. A ultrasonic technique has been proposed for detecting defects at the concrete-FRP interface. Defining the crack path numerically is not easy, due to several unknowns: if the direction of crack propagation can be computed by means of one of the existing criteria, it is not known whether this direction will remain constant during crack propagation. A crack initiation leads to an enhanced stress field at crack tip, which propagates into the solid during propagation, locally interacting with the pre-existing stress field. This interaction can lead to modifications of the propagation direction or crack arrest. A numerical code for use with the CM has been developed which returns accurate crack paths for brittle and non-brittle cracks. The CM code has been employed for modelling crack propagation in concrete and masonry. The main advantage of using the CM for numerical analyses of masonry is that mortar, bricks and interfaces between mortar and bricks can be modelled without any need to use homogenization techniques. The capability of the CM to handle domains with more than one material has been exploited to capture how the propagation direction changes when the crack overcome the joints or passes from the brick to the interface and to the mortar. The CM code is able to self-compute the position of crack initiation, manage several cracks propagating at the same time, take into account interactions between propagating cracks, self-estimate whether or not one or more cracks bifurcate and follow the propagation of each branch of bifurcation. Fig. 1. Tiles separation in radiant heat floors. Fig. 2. Stress field for masonry wall in shear-test. Fig. 3. Lok-Test on concrete. 193 Research Projects and Activities 2015 MAIN PUBLICATIONS Ferretti E. (2013). A Cell Method Stress Analysis in Thin Floor Tiles Subjected to Temperature Variation. Proc. ICCES’13, International Conference on Computational & Experimental Engineering and Sciences. Seattle, USA. 24-28 May. Daghia F., Giammarruto A., Pascale G. (2009). Monitoring with FBG to control cracking of R.C. structures before retrofitting. In Furuta, Frangopol & Shinozuka. Safety, Reliability and Risk of Structures, Infrastructures and Engineering Systems. LONDON: Taylor & Francis Group (UNITED KINGDOM). 10th International Conference on Structural Safety and Reliability ICOSSAR2009. Osaka. 13-17 September, 1-10. Ferretti E. (2009). Cell Method Analysis of Crack Propagation in Tensioned Concrete Plates. Computer Modeling in Engineering & Sciences 54, 253-282. Pascale G., Bastianini F. (2009). The role of quality control and of long-term monitoring in the structural applications of composite materials. In A. Di Tommaso. Meccanica delle strutture in muratura rinforzate con compositi. Bologna: Pitagora (Italy). Convegno Nazionale MURICO3 - Meccanica delle strutture in muratura rinforzate con compositi. Venezia. 22-24 April. 399-406. Ferretti E., Casadio E., Di Leo A. (2008). Masonry Walls under Shear Test: a CM Modeling. Computer Modeling in Engineering & Sciences 30, 163-190. Pascale G. (2008). Diagnostica ad ultrasuoni per l’edilizia: strutture civili, beni culturali. Pascale G. (2007). La valutazione del calcestruzzo nelle strutture esistenti. In Concreto 78, 64-73. Pascale G., Bonfiglioli B. (2006). Dynamic assessment of reinforced concrete beams repaired with externally bonded FRP sheets. Mechanics of Composite Materials 42, 1-12. Lanza di Scalea F., Rizzo P., Coccia S., Bartoli I., Fateh M., Viola E., Pascale G. (2005). Non-contact ultrasonic inspection of rails and signal processing for automatic defect detection and classification. Insight 47, No. 6, 346353. Strauss A., Bergmeister K., Bonfiglioli B., Pascale G. (2005). Basic Study of Monitoring with FRP. Smart Materials and Structures 14, S12-S23. Ferretti E. (2004). A Cell Method (CM) Code for Modeling the Pullout Test Step-Wise. Computer Modeling in Engineering & Sciences 6, 453-476. Ferretti E. (2004). Crack-Path Analysis for Brittle and Non-Brittle Cracks: a Cell Method Approach. Computer Modeling in Engineering & Sciences 6, 227-244. Stratford T., Pascale G., Manfroni O., Bonfiglioli B. (2004). Shear strengthening masonry panels with sheets. Journal of Composites for Construction 8, No. 5, 434-443. RESEARCH PROJECTS SMooHS – Smart Monitoring of Historical Structures, Unità di Bologna, European Research project ENV.2007.3.2.1.1. A. Di Leo. (2006). Homogenization of elementary cells of masonry by means of the Cell Method, PRIN. Di Leo. (2004). Historical-monumental heritage: modelling and stochastic identification of damage and risk, PRIN. CONTACTS [email protected] [email protected] www.dicam.unibo.it/DICAM/Risorse e strutture/Laboratori 194 Structures – Seismic Design Technologies SEISMIC ISOLATION SYSTEMS RESEARCH GROUP: Pier Paolo Diotallevi, Giada Gasparini, Luca Landi, Stefano Silvestri, Tomaso Trombetti KEYWORDS: base seismic isolation, HDRB isolator, application to existing buildings The use of innovative techniques as the insertion of isolators at the base seems to be a promising solution both for the control of seismic effects in new buildings and for the retrofit of existing buildings. For the latter case the objective of satisfying seismic requirements of new structures is often significantly onerous and prohibitive. This occurs especially in case of strategic buildings. The introduction of isolators at the base, as it is known, allows to reduce the accelerations in the structure by an increase of the fundamental period of the isolated structure and a concentration of seismic demand at the level of the isolators. The research works on seismic isolation have regarded in general the different typologies of isolation devices, the modeling of the devices, the design criteria and the applicative problems. A group of studies have been aimed to evaluate the effectiveness of seismic retrofit through insertion of high damping rubber bearings at the base. Once the isolation system has been designed, the response of the structure has been analyzed considering a 3D model characterized by variable parameters for the isolators and non-linear behaviour for the superstructure. In particular the effects on near-field earthquakes on the response of base-isolated buildings has been investigated and the possibility of using viscous dampers at the base to reduce these effects on isolators has been examined. These studies have been repeated also with reference of new buildings. The research group has also completed the study of few first applications of PBSD approaches for the seismic retrofits, using base isolators, of existing masonry structures, such as the ex-barracks Zucchi in Reggio Emilia within the bounds of the research project founded by the Italian Ministry of Research titled “Seismic protection of new and existing buildings” (1997), and the Teatro Galli in Rimini within the bounds of the research project founded by the Italian Ministry of Research titled “Seismic retrofit of monumental buildings with seismic isolation and innovative materials” (2000). Total number of publications: 15. Fig. 1. Rubber Bearing isolator. 195 Fig. 2. FEM model of the ex-barracks Zucchi in Reggio Emilia. Research Projects and Activities 2015 MAIN PUBLICATIONS Trombetti T., Ceccoli C., Polazzi D., Gasparini G., Silvestri S., “Sistemi di Isolamento Sismico per Edifici in Muratura secondo il Performance Based Design”, Memoria n. 390, Atti ANIDIS 2007, Pisa, 10-14 June 2007. P.P. Diotallevi, L. Landi, S. Benni. (2006). “Effect of near-fault ground motions on the response of base-isolated structures”, Proceedings of the 100th Anniversary Earthquake Conference Commemorating the 1906 San Francisco Earthquake, San Francisco, California, April 2006. P.P. Diotallevi, L. Landi, S. Benni. (2006). “Seismic isolation of RC structures subjected to nearfault ground motions”, Proceedings of the 1st European Conference on Earthquake Engineering and Seismology, Ginevra, Settembre 2006. Ceccoli C., Trombetti T., Polazzi D., Bergonzoni S., Silvestri S., Gasparini G., Monachesi A., “L’Isolamento Sismico del Teatro Galli di Rimini secondo la Metodologia del Performance Based Design. Parte I: Analisi del comportamento dinamico della struttura”, Convegno Conclusivo del Programma di Ricerca di Interesse Nazionale - COFIN 2000 dal titolo: “Adeguamento sismico di edifici monumentali tramite isolamento sismico e materiali innovativi”, coordinatore nazionale: Prof. Antonello De Luca (Università di Napoli Federico II), Napoli, 28 Febraury - 1 March 2003. Ceccoli C., Trombetti T., Polazzi D., Bergonzoni S., Silvestri S., Gasparini G., Monachesi A., “L’isolamento sismico del Teatro Galli di Rimini secondo la metodologia del Performance Based Design. Parte II: Risultati significativi”, Convegno Conclusivo del Programma di Ricerca di Interesse Nazionale - COFIN 2000, Napoli, 28 February-1 March 2003. P.P. Diotallevi, L. Landi, S. Benni. (2002). “Adeguamento sismico di una struttura in c.a. esistente mediante isolamento alla base: progettazione, modellazione ed analisi”, Atti del 14° Convegno CTE, Mantova, 7-9 Novembre 2002. Trombetti T., Ceccoli C., Silvestri S., “A Simplified Approach to the Analysis of Torsional Problems in Seismic Base Isolated Structures”, 1st Int.al Structural Engineering and Construction Conference (ISEC-01), Honolulu, Hawaii, January 2001. Ceccoli C., Diotallevi P. P., Trombetti T., Mazzotti C. Cosentino N., Savoia M., Tullini N. “Studio dell’isolamento di un edificio monumentale italiano: la ex Caserma Zucchi a Reggio Emilia”. Atti ANIDIS 1999, Torino, Italy, September 1999. Trombetti T. Ceccoli C., Sandrolini, F. Bignozzi M.C., Bravi B. “Ottimizzazione dello smorzamento nei sistemi di isolamento sismico alla base”. Atti ANIDIS 1999, Torino, Italy, September 1999. Ceccoli C., Cosentino N., Trombetti T. “L’isolamento degli edifici monumentali in presenza di sismi epicentrali” Atti ANIDIS 1999, Torino, Italy, September 1999. Ceccoli C., Trombetti T., Cosentino N. “Efficienza degli isolatori sismici HRDB per strutture in c.a. in presenza di sismi epicentrali”. 441 – 452. Atti del 12 Congresso CTE, Padova Novembre 1998. RESEARCH PROJECTS 2000-2002: Progetto di Ricerca di Interesse Nazionale 2000 (PRIN 2000, ex 40%): “Adeguamento sismico di edifici monumentali tramite isolamento sismico e materiali innovativi”; Coordinatore Scientifico: Prof. A. De Luca, Università “Federico II” di Napoli; Responsabile Scientifico Unità di Bologna: Prof. C. Ceccoli. 1997-1999: Progetto di Ricerca di Interesse Nazionale 1997 (PRIN 1997, ex 40%): “Protezione Sismica dell’edilizia esistente e di nuova edificazione”; Coordinatore Scientifico: Prof. A. De Luca, Università “Federico II” di Napoli; Responsabile Scientifico Unità di Bologna: Prof. C. Ceccoli; sottoprogetto: “Tecniche operative e metodi di analisi per l’isolamento sismico di edifici con l’impiego di HRDB”. CONTACTS [email protected] [email protected] 196 Structures – Seismic Design Technologies OPTIMAL INSERTION OF VISCOUS DAMPERS INTO STRUCTURES FOR THE MITIGATION OF THE SEISMIC EFFECTS RESEARCH GROUP: Pier Paolo Diotallevi, Giada Gasparini, Luca Landi, Stefano Silvestri, Tomaso Trombetti KEYWORDS: viscous dampers, shear-type structure, optimal sizing, practical design procedure Dissipative systems have widely proven to be able to effectively mitigate seismic effects on buildings. However, still the issue is open of how to insert viscous dampers into shear-type structure in order to reach the best dissipative performances of the dynamic system (structure + dampers). The researches carried out at the University of Bologna in the last few years have focused upon the search for the system of added viscous dampers capable of maximising its dissipative effectiveness taking into consideration at once all possible dampers sizing and placement. These researches were performed using both physically-based and numerically-based approaches and have indicated that the mass proportional damping (MPD) component of a Rayleigh damping systems (which is actually physically implementable through a damper arrangement that sees dampers (a) placed so that they connect each storey to a fixed point and (b) sized proportionally to each storey mass) is capable of providing the best overall dissipative properties. This suggests a new and efficient way of inserting viscous dampers in structures to be built in seismic areas, which is alternative to the common (and less efficient) interstorey damper placement. Also, a practical 5-step procedure has been developed for the seismic design of building structures equipped with viscous dampers, which aims at providing practical tools for an easy identification of the mechanical characteristics of the manufactured viscous dampers which allow to achieve target levels of performances. The group has also developed simplified formulas (in terms of reduction factors for the earthquake forces) for the seismic design of structures which exploit the combined effects of viscous and hysteretic dissipation, as provided by dampers and by post-yielding behavior of the structural members, respectively. Some other studies regarded finally the use of dampers in the seismic retrofit of existing RC buildings and the proposal of simplified design criteria for nonlinear fluid-viscous dampers. Fig. 1. Viscous damper in diagonal bracing system. 197 Fig. 2. Effectiveness of damper systems in shear-type structures. Fig. 3. Ratio between force reductions factors a30 = R30/R5 as a function of period and ductility demand. Research Projects and Activities 2015 MAIN PUBLICATIONS Palermo M., Silvestri S., Trombetti T., Landi L. (2013) Force reduction factor for building structures equipped with added viscous dampers, Bull Earthquake Eng 11, DOI 10.1007/ s10518-013-9458-z. Palermo M., Muscio S., Silvestri S., Landi L., Trombetti T. (2013) On the dimensioning of viscous dampers for the mitigation of the earthquake-induced effects in moment-resisting frame structures, Bull Earthquake Eng 11, DOI 10.1007/s10518-013-9474-z. Diotallevi, P. P., Landi, L., Dellavalle, A. (2012). “A methodology for the direct assessment of the damping ratio of structures equipped with nonlinear viscous dampers”. Journal of Earthquake Engineering, vol. 16(3), pp. 350-373, ISSN: 1363-2469. Silvestri S., Gasparini G., Trombetti T., (2011). Seismic design of a precast r.c. structure equipped with viscous dampers. Earthquake and Structures, Vol. 2 (3), pp. 297-321. Trombetti T., Gasparini G., Silvestri S., “Two-storey pre-cast reinforced concrete structure equipped with viscous dampers: a case study”, Proceedings of “The third International Conference on Structural Engineering, Mechanics and Computation SEMC2007”, Cape Town, South Africa, 10-12 September 2007. Trombetti T., Silvestri S., “On the modal damping ratios of shear-type structures equipped with Rayleigh damping systems”, Journal of Sound and Vibration, Vol. 292(2) (2006), pp. 21-58. Gasparini G., Silvestri S., Trombetti T., “Optimal insertion of viscous dampers into torsionally coupled structures”, Paper No. 949, Proceedings of the “First European Conference on Earthquake Engineering and Seismology”, Geneva, Switzerland, 3-8 September 2006. Trombetti T., Silvestri S., “Added viscous dampers in shear-type structures: the effectiveness of mass proportional damping”, Journal of Earthquake Engineering, Vol. 8, No. 2 (2004), pp 275313. Silvestri S., Gasparini G., Trombetti T., “A FiveStep Procedure for the Dimensioning of Viscous Dampers to Be Inserted in Building Structures”, Journal of Earthquake Engineering, Vol. 14(3) (2010), pp 417-447. Silvestri S., Trombetti T., Ceccoli C. Inserting the Mass Proportional Damping (MPD) system in a concrete shear-type structure. Structural Engineering and Mechanics, Vol. 16(2) (2003), 177-193. P.P. Diotallevi, L. Landi, A.Busca. (2008). “Seismic assessment of an existing RC hospital building: study for the rehabilitation with supplemental fluid-viscous dampers”, Proceedings of the 14th World Conference on Earthquake Engineering, Beijing, China, 12-17 October 2008. RESEARCH PROJECTS Trombetti T., Silvestri S., “Novel schemes for inserting seismic dampers in shear-type structures based upon the mass proportional component of the Rayleigh damping matrix”, Journal of Sound and Vibration, Vol. 302, No. 3 (2007), pp 486-526. Silvestri S., Trombetti T., “Physical and numerical approaches for the optimal insertion of seismic viscous dampers in shear-type structures”, Journal of Earthquake Engineering, Vol. 11, No. 5 (2007), pp. 787-828. Progetto RELUIS Linea 7: “Tecnologie per l’isolamento ed il controllo di strutture ed infrastrutture” (Progetto Esecutivo 2005-2008); Coordinatori: Prof. M. Dolce e Prof. G. Serino; Responsabile della ricerca per l’Unità di Ricerca di Bologna: Prof. M. Savoia. Progetto RELUIS2, Area Tematica 2, Linea di Ricerca 3, Task 2: “Sviluppo ed analisi di nuove tecnologie per l’adeguamento sismico” (Progetto Esecutivo 2010-2013); Coordinatori: Prof. L. Ascione e Prof. G. Serino; Responsabile della ricerca per l’Unità di Ricerca di Bologna: Prof. T. Trombetti. CONTACTS [email protected] 198 Structures – Seismic Design Technologies EXPERIMENTAL RESEARCH UPON LARGE LIGHTLY-REINFORCED CONCRETE WALLS RESEARCH GROUP: Giada Gasparini, Stefano Silvestri, Tomaso Trombetti KEYWORDS: large lightly-reinforced concrete walls; wood-concrete caisson blocks; pseudo-static tests Buildings made up of reinforced-concrete walls represent a structural typology which has been widely used in economic public housing. Such building structures characterised by small wall-thickness (15-25 cm) and by small percentage values of steel reinforcement have shown excellent strength resources even against strong earthquake ground motions: the structural overstrength allows to reduce the ductility demand. However, still few experimental and analytical studies have been performed up to now with the aim of evaluating the ultimate (near-collapse) seismic performances of buildings realised using large lightly-reinforced concrete walls. The research group has recently organised, designed and interpreted (by means of appropriately-developed analytical models capable of capturing the experimental behaviour) a series of experimental tests with cyclic horizontal loading and shaking table tests (conducted at the laboratory of the European Seismic Centre EUCENTRE in Pavia) upon a peculiar typology (with non-returnable block-formwork) of lightly reinforced concrete walls. Due to the peculiar conformation of the block-formwork, the structural wall so-obtained is characterised by the presence of lightening alveolar zones. Inside the blocks, before casting the concrete, appropriate horizontal and vertical reinforcement steel bars are placed, so that the structural walls is actually a reinforced-concrete wall. To obtain an adequate characterisation of the seismic behaviour (stiffness, strength, ductility) of such walls, experimental pseudo-static tests with constant vertical loading and increasing horizontal loading have been carried out both upon single walls and upon a H-shaped 2-storey structural system. The results obtained show a good ductile behaviour, yielding horizontal loads comparable with applied vertical loads, and the maintenance of strength to vertical loads after damaging. Total number of publications: 20 Fig. 1. Examples of solutions for reinforced-concrete walls. Fig. 2. Results of experimental tests with cyclic horizontal loading. Fig. 3. Shaking-table tests upon a full-scale 3-storey building. 199 Research Projects and Activities 2015 MAIN PUBLICATIONS Ricci I., Palermo M., Gasparini G., Silvestri S., Trombetti T. (2013) “Results of pseudo-static tests with cyclic horizontal load on cast in situ sandwich squat concrete walls”, Engineering Structures 54: 131-149, DOI 10.1016/j.engstruct.2013.03.046. T. Trombetti, S. Silvestri, G. Gasparini, I. Ricci, S. Ivorra, D. Foti (2013). Preliminary results of a shaking table tests on a 3-story building realized with cast in place sandwich squat concrete walls, ISEC-7, Honolulu, June 18-23, 2013. S. Ivorra, B. Ferrer, D. Foti, L. Stempniewski, T. Trombetti, S. Silvestri, G. Gasparini, I. Ricci, A. Catalini, C.M. Campian, D. Malavolta, Final Report - SE. SI. CO. WA. Project, December 2012. T. Trombetti, S. Silvestri, G. Gasparini, I. Ricci, S. Ivorra, D. Foti (2012). Shaking table tests on a 3-storey building specimen composed of castin-situ concrete walls, 15th World Conference on Earthquake Engineering, Lisbon, Portugal, 2428 September 2012. T. Trombetti, S. Silvestri, G. Gasparini, I. Ricci, S. Ivorra, D. Foti (2011). Progettazione di una prova su tavola vibrante di un edificio a tre piani in scala reale costituito da pareti sandwich in c.a. gettato in opera, XIV Convegno Nazionale “L’Ingegneria Sismica in Italia” ANIDIS 2011, Bari, 19-22 Settembre 2011. Trombetti T., Silvestri S., Gasparini G., Ricci I., “Results of pseudo-static tests with cyclic horizontal load on concrete/polystyrene sandwich bearing panels”, Atti del Convegno “Le Nuove Frontiere del Calcestruzzo Strutturale”, Università degli Studi di Salerno – ACI Italy Chapter, 22-23 Aprile 2010. Trombetti T., Silvestri S., Gasparini G., Ricci I., “Correlations between the experimental results of pseudo-static tests with cyclic horizontal load on concrete/polystyrene sandwich bearing panels and their analytical counterparts”, Atti “Le Nuove Frontiere del Calcestruzzo Strutturale”, Università di Salerno – ACI Italy Chapter, 2223 Aprile 2010. Ricci I., Gasparini G., Silvestri S., Trombetti T., “Correlations between the experimental results of pseudo-static tests with cyclic horizontal load on concrete/polystyrene sandwich bearing panels and their analytical and numerical counterparts”, Proc. “Sustainable Development Strategies for Constructions in Europe and China”, Roma, Italy, April 19-20, 2010. Ricci I., Malavolta D., Gasparini G., Silvestri S., Trombetti T., Ceccoli C., “Risultati di prove sperimentali pseudo-statiche con carico orizzontale ciclico effettuate su pannelli “sandwich” in conglomerato cementizio debolmente armato” articolo ID401 (S5.7) negli Atti ANIDIS 2009, Bologna, 28 Giugno-2 Luglio 2009. Ricci I., Malavolta D., Gasparini G., Silvestri S., Trombetti T., Ceccoli C., “Interpretazione dei risultati di prove sperimentali pseudo-statiche con carico orizzontale ciclico effettuate su pannelli “sandwich” in conglomerato cementizio debolmente armato” articolo ID402 (S5.8) Atti ANIDIS 2009, Bologna, 28 Giugno-2 Luglio 2009. Gasparini G., Trombetti T., Silvestri S., Ceccoli C., Malavolta D., “Results of “pseudo-static” tests with cyclic horizontal load on r.c. panels made with wood-concrete caisson blocks”, Paper 12-03-0054. Proceedings of the 14th World Conference on Earthquake Engineering (14WCEE), Beijing, China, 12-17 October 2008. RESEARCH PROJECTS Convenzione C&P Costruzioni – DISTART. Responsabile scientifico: Prof. Claudio Ceccoli. Convenzione Nidyon Costruzioni – DISTART. Responsabile scientifico: Prof. Claudio Ceccoli. Progetto di ricerca SERIES (2010-2011): “Seismic behavior of structural systems composed of cast in situ concrete walls”, EUCENTRE TREES Lab facility (Pavia, Italy), Lead User: Prof. Salvador Ivorra Chorro, University of Alicante, Responsabile Unità di Bologna: Prof. Tomaso Trombetti. CONTACTS [email protected] 200 Structures – Advanced Analysis Tools for Earthquake Engineering DEVELOPMENT AND APPLICATIVE EXAMPLES OF PERFORMANCE BASED SEISMIC DESIGN AND DISPLACEMENT BASED DESIGN APPROACHES RESEARCH GROUP: Andrea Benedetti, Pier Paolo Diotallevi, Giada Gasparini, Luca Landi, Stefano Silvestri, Tomaso Trombetti KEYWORDS: Performance Based Seismic Design (PBSD), Displacement Based Design (DBD), case-studies In recent years innovative methodologies have been proposed for the seismic design of building structures, such as Performance Based Seismic Design (PBSD) and Displacement Based Seismic Design (DBD). The core idea of the PBSD (PEER, Vision 2000, California) resides in the capacity of defining and satisfying a number of given performance objectives (association of a structural performance level to an earthquake design level). The new concept introduced by the DBD (Priestley and Calvi) lies in the development of a design method based upon the displacements (instead upon the forces). The research group has carried out a comprehensive and complete study of few first applications of PBSD approaches for the seismic retrofits of existing masonry structures (the Palazzo della Civiltà Italiana in Roma Eur). Some of the studies performed by the group have been aimed to the validation of the DBD methodology developed by Priestley and Calvi with reference to new and existing RC structures. Within the related research projects a collaboration is activated for the preparation of a model code and examples. Moreover extensions of the DBD procedure have been proposed for asymmetric structures and infilled RC frames. The research group is currently developing an innovative approach for the optimal seismic design of structures which encompasses recent scientific contributions in the field. This approach (stiffness-strength-ductility design, SSDD) : (1) defines a set of desired performance objectives for the structure; (2) obtains, assuming a splitting between the lateral- and the vertical-resisting systems and imposing the performance objectives, the characteristics (in terms of stiffness, strength and ductility) of the lateral resisting-system (realised using special bracing elements called “crescent shaped braces”); and (3) checks the satisfaction of the performance objectives by means of non-linear dynamic analyses. Total number of publications: 42. Fig. 1. Displacement spectrum. Fig. 2. FEM model of the Galli Theatre. Fig. 3. F-delta curve of the performance objectives in a SSDD approach. 201 Research Projects and Activities 2015 MAIN PUBLICATIONS Benedetti A., Landi L., Merenda D.G. (2013) A displacement-based method for the retrofit of existing masonry Structures with ADAS dampers and external concrete walls, Fourteen International Conference on Advances and Trends in Engineering Materials and their Applications. Paparo A., Landi L., Diotallevi P.P. (2012). Extension of Direct Displacement-Based Design to Plan-Asymmetric RC Frame Buildings. Journal of Civil Engineering and Architecture. vol. 6 (10), pp. 1280 - 1291 ISSN: 1934-7359. Ricci I., Gagliardi S., Gasparini G., Silvestri S., Trombetti T., Palermo M. (2012). First-Storey Isolation Concept for Multi-Performance Seismic Design of Steel Buildings. Proceedings of the 15th World Conference on Earthquake Engineering. Lisbon, Portugal, Paper n. 3028. Landi L., Diotallevi P.P., Tardini A. (2012). Equivalent Viscous Damping for the Displacement-Based Seismic Assessment of Infilled RC Frames. Proc. of the 15th World Conference on Earthquake Engineering. Lisbon, Portugal. Ceccoli C., Trombetti T., Biondi. D. (2011). Structural evaluation of the Palazzo della Civilta` Italiana in Rome. Structure and Infrastructure Engineering. vol. 7, pp. 147-162 ISSN: 1573-2479 Trombetti T., Gasparini G., Silvestri S., Ricci I.. (2011). Use of Crescent Shaped Braces for Controlled Seismic Design of Ductile Structures. Journal of Civil Engineering and Architecture. vol. 5 (8), pp. 562-574 ISSN: 1934-7359. Trombetti T., Ceccoli C., Gasparini G., Silvestri S., “Seismic Analysis for the Structural Retrofit of “Palazzo della Civiltà Italiana” in Rome EUR, Italy” Advanced Materials Research, Vols. 133134 (2010) pp 753-758, (2010) Silvestri S., Gasparini G., Ricci I., Trombetti T., “An Application of a Proposed Stiffness-Strength-Ductility Design Approach to a Five-storey Steel Building Structure”, Paper ID 626, Proceedings of the EARTH & SPACE CONFERENCE 2010, Honolulu, Hawaii, March 14-17, 2010. Trombetti T., Silvestri S., Gasparini G., Ricci, I., “Stiffness-Strength-Ductility-Design Approaches for Crescent Shaped Braces”, The Open Construction and Building Technology Journal, Vol. 3 (2009), pp 127-140. Gasparini G., Silvestri S., Trombetti T., Ceccoli C., “Reinforcement design of the “Filetto” Bridge on the Santerno River near Bologna, Italy”, Proceedings of 5th New York City Bridge Conference, New York, USA, 17-18 August, 2009. Trombetti T., Silvestri S., Gasparini G., “Stiffness-Strength-Ductility Design Approaches”, Keynote lecture. Proceedings of AES - ATEMA’ 2008, 2nd International Conference on Advances and Trends in Engineering Materials and their Applications, Cesena, Italy, 1-5 September 2008. Pages 121-125. ISBN 0-9780479. Ceccoli C., Trombetti T., Polazzi D., Bergonzoni S., Silvestri S., Gasparini G., Monachesi A., “Un Esempio Completo di Applicazione della Metodologia del Performance Based Design: l’Isolamento Sismico del Teatro Galli di Rimini. Parte I: Analisi del comportamento dinamico della struttura”, Memoria n. 393, Atti ANIDIS 2007”, Pisa, 10-14 June 2007. RESEARCH PROJECTS Research Project RELUIS Line 4: “Development of displacement based approaches for the design and vulnerability evaluation” (Executive Project 2005-2008); National Coordinators: Prof. Calvi e Prof. Priestley; Chief-responsible for the Bologna Research Unit (Unit n. 2): Prof. A. Benedetti; task: “Reinforced concrete frame structures”. Progetto RELUIS2, Linea 2: “Development of displacement based approaches for the vulnerability evaluation” (Executive Project 20102013); National Coordinators: Prof. G. M. Calvi e Prof. T. J. Sullivan; Chief-responsible for the Bologna Research Unit (Unit n. 2): Prof. A. Benedetti; task: “Reinforced concrete structures with and without masonry infills”. CONTACTS [email protected] [email protected] 202 Structures – Advanced Analysis Tools for Earthquake Engineering MODELS AND PROCEDURES FOR THE NONLINEAR SEISMIC ANALYSIS OF RC STRUCTURES RESEARCH GROUP: Pier Paolo Diotallevi, Barbara Ferracuti, Luca Landi, Marco Savoia KEYWORDS: global models, fibre models, nonlinear dynamic analysis, RC structures, nonlinear static analysis The research group is involved in the development of new analytical models and in the implementation of original computer programs for the nonlinear static and dynamic analysis of reinforced concrete (RC) structures. The prediction and the control of the inelastic response represent, indeed, fundamental elements of the seismic design. The research started with the realization of a new global model based on the subdivision of the elements in segments. A moment-curvature law for cyclic loading has been introduced for the control sections. The model has been extended in order to include the effects of changing axial forces on the moment-curvature relationship. Subsequently it has been proposed a new fibre model based on the flexibility approach, able to account for the nonlinear flexural-shear interaction of RC members. For the concrete fibres a biaxial constitutive relationship based on MCFT theory has been introduced. Both models have been validated through comparisons with available experimental results. The models have been then applied for studying various aspects of the nonlinear seismic response of RC structures. The pushover analysis, that is a non-linear static analysis performed by applying lateral forces gradually increasing up to collapse, may provide an alternative both to conventional linear methods and to more complex methods based on non-linear dynamic analyses. The pushover techniques require particular attention with regard to some aspects, as the evaluation of seismic demand and the definition of a proper distribution of lateral forces. In particular, several numerical investigations have been performed in order to evaluate the effectiveness of standard procedures, based on single invariant load distributions, and advanced procedures. Among these, the study have examined the multi-modal procedure, aimed to include higher mode effects, and the adaptive procedures, aimed to account for the variation of lateral load vector in the inelastic range. The effectiveness has been evaluated through the comparison with non-linear dynamic analyses with reference to regular and irregular structures in elevation and in plan. Total number of publications: 42 Fig. 1. Spread plasticity model with degradation. Fig. 2. Fibre model. Fig. 3. Adaptive pushover analysis. 203 Research Projects and Activities 2015 MAIN PUBLICATIONS Landi, L., Tardini, A., Diotallevi, P.P. (2013). Nonlinear seismic analysis of infilled RC frames with an equivalent strut model. 4th ECCOMAS Thematic Conference on Computational Methods in Structural Dynamic and Earthquake Engineering COMPDYN. Kos Island, Greece. the 1908 Messina and Reggio Calabria Earthquake, 08-11 July 2008. B. Ferracuti, M. Savoia, R. Pinho (2008). Force/ Torque Pushover Method For Plan Irregular Structures. Nonlinear Static Methods for Design/ Assessment of 3D Structures. R. Bento & R. Pinho (Eds.) 5-6 May 2008 Lisbon, Portugal. B. Pollio, P. P. Diotallevi, L. Landi. (2011). A modal combination method for multi-modal pushover analysis. Proceedings of the 2011 World Congress on Advances in Structural Engineering and Mechanics. (ASEM). Seoul, Korea. 18-22 September, pp. 5752-5762. R. Pinho, B. Ferracuti, M. Savoia, R. Francia (2007). Validation of non-linear pushover analyses by Statistical Incremental Dynamic Analysis (S-IDA). Computational Methods in Structural Dynamics and Earthquake Engineering, COMPDYN, 13-16 June 2007. P.P. Diotallevi, L. Landi, C. Gianni. (2010). “Effectiveness of 3D multi-modal pushover for plan-asymmetric RC frames”. Proceedings of the 14th European Conference on Earthquake Engineering, Ohrid, Republic of Macedonia, August 30-September 03, 2010. P.P. Diotallevi, L. Landi. (2006). “Response of RC structures subjected to horizontal and vertical ground motions”, Proceedings of the 100th Anniversary Earthquake Conference Commemorating the 1906 San Francisco Earthquake, San Francisco, California, April 2006. B. Ferracuti, R. Pinho, M. Savoia, R. Francia (2009). Verification of Displacement-based Adaptive Pushover through multi-ground motion incremental dynamic analyses. Engineering Structures, Volume 31, Issue 8 (2009), pp. 1789-1799. P.P. Diotallevi, L. Landi. (2000). “Effect of the axial force and of the vertical ground motion component on the seismic response of RC frames”. Proceedings of the 12th World Conference on Earthquake Engineering, Auckland, New Zealand, 30 January-4 February 2000. F. Biserna, B. Ferracuti, M. Savoia, R. Pinho (2009). Distributed and lumped-plasticity approaches for modeling RC frame structures under seismic action. Atti del XIII Convegno Nazionale L’Ingegneria Sismica in Italia, ANIDIS. Bologna. 28 Giugno-2 Luglio 2009. P. P. Diotallevi, L. Landi, B. Pollio, (2008). “Evaluation of conventional and advanced pushover procedures for regular and irregular RC frames”, Proceedings of the 14th World Conference on Earthquake Engineering, Beijing, China, 12-17 October 12-17, 2008. P.P. Diotallevi, L. Landi, F. Cardinetti. (2008). “A fibre beam-column element for modelling the flexure-shear interaction in the non-linear analysis of RC structures”. Proceedings of the 14th World Conference on Earthquake Engineering, Beijing, China, 12-17 October 2008. P.P. Diotallevi, L. Landi, F. Cardinetti. (2008). “Influence of shear in the non-linear analysis of RC members”. Proceedings of the 2008 Seismic Engineering International Conference commemorating P.P. Diotallevi, L. Landi. (1998). “About influence of axial force on the non linear seismic response of R/C frame”. Proceedings of the 11th European Conference on Earthquake Engineering, Paris, 6-11 September 1998. RESEARCH PROJECTS National Research Project PRIN ex 40%: “The safety of reinforced concrete structures under seismic actions with reference to design criteria of resistance to collapse and damage limitation of Eurocode 8” – Research Unit of Bologna: “Study of the effect of axial loads on the seismic behaviour of RC frames designed with Eurocode 8”, Chief-responsible for the Bologna Research Unit: Prof. Pier Paolo Diotallevi; National Coordinator: Prof. A. Castellani, 1999-2001. Eucentre Research Project “Seismic Risk”. CONTACTS [email protected] [email protected] 204 Structures – Advanced Analysis Tools for Earthquake Engineering ANALYSIS OF THE TORSIONAL EFFECTS INDUCED BY THE SEISMIC ACTION IN PLAN ASYMMETRIC STRUCTURES RESEARCH GROUP: Giada Gasparini, Stefano Silvestri, Tomaso Trombetti KEYWORDS: plan asymmetric structures, maximum rotational response, seismic excitation Structures characterized by not coincident centre of mass and centre of stiffness (eccentric structures) when subjected to dynamic excitation, develop a coupled lateral-torsional response that may increase the local peak dynamic response. This behaviour has been investigated by many researchers since the late 1970s. Nevertheless a number of issues still remain unresolved in the areas of inelastic response and development of simplified, yet physically-based design procedures. In particular, in order to effectively apply the Performance-Based Design approach to seismic design, there is a growing need for code oriented methodologies aimed at predicting deformation parameter. Starting from the governing equations of motion of linear elastic eccentric systems, a key system parameter which controls the maximum rotational response of such systems under free and forced vibration, is identified. This parameter, called ALPHA, is defined as the mass radius of gyration of the structure multiplied by the ratio of the maximum rotational to the maximum longitudinal displacement response developed by a one-story eccentric system in free vibration. A number of numerical, experimental (through shaking table tests of linear elastic and inelastic systems) and field data (from historically recorded structural responses) analyses have shown that the parameter ALPHA is capable of providing a tight upper bound for the maximum rotational response developed by the eccentric systems starting from the knowledge of the maximum longitudinal response of the “equivalent” non-eccentric system. Total number of publications: 30. Fig. 1. Plan asymmetric structure. 205 Fig. 2. Predictive capabilities of the ALPHA parameter. Fig. 3. Maximum corner displacement magnification with respect to centre mass displacement of the centre mass displacement of the equivalent not-eccentric system. Research Projects and Activities 2015 MAIN PUBLICATIONS Palermo M., Silvestri S., Gasparini G., Trombetti T. (2013) “Physically-based prediction of the maximum corner displacement magnification of one-storey eccentric systems”, Bull Earthquake Eng 11, DOI 10.1007/s10518-013-9445-4. Trombetti T., Silvestri S., Gasparini G., Palermo M. (2013), “Physically Based Prediction of the Maximum Corner Displacement of One-Storey Eccentric Systems”, Chapter 10, in O. Lavan, M. De Stefano (Eds.), Seismic Behaviour and Design of Irregular and Complex Civil Structures. Series: Geotechnical, Geological and Earthquake Engineering, Vol. 24, 2013, XIV, 374 p. 206 illus., 91 illus. in color. ISBN: 978-94-007-5376-1 (print), 978-94-007-5377-8 (ebook). Trombetti T., Palermo M., Silvestri S., Gasparini G. (2012). Period Shifting Effect on the Corner Displacement Magnification of One-Storey Asymmetric Systems. Proceedings of the 15th World Conference on Earthquake Engineering. Silvestri S., Gasparini G., Trombetti T., “Maximum seismic rotational response of multi-storey structures”, Proc. SEMC 2010, Cape Town, South Africa, September 6-8, 2010. Gasparini G., Silvestri S., Orci C., Trombetti T., “A synthetic formulation for evaluating the maximum displacement of the corner points in eccentric structures due to the seismic effects” Paper n. 212b, Proceedings of 5th International Structural Engineering and Construction Conference – ISEC5 – Las Vegas, Nevada, USA, September 21-27, 2009. Gasparini G., Silvestri S., Trombetti T., “A simple code-like formula for estimating the torsional effects on structures subjected to earthquake ground motion excitation”, Paper 05-01-0269. Proceedings of the 14th World Conference on Earthquake Engineering (14WCEE), Beijing, China, 12-17 October 2008. Silvestri S., Trombetti T., Gasparini G., “An upper bound and an estimation for the maximum non-linear rotational response of one-storey asymmetric buildings”, Proc. of the 5EWICS, Catania, Italy, 16-17 September 2008. Pg 51-62. Silvestri S., Trombetti T., Gasparini G., “Closedform solutions for corrective eccentricity, sensi206 tivity to accidental eccentricity and increase in peak local displacements”, Proc. of the 5EWICS, Catania, Italy, 16-17 September 2008. Pg 63-77. Trombetti T., Silvestri S., Gasparini G., Pintucchi B., De Stefano M., “Numerical verification of the effectiveness of the “ALPHA” method for the estimation of the maximum rotational response of eccentric systems”, Journal of Earthquake Engineering, Vol. 12, No. 2 (2008), pp 249-280. Gasparini G., Silvestri S., Trombetti T., “A synthetic parameter capable of capturing the torsional behaviour of one-storey asymmetric structures”, Paper n. 1282, Proceedings of the 100th Anniversary Earthquake Conference, EERI’s Eight U.S. National Conference on Earthquake Engineering, 8NCEE, 18-22 April 2006. Trombetti T.; Conte J.P. (2005). New Insight Into and Simplified Approach to Analysis of Laterally-Torsionally Coupled One-Story Systems. Journal of Sound and Vibration. Gasparini G., Silvestri S., Trombetti T., Pintucchi B., De Stefano M., “A genetic approach for the optimal insertion of viscous dampers into torsionally coupled structures”, Proceedings of the 4EWICS, Thessaloniki (Greece), 26-27 August 2005. Pintucchi B., De Stefano M., Gasparini G., Silvestri S., Trombetti T., “Numerical verification of the effectiveness of the “alpha method” for the estimation of the maximum rotational response of eccentric systems”, Proceedings of the 4EWICS, Thessaloniki (Greece), 26-27 August 2005. Gasparini G., Trombetti T., Silvestri S., Ceccoli C., “Predictive capabilities of the alpha method: shaking table tests and field data verification”, Proceedings of the “13th World Conference on Earthquake Engineering”, 13WCEE, Vancouver, B.C., Canada, 1-6 August 2004, Paper No. 472. RESEARCH PROJECTS Research project RELUIS Line 2: “Evaluation and reduction of vulnerabilità of existing RC buildings.” (Executive Project 2005-2008); National Coordinators: Prof. E. Cosenza and Prof. G. Monti; Chief-Responsible for the Bologna Research Unit: Prof. A. Benedetti. CONTACTS [email protected] Transportation Infrastructures and Transports Transportation Infrastructures and Transports – Materials for Roads, Railways and Airports INNOVATIVE MATERIALS FOR PAVEMENTS IN TRANSPORTATION INFRASTRUCTURES RESEARCH GROUP: Giulio Dondi, Andrea Simone, Cesare Sangiorgi, Valeria Vignali, Matteo Pettinari, Claudio Lantieri, Pierpaolo Viola, Francesco Mazzotta, Piergiorgio Tataranni, Luca Noferini KEYWORDS: pavements, recycling, scrap tires (PFU), construction and demolition waste (C&D) The growing global awareness on the reduction of impacts on the environment is directing the research towards the use of eco-friendly materials also in the field of transportation infrastructures. Sustainability applied in this field to the design and production of construction materials, finds its basis in the recycling of resources that, otherwise, will be dumped. Transportation infrastructures offer a number of possibilities to the recycling processes, both for what concerns the recycling of the pavement materials themselves and for the use, in the structural layers, of recycled material coming from other activities, in particular the construction and demolition (C&D) one and the reclamation of scrap tires (PFU) one. Simultaneously, the environmental preservation in the construction of pavements is carried out also through the use of production and construction technologies with low energy consumptions or, in any case, with reduced environmental impact in its broad sense. In this direction it is spreading the use of cold mixed asphalt concretes (Cold mixes) and AC produced at intermediate temperatures (Warm mixes). The DICAM Roads proposes researches addressed to Management Authorities and Companies that operates in the transportation infrastructures field, providing solutions aimed to the production of recycled and reduced consumption materials with high mechanical performances and low environmental impact. The study started some years ago and has lead to the definition of admixtures to be successfully adopted in the construction and maintenance of transportation pavements. These innovative materials have equivalent or better performances when compared to traditional materials. In the adverse economic circumstance for Public Authorities, the proposal of an alternative structural solution with low environmental impact and good performances, to be adopted for new constructions and maintenance interventions, seems to be definitely valid from the environmental and technical point of view. Fig. 1. Fatigue testing on recycled material. Fig. 2. Comparing volumes of sand and substituting rubber in bituminous specimens. 209 Fig. 3. SEM Image of a bituminous cold mix with crumb rubber particle. Research Projects and Activities 2015 MAIN PUBLICATIONS Pettinari M., Dondi G., Sangiorgi C., Petretto F. (2013) The Use of Cryogenic Crumb Rubber in the Cold Recycling Technique. Proceedings of the 2013 Airfield and Highway Pavement Conference: Sustainable and Efficient Pavements. T&DI and ASCE Conference. Pp. 1088-1099. Los Angeles 9-12 June 2013. ISBN 978-07844-1300-5. Dondi G., Pettinari M., Sangiorgi C., Wu R. (2012). Designing long life pavements including eco-friendly ACs by means of the Mechanistic-Empirical approach. SIIV-5th International Con-gress - Sustainability of Road Infrastructures. Rome 29-21 October 2012. Procedia - Social and Behavioral Sciences. Vol 53. Pp. 1162-1172. ISSN 1877-0428. Pettinari M., Sangiorgi C., Dondi G. (2012). Fa-tigue resistance of Warm Mix Asphalt and Rubber Asphalt Concrete with the Dissipated Energy Approach, Proceedings 7th International confer-ence on maintenance and rehabilitation of pave-ments and technological control, MAIREPAV7, Auckland, New Zealand, 28-30 August 2012 Simone A., Lantieri C., Vignali V. (2012). A new “Frugal” approach to road maintenance: 100% recycling of a deteriorated flexible pavement, Proceedings 7th International conference on maintenance and rehabilitation of pavements and technological control, MAIREPAV7, Auckland, New Zealand, 28-30 August 2012 Pettinari M., Wu R., Simone A. (2010). Perfor-mance evaluation of Eco-friendly asphalt concrete using the Mechanistic Empirical method, Poster session at the Fourth European As- phalt Technology Association EATA Conference, 15-16th June 2010 Parma, Italy. Oliveira J.R.M., Sangiorgi C., Fattorini G., Zoorob S.E. (2009). Investigating the Fatigue Performance of Grouted Macadams, ICE Transport, Vol.162, Issue TR2, pp. 1115-123, 2009. ISSN 0965-092X. A. Cocurullo, G.D. Airey, A.C. Collop, C. San-giorgi. (2008). Indirect Tensile versus Two Point Bending Fatigue Testing. ICE Transport, Vol.161, Issue TR4, pp. 207-220, 2008. ISSN 0965-092X. RESEARCH PROJECTS Research Project Agreement between DICAM and Frantoio Fondovalle srl. Cold Recycling of C&D and rubber waste materials: development of ad hoc solutions for the factory production. Year 2013. Research Project Agreement between DICAM and Ecopneus scpa. Cold recycling of aggregates with rubber from scrap tires. Year 2012. Research Project Agreement between DICAM and Consorzio cave Bologna Soc.Coop. Adding value to waste materials in construction resources. Year 2012. Joint Research Project DICAM, Valli Zabban SpA, Elletipi srl and UC Berkeley. Using the energetic approach for the analysis of fatigue test results on modified warm mix asphalts. Year 2010. CONTACTS [email protected] [email protected] [email protected] [email protected] 210 Transportation Infrastructures and Transports – Materials for Roads, Railways and Airports FLEXIBLE PAVEMENT SIMULATION WITH DISTINCT PARTICLE ELEMENT METHOD RESEARCH GROUP: Giulio Dondi, Andrea Simone, Cesare Sangiorgi, Valeria Vignali, Matteo Pettinari, Claudio Lantieri, Francesco Mazzotta KEYWORDS: Asphalt pavement, Rheology, Asphalt Concrete, Asphalt mastic, DEM Road pavement performances are still not fully understood because it has been necessary to simplify its materials behavior, modeling them as continuous. In reality, however, they exhibit discontinuous performances, which do not always fit for the advanced continuum models. Numerous research works, in fact, show that for these types of mixtures it is very important to take into consideration their micromechanical behavior, at the scale of an aggregate particle, because this is an essential factor in terms of overall system performance. To overcome this limitation, the Distinct Particle Elements Method (DEM), which schematizes a granular material by means of particles that displace independently from one another and interact only at contact points, becomes a good answer. In this way, in fact, is possible to analyze the discrete character of mixes through a microscopic approach. The aim of the research is the microscale DEM analysis of the interaction between aggregates, bitumen and filler and the evaluation of its influence on the macroscale performances of the asphalt mixture. The obtained results in previous research works have permitted to evaluate that DEM approach, allowing a very reliable description of real phenomena, represents a valid evolution of the traditional methods in the simulation of the visco-elastic behavior of asphalt mixtures both for small samples during laboratory tests, and for flexible pavements and theirs fatigue performances. Using the DEM method, moreover, a “virtual laboratory” could be created to study the details of asphalt mixtures that cannot be measured in conventional laboratory tests. With the advancement in computer speed and storage capacity, this approach could be an inexpensive tool to provide a precise control of every variable being studied. Once the model is calibrated, it could be used to run as many simulations as required. In time, therefore, these models could provide a crucial missing link for the development of true performance-related specifications for asphalt pavements. Fig. 1. DEM approach for asphalt concrete simulation. Fig. 2. 3D DEM simulation of a flexible pavement - contact forces inside the layers produced by road traffic. Fig. 3. 3D DEM simulation of a Dynamic shear rheometer test on a bitumen sample. 211 Research Projects and Activities 2015 MAIN PUBLICATIONS Dondi G., Simone A., Vignali V. and Manganelli G. (2012). Numerical and experimental study of granular mixes for asphalts. Powder Technology 232, 31-40. Dondi G., Simone A., Vignali V. and Manganelli G. (2012). Discrete element modelling of influences of grain shape and angularity on performance of granular mixes for asphalts, Procedia - Social & Behavioral Sciences. 53, 399-409. Dondi G., Simone A., Vignali V. and Manganelli G. (2012). Discrete particle element analysis of aggregate interaction in granular mixes for asphalt: combined DEM and experimental study, Proceedings of 7th RILEM International Conference on Cracking in Pavements, Delft, The Netherlands, ISBN 978-94-007-4565-0. Dondi G., Simone A. and Vignali V. (2010). Micromechanical modelling of aggregate–aggregate interactions with distinct particle element method for virtual laboratory simulation. Proceedings of the 11th International Conference on Asphalt Pavement. Nagoya. Dondi G., Bragaglia M. and Vignali V. (2008). Evoluzione dei criteri di calcolo delle pavimentazioni flessibili: i modelli particellari. Atti del XVII Convegno Nazionale SIIV “Le reti di trasporto urbano. Progettazione, costruzione, gestione”. Enna (CT). Edizioni Caracol (ITALY). ISBN 978-88-89440-40-7. Dondi G., Bragaglia M. and Vignali V. (2007). Flexible pavement simulation with distinct particle element method. Proceedings of the 4th In- ternational SIIV Congress “Advances in transport infrastructures and stakeholders expectations”. Palermo (ITALY). PALERMO Grafill (ITALY). ISBN: 139788882072605. Dondi G. and Bragaglia M. (2006). Modellazione ad elementi distinti particellari della prova ITSM. Atti del XVI Convegno Nazionale SIIV. Arcavacata di Rende (CS). Centro Editoriale e Librario (ITALY). ISBN: 88-7458-050-9. Dondi G., Vignali V. and Bragaglia M. (2006). Modellazione mediante elementi distinti particellari delle prove sui materiali granulari. Atti del XVI Convegno Italiano Di Meccanica Computazionale. Bologna. ISBN 88-371-1621. Dondi G., Bragaglia M. and Vignali V. (2005). Bituminous Mixtures Simulation With Distinct Particle Elements Method. Proceedings of the 3rd International SIIV Congress. Bari, Italy. RESEARCH PROJECTS PRIN 2007. Advanced Numerical Techniques for Perpetual Pavement Modelling. Chief researcher: Prof. Ing. E. Santagata, Politecnico di Torino. Operative Units: Università di Bologna (Ref: Prof. Ing. A. Simone), Università Politecnica delle Marche, Università di Parma, Università di Pisa. CONTACTS [email protected] [email protected] [email protected] [email protected] 212 Transportation Infrastructures and Transports – Safety and Management of Road Infrastructures ANALYSIS OF SURFACE CHARACTERISTICS AND MAINTENANCE TECHNIQUES FOR ROAD AND AIRPORT INFRASTRUCTURES RESEARCH GROUP: Giulio Dondi, Andrea Simone, Cesare Sangiorgi, Valeria Vignali, Claudio Lantieri, Matteo Pettinari, Federico Irali, Riccardo Lamperti KEYWORDS: Mobile Mapping System, Laser Scanner, Texture, Damage, Maintenance Knowing the state of the pavement is required in order to establish a maintenance strategy within the Pavement Management System, which optimizes the available resources, ensuring the maintenance of given standards. In this context, the activity of the research group covers two main themes: (1) the assessment of the pavement conditions: the goal is to develop high performance methods for the characterization of the road geometry and for the evaluation of the state of damage. For this purpose, some research projects are underway both on roads and on runways by using the Mobile Mapping System (MMS) for the measurement of many geometric parameters such as profile, sections, the assessment of longitudinal and cross slopes, the identification of deterioration and for the calculation of status indicators such as PSI and PCI or similar. Other ongoing studies have been started to define new methods for the detection of the skid resistance of surfaces. In particular, the objective is the use of a high precision laser scanning system, a type with triangulation, to analyze the texture of the road surface, obtaining the morphology of the surface of areal basis in addition to the traditional profilometry. (2) the maintenance of the infrastructure: the purpose is the development of innovative maintenance allowing an easy reinstatement and a quick opening to traffic. Specifically, the ongoing studies focus on: (a) solutions for the functional recovery of the skid resistance through cold laid microsurfacings containing rubber powder which also have the purpose of reducing noise emissions; (b) solutions for the maintenance works on urban underground networks, including both methods for the prequalification of materials, and techniques for laying and the control of trench reinstatement. These activities are supported by agreements in place at the DICAM and collaborations with the Universities of Belfast, Nottingham and Delft. Fig. 1. MMS application: laser scanning. Fig. 2. Cold laid micro-surfacing. Fig. 3. Laser scanning of pavement texture. 213 Research Projects and Activities 2015 MAIN PUBLICATIONS Sangiorgi C., Bitelli G., Lantieri C., Girardi F., Irali F. (2012). A study on texture and acoustic properties of cold laid Microsurfacings, 5th International Congress Sustainability of Road Infrastructures, Rome, Italy 29-31 October 2012, Procedia Social and Behavioral Sciences Volume 53, 3 October, Pages 223–234 - ISSN 1877-0428. Simone A., Lantieri C., Vignali V., Bitelli G. , Girardi F. (2012). 3D Laser Scanner Technique for in situ analysis of road pavement surface texture, 7th International conference on maintenance and rehabilitation of pavements and technological control, Auckland, New Zealand, 28-30 August 2012. Bitelli G., Simone A., Girardi F., Lantieri C. (2012). Laser scanner on road pavements: a new approach for characterizing surface texture, Sensors, 12(7), 9110-9128; mazione professione, Portonovo, Ancona, 22-24 Giugno 2011 - ISBN 978-88-905917-2-3. Dondi G., M. Barbarella M., Sangiorgi C., Lantieri C., De Marco L. (2011). A semi-authomatic methodology to identify defects on a road surface”, International Conference on Sustainable Design and Construction, March 23–25, Hyatt Regency Crown Center Hotel, Kansas City, Mo. Dondi G., Simone A., Lantieri C., Vignali V. (2010). Characterization of pavement surface texture using 3D Laser scanner technique, Proceedings of the 11th International Conference on Asphalt Pavement, august 1-6, Nagoya, Japan. Simone A., Bitelli G., Girardi F., Lantieri C. (2009). Caratterizzazione di superficie e tessitura del manto stradale mediante tecniche a scansione laser. Bollettino della Società Italiana di Fotogrammetria e Topografia, n°3. RESEARCH PROJECTS Sangiorgi C., Lantieri C., Volta E., Irali, F., Campesato M. (2012). Microtappeti a freddo multifunzionali, La Rassegna del Bitume n°7012 anno 2012, pp. 27-35 ISSN 1723-2155. Research Project Agreement between DICAM and Società Strada dei Parchi S.p.A. Maintenance of the A25 motorway Torano-Avezzano. Year 2013. Sangiorgi C., Lantieri C., Volta E., Irali, F. (2012) “Microtappeti multifunzionali contro il rumore stradale”, (n. 1475) Le Strade n°3 anno CXIV, Marzo 2012, pp. 90-96, ISSN 0373-2916; Research Project agreement between DICAM and SAVE S.p.A. Upgrading of the infrastructures of the Venice Marco Polo Airport. Year 2013. Dondi G., Burchi A. (2011). Il PMS sostenibile per le pubbliche amministrazioni. Le Strade, n. 10, ISSN 0373-2916, pp. 100-104. Barbarella M., Dondi G., Gandolfi S., Lantieri C., CSangiorgi. (2011). Rilievo geometrico e caratterizzazione degli ammaloramenti stradali mediante uso di Mobile Mapping Systems, Proceedings Convegno nazionale SIFET Applicazioni interdisciplinari della geomatica: ricerca, for- Research Project Agreement between DICAM and SITECO Informatica s.r.l. Study of a decision support system for scheduled maintenance of roads. Year 2010. CONTACTS [email protected] [email protected] [email protected] [email protected] 214 Transportation Infrastructures and Transports – Safety and Management of Road Infrastructures ROAD SAFETY DESIGN AND HUMAN FACTOR INTERACTION RESEARCH GROUP: Giulio Dondi, Andrea Simone, Cesare Sangiorgi, Valeria Vignali, Claudio Lantieri, Riccardo Lamperti KEYWORDS: Road Safety, Human Factor, Driver psychology, Self-Explaining Roads, Workload management Road safety depends on the integrated and complex relationship between various components: the driver’s psychology, the traffic, the vehicle, the environment and the road infrastructure. The human element is certainly the most vulnerable, but also the most flexible, in any decision-making process. Road users try to do their best but the task is complex and the environment is not designed to prevent errors occurring this research starts from a different perspective. We believe that in many cases the design of the environment can be further adjusted to human capabilities. The central theme of this study is to estimate how design principles can reduce the probability of errors while driving. In order to study the driver-road interaction we assess the looking behaviour using a mobile eye tracker. Specifically, the ongoing studies focus on: (a) the role of vertical traffic signs in influencing driving and the study of new engineering solutions to make traffic signs more conspicuous; (b) the transition zones between rural and urban areas and the study of the most common safety measures such as “town gate”, constituted by a restriction of the carriageway with appropriate vertical and horizontal signs; (c) the understanding of the risks associated with roadside advertising in its various guises so that informed guidelines for the regulation of such advertising can be formulated. The actual road design standards focus mainly on motorized traffic from a historical point of view, some more “human behavior” and less car- oriented tools for infrastructure safety design are the main aim of this research. Together with the car drivers, the pedestrians, the bike riders, the Powered Two Wheelers users and all the unprotected road users are carried into the focus of concern. These activities are supported by agreements in place at the DICAM and collaborations with the Psychology Department of the University of Bologna. Fig. 1. Mobile Eye-XG glasses for examination of human eye movement and pupil dynamicsinstallation. Fig. 2. Mobile Eye-XG glasses for examination of human eye movement and pupil dynamicsoutput. Fig. 3. “Town gate” in the transition zone between rural and urban areas. 215 Research Projects and Activities 2015 MAIN PUBLICATIONS Costa M., Simone A., Vignali V., Lantieri C., Bucchi A., Dondi G. (2013). Looking behaviour for vertical road signs, manuscript under review Accident Analysis & Prevention, Manuscript Number: AAP-D-13-00501. Dondi G., Lantieri C., Vignali V., Manganelli G. (2012). Effects of Flickering Seizures on Road Drivers and Passengers, 5th International Congress Sustainability of Road Infrastructures, Rome, Italy 29-31 October 2012, Procedia Social and Behavioral Sciences Volume 53, 3 October 2012, Pages 712-721 - ISSN 1877-0428. Bucchi A., Sangiorgi C., Vignali V. (2012). Traffic psychology and driver behaviour, 5th International Congress Sustainability of Road Infrastructures, Rome, Italy 29-31 October 2012, Procedia Social and Behavioral Sciences Volume 53, 3 October 2012, Pages 973-980 - ISSN 1877-0428. Dondi G., Simone A., Lantieri C., Vignali V. (2011). Bike lane design: the Context Sensitive Approach, Procedia Engineering , vol. 21, pp. 897-906, ISSN: 1877-7058. Bonivento C., Dondi G., Paoli A., Sartini M., Simone A. (2011). Modular model building for vehicular traffic systems with macroscopic dynamics, 18th IFAC World Congress, August 28 - September 2, 2011, Milano, Italy. IFAC Papers OnLine, World Congress, Volume # 18 | Part# 1, ISSN 1474-6670. Bucchi A., Lantieri C. (2011). Introduzione alla psicologia del traffico, Strade e Autostrade, n°1-2011, n. 85 Anno XV, ISSN 1723-2155, pp. 150-156. Dondi G., Simone A., Marinelli M. (2010). Capitolo 5 – Compatibilità di motocicli e moderazione del traffico (traffic calming) in ambito urbano– pp. 71-104 - Monografia “Tecniche di moderazione del traffico: linee guida per l’applicazione in Italia” a cura di Giulio Maternini e Silvia Foini– Volume XIV Collana “Tecniche per la sicurezza in ambito urbano” – direttore Prof. Roberto Busi – egaf edizioni – Forlì, Ottobre 2010 – ISBN 978-88-8482-364-9. Dondi G., Vignali V. (2010). Capitolo 8 – Tecniche per la messa in sicurezza delle fermate del TPL – pp. 131-154 - Monografia “Linee guida per la realizzazione delle fermate del trasporto pubblico locale” a cura di Giulio Maternini e Silvia Foini – Volume XIII Collana “Tecniche per la sicurezza in ambito urbano” – direttore Prof. Roberto Busi – egaf edizioni – Forlì, Ottobre 2009 – ISBN 978-88-8482-301-4. Dondi G., Vignali V., Simone A., Lantieri C. (2008). Capitolo 10 – Assetto degli elementi marginali, zone di sicurezza e letti di arresto – pp. 243-270 - Monografia “Progettazione e gestione degli spazi esterni alla carreggiata” a cura di Giulio Maternini e Silvia Foini– Volume XII Collana “Tecniche per la sicurezza in ambito urbano” – direttore Prof. Roberto Busi – egaf edizioni – Forlì, Ottobre 2008 –ISBN 978-88-8482-272-7. Simone A., Vignali V., Marinelli M. (2007). Intersection design and powered two wheelers interaction: experimental investigation of an accident prediction model, Proceedings 4th International SIIV Congress – Palermo (ITALY), 12-14 September 2007 – ISBN 13-978-88-8207-260-5. Bucchi A., Biasuzzi K., Simone A. (2004). Evaluation of Design consistency: a new operating speed model for rural roads with different grades, (invited paper) Proceedings 2nd International SIIV Congress – Firenze, 27-29 ottobre 2004 – ISBN 888-4532-698. Simone A. (2002). Road Design and Human Factor Interaction, Human Factors in Transportation, Communication, Health and the Workplace, D. de Waard, K.A. Brookhuis, C.M. Weikert, and A. Toffetti Editors, Maastricht, the Netherlands; Shaker Publishing, pp. 205-208, ISBN 90-423-0206-2. RESEARCH PROJECTS Research Project Agreement between DICAM and Provincia di Bologna Road Administration. Road safety analysis of the Province Road N.610 “Selice Montanara”. Year 2013. CONTACTS [email protected] [email protected] [email protected] [email protected] 216 Transportation Infrastructures and Transports – Materials for Roads, Railways and Airports INNOVATIVE PAVEMENT DESIGN FOR URBAN HISTORICAL CENTER AND AIRPORTS RESEARCH GROUP: Giulio Dondi, Andrea Simone, Cesare Sangiorgi, Valeria Vignali, Claudio Lantieri, Riccardo Lamperti, Francesco Mazzotta KEYWORDS: pavements, design, airport, urban historical areas, traffic vibration, warm mix asphalt, cold mixtures Pavement performance requirements have been progressively evolving, both in terms of quantity and quality, because of changing users’ demands. Particularly, other aspects have become important in the last decades: besides bearing capacity, skid resistance and evenness, the acoustic and vibration pollution caused by road traffic was taken in consideration. Road infrastructure designers and constructors should mainly be oriented to a search for adequate design criteria and constructive technologies aimed at guaranteeing a reduction in these harmful undesired events. Vibration phenomena produced by road traffic are very interesting in terms of induced annoyance in the human body and in buildings, especially in urban historical areas. An accurate study of vehicle-pavement-building interaction thus becomes a primary requirement (Fig. 1). By means of a finite differences technique, the research group developed a numeric analysis in order to evaluate the propagation and reduction of traffic-induced vibration (Fig. 2). The awareness of the Performance-related Specifications importance has nationally and internationally widespread in the last few years for airport pavement design, but the actual employment of these needs has not. Hence, most of the national Specifications are still Requirement-related without taking into account the pavement serviceability life. This research proposes the use of new procedures and techniques for the surfacings characterization on the basis of the Performance-related procedures already employed in the Italian Specifications. In particular, Gyratory Compactor, ITSM, ITFT, Shear Bond Test and Thermography techniques are suggested for assessing respectively asphalt volumetric mix-design properties, asphalt fatigue fracture and dynamic properties, surfacings bonding properties and binder thermal properties. The obtained results provided also valuable indications for the development of new specifications and Performance-related Airport design procedures (Fig. 3). Fig. 1. Innovative anti-vibration pavement in the historical center of Demonte (CN). Fig. 2. The FD building and damping mat pavement model. Fig. 3. The rigid pavement of the Venice Airport. 217 Research Projects and Activities 2015 MAIN PUBLICATIONS Simone A., Pettinari M., Sangiorgi C., Wu R. (2012). Performance Evaluation Of Eco-Friendly Asphalt Concretes Using The Simple Shear And 4p Bending Tests, 5th International Congress Sustainability of Road Infrastructures, Rome, Italy 29-31 October 2012, Procedia Social and Behavioral Sciences - Volume 53, 3 October 2012, Pages 410-420 - ISSN 1877-0428. Dondi G., Pettinari M., Sangiorgi C., Wu R. (2012). Designing Long Life Pavements including eco-friendly ACs by means of the Mechanistic Empirical approach, 5th International Congress Sustainability of Road Infrastructures, Rome, Italy 29-31 October 2012, Procedia Social and Behavioral Sciences Volume 53, 3 October 2012, Pages 1162-1172 - ISSN 1877-0428. Simone A., Pettinari M., Petretto F., Madella A. (2012). The influence of the binder viscosity on the laboratory short term aging, 5th International SIIV Congress Sustainability of Road Infrastructures, Rome, Italy 29-31 October 2012, Procedia Social and Behavioral Sciences - Volume 53, 3 October 2012, Pages 421-431 - ISSN 1877-0428. Simone A., Pettinari M., Petretto F., Madella A. (2011) A high workability bituminous mixture for the construction of an innovative high performance pavement in an urban historical center, Mezclas bituminosas de alta trabajabilidad para la realizacion di pavimentos de altas prestaciones estructurales y ambientales en ambito urbano, Conglomerats bitumeneux à haute plasticité pour la réalisation de chaussées à hautes performances structuralles et environnementales en milieu urban, Conglomerati bituminosi ad alta lavorabilità per la realizzazione di pavimentazioni ad elevate prestazioni strutturali ed ambientali in ambito urbano (2011) Le Strade, Special Issue, XXIV PIARC World Road Congress – Mexico City 2011, ISSN 0373-2916. pp. 84-92. Dondi G., Grandi F. & Vignali V. (2006). Traffic induced vibration theoretical-experimental study of dumping pavements, 10th International Conference on Asphalt Pavement, august 1217, Quebec, Canada. Dondi G., Simone A., Sangiorgi C. (2004). From requirement-related to performance-related specifications, Proceedings 3rd Eurasphalt & Eurobitume Congress, Vienna 12-14 May 2004, ISBN 90-802884-4-6. Sangiorgi C., Collop A.C., Thom N.H. (2002) Laboratory Assessment of Bond Condition Using the Leutner Shear Test, 3rd International Conference Bituminous Mixtures and Pavement, Thessaloniki, GR, November 2002. RESEARCH PROJECTS Progetto in convenzione di Ricerca tra DICAM e SAVE S.p.A. Lavori di riqualifica delle infrastrutture di volo dell’Aeroporto Marco Polo di Venezia. Anno 2013. Progetto in convenzione di Ricerca tra DICAM e api S.p.A. Studio finalizzato al controllo della qualità dei bitumi ed alla caratterizzazione prestazionale di conglomerati bituminosi. Anno 2009. CONTACTS [email protected] [email protected] [email protected] [email protected] 218 Transportation Infrastructures and Transports – Transports PERSONAL RAPID TRANSIT OPTIMIZATION AND SIMULATION RESEARCH GROUP: Joerg Schweizer, Luca Mantecchini, Federico Rupi KEYWORDS: Personal Rapid Transit, PRT, micro simulation, podcar, ATN, AGT Car dependency of urban transport is the main challenge for most cities: automobiles produce greenhouse gases; cause a significant number of deaths and injuries; limit accessibility to transport and occupy a disproportioned share of urban space, thus preventing the use of more sustainable modes. Yet the car’s convenience remains unquestioned. A promising emerging public transport technology, called Personal Rapid Transit (PRT), has the potential to attract car drivers where conventional mass transit fails: PRT is a fully automated guided public transportation which became commercially available only recently. With PRT up to 6 persons or light freight travel in small, individually controlled and electrically driven vehicles on a network of light guideways. The narrow guideways is grade-separated; guideways can either be elevated, in underground shafts or on-ground if separated by fences. Due to their small cross section (roughly 1m2) and tight minimum turning radius (ca. 5m), guideways can be routed through streets and buildings at minimum visual impact. From the service point of view, PRT has three distinctive features: (1) passengers can travel from any station of the network to any other station, without intermediate stops or transfers; (2) Passengers do not need to share the vehicle with other passengers; (3) there are no fixed time schedules, vehicles wait at stations or do arrive on demand. This sustainable taxi-alike service is thought to be attractive for many who would currently hesitate to use public transport. Research objectives are (1) the development of software tools to design and simulate PRT networks; (2) optimal empty and occupied vehicle assignment, (3) network topology optimization (4) stations capacity models (5) development of safe short headway PRT control systems. While offering customized solutions for PRT planning and simulations, we have been cooperating with private consulting firms on the following PRT projects: Masdar, Abu Dhabi, UEA; Heathrow, London Airport; Rimini Congress hall, Italy; Vienna, Suedbahnhof, Austria; Izmit, Turkey. 219 Fig. 1. Snapshot of a network simulation. Shown is an off-line station with waiting passengers. Fig. 2. Optimum occupied vehicle flows (orange) and empty vehicle flows (green) at a roundabout of a PRT network. Fig. 3. Scale model of 2 PRT vehicles with short headway control system. Research Projects and Activities 2015 MAIN PUBLICATIONS Danesi A., Rupi F., Traversi E., Schweizer J. (2012). Comparison of static vehicle flow assignment methods and microsimulations for a personal rapid transit network. Journal of Advanced Transport, vol. 46, p. 340-350, ISSN: 0197-6729, doi: 10.1002/atr.1196 Danesi A., Lepori C., Lupi M., Rupi F., Schweizer J. (2008). Sistemi innovativi per la mobilità urbana: il Personal Automated Transport a servizio misto. T&T Trasporti e Territorio, vol. 3-4, pp. 165-172, ISSN: 1723-7432 Schweizer J., Mantecchini L., Greenwood J. (2011). Analytical capacity limits of Personal Rapid Transit stations. In: Automated People Movers and Transit Systems 2011”From People Movers to Fully Automated Urban Mass Transit”. pp. 326-338, RESTON (VIRGINIA): American Society of Civil Engineers (ASCE), ISBN: 9780784411933, doi: 10.1061/41193(424)30 Danesi A., Lupi M., Rupi F., Schweizer J. (2011). Personal Rapid Transit : a self financing solution for tourist transport at the city of Rimini. In: Transport management and land-use effects in presence of unusual demand. pp. 63-79, Milano:FrancoAngeli, ISBN: 9788856841749 Danesi A., Lepori C., Lupi M., Rupi F., Schweizer J. (2009). Strategie per l’aumento della capacità e della sostenibilità di una rete Personal Automated Transport: il servizio misto individuale/collettivo e passeggeri/merci. In: inter- venti e metodologie di progetto per una mobilità sostenibile. pp. 235-249, Milano: Franco Angeli, ISBN: 978-88-568-1230-5 Rupi F., Danesi A., Lupi M., Rudi A., Schweizer (2009). Economical feasibility study of a personal automated transport for leisure holidays and special events. In: Transport management and land-use effects in presence of unusual demand. vol. 1, p. 47-52, Milano: Maggioli Editore, ISBN: 8856841746, Milano, 29-30 giugno 2009. Caprara A., Traversi E., Schweizer J. (2008). An Application of Network Design with Orientation Constraints. In: Proceedings of the 7th Cologne-Twente Workshop on Graphs and Combinational Optimization. pp. 16-21, Gargnano, Italy, 13-15 May 2008. RESEARCH PROJECTS PRT study at Rimini, supported by the province of Rimini and Europa Inform. PRT study at Masdar, Abu Dhabi, supported by Systematica S.p.A and Mott McDonalds, UK. PRT micro-simulator development supported by Novitran, USA and Tabosan, Turkey. CONTACTS [email protected] [email protected] [email protected] 220 Transportation Infrastructures and Transports – Transports ENVIRONMENTAL IMPACT ANALYSES OF TRANSPORT SYSTEMS RESEARCH GROUP: Federico Rupi, Joerg Schweizer KEYWORDS: impact analyses, sustainable transport, emission models, demand models, traffic counts, micro-simulation The quantification of environmental impacts and energy consumption of present and future traffic scenarios is becoming increasingly important as guidance for decision makers and for the resource efficient allocation of investments in transport infrastructure and services. The full application of “user pays” and “polluter pays” principle is a goal set out in the European whitepaper 2011 “Roadmap to a Single European Transport Area”. A large variety of data acquisition and processing methods have been developed to estimate the emission of CO2, pollutants, noise, and fuel consumption. Current mobility scenarios have been analysed through traffic counts or surveys. Present and future transport scenario are estimated based on static- and micro-simulation models. Particular attention is devoted to quantify the positive impacts of bicycle mobility and high quality public transport such as Personal Rapid Transit (PRT). Current research is focused on (1) calibrations of generalized cost function model for bicycle ways using geometric information from Openstreetmap and geo-referenced speed profiles from real bicycle trips; (2) calibration of path choice models as support for bikeway planning; (3) development of assessment software based on multi-modal micro-simulation models and the estimation of a virtual population. Once completed this software will allow to estimate the environmental impacts of present and hypothetical traffic scenarios – for instance after the implementation of bicycle ways or public transport services. There have been activities in the following projects: (1) Annual bicycle flow measurements for city of Bologna; radar and tube based 24h bicycle counts and the estimation of increased bicycle usage. (2) Central Europe project BICY: mobility survey, future demand estimation and impact analyses for 13 European cities. (3) Participation in the joint development of the SUMO micro simulation tool, in cooperation with the main developer at the German Aerospace Center, Institute of Transportation Systems Berlin, Germany. Fig. 1. Pressurized tube based 24h-bicycle counting. Fig. 2. Averaged bicycle flows for a one day period at a particular intersection of a bicycle way. Fig. 3. CO2 reductions (averaged over 13 cities) for different bicycle infrastructure scenarios, corresponding to projected increases in bicycle travel (substituting motorized traffic). 221 Research Projects and Activities 2015 MAIN PUBLICATIONS RESEARCH PROJECTS Meggs J.N., Rupi F., Schweizer J. (2013). Can PRT overcome the conflicts between public transport and cycling?. In: Living and walking in cities. Cultures and techniques for accessibility. p. 215-220, Forlì:EGAF Edizioni SRL, ISBN: 9788884825018, Brescia, 14-15 giugno 2012. EU 2CE108P2 Project: BICY – Cities & Regions of Bicycles; a project of Central Europe and co-financed by the European Regional Development Fund, ERDF, http://www.bicy.it Schweizer J., Meggs J.N., Dehkordi N.R., Rupi F., Pashkevich A. (2012). Unified, Low-Cost Analysis Framework for the Cycling Situation in Cities. In: International Journal of Civil and Environmental Engineering. p. 356-363. [email protected] [email protected] CONTACTS Meggs J.N., Schweizer J. (2012). The future of bicycling given a world in degrowth: perspectives and lessons based on the Central European project, BICY. In: 3rd International Conference on Degrowth, Ecological Sustainability and Social Equity . p. 1-22. Dehkordi N.R., Meggs J.N., A. Pashkevich A., Rupi F., Schweizer J. (2012). Automobile, public transport and bike usage in West and Eastern Europe: a comparative survey. In: 15th International Conference on Transport science 2012, ICTS, Portoroz, Slovenia, ISBN: 9789616044943. Rupi F., Bernardi S., Bertoni S. (2013). Analisi delle distribuzioni delle velocità sull piste ciclabili e sulle carreggiate stradali adiacenti. In Living and walking in cities. Safety and vulnerable road users. XX Conferenza Internazionale Living and Walking in Cities, Brescia 13-14 Giugno 2013. In press. 222 Transportation Infrastructures and Transports – Transports ENVIRONMENTAL, FINANCIAL AND OPERATIONAL PERFORMANCE OF AIRPORTS RESEARCH GROUP: Luca Mantecchini, Filippo Paganelli, Nicola Gualandi KEYWORDS: air transportation, airports, level of service, environmental impact, performance evaluation The air traffic growth and the development of regional airports represent one of the most important by-product of deregulation. The traffic analysis shows that low costs carriers have been largely responsible for passenger growth at a number of regional airports. This scenario has determined a redistribution of air traffic in favor of underused regional airports, characterized by high rates of growth during the last years. Moreover it is widely recognized the importance of regional airports for local communities in terms of increase in air accessibility that determines profound repercussions in the economic development and in the growth of employment. However the prolonged low traffic at regional airports and the insufficiency of land use planning have determined, in many cases, that the suburban sprawl expanded until the airport boundaries. Traffic expansion due to the causes previously described had caused a situation difficult to handle because of externalities generated by air traffic and noise is the principal. The last twenty years have witnessed a tremendous reduction of airplane noise at source. Recent psychoacoustic studies have shown that annoyance is strongly influenced not only by the maximum sound level but also by the number of events. It has been proven that a given level of annoyance can be generated by a low number of noisy aircrafts or by a much higher number of events characterized by a lower level. The adoption of the Directives n. 49/2002/ CE and n. 30/2002/CE embodies the purpose of the European Commission of reducing airport noise within the EU. The introduction of airport operating restrictions represents a serious threat for airports expansion. Many international organizations recognize the importance of environmental issues as a threat to the growth of aviation market in Europe, unless airport environmental capacity is efficiently managed. Since noise represents the principal externality of aviation at local level, acoustical capacity seems to be one among the first constraints to airport growth. The need to investigate airport environmental performances with special regard to the parameters closely related with airport management is the focus of this research activity. Fig. 1. Takeoff radar tracks – Bologna Airport. Fig. 2. Example of noise contours. 223 Research Projects and Activities 2015 MAIN PUBLICATIONS 2010, 189-198. Mantecchini L., Gualandi N., Paganelli F. (2013). Integration and concentration of European air transport market. International Journal for Traffic and Transport Engineering, No. 3(2), 204-219. Gualandi N., Mantecchini L. (2008). Aircraft noise pollution: a model of interaction between airports and local communities. International Journal of Mechanical Systems Science and Engineering, No. 2(2), 137-141. Paganelli F., Tondelli S., Mantecchini L., Gualandi N. (2013). Network capability and air transport cross-supply in the Adriatic sea basin. Proc. ICTS 2013, 280-296. Gualandi N., Mantecchini L. (2008). Aircraft noise performance evaluation and management. In: Methods and Models for Planning the Development of Regional Airport Systems, Franco Angeli ed., 98-109. Gualandi N., Mantecchini L. (2009). A comparative analysis of aircraft noise performances. Journal of Engineering and Applied Sciences 4, 75-81. Gualandi N., Mantecchini L. (2009). Managing uncertainty in airport parking facility development. In: Transport Management and Land-Use Effects in Presence of Unusual Demand, 279-284. Mantecchini L., Gualandi N., Paganelli F. (2010). Integration and concentration: the evolution of air transport in the EU. Proc. ICTS RESEARCH PROJECTS INTERREG IVC 1129R4 Project: ECOTALE. External Costs of Transport and Land Equalization. INTERREG IVC Project: D-AIR. Decarbonized Airport Region. CONTACTS [email protected] 224 Transportation Infrastructures and Transports – Transports SAFETY AND REGULARITY OF LAND TRANSPORT RESEARCH GROUP: Alfonso Micucci KEYWORD: trasporti ferroviari, trasporti stradali, infortunistica, ricostruzione incidenti The research conducted by the group is divided into two distinct themes. The first activity concerns the optimization of decisions and acts to improve the transformation of today local railway services, trough Bologna area, in cadenced and regular Metropiltan Railway Services of SFM project. Especially, starting from an accurate analysis of non-aggregate data about actual railway services frequentation, acquired by Trenitalia and FER operators, we obtain aggregate values for the future SFM passengers, using forecasting models original designed. Based on these results, combined with service levels provided by SFM project, we study the optimization of rolling stock, doing an analysis of the trains currently produced but also the prototypes currently under development, as well as the characteristics of the rolling stock already available at operators. Finally, we develop an original model implementation of services, based on a limited type of rolling stock, to achieve flexibility of use and economies in handling and maintenance. The second one concerns the study of the dynamic behavior of a vehicle on the road, the resistances to the motion and the car set-up with the purpose to improve the tires exploitation. The topic of the road accident study is analyzed: throughout adequate test series, it is empirically determined the vehicle reaction in emergency conditions, in particular the technical time needed for the braking system activation and the maximum deceleration achieved. For this purpose, representative vehicles belonging to the current available European car stock where equipped with suitable instrumentation and were subjected to stopping tests in emergency conditions, on different types of pavement (asphalt, grass, concrete, gravel and relative combinations) with various weather conditions ( winter with wet road surface, summer end with dry road surface). Fig. 1. Graphic timetable Porretta – Bologna – Imola. Fig. 2. Braking test. Fig. 3. Braking diagram. 225 Research Projects and Activities 2015 MAIN PUBBLICATIONS CONTACTS Micucci A., Strangi M. (2012). Determinazione sperimentale del tempo tecnico e della decelerazione in frenate d’emergenza – ASAIS Bologna [email protected] Micucci A., Simoncini S., Perrone R. (2011). L’assorbimento di energia negli urti contro manufatti – ASAIS Verona Micucci A, Masselli P. (2007). Un Modello Di Esercizio Per La Linea Ferroviaria Vignola – Portomaggiore Sfm 2 di Bologna Micucci A, Mantecchini L. (2006). Alcune considerazioni sulle resistenze al moto per carri ferroviari merci – Ingegneria Ferroviaria. 226 Water Engineering Water Engineering – Coastal and Ocean Engineering COASTAL HYDROMORPHODYNAMICS: MONITORING AND MODELLING RESEARCH GROUP: Renata Archetti, Sara Mizar Formentin, Gabriella Gaeta, Alberto Lamberti, Andrea Natalia Raosa, Achilleas Samaras, Barbara Zanuttigh KEYWORDS: remote sensing, videomonitoring, hydrodynamic codes, sediment transport, coastal evolution Near-shore zone morphodynamic evolution – in terms of the bathymetric variability, surface waves, and circulation patterns – is crucial for beach management and inland protection against flooding. Assessment is performed using in-situ monitoring and numerical modelling. Due to the characteristics of both the approaches an integrated use of them is preferred. DICAM has a consolidated experience in both approaches: development of technologies (instrumentations, software etc.) for the hydrodynamics and morphodynamics monitoring both in laboratory and in the field and development and use of complex, integrated wave-current-sediment numerical models that simulate near-shore processes and wave structures interaction. Remote monitoring of coastal conditions is a fast growing application of information technology. Video camera systems provide a potentially rich source of information on the state of the coastal zone. DICAM since 2003 has installed several video stations in Italy with the aim to analyse the coastal morphodynamics. On-going studies regards: • Shoreline detection, beach evolution (Fig. 1), volume changes; bar location, morphology; Times series, trends analyses; Near shore hydrodynamics. Moreover DICAM owns several acoustic instruments used to measure velocity waves and water level. Several surveys have been carried out in order to measure: turbulence in the surf and in the swash zone – velocity profiles and waves in presence of coastal defence structures. Coastal area hydro-morphodynamic models are applied to describe wave and currents fields and to predict the short, medium and long term of bathymetric changes and coastal evolution associated with such coastal features as groynes, breakwaters and entrance channels. Research is based on the use of several codes: 2DH MIKE21, Telemac Mascaret, both for wave, hydrodynamics (Fig. 2) and sediment transport simulation (Fig. 3). Coastal evolution model (Litpak) and 2DV hydrodynamic (COBRAS). Fig. 1. Shoreline evolution in Lido di Dante frequently monitored with videocameras. Fig. 2. Velocity field induced by wave breaking. Fig. 3. Simulation of bed level changes at the Reno mouth during an intensive storm. 229 Research Projects and Activities 2015 MAIN PUBLICATIONS Carniel S., Sclavo M., Archetti R. 2011. Towards validating a last generation, integrated wave-current-sediment numerical model in coastal regions using video measurements. Oceanological and hydrobiological studies. 40 (4), 11-20. Kroon A., Aarninkhof S.G.J., Archetti R., Armaroli C., Gonzalez M., Medri S, Osorio A., Aagaard T., Davidson M.A., Holman R.A., Spanhoff R. 2007. Application of remote sensing video systems for coastline management problems. Coast. Eng. 54, (6-7), 493-505. Archetti, R. and Romagnoli, C. 2011, Analysis of the effects of different storm events on shoreline dynamics of an artificially embayed beach. Earth Surface Processes and Landforms. doi: 10.1002/ esp.2162. Jimenez, A., A. Osorio, I. Marino-Tapia, M. Davidson, R. Medina, A. Kroon, Archetti R., P. Ciavola, S. Aarninkhof. (2007). Beach recreation planning using video-derived coastal state indicators. Coast. Eng. 54, (6-7). pp. 504-522. Parlagreco l., Archetti R. Simeoni U., Devoti S. Valentini A., Silenzi S. 2011. Video-monitoring of a barred nourished beach (Latium, Central Italy). J. of Coastal Research. SI 64. 110-114. RESEARCH PROJECTS Romagnoli C., R. Archetti. 2011. Post-nourishment shoreline evolution of a partially protected beach. Geoacta. 10, 69-77. EVK3 - CT-2001-0054 COASTVIEW: Developing coastal video monitoring systems in support of coastal management. Martinelli, L. & B. Zanuttigh, N. De Nigris & M. Preti, 2011. Geosynthetic barriers for coastal pro-tection along the Emilia Romagna littoral, Northern Adriatic Sea, Italy. Geotextiles and Ge-omembranes, 29, 370-380. Liang Q., Wang Y., Archetti R.. 2010. A Well-Balanced Shallow Flow Solver for Coastal Simulations. International journal of offshore and polar engineering. 20 (1), 41-47. Archetti R. Zanuttigh B. 2010. Integrated monitoring of the hydro-morphodynamics of a beach protected by low crested detached breakwaters. Coastal Engineering 57 (10), 879-891. Archetti R. 2009. Study of the evolution of a beach protected by low crested structures using video monitoring. Journal of Coastal Research . 25(4). 884-899. Zanuttigh, B., 2007. Numerical modeling of the morphological response induced by low-crested structures in Lido di Dante, Italy, Coastal Engineering, 54 (1), 31-47. Davidson M., M. Van Koningsveld, A. de Kruif, J. Rawson, R. Holman, A. Lamberti, R. Medina, A. Kroon, S. Aarninkhof. (2007). The CoastView project: Developing video-derived Coastal State Indicators in support of coastal zone management. Coast. Eng. vol. 54 (6-7), 463-475. EU-FP7-ENV2009-1 ID 244104 Project: THESEUS. Innovative technologies for safer European coasts in a changing climate. www.theseusproject.eu EVK3 - CT-2000-0041: DELOS. Environmental Design of Low Crested Coastal Defence Structures. National project supported by the Italian Ministry of University and Research. Project: RITMARE. www.ritmare.it/en. PON01 2823. Sviluppo di Tecnologie per la Situational Sea Awareness. http://tessa.linksmt. it/. INTERREG IIIc Beachmed-e La gestione strategica della difesa dei litorali per uno sviluppo sostenibile delle zone costiere del Mediterraneo. 2005-2008. www.beachmed.it. Research contracts funded by ARPA Emilia Romagna on Coastal defence in Igea Marina, Foce Reno, Cesenatico. ASI Agenzia Spaziale Italiana. Progetto CoastSat. Coste: Monitoraggio e gestione del rischio. British Council – CRUI, New numerical and experimental approach for the assessment of flooding risk of urban area in coastal zones. CONTACTS [email protected] [email protected] [email protected] 230 Water Engineering – Hydrology COASTAL RISKS IN A CHANGING CLIMATE RESEARCH GROUP: Renata Archetti, Stefano Bagli, Sara Mizar Formentin, Alberto Lamberti, Marinella Masina, Andrea Natalia Raosa, Barbara Zanuttigh KEYWORDS: Coastal flood, climate change, sustainable design, decision support system Major threats for large stretches of European coasts are erosion and flooding. Climate change may cause very significant impacts on coastal zones, particularly because of the foreseen sea-level rise and increase of frequency and intensity of extreme events (Fig. 1). This research aims at risk assessment and mitigation in short, mid and long term scenarios. Flooding probability and extension are assessed through 1D and 2D numerical modelling. The water level is estimated from tide and combination of set-up and run-up. The 1D investigation is performed on typical beach profiles that are statistically described Flooding probability and its sensitivity to the most relevant geometric parameters and forcing conditions are examined with the STRUREL code. The 2D map of flood depths and velocities in case of combined storm and river flood is obtained with a standard 2DH Flexible Mesh model, provided that boundary conditions are properly fixed. A 2D simplified model based on the watershed segmentation algorithm has been developed to run multiple flooding scenarios with limited computational effort and sufficient accuracy (Fig. 2). Coastal defence strategies have to be planned with the aim at sustainable and resilient coasts, considering ecological, social and economic impacts and design optimisation. Research performed within THESEUS Project has developed a holistic, participatory and interdisciplinary approach to addressing coastal risk based on the Source-Pathway-Receptor-Consequence model. One of the major outcome is the new Decision Support System, a GIS based tool to help decision makers in scoping optimal strategies to minimize coastal risks. The tool allows the users to perform an integrated coastal risk assessment, to analyse the effects of combinations of engineering, social, economic and ecologically based mitigation options, to explore short, medium and long term scenarios taking into account physical and non-physical drivers, such as climate change, subsidence, population and economic growth. The THESEUS DSS is intended as a vehicle for communication, training, forecasting and experimentation. 231 Fig. 1 High sea water level overflowing Cesenatico canal harbour. Fig. 2. Map of flood depths in the area of Garibaldi harbour – Reno mouth. Research Projects and Activities 2015 MAIN PUBLICATIONS Engineering, 57, No. 11-12, 1042-1058. Masina M. and Lamberti A. (2013). A non-stationary analysis for the Northern Adriatic extreme sea levels. Journal of Geophysical Research - Oceans. DOI: 10.1002/jgrc.20313. Zanuttigh B., Losada I. J. and Thompson R. C., (2010). Ecologically based approach to coastal defence design and planning, Proc. of the Int. Conf. on Coastal Eng., No. 32(2010), Paper #: management5.0. http://journals.tdl.org/ ICCE/. Zanuttigh B. (2013). THESEUS framework for coastal risk assessment and sustainable risk management decision-making. Proc. Of The Eleventh International Workshop on Coastal Disaster Prevention, PARI, Tokyo, Invited talk. Zanuttigh, B. (2011). Coastal flood protection: what perspective in a changing climate? The THESEUS approach, Environmental Science and Policy, 14, 845-863. Archetti R., Bolognesi, A. Casadio, A. and Maglionico M.. (2011). Development of flood probability charts for urban drainage network in coastal areas through a simplified joint assessment approach. Hydrology and earth system sciences, 15, 3115-3122. De Vries W. S., Zanuttigh B., Steendam G. J., Kloosterboer H., Van der Nat A. and Graaf, H. (2011). Integrating science and policy for creating tools for safer European coasts in a changing climate, Irrig. and Drain. 60 (Suppl. 1): 77-83. Zanuttigh B. (2011). Innovative technologies for safer European coasts in a changing climate. Proc. Coastal Structures 2011, Japan. Martinelli L., Zanuttigh B. and Bagli S., (2011). Modelling coastal risk along the Northern Adriatic Sea, Proc. Coastal Structures 2011, Japan. Umgiesser G., Martinelli L., Zanuttigh B., Bellafiore, D. and Ferrarini L. (2011). Sea level rise and coastal flood protection in Cesenatico, Italy. Proc. Acqua Alta, Hamburg. Martinelli L., Zanuttigh B. and Corbau C. (2010). Assessment of coastal flooding risk along the Emilia Romagna littoral, Italy. Coastal Corbau C., Simeoni U., Archetti R. Peretti A. and Farina M. (2009). Winter Sandy Protections of the Northern Adriatic Coast against flooding: Preliminary Results. J. of Coast. Res. SI 56. 1194 – 1198. Martinelli L., Zanuttigh B. and Lamberti A., (2009). Analysis of coastal flooding hazard in low lying areas of the Northern Adriatic Sea, Proc. Coastal Eng. 2008, 2, 1160-1172. Zanuttigh, B., Martinelli, L., Lamberti, A., Moschella, P., Hawkins, S., Marzetti, S. and Ceccherelli V. U., (2005). Environmental design of coastal defence in Lido di Dante, Italy, Coastal Engineering, 52, No.10-11, 1089-1125, Elsevier. Lamberti, A. and Zanuttigh B., (2005). An integrated approach to beach management in Lido di Dante, Italy., Estuarine Coastal and Shelf Science, 62, No. 3, 441-451. RESEARCH PROJECTS EU-FP7-ENV2009-1 ID 244104 Project: THESEUS. Innovative technologies for safer European coasts in a changing climate. www. theseusproject.eu PRIN-2008. Project: 2008YNPNT9, Tools for the assessment of coastal zone vulnerability related to the foreseen climate change CONTACTS [email protected] [email protected] [email protected] 232 Water Engineering – Coastal and Ocean Engineering RENEWABLE ENERGY FROM THE SEA RESEARCH GROUP: Elisa Angelelli, Alessandro Antonini, Renata Archetti, Alberto Lamberti, Adria Moreno Miquel, Barbara Zanuttigh KEYWORDS: Wave Energy Converters, Wave Farm, Mooring Systems, Off-shore Platforms, Coastal Protection The huge potential of the European seas is still far from being recognised and can significantly contribute to the mitigation of climate change effects thanks to the extraction of renewable energy from wind, waves and tides. However these installations are still not competitive in terms of costs, and require design optimization for improving device survivability and conversion efficiency also in milder climates. Due to the massive development of marine infrastructures, it is crucial to adopt a holistic approach towards sustainable use of the marine space. This research tackles the challenge to combine the installations for renewable energy from the sea, and specifically Wave Energy Converters (WECs), with other off-shore installations for aquaculture, transportation, etc. and with nearshore and on-shore installations for coastal and harbour protection purposes. The research on floating WECs focuses mainly on the wave loads on the devices, on the design of mooring systems (Fig. 1) and on the hydrodynamics around WEC farms. Experiments have been carried on single and multiple WECs with Power Take Off (PTO) system on board in the wave basin at Aalborg University by varying wave attacks, depth of installation and mooring type (Fig. 2). Numerical modelling of wave-WEC interaction and dynamic response of moorings is performed under simplifying assumptions with the 2DH Mike 21 BW code (Fig. 3) and with the software ANSYS AQWA. Research has been carried out on the development and optimisation of a WEC point absorber specifically designed for the Mediterranean conditions. The research on WECs integrated in harbour structures has been carried out through laboratory experiments in wave flume on an overtopping devices at Aalborg University and is ongoing with numerical modelling of wave-structure interaction by adopting a 2DV research code based on the RANS-VOF technique. Fig. 1 Wave flume experiments on the dynamics of mooring systems. Fig. 2. Experiments on a farm of WECS with a spread mooring system and PTO on board. Fig. 3. Numerical modelling of a farm of WECs with MIKE21 BW. 233 Research Projects and Activities 2015 MAIN PUBLICATIONS Zanuttigh, B., Angelelli, E. and Kofoed, J. P., (2013). Effects of mooring systems on the performance of a wave activated body energy converter, Renewable Energy, 57 (9), 422-431. Zanuttigh, B. and Angelelli, E. (2013). Experimental investigation of wave energy converters for coastal protection purpose, Coastal Engineering, 80, 148-159. Bozzi, S., Miquel, A.M., Antonini, A., Passoni, G. and Archetti, R. (2013). Modelling of a point absorber for energy conversion in Italian Seas. Energies, 6, No 6, 3033-3051. Angelelli, E. and Zanuttigh, B. (2012). A farm of wave activated bodies for coastal protection purposes, Proc. 33rd Int. Conf. on Coastal Eng., 10.9753/icce.v33.structures.68, electronic format. Angelelli, E. and Zanuttigh, B. (2012). Numerical modelling of the hydrodynamics around the farm of WAB, Proc. ICOE2012, electronic format. Martinelli, L. , Zanuttigh, B. and Kofoed, J. P. (2011). Method for selection of maximum PTO design power based on statistical analysis of small scale experiments on Wave Energy Converters. Renewable Energy, 36, No 11, 3124-3132. Archetti, R.; Bozzi, S., Passoni, G. (2011). Feasibility Study of a Wave Energy Farm in the Western Mediterranean Sea: Comparison among Different Technologies. Proc. of the 30th Int. Conf. on Ocean, Offshore and Arctic Eng., electronic format. Angelelli, E., Zanuttigh B., Kofoed, J. P. and Glejbol, K. (2011). Experiments on the Wave Piston wave energy converter. Proc. EWTEC 2011, electronic format. Zanuttigh, B., Angelelli, E., Castagnetti, M., Kofoed, J. P. and Clausen, L. (2011). The wave field around DEXA devices and implications for coastal protection. Proc. EWTEC 2011, electronic format. Zanuttigh, B., L. Martinelli, Castagnetti, M., P. Ruol, J. P. Kofoed and Frigaard, P. (2010). Integration of wave energy converters into coastal protection schemes, Proc. ICOE2010, electronic format. Martinelli, L., Zanuttigh, B. and Kofoed, J. P. (2009). Statistical analysis of power production from OWC type wave energy converters, Proc. EWTEC 2009, electronic format. Zanuttigh, B., Margheritini L., Gambles, L. and Martinelli, L. (2009). Analysis of wave reflection from wave energy converters installed as breakwaters in harbours, Proc. EWTEC 2009, electronic format. Martinelli, L., Ruol, P. and Zanuttigh, B. (2008). Forces on floating breakwaters and moorings: effects of layout and wave obliquity. Applied Ocean Research, 30, No 3, 199-207. RESEARCH PROJECTS EU FP7-OCEAN-2011-1 ID 288710. Project: MERMAID. Innovative Multi-purpose offshore platforms: planning, design and operation. www. mermaidproject.eu EU-FP7-ENV2009-1 ID 244104 Project: THESEUS. Innovative technologies for safer European coasts in a changing climate. www.theseusproject.eu EU-FP7- ENERGY ID 213633. Project: CORES. Components for Ocean Renewable Energy Systems. www.fp7-cores.eu/index.html. International Research Alliance supported by the Danish Council for Strategic Research. Project: SDWED. Structural Design of Wave Energy Device. www.sdwed.civil.aau.dk. EU-FP7-Capacities MARINET. Project: REDEM. Reliable design of mooring system of Wave Energy Converters. www.fp7-marinet.eu/. National project supported by the Italian Ministry of University and Research. Project: RITMARE. www.ritmare.it/en. Research contract funded by ENEA: Analysis of the existing technologies for the deployment of marine renewable energy along the Italian seas Research contract funded by INGV: Assessment of the renewable energy potential from the sea offshore the Italian coasts. CONTACTS [email protected] [email protected] [email protected] 234 Water Engineering – Environmental Hydraulics RIVER AND TORRENTS HYDROMORPHODYNAMICS RESEARCH GROUP: Renata Archetti, Vittorio Di Federico, Gabriella Gaeta, Massimo Guerrero, Alberto Lamberti, Michael Nones, Barbara Zanuttigh KEYWORDS: debris flow, measuring technologies, river morphodynamics, roll waves The study of fluids motion in river and torrents is preliminary to the assessment of sediment fluxes and to the final prediction of consequent morphology changes (i.e., the morphodynamics). Engineer applications range from alps to alluvial plains concerning many aspects of human settlement and civil infrastructures. As instance, in mountain torrents, intense and localised storms may cause flash floods with important sediment transport. In steep torrents, the sediment discharge may increase so that the solid concentration often exceeds 40-50%: this is the case of debris flows that transport downstream huge volumes of sediments that are then deposited on the alluvial fans. In addition, a steady discharge in a constant slope channel will not always result in a steady uniform flow. If the channel is sufficiently steep and long, a series of shallow water waves may develop, propagating downstream, eventually break and overtake one another (i.e., roll waves). More downstream river channels tends to divagates in large flood plains changing position of kilometres in decades. In others cases, river-bed degradation of meters was recorded when the channel planimetric position was fixed by flood embankments. All these processes taking place from upstream to downstream parts of the watershed undermine civil structures such as buildings, dams, viaducts, bridges, embankments, pump intakes and the navigation channel. The aim of our research is to develop measurement, experimental and mathematical methods for the optimized design of hydraulic structures and the related assessment of risk inherent in the climate-hydrology forcing term. Field campaigns, laboratory tests were performed and numerical-analytical modelling were implemented also taking advantages from novel underwater-acoustic technologies (Doppler profiler and Multi-beam sonar) and the advancement in computational fluid mechanics (1, 2 and 3 dimensional models). Fig. 1. Po river: bathymetry from Multibeam survey and concentration from numerical modelling. Fig. 2. Debris flow consequences in Letze torrent. 235 Research Projects and Activities 2015 MAIN PUBLICATIONS Guerrero, M., Di Federico, V. & A. Lamberti, 2013. Calibration of a 2-D morphodynamic model using water-sediment flux maps derived from an ADCP recording. J. Hydroinformatics 15, No. 3, 813-828. Guerrero, M. & A. Lamberti, 2013. Bed-roughness investigation for a 2-D model calibration: the San Martìn case study at Lower Paranà. Int. J. Sediment Res. 28, No. 4, in press. Guerrero, M., Re, M., Kazimierski, L.D., Menéndez, A.N. & R. Ugarelli, 2013. Effect of Climate Change on Navigation Channel Dredging of the Parana River. Int. J. of River Basin Management Doi:10.1080/15715124.2013 .819005 (0.52;0) Guerrero, M., Ruther, N. & R. Szupiany, 2012. Laboratory validation of ADCP techniques for suspended sediments investigation. Flow Meas. Instr. 23, No. 1, 40-48. Guerrero, M. & A. Lamberti, 2011. Flow Field and Morphology Mapping Using ADCP and Multibeam Techniques: Survey in the Po River. ASCE, J. of Hydr. Eng. 137, No. 12, 1576-1587. Guerrero, M., Szupiany, R & M. Amsler, 2011. Comparison of acoustic backscattering techniques for suspended sediments investigation. Flow Meas. Instr. 22, No. 5, 392-401. Di Cristo, C., Iervolino, M., Vacca, A. & B. Zanuttigh, 2010. Influence of Relative Roughness and Reynolds Number on the Roll-Waves Spatial Evolution. ASCE, J. of Hydr. Eng. 136, No. 1, 24-33. Zanuttigh B. & P. Ghilardi, 2010. Segregation process of water-granular mixtures released down a steep chute. J. of Hydrology 391, No. 1-2, 175-187. Zanuttigh B. & A. Lamberti, 2007. Instability and surge development in debris flows. AGU, Reviews of Geophysics 45, RG3006. Zanuttigh B. & A. Lamberti, 2006. Experimental analysis of the impact of dry avalanches on structures and implication for debris flows. IAHR, J. Hydraul. Res. 44, No. 4, 522-534. Zanuttigh B. & A. Di Paolo, 2006. Experimental analysis of the segregation of dry avalanches and implication for debris flows. IAHR, J. Hydraul. Res. 44, No. 6, 796-806. Zanuttigh B. & A. Lamberti, 2004. Analysis of debris wave development with one-dimensional shallow water equations. ASCE, J. of Hydr. Eng. 130, No. 4, 293-304. Zanuttigh B. & A. Lamberti, 2004. Numerical modelling of debris surges based on Shallow-Water and homogeneous material approximations. IAHR, J. Hydraul. Res. 42, No. 4, 376-389. Archetti R. & A. Lamberti, 2003. Assessment of risk due to debris flow events. ASCE, Natural Hazards Review, 4, No. 3, 115-125. RESEARCH PROJECTS CAID+11 UNL-Argentina, 2013-2015. El transporte de sedimentos en ríos aluviales: desarrollo de métodos de medición basados en la tecnología acústica Doppler. Yggdrasil exchange program with NTNU-Norway, 2012. Dual-frequency ADCP measurement to quantify suspended sediment concentrations and to determine grain size distribution. EU FP7, 2009-2012. CLARIS-LPB, A Europe-South America Network for Climate Change Assessment and Impact Studies in La Plata Basin. PRIN, 2003. Analisi integrata di casi scelte di colate detritiche nell’arco alpino. CONTACTS [email protected] [email protected] [email protected] 236 Water Engineering – Environmental Hydraulics NON-NEWTONIAN FLUID MECHANICS RESEARCH GROUP: Renata Archetti, Valentina Ciriello, Irene Daprà, Vittorio Di Federico, Giambattista Scarpi KEYWORDS: rheology, analytical solutions, numerical modelling, laboratory experiments, gravity currents Non-Newtonian fluids exhibit a complex rheology involving a non-linear relationship between the shear rate and the applied shear stress. Different rheological models have been proposed in literature to represent their behavior: power-law, Prandtl-Eyring, Williamson, and Giesekus models are frequently used. The aim of the research is to study the behavior of these fluids in industrial and environmental applications. The main categories of problems investigated are: (1) Start-up and pulsatile flows of Bingham fluids in different geometries mimicking industrial and mining engineering settings (e.g. flow between two coaxial cylinders). Here approximated analytical solutions were derived with a regularisation of the Bingham law and compared with numerical ones. (2) Flow of thixotropic fluids, with a complex molecular structure, whose rheological characteristics change with time, owing to an applied external shear stress. Typical application of thixotropic fluids are electronic packaging, where epoxy and adhesives are used for encapsulation and surface mounting, and the drill industry, in which fluids are subject to cyclic pressure and temperature loads when circulating in the bore. (3) Viscous gravity currents of power-law fluids in plane and radial geometry, representing the intrusion of a non-Newtonian fluid into another driven by a density difference. Closed form solutions describing the flow field are derived and compared with results of extensive laboratory investigations. (4) Hydraulic jump for muds described by a Herschel-Bulkley constitutive equation fluid in channels of given cross-section. (5) Flow of power-law fluids in porous media in confined and free-surface flow, representing environmental contaminants, remediation agents, and fluids used to enhance oil recovery from underground reservoirs. Approximated closed-form solutions are derived and compared with results of laboratory investigations in reconstructed media. Some of the indicated activities are carried out in collaboration with research groups of the University of Parma (Department of Civil, Environmental, Territory Engineering and Architecture). Fig. 1. Reconstructed porous media for non-Newtonian flow experiments. Fig. 2. Spreading of a dilatant gravity current. Power consumption for a Bingham fluid in the gap between two coaxial pipes under the action of a pulsating pressure gradient (p) and/or a periodic displacement (d) of the internal pipe. 237 Research Projects and Activities 2015 MAIN PUBLICATIONS Ciriello V., Longo S., Di Federico V. (2013). On shear thinning fluid flow induced by continuous mass injection in porous media with variable conductivity. Mechanics Research Communications, in press. Ciriello V., Di Federico V. (2013). Analysis of a benchmark solution for non-Newtonian radial displacement in porous media. International Journal of Non-Linear Mechanics 52, 46-57. Ciriello V., Di Federico V. (2013). Analytical modeling of spherical displacement for power-law fluids in porous media. Applied Mathematical Sciences 7(60), 2993-3005. Ciriello V., Di Federico V. (2012). Similarity solutions for flow of non-Newtonian fluids in porous media revisited under parameter uncertainty. Advances in Water Resources 43, 38-51. Daprà I., Scarpi G. (2010). Numerical solution for unsteady plane flow of dilatant fluids, 8th International Symposium Computational Civil Engineering, Iasi, 248-256. Daprà I., Scarpi G. (2010). Unsteady simple shear flow in a viscoplastic fluid: comparison between analytical and numerical solutions. Rheologica Acta 49, 15-22. Di Federico V., Pinelli M., Ugarelli R. (2010). Estimates of effective permeability for non-Newtonian fluid flow in randomly heterogeneous porous media. Stochastic Environmental Research and Risk Assessment 24, 1067-1076. Daprà I., Scarpi G. (2009). Couette–Poiseuille flow of the Giesekus model between parallel plates. Rheologica Acta 48, 117-120. Daprà I., Scarpi G. (2012). Moto periodico di un fluido di Ostwald-De Waele. Atti del XXXIII Conv. di Idraulica e Costruz. idrauliche. pp. 10. Ugarelli R., Bottarelli M., Di Federico V. (2008). Displacement of non-Newtonian compressible fluids in plane porous media flow, Advances in Fluid Mechanics VII, 21 - 23 May 2008, The New Forest, UK, 235-245. Di Federico V., Ciriello V. (2012). Generalized solution for 1-D non-Newtonian flow in a porous domain due to an instantaneous mass injection. Transport in Porous Media 93, 63-77. Daprà I., Scarpi G. (2007). Perturbation solution for pulsatile flow of a non-Newtonian Williamson fluid in a rock fracture. International journal of rock mechanics and mining sciences 44, 271-278. Di Federico V., Archetti R., Longo S. (2012). Spreading of axisymmetric non-Newtonian power-law gravity currents in porous media. Journal of Non-Newtonian Fluid Mechanics 189-190, 31-39. Ugarelli R., Di Federico V. (2007). Transition from supercritical to subcritical regime in free surface flow of yield stress fluids. Geophysical Research Letters 34, L21402. Di Federico V., Archetti R., Longo S. (2012). Similarity solutions for spreading of a two-dimensional non-Newtonian gravity current in a porous layer. Journal of Non-Newtonian Fluid Mechanics 177-178, 46-53. Ugarelli R., Di Federico V. (2007). Self-similar solutions for unsteady-state flow of non-Newtonian fluids in porous media, Atti del XVIII Congresso AIMETA, Brescia, 11-14 September 2007, pp. 6. Daprà I, Scarpi G. (2011). Pulsatile Poiseuille flow of a viscoplastic fluid in the gap between coaxial cylinders, J. Fluids Eng. 133, 81203 1-7. Daprà I., Scarpi G. (2006). Pulsatile pipe flow of pseudoplastic fluids. Meccanica 41, 501-508. Di Federico V., Archetti R. (2011). Self-similar solutions for spreading of non-Newtonian gravity currents in a porous layer, Atti del XX Congresso AIMETA, Bologna, 12-15 settembre 2011, pp. 10. CONTACTS Di Federico V., Ciriello V. (2011). Non-Newtonian flow through porous media due to an instantaneous mass injection, Atti del XX Congresso AIMETA, Bologna, 12-15 settembre 2011, pp. 10. Daprà I., Scarpi G. (2005). Start-up of a Bingham fluid in a pipe. Meccanica 40, 49-63. [email protected] [email protected] [email protected] [email protected] [email protected] 238 Water Engineering – Fluid Mechanics STOCHASTIC MODELING OF FLOW AND TRANSPORT PROCESSES IN POROUS MEDIA RESEARCH GROUP: Valentina Ciriello, Vittorio Di Federico, Giada Felisa KEYWORDS: porous media, heterogeneity, model reduction, inverse problems, risk analysis The aim of the research consists in developing realistic models for the description of fluid flow, and conservative or reactive solute transport in porous media. The first research line deals with fractured and heterogeneous media as geological heterogeneity strongly affects flow and transport processes. At the same time, the impossibility of a detailed medium characterization through field data, leads necessarily to the adoption of probabilistic modeling incorporating multiscale representations of media. In this framework, complex environmental scenarios, such as groundwater overexploitation and contamination and saltwater intrusion, are investigated by resorting to accurate and efficient computational strategies for the characterization of the uncertainties, in order to make consistent predictions and to provide proper indications for resources management and mitigation actions. The implementation of these strategies represents an important transversal research activity. The approach followed is based on model reduction techniques allowing in a straightforward manner to perform risk analysis, global sensitivity analysis or to solve calibration and optimization problems. To this aim, a numerical code based on the Polynomial Chaos Expansion theory has been developed. This approach is consequently adopted in the other research lines. One of these concerns the investigation of optimum design solutions for the improvement of thermal efficiency of ground heat exchangers. Other studies regard the analysis of parameter uncertainty in non-Newtonian flow in porous domains, seawater intrusion and the adoption of flow and transport formulations in the context of biomedical applications. Some of the indicated activities are carried out in collaboration with research groups of the Politecnico in Milan (Department of Civil and Environmental Engineering), the University of Ferrara (Department of Architecture), the Technical University of Catalonia in Barcelona (Department of Geotechnical Engineering and Geosciences), the Weizmann Institute of Science in Rehovot (Department of Environmental Sciences and Energy Research) and the University of California in San Diego (Department of Mechanical and Aerospace Engineering). Fig. 1. Heterogeneous hydraulic conductivity field. Fig. 2. Numerical model of seawater intrusion. Fig. 3. Modeling of ground heat exchangers. 239 Research Projects and Activities 2015 MAIN PUBLICATIONS Ciriello V., Guadagnini A., Di Federico V., Edery Y., Berkowitz B. (2013). Comparative analysis of formulations for conservative transport in porous media through sensitivity-based parameter calibration. Water Resources Research, doi: 10.1002/wrcr.20395. Ciriello V., Di Federico V., Riva M., Cadini F., De Sanctis J., Zio E., Guadagnini A. (2013). Polynomial chaos expansion for global sensitivity analysis applied to a model of radionuclide migration in a randomly heterogeneous aquifer. Stochastic Environmental Research and Risk Assessment 27, 945-954. Ciriello V., Di Federico V. (2013). Analysis of a benchmark solution for non-Newtonian radial displacement in porous media. International Journal of Non-Linear Mechanics 52, 46-57. Ciriello V., Di Federico V. (2012). Similarity solutions for flow of non-Newtonian fluids in porous media revisited under parameter uncertainty. Advances in Water Resources 43, 38-51. Di Federico V., Ciriello V. (2012). Generalized solution for 1-D non-Newtonian flow in a porous domain due to an instantaneous mass injection. Transport in Porous Media 93, 63-77. Ciriello V., Di Federico V. (2012). Espansione in caos polinomiale per l’analisi di sensitività globale applicata al trasporto in acque sotterranee, L’Acqua, Suppl. n. 4, 129-136. Bottarelli M., Di Federico V. (2012). Numerical comparison between two advanced HGHEs. International Journal of Low-Carbon Technologies 7(2), 75-81. Bottarelli M., Di Federico V. (2012). Field monitoring of a HGHE Flat Panel, in Education, Science, Innovations, Conference Proceedings of the First International Conference, 9-10 June 2011, Sofia, Bulgaria, 429-436. Bottarelli M., Di Federico V. (2011). Numerical comparison between two advanced HGHEs, 10th International Conference on Sustainable Energy Technologies, 4-7th September 2011, Istanbul, Türkiye, pp. 6. Ciriello V., Di Federico V. (2011). Analisi di sensitività globale ed espansione in caos polinomiale: un’applicazione al flusso in acque sotterranee, Atti del XX Congresso AIMETA, Bologna, 12-15 settembre 2011, pp. 10. Bottarelli M., Di Federico V. (2010). Adoption of flat panels in soil heat exchange, WREC 2010, Abu Dhabi, United Arab Emirates, 25-30 September 2010, Future Technology Press, 330-335. Di Federico V., Pinelli M., Ugarelli R. (2010). Estimates of effective permeability for non-Newtonian fluid flow in randomly heterogeneous porous media. Stochastic Environmental Research and Risk Assessment 24, 1067-1076. Cintoli S., Neuman S. P., Di Federico V. (2005). Generating and scaling fractional Brownian motion on finite domains. Geophysical Research Letters 32, L08404. Cintoli S., Neuman S.P., Di Federico V. (2005). Scaling Effects on Finite-Domain Fractional Brownian Motion, Proceedings geoENV 2004, Neuchatel (Switzerland), 13-15 October 2004, 75-86. Di Federico V., Bizzarri G. (2004). Bingham fluid flow in spatially variable fractures, Advances in Fluid Mechanics V, 169-177, WIT Press. Neuman S. P., Di Federico V. (2003). Multifaceted nature of hydrogeologic scaling and its interpretation. Reviews of Geophysics 41(3), 1014. Hyun Y., Neuman S.P., Vesselinov V.V., Illman W.A., Tartakovsky D.M., Di Federico V. (2002). Theoretical interpretation of a pronounced permeability scale effect in unsaturated fractured tuff. Water Resources Research 38(6), 281-288. RESEARCH PROJECTS National Project funded by the Italian Ministry of Research, Project: Subsurface fluxes in heterogeneous geologic media, 2000-2002. CONTACTS [email protected] [email protected] [email protected] 240 Water Engineering – Hydraulic Networks SUSTAINABILITY OF URBAN WATER SYSTEMS RESEARCH GROUP: Valentina Ciriello, Vittorio Di Federico, Tonino Liserra KEYWORDS: urban water cycle services, sustainability, risk, long-term planning, reliability Climate change, pollution of drinkable water sources, progressive aging of existing infrastructures and limited financial resources render the water cycle management in urban areas one the major issues of the next generations. To effectively cope with the aforementioned problems a new paradigm, aimed to sustainability of water usage, needs to be adopted by decision and policy makers, planners and users. Methods, technologies, field experiences and tools need to be provided to stakeholders to support the planning of infrastructure and water usage adaptation to the anthropic pressures exacerbated by climate change under limited financial resources. This approach requires water companies and research institutions to coproduce methods and tools, and the involvement of decision makers and stakeholders to select objectives and interventions in the urban water cycle aimed to an improved sustainability; the set sustainability targets need to be reached in a strategic horizon of a few decades. The sustainability concept is adapted to include: the assets and the governance domains; the tools needed to test the effects of planned actions on the sustainability objectives and to select the best adaptation path to reach sustainability. These tools include: (1) a metabolism model of the entire water cycle, able to compute mass, energy, pollutant and financial fluxes; (2) a risk model, aimed at quantifying the risk to fail sustainability targets; (3) a DSS to select the sustainability paths. All these tools need to be assisted by guidelines, procedures and inventories of technologies suitably developed. This overall approach at the strategic network level needs to be coupled with: (1) methods for optimizing rehabilitation interventions of water mains via risk analysis (Life Assessment Model); (2) extension of the above methodologies to the management of transport infrastructures and their interaction with the water infrastructure; (3) open source framework for Life Cycle Energy Analysis calculations; (4) evaluation of hydraulic capacity of deteriorating water networks; (5) reliability indicators describing hydraulic and water quality performance at nodal and network level. Fig. 1. An outline of risk methodology developed in TRUST project. Fig. 2. The Financial Sustainability Rating Tool (FSRT) developed in TRUST by UNIBO and IWW. 241 Research Projects and Activities 2015 MAIN PUBLICATIONS Conestabile della Staffa B., Ugarelli R., Di Federico V. (2013). La stima dei flussi energetici come strumento di valutazione ambientale per le reti di distribuzione idrica, L’Acqua 2/2013, 9-18. Liserra T., Maglionico M., Ciriello V., Di Federico V. (2013). Uncertainty in design and management of sewer systems, Irrigation & Drainage Systems Engineering, 2:1, 1000105, doi: 10.4172/21689768.1000105. Conestabile Della Staffa B., Ugarelli R., Di Federico V. (2012). Applicazione di una metodologia LCEA per la stima del carico energetico e ambientale relativo alle condotte idriche urbane, L’Acqua suppl. 4/2012, 137-144. Liserra T., Di Federico V. (2012). Sostenibilità dei sistemi idrici urbani: L’approccio del progetto TRUST, Atti del XXXIII Convegno di Idraulica e Costruzioni Idrauliche, Brescia, 10-14 settembre 2012, pp. 1-10. Liserra T., Di Federico V., Maglionico M. (2012). Calcolo di indicatori di affidabilità delle reti idriche mediante modelli di simulazione idraulica, Atti del XXXIII Convegno di Idraulica e Costruzioni Idrauliche, Brescia, 10-14 settembre 2012, pp. 1-10. Ugarelli R., Di Federico V (2012). Towards sustainability of urban water networks: addressing management issues with innovative approaches, Irrigation & Drainage Systems Engineering, 1:e103, doi: 10.4172/2168-9768.1000e103. Ugarelli R., Venkatesh G., Brattebø H., Di Federico V., Sægrov S. (2010). Historical analysis of blockages in wastewater pipelines in Oslo and diagnosis of causative pipeline characteristics, Urban Water Journal 7(6), 335–343. Ugarelli R., Venkatesh G., Brattebø H., Di Federico V., Sægrov V. (2010). Asset management for urban wastewater pipeline networks, ASCE Journal of Infrastructure Systems 16(2), 112-121. Ugarelli R., Di Federico V. (2010). Optimal scheduling of replacement and rehabilitation in wastewater pipeline networks, ASCE Journal of Water Resources Planning and Management 136(3). Ghedin M., Ugarelli R., Liserra T., Di Federico V., Maglionico M. (2010). Esternalità generate sul traffico urbano dagli interventi di riabilitazione nelle reti idriche, L’Acqua 2/2010, 25-34. Di Federico V., Ugarelli R. (2010). La gestione integrata delle reti idriche urbane, L’Acqua suppl. 2/2010, 5-10. Ugarelli R., Kristensen S.M., Røstum J., Sægrov S., Di Federico V. (2009). Statistical analysis and definition of blockages-prediction formulae for the wastewater network of Oslo by evolutionary computing, Water Science and Technology 59(8), 1457-1470. Ugarelli R., Venkatesh G., Brattebø H., Sægrov S. (2008). Importance of investment decisions and rehabilitation approaches in an ageing wastewater pipeline network. A case study of Oslo (Norway), Water Science And Technology 8(12), 2279-2293. Liserra T., Ugarelli R., Di Federico V., Maglionico M. (2008). A GIS based approach to assess the vulnerability of water distribution systems, Water Asset Management International, 4.2 June 2008, 15-19. Ugarelli R., Di Federico V., Sægrov S. (2007). Riskbased Asset Management for wastewater systems, NOVATECH 2007, Lyon, France, June 2007, vol. 2, 917-924. Pollert, J., Ugarelli R., Saegrov S., Schilling W., Di Federico V. (2005). The hydraulic capacity of deteriorating sewer systems, Water Science and Technology 52(12), 207–214. RESEARCH PROJECTS EU FP7-ENV.2010.3.1.1-1 ID 265122 Project: TRUST. Transitions to the urban water services of tomorrow. http://www.trust-i.net/ EU FP 5 2002-2005 CARES: Computer Aided Rehabilitation of Sewer Networks, Po No EVK1-CT-2002-00106. http://www.sintef. no/care-s EU FP 5 2001-2004 CAREW: Computer Aided Rehabilitation of Water Networks, Po No EVK1CT-2000-00053. http://www.sintef.no/care-w CONTACTS [email protected] [email protected] [email protected] 242 Water Engineering – Urban Drainage Systems DESIGN AND MAINTENANCE OF URBAN DRAINAGE SYSTEM DEVICES RESEARCH GROUP: Sandro Artina, Andrea Bolognesi, Sara Simona Cipolla, Marco Maglionico KEYWORDS: gully pot, maintenance, management, rehabilitation, storage units The continuous growth of urban areas and soil sealing impact highlights several problems associated with stormwater disposal. Serious consequences may arise on both hydraulic and environmental sides. Urban catchments are characterised by shorter concentration time than rural areas. As a consequence CSOs activate and spill pollutants into the receiving water bodies when they are still in low flow condition, providing insufficient dilution. A number of studies within urban streams have demonstrated that general stream health declines as the area of impervious cover increases. These effects can be controlled by inserting storage units within the network, whose function is of temporarily accumulating a portion of the rain event volume, and later sending it to the treatment plant or to return it to receiving waters. Larger volumes are required for the hydraulic protection (detention or retention tanks), while smaller first flush tanks provide a mitigation effects on pollutant spills. Ongoing investigations aim to understand the real operation of the reservoirs with respect to the simplified design criteria traditionally used in engineering practice. In addition to tanks, our research is also interested in other relevant components of urban drainage systems, such as roadside gully pots. Their main function is to retain part of the solid material washed off paved surfaces in order to reduce problems associated with sediment transport and deposition in drainage structures. However, these structures are subject to clogging problems that can hardly affect their conveying capacity, leading to street flooding during rain events. Current research has aimed to determine which variables affect the gully pots capability of retaining particulate matter by means of pilot-scale laboratory tests and field monitoring activities. Infiltration and exfiltration in sewer systems deserve further interest: the former may cause groundwater pollution, the latter can generate hydraulic overloads and damage the operation of wastewater treatment plants. Since stakeholders are often not able to bear the costs of all required interventions, it becomes essential to develop tools capable of planning and setting intervention priorities. This research has seen real cases application DSS, based on Bayesian algorithms. Fig. 1. Gully pot field monitoring. 243 Fig. 2. Laboratory test facility for exfiltration analysis. Research Projects and Activities 2015 MAIN PUBLICATIONS Ying, G., Sansalone, J., Pathapati, S., Garofalo, G., Maglionico, M., Bolognesi, A., Artina, S. (2012) Stormwater treatment: Examples of computational fluid dynamics modeling, Frontiers of Environmental Science and Engineering in China 6 (5), pp. 638-648. Bolognesi, A., Ciccarello, A., Maglionico, M., Kim, J.-Y., Artina, S., Sansalone, J. (2012) Can surface overflow rate predict particulate matter load capture for common urban drainage appurtenances? Journal of Environmental Engineering (United States) 138 (7), pp. 723-733. Ciccarello, A., Bolognesi, A., Maglionico, M., Artina, S. (2012) The role of settling velocity formulation in the determination of gully pot trapping efficiency: Comparison between analytical and experimental data, Water Science and Technology 65 (1), pp. 15-21. Ciccarello A., G. Garofalo, J.J. Sansalone, A. Bolognesi, M. Maglionico, S. Artina. Studio mediante modello fisico di un “Hydrodinamic Separator” in regime di portata non costante. IDRA, Palermo, 2010. Bolognesi A., M. Maglionico. Long term simulation analysis under two different rainfall regimes as an aid to gully pot management. 7th Conference NOVATECH 2010, Lyon 28/0601/07/2010. Giovanelli M., M. Maglionico; Identification of the optimal level of service for sewer networks by means of expert procedure; 11th ICUD, Edinburgh, Scotland, UK, 2008. Bolognesi A., Casadio A., Ciccarello A., Maglionico M., Artina S., Experimental study of roadside gully pots efficiency in trapping solids washed off during rainfall events. 11th ICUD, Edinburgh, Scotland, UK, 2008. Gottardi G., M. Maglionico; Analisi del metodo dell’invaso per il dimensionamento delle vasche di laminazione a servizio delle reti di drenaggio urbano. IDRA, Perugia, 9-12 settembre 2008. Bolognesi A., M. Maglionico, S. Artina; Vali- dation of tracer dilution methods for the quantification of exfiltration from sewer systems through laboratory tests; 6th Conference NOVATECH 2007 Lyon France 25-28/06/2007. Gottardi G., M. Maglionico; Analisi del metodo cinematico per il dimensionamento degli invasi di laminazione a servizio delle reti di drenaggio urbano; I, 10-15 Settembre 2006, Roma. Artina S., Becciu G., Maglionico M., Paoletti A., Sanfilippo U.; Performance indicators for the efficiency analysis of urban drainage systems; “Water Science and Technology”, Vol. 51 N. 2, pp. 109-118 – Febbraio 2005. RESEARCH PROJECTS Research and Consulting Contract with Province of Rimini (2011), Scientific support for the plan for the CSO management in the coastal area of the province of Rimini. Scientific Coordinator: Marco Maglionico. Convenzione tra la SIRCI SpA di Gubbio (PG) ed il dipartimento DISTART: “Verifica in laboratorio su modello fisico la funzionalità idraulica del prototipo di un nuovo tipo di pozzetto per la raccolta delle acque pluviali dalle superfici stradali”; Responsabile: Marco Maglionico (2008). Convenzione Caprari S.p.A. di Modena -Dipartimento DISTART: “Attività di consulenza finalizzata a sviluppare procedure e sistemi applicativi per il funzionamento e la gestione delle vasche di prima pioggia”; Responsabile: Marco Maglionico (2007). Convenzione HERA S.p.A. di Forlì - Dipartimento DISTART: “Definizione di criteri di progettazione, realizzazione e gestione di vasche di prima pioggia e di vasche di laminazione nell’ambito dei sistemi fognari”; Responsabile: Marco Maglionico (2007). FP7-ENV-2010 TRUST - Transactions to the Urban Water Services of Tomorrow. CONTACTS [email protected] [email protected] 244 Water Engineering – Urban Drainage Systems MONITORING AND MODELLING OF URBAN DRAINAGE NETWORKS RESEARCH GROUP: Sandro Artina, Andrea Bolognesi, Sara Simona Cipolla, Marco Maglionico KEYWORDS: numerical model, pollution, sewer networks Numerical simulation models for urban drainage networks have become increasingly important for both hydraulic aspects (design or verification of conduits and devices) and for environmental issues, with particular reference to the Combined Sewer Overflows impact on receiving water bodies (“first flush” phenomenon). The models reproduce quali-quantitative processes separating what happens in the drainage network from what happens on the basin’s surface. Quantitative (hydraulic) aspects, may be outlined as follows: net rainfall calculation, surface runoff and flow through the drainage system conduits. Water quality aspects include: accumulation (build-up) of pollutants on the basin’s surface during the dry weather period, the mobilization and transport (wash-off ) of pollutants due to rain, propagation into the drainage system. In order to estimate the parameters required for a reliable numerical model, long and accurate monitoring campaign are recommended. Actually, monitoring activities are a relevant part in the analysis of quali-quantitative processes, as both qualitative and hydraulic data are useful not just for calibrating the models, but also to understand the studied phenomena. Numerical simulations, either based on individual rainfall events (real or synthetic) or over long time series allow to evaluate the behaviour of the network and compare the effects of possible interventions in order to mitigate the environmental impact. 245 Fig. 1. CSO impact for the Bologna sewer network. Fig. 2. Example of water quality simulation. Research Projects and Activities 2015 MAIN PUBLICATIONS Archetti, R., Bolognesi, A., Casadio, A., Maglionico, M.,(2011) Development of flood probability charts for urban drainage network in coastal areas through a simplified joint assessment approach, Hydrology and Earth System Sciences 15 (10) , pp. 3115-3122. Artina S., A. Bolognesi, T. Liserra, M. Maglionico, G. Salmoiraghi; Experimental analysis of first foul flush in an industrial area; Transactions on Ecology and the Environment (ISSN 1743-3541), Wessex Institute of Technology Press, 2006. Artina S., A. Bolognesi, T. Liserra, M. Maglionico; Simulation of a storm sewer network in industrial area: comparison between models calibrated through experimental data; Environmental Modelling & Software, n. 22 (2007) pp. 1221-1228 – (2007). Nazionale di Idraulica e Costruzioni Idrauliche, Perugia, 9-12 settembre 2008. Casadio, A., Maglionico, M., Bolognesi, A., Artina, S. (2010) Toxicity and pollutant impact analysis in an urban river due to combined sewer overflows loads, Water Science and Technology 61 (1) , pp. 207-215. Freni G., Maglionico M., Mannina G., Viviani G.; Comparison between a detailed and a simplified integrated model for the assessment of urban drainage environmental impact on an ephemeral river; Urban Water Journal; Vol. 5, No. 1, March 2008, pp. 21-31 - ISSN 17449006 (2008). Maglionico M., Pollicino F.; Experimental analysis of the build-up of pollutants on an urban road surface; pp. 745-752 - International Conference Novatech 2004, Lyon, France; 6-10 Giugno 2004. Artina S., A. Bolognesi, T. Liserra, M. Maglionico; I modelli quali-quantitativi a supporto della progettazione e gestione delle reti fognarie; Atti della giornata di studio “La separazione delle acque nelle reti fognarie urbane” Roma 25 giugno 2003 – pp. 5-16 – ISBN 978-88-900282-6-7 (2007). Simone A., Vignali C., Bragalli C., Maglionico M., Surface runoff: a rainfall simulator for wash-off modelling and road safety auditing under different rainfall intensities, SIIV2004 – New technologies and modeling tools for road, Firenze, 27-29 ottobre 2004. Benedetti L., A. Casadio, M. Maglionico, P. A. Vanrolleghem; Metodologia di realizzazione di un connettore fra ASM2d e RWQM1 per un modello di simulazione integrato: rete fognaria - impianto di depurazione - corpo idrico ricettore; IA Ingegneria Ambientale; Vol. XXXVII n. 1-2 – pp. 12-19 - gen-feb 2008. “Attività di modellazione relativamente alla rete fognaria di Rimini” (Numerical modelling of Rimini sewer system). Research contract funded by HERA S.r.l. Rimini. Responsibile: Marco Maglionico (2009). Calabrò P. S., M. Maglionico; Comparison between detailed and conceptual models in water quality simulation; 9th International Conference on Urban Drainage, 8-13 Settembre 2002, Portland (USA). Casadio A., M. Maglionico, A. Bolognesi, S. Artina. Analisi dell’impatto degli scaricatori di piena sui corpi idrici ricettori: il caso di studio del Canale Navile a Bologna, XXXI Convegno RESEARCH PROJECTS FP7-ENV-2010 TRUST - Transactions to the Urban Water Services of Tomorrow. Research and Consulting Contract with HERA S.r.l. Ravenna (2011), Scientific support for the numerical modelling of the sewer network of Ravenna. Scientific Coordinator: Marco Maglionico CONTACTS [email protected] [email protected] 246 Water Engineering – Urban Drainage Systems WATER AND ENERGY RECOVERY IN WATER DISTRIBUTION SYSTEMS RESEARCH GROUP: Sandro Artina, Andrea Bolognesi, Cristiana Bragalli, Matteo Fortini KEYWORDS: energy efficiency, design, optimization, water scarcity, water supply systems, miny-hydro The contribution in the enhancement of leakage control methods in water distribution systems is closely related to the need for an integrated water and energy resource management. Both consolidated and emerging technologies and management practices have been analysed in order to improve efficiency in the use of water and energy resources. In fact, leakage can modify the operational conditions of the network and of pumps, causing relevant effects on energy efficiency. The understanding of leakage-energy nexus shows non-trivial relationships and the definition of methodologies and indicator to evaluate the actual level of water demand, leakage and energy consumed is a key issue either under a management or an environmental perspective. Optimization process has been used to determine the configurations representing the optimal scenarios in terms of watergy efficiency, i.e.: the satisfaction of water demand with the lowest possible energy-demanding networks and, among the low energy networks, those showing the highest energy-efficiency. The contribution on the enhancement of leakage control methods in water distribution systems derives from a number of research projects carried out in strictly collaboration with water utilities operating particularly in Emilia Romagna and Marche regions. Recently some real applications of automatic meter readings (Forlì, HERA network; Fano, ASET network; Reggio Emilia, ENIA network) have been considered. Remote monitoring systems are able to read users’ water meters and it is possible to use this feature for a dynamic water balance, and also it is an excellent starting point for a water losses dynamic control approach that links the benefits of active leakage control and the ones of passive leakage control. In conjunction with the previous mentioned aspects, the research activity is regarded the increasing of the energy self-sufficiency of water distribution systems by means the installation of turbine/PAT, assuming that the installations of Micro–Hydro and Mini–Hydro could be seen as a point of convergence between the pressure control (in order to reduce the losses 247 of water) and the exploitation of a renewable energy source. Fig. 1. Energy self-sufficiency of water distribution systems by installation of turbine/PAT. Fig. 2. Smart technologies for Automatic Meter Reading. Research Projects and Activities 2015 MAIN PUBLICATIONS Artina S., Naldi G., Marchi A., Bragalli C., Lenzi C., Liserra T. (2008). Dal controllo della pressione al recupero energetico nei sistemi di distribuzione idrica. IDRA08. p. 1-8, PERUGIA: Morlacchi Editore, ISBN: 978-88-6074-220-9. Artina S., Bragalli C., Lenzi C., Liserra T., Marchi A., Benini A. (2010), Relazione sperimentale tra perdite ed energia in reti idriche alimentate da pompe a giri variabili, Supplemento alla rivista bimestrale dell’Associazione Idrotecnica Italiana L’ACQUA 2/2010. Artina, A. Bolognesi, C. Bragalli, D. Galeri, M. Maglionico (2012). Implicazioni gestionali dell’applicazione estesa della telelettura ai contatori. L’ACQUA, vol. 4, p. 85-94, ISSN: 11251255. Bragalli C., Sacchi S., Burst frequency and leakage related to pressure control in water distribution network, Leakage Management – IWA Conference, Cyprus 20-22 November 2002. IWA Specialised Conference, Leakage Management, Cyprus, November 2002, Conference Proceedings, ISBN 9963875904. Bragalli C., Liserra T., Maglionico M., A procedure based on performance indicators in water distribution system for the identification of scenarios in terms of water losses reduction and structural improvement; International Water Association Conference - Water Loss 2007 - Bucharest 23-26 September 2007, Romania, ISBN 9789737681249. Lenzi C., Bragalli C., Bolognesi A., Artina S. (in stampa). From energy balance to energy efficiency indicators including water losses. WATER SCIENCE AND TECHNOLOGY: WATER SUPPLY, vol. 13, p. 1-8, ISSN: 16069749, doi: 10.2166/ws.2013.103. Liserra T., Artina S., C. Bragalli, C. Anzalone, G. Leoni, D. Giunchi. (2006). Approccio pre-attivo per il controllo delle perdite idriche con monitoraggio in telelettura. XXX Convegno di Idraulica e Costruzioni Idrauliche. XXX Convegno di Idraulica e Costruzioni Idrauliche. ROMA. 10-15 Settembre 2006. (vol. 1). ISBN: 88-87242-81-X. Liserra T., Artina S., Bragalli C., Lenzi C. (2009). Water loss dynamic control by Automatic Meter Readings in water distribution network. Integrating Water Systems, Proc. 10th International Conference on Computing and Control for the Water Industry (CCWI), Sheffield, ISBN 13-978-0-415-54851-9 Taylor & Francis Group, London, UK. Maglionico M., Liserra T., Bragalli C., (2009). Performance indicators in water distribution systems aggregated by means of bayesian networks, Performance Indicators for the Planning, Design and Management of water supply systems, CSDU Milano, ISBN 978-88-9032230-3. Naldi G., Artina S., Bragalli C., Liserra T., Marchi A. (2010). Experimental investigation of characteristic curves of centrifugal pumps working as turbines. In: Integrating Water Systems. p. 571-576, LONDON: CRC Press Taylor & Francis Group, ISBN: 9780415548519, Sheffield (UK). RESEARCH PROJECTS LIFE08/INF/IT/000308 “WATACLIC WATER AGAINST CLIMATE CHANGE. Sustainable water management in urban areas”, approvato dalla CE (2010 - 2012). FP7-ENV-2010 TRUST - Transactions to the Urban Water Services of Tomorrow. INTERREG IV C “WATER CoRe WATER SCARCITY AND DROUGHTS -COORDINATED ACTIVITIES IN EUROPEAN REGIONS” Priority 2: Environment and Risk Prevention, Sub-Theme: Water Management, approvato dalla CE (2010-2013). CONTACTS [email protected] [email protected] 248 Water Engineering – Water Supply Systems APPLICATION OF OPTIMIZATION ALGORITHMS TO DESIGN AND OPERATION OF WATER SUPPLY SYSTEMS RESEARCH GROUP: Sandro Artina, Andrea Bolognesi, Cristiana Bragalli, Matteo Fortini KEYWORDS: energy efficiency, design, optimization, water scarcity, water supply systems Water distribution systems are complex and extensive systems, characterized by significant temporal variability of users’ demand and, in some cases, even of supply sources. This means that interventions must be evaluated for different operational conditions. The search for optimal solutions in economic terms, so to satisfy the functional constraints and performance levels, has become more important with the Law 36/94, which introduced the criteria of entrepreneurship, and also the necessity to reduce the environmental impact in terms of water and energy needs for drinking water. Planning and management problems can be translated into an optimization problem where a set of solutions are found, from which the decision maker can find the final one. The optimization problem is of NP-hard type and is extremely complex due to the nonlinearity of the equations of motion and the presence of discrete variables. To overcome these difficulties heuristic algorithms able to explore the solution space in a stochastic way are applied, leaving to the simulator just the numerical solution of the hydraulic equations. Optimization algorithms considered in the research are manyfold. Multi-objective genetic agorithm (MOGA) NSGA-II based on analogy of evolution in nature has been used in collaboration with University of Exeter (UK). Also, in collaboraztion with CINECA Center, NSGA-II parallelization has been developed. An evolutionary algorithm named GHEST (Genetic Heritage Evolution by Stocastic Transmission) of recent development has been tested on several water distribution networks. Finally, an exact Mixed Integer Non Linear Programming approach has been used in collaboration with the Department DEIS of University of Bologna. The optimization techniques can be applied in the search of appropriate strategies for the mitigation of the effects of water scarcity. Water supply systems have now reached a high degree of complexity. The research may help to improve, through developments of modelling and analysis tools, the assessment of impact on urban area of possible prevention and mitigation actions actions. Fig. 1. Framework of GHEST algorithm. Fig. 2. Optimal design of water supply system using GHEST. 249 Research Projects and Activities 2015 MAIN PUBLICATIONS Artina S., Bolognesi A., Bragalli C., D’Ambrosio C., Marchi A. (2011). Comparison among best solutions of the optimal design of water distribution networks obtained with different algorithms. In: CCWI 2011 Urban Water Management: challenges and opportunities. Artina S., Bragalli C., Erbacci G., Marchi A., Rivi M. (2012). Contribution of parallel NSGA-II in optimal design of water distribution networks. Journal of Hydroinformatics, vol. Volume: 14 Issue: 2, p. 310-323, ISSN: 14647141. Bolognesi A., Bragalli C., Marchi A., Artina S., Genetic Heritage Evolution by Stocastic Transmission in the optimal design of water distribution networks, Advances in Engineering Software – Elsevier 41 (2010) 792-801. Bragalli C., D’Ambrosio C., Lee J., Lodi A., Toth P. (2006). An MINLP Solution Method for a Water Network Problem. LECTURE NOTES IN COMPUTER SCIENCE. Algorithms – ESA 2006. Zurich, Switzerland. September 11-13, 2006. vol. 4168, pp. 696 - 707 ISSN: 0302-9743. Bragalli C., D’Ambrosio C., Lee J., Lodi A., Toth P. (2008). Water network design by MINLP. p. 1-18, NEW YORK: IBM Reserach. Bragalli C., Marchi A., Bolognesi A., S. Artina S., Todini E. (2010). Applicazione dell’algoritmo euristico ghest al progetto della rete idrica di Balerma, XXXII Convegno Nazionale di Idraulica e Costruzioni Idrauliche Palermo, 1417 settembre 2010. Bragalli C, C. D’Ambrosio, J. Lee, A. Lodi, P. Toth (2012). On the Optimal Design of Water Distribution Networks: a Practical MINLP Approach. OPTIMIZATION AND ENGINEERING, vol. 13, p. 219-246, ISSN: 13894420. Bolognesi A., Marchi, A., Bragalli, C., Artina, S. (2013) “Multi-objective design of water distribution networks through the generation of pseudo-fronts in the hydraulically feasibile region.” Journal of Comp. in Civ. Eng. ASCE, posted ahead of print.doi:10.1061/(ASCE) CP.19435487.0000280. Bolognesi A., Bragalli C., Artina S. (2012). Ottimizzazione di una rete di distribuzione idrica nela rispetto integrale del livello di servizio. In: XXXIII Convegno di Idraulica e Costruzioni Idrauliche. p.1-14, Cosenza:Edibios, ISBN: 97888-97181-18-7, Brescia, 10-14 settembre 2012. Bragalli C., Freni G., La Loggia G. (2007). Assessment of water shortage in urban areas. WATER SCIENCE AND TECHNOLOGY LIBRARY, p. 375-398, DORDRECHT:Springer, ISBN: 9781402059230. Conte G., Bolognesi A., Bragalli C., Branchini S., Carli A.D., Lenzi C., Masi F., Massarutto A., Pollastri M., Principi I. (2012). Innovative Urban Water Management as a Climate Change Adaptation Strategy: Results from the Implementation of the Project “Water Against Climate Change (WATACLIC)”. WATER, vol. 4, p. 1025-1038, ISSN: 2073-4441, doi: 10.3390/ w4041025. RESEARCH PROJECTS LIFE08/INF/IT/000308 “WATACLIC WATER AGAINST CLIMATE CHANGE. Sustainable water management in urban areas”, approvato dalla CE (2010 - 2012). FP7-ENV-2010 TRUST - Transactions to the Urban Water Services of Tomorrow. INTERREG IV C “WATER CoRe WATER SCARCITY AND DROUGHTS -COORDINATED ACTIVITIES IN EUROPEAN REGIONS” Priority 2: Environment and Risk Prevention, Sub-Theme: Water Management, approvato dalla CE (2010 - 2013). CONTACTS [email protected] [email protected] 250 Water Engineering – Water Supply Systems NUMERICAL HYDRAULIC MODELLING AND FLOOD-RISK ASSESSMENT AND MITIGATION RESEARCH GROUP: Armando Brath, Emanuele Baratti, Attilio Castellarin, Serena Ceola, Alessio Domeneghetti, Alberto Montanari, Alessio Pugliese, Elena Toth KEYWORDS: 1D and 2D numerical hydraulic models, flood-risk assessment, mitigation and mapping, residual risk Modern techniques for topographical survey (see e.g., LiDAR, laser-scanning) enable numerical descriptions of the morphology of riverbanks and floodplain with high planimetric resolution. These techniques triggered research activities related to the application of one-dimensional (1D), quasi two-dimensional (quasi-2D) or fully two-dimensional (2D) hydraulic models. Ongoing research activities make use of these high resolution digital elevation models to reproduce the complexity of the river bed, protected and not-protected floodplains and flood prone areas. Starting from these altimetric information 1D, quasi-2D and 2D hydraulical model are implemented with different geometry discretizations and mesh resolutions. The main objective is to achieve, by means of mathematical simulations, some points of discussions for listed fields of research: - flood hazard mitigation strategies associated with different floodplain management policies (i.e. open floodplain, dike-protected floodplains or controlled floodding); - guidelines for the identification of the optimal topographic resolution for hydraulic models (i.e. optimal cross-section spacing and orientation); - evaluation of flood hazard and vulnerability indicator (i.e. water depth, stage-damage curve) for flood risk mapping, even in cases of levee failure scenarios; - definition of strategies for an effective management of extreme flood events (e.g. recurrence intervals >> 200 years), such as controlled flooding of areas outside the main embankments. Research activities are carried out in collaboration with Italian and foreign partners (Po River Basin Authority; Interregional Agency for the Po River; Emilia-Romagna District; District Agency for the Civil Protection; University of Bristol - School of Geographical Sciences; UNESCO-IHE Institute for Water Education, GeoForschungsZentrum Potsdam, GFZ, Germany). Fig. 1. Example of 2D model application for the evaluation of flood hazard indicator. Fig. 2. Probabilistic flood hazard map along the River Po in cases of levee failures. 251 Research Projects and Activities 2015 MAIN PUBLICATIONS Domeneghetti A. Vorogushyn S., Castellarin A., Merz B., Brath A. (2013). Effects of rating-curve uncertainty on probabilistic flood mapping. Hydrol. Earth Syst. Sci., in print; doi: 10.5194/hessd-9-9809-2012. Domeneghetti A., Castellarin A., Brath A. (2012). Assessing rating-curve uncertainty and its effects on hydraulic model calibration, Hydrology and Earth System Sciences, 16(4), 1191–1202, doi:10.5194/ hess-16-1191-2012. Available from: http://www. hydrol-earth-syssci.net/16/1191/2012/ Castellarin A., Di Baldassarre G., Brath A. (2010) Floodplain management strategies for flood attenuation in the River Po, River Research and Application , DOI: 10.1002/rra.1405. Domeneghetti, A., Castellarin A., Brath A. (2010). Identifying robust large-scale flood risk mitigation strategies: a quasi 2D hydraulic model as a tool for the Po River, Physics and Chemistry of the Earth, Special Issue: Flood Hydrology and Remote Sensing, paper under review. Brath, A., Castellarin A., Di Baldassarre G., Domeneghetti A. (2010). Linee strategiche di intervento per la mitigazione del rischio alluvionale lungo il corso medio-inferiore del Fiume Po. L’Acqua, 2, pp. 9-24, ISSN 1125-1255. Domeneghetti A., Castellarin A., Brath A. (2010). Effects of rating-curve uncertainty on the calibration of numerical hydraulic models. First IAHR European Congress, Edinburgo, 4-6 Maggio, 2010. Brath, A., Castellarin A., Di Baldassarre G., Domeneghetti A. (2010). Nuovi indirizzi per la difesa dal rischio idraulico lungo l’asta fluviale del Fiume Po. Biologia Ambientale, Atti del XVIII congresso S.It.E., Parma 1-3 Settembre 2008, 24 (1): 41-58. Castellarin, A., G. Di Baldassarre, Bates P.D., Brath A. (2009). Optimal cross-section spacing in Preissmann scheme 1D hydrodynamic models, J. Hydraul. Eng., ASCE, 135(2), 96-105. Di Baldassarre, G., Castellarin A., Montanari A., Brath A. (2009). Probability weighted hazard maps for comparing different flood risk manage- ment strategies. A case study, DOI: 10.1007/ s11069-009-9355-6, Natural Hazards, 50: 479496. Di Baldassarre, G., Montanari A. (2009). Uncertainty in river discharge observations: a quantitative analysis, Hydrology and Earth System Sciences, 13, 913-921. Di Baldassarre, G., Castellarin A., Brath A. (2009). Analysis on the effects of levee heightening on flood propagation: some thoughts on the River Po, Italy. Hydrological Sciences Journal, 54(6), 1007-1017. Castellarin A., Di Baldassarre G., Bates P.D., Brath A. (2008). Optimal geometric description in one-dimensional hydraulic models. In New Topics in Water Resources Research and Management. (pp. 235 - 259). ISBN: 1-60021-974-8. Hauppauge NY: Novapublisher (United States). Castellarin A., Brath A., Di Baldassarre G. (2008). Analisi della capacità di laminazione del sistema golenale del corso medio inferiore del Fiume Po. 31° Convegno di Idraulica e Costruzioni Idrauliche. Perugia, 9-12 settembre 2008. (pp. 350-1 - 350-11). ISBN: 978-88-6074-2209. Brath A., Di Baldassarre G. (2007). LiDAR e immagini ASAR per la messa a punto di una affidabile modellistica bidimensionale dei fenomeni di allagamento. Ambiente Territorio. vol. 6, pp. 38 - 45 ISSN: 1971-5455, 2007. RESEARCH PROJECTS Research and Study Agreement: strategic project for flood-risk mitigation along the middle lower reach of the Po River. Po River Basin Authority (Autorità di Bacino del Po). Scientific activity associated to the donation of the Interregional Agency for the Po River (Agenzia Interregionale per il Fiume Po). CONTACTS [email protected] [email protected] [email protected] [email protected] 252 Water Engineering – Hydraulic Protection REAL-TIME FLOOD FORECASTING SYSTEMS RESEARCH GROUP: Armando Brath, Emanuele Baratti, Attilio Castellarin, Serena Ceola, Alessio Domeneghetti, Alberto Montanari, Alessio Pugliese, Elena Toth KEYWORDS: flood forecasting, real-time updating, precipitation spatial field, confidence bands Two crucial components of real-time flood forecasting systems are the estimation and forecasting of the meteorological forcing and the use of the last streamflow observations, that allow to update the rainfall-runoff model simulations and to derive an uncertainty assessment of the issued forecast. Such aspects have been analysed in the following research activities: a) Integrated use of time-series analyisis techniques and determistic rainfall-runoff models for flood forecasting: along with traditional linear stochastic models, non-linear time-series models have been applied, that is Artificial Neural Networks (ANN) and the “nearest neighbours” method, which is a non-parametric regression methodology; such techniques are applied for forecasting the short-term future rainfall to be used as real-time input to the rainfall-runoff model and for updating the discharge predictions provided by the model (see Fig. 1). b) Estimates and nowcasting of rainfall fields through remote-sensing techniques: the performances of an integrated flood forecasting system, based upon the use of Meteosat satellite derived rainfall maps and of a distributed rainfall-runoff model were first analysed, comparing both the input fields and the obtained streamflow forecasts. A second research topic is the evaluation of system analysis techniques for obtaining short-term (of the order of a few hours) quantitative precipitation forecasting, based on radar images (see Fig. 2). Another important issue in flood forecasting is the analysis of the reliability and uncertainty of the streamflow forecasts. A technique for assessing the uncertainty of rainfall-runoff simulations was proposed, that makes use of a meta-Gaussian approach in order to estimate the probability distribution of the model error conditioned by the simulated river flow. The proposed technique is applied to real-world case studies, for which the confidence limits of simulated river flows are derived and compared with the actual hydrometric observations (see Fig. 3). Fig. 1. Real-time upodating of streamflow forecasts through simulation error modelling. Fig. 2. Precipitation fields (time-resolution 15mins, spatial resolution 1x1 km2) captured by the Doppler radar. Fig. 3. Observed and real-time simulated streamflow and relative forecast confidence bands. 253 Research Projects and Activities 2015 MAIN PUBLICATIONS Toth E., Brath, A., Montanari, A., Real-time flood forecasting via combined use of conceptual and stochastic models. Physics and Chemistry of the Earth Part B-Hydrology Oceans And Atmosphere. vol. 24(7), pp. 793-798 ISSN: 14641909, 1999. Toth E., Brath, A., Montanari, A., Comparison of short-term rainfall prediction models for real-time flood forecasting. Journal of Hydrology. vol. 238, pp. 132-147 ISSN: 0022-1694, 2000. Brath A, Montanari, A., Toth, E., On the use of neural networks and non-parametric methods for improving real-time flood forecasting obtained through conceptual hydrologic models. Hydrology and Earth System Sciences. vol. 6, pp. 627-640 ISSN: 1027-5606, 2002. Montanari, A., Brath, A., A stochastic approach for assessing the uncertainty of rainfall-runoff simulations, Water Resources Research, Vol. 40, W01106, doi: 10.1029/2003WR002540, 2004. Montanari L., Montanari, A., Toth, E., A comparison and uncertainty assessment of system analysis techniques for short-term quantitative precipitation nowcasting based on radar images. Journal of Geophysical Research. Atmospheres. vol. 111 ISSN: 0148-0227, 2006. Montanari, A., What do we mean by ‘uncertainty’? The need for a consistent wording about uncertainty assessment in hydrology, Hydrological Processes, Vol. 21, 841-845, 2007. Toth E, Data-driven streamflow simulation: the influence of the temporal resolution of input and output variables. In: “Hydroinformatics in practice: computational intelligence and technological developments in water applications” (Eds. R. Abrahart, L. See, D. Solomatine), ISBN: 3540798803, BERLIN, Springer-Verlag, GERMANY, 2008. Toth, E., Classification of hydro-meteorological conditions and multiple artificial neural networks for streamflow forecasting, Hydrology and Earth System Sciences, 13, 1555-1566, 2009. Abrahart, R.J., Anctil, F., Coulibaly, P., Dawson, C.W., Mount, N.J., See, L.M., Shamseldin, A.Y., Solomatine, D.P., Toth, E., Wilby, R.L., Two decades of anarchy? Emerging themes and outstanding challenges for neural network river forecasting, Progress in Physical Geography, doi: 10.1177/0309133312444943, 36(4), 480513, 2012. RESEARCH PROJECTS Research contracts (from 1999 on) with the Regional Civil Protection Agency of Regione Emilia-Romagna. Italian Research Project of National Relevance 2006, “Advanced techniques for estimating the magnitude and forecasting extreme hydrological events, with uncertainty analysis (SPIE)”, financed by the Italian Ministry of University and Research (MIUR). CONTACTS [email protected] [email protected] [email protected] [email protected] 254 Water Engineering – Hydrology WATER RESOURCES MANAGEMENT AND WATER SECURITY RESEARCH GROUP: Armando Brath, Emanuele Baratti, Attilio Castellarin, Serena Ceola, Alessio Domeneghetti, Alberto Montanari, Alessio Pugliese, Elena Toth KEYWORDS: water resources; land-use change; hydrological change; environmental restoration; water for food Water resources management and water security are topical issues today in many countries in Europe and other areas. In fact, environmental change, and in particular hydrological change, is inducing relevant perturbations in water resources availability and water demands. This problem is recognized at the international level, as the numerous scientific and governmental initiatives developed in the last decade and dedicated to water security and society clearly testify. It is an extremely complex scientific and technical problem, because the increase of the water demands and the overexploitation of water resources is superimposed to environmental changes that may themselves imply a reduction of water availability. Finding a solution to such a problem requires gaining an improved interpretation of the connections and feedbacks between water dynamics and society. Traditional scientific and technical approaches for water engineering design are based on the assumption that environmental conditions are marginally affected by human influence and therefore the environment is often assumed to be stationary. The research and consulting activities set up innovative approaches for studying and modeling the mutual interaction between water and humans (socio-hydrology), hence developing new methods for estimating design variables to support engineering design. The ongoing research activities deal with the following subjects: - identification of optimal techniques for water resources management in a changing environment; - impact of climate and hydrological change in water resources; - integrated methods for flood risk mitigation and flood management through an improved mathematical representation of the connections and feedbacks between society and water processes; - design of hydro-power plants under environmental change; - environmental impact analysis for human activities; - large scale analysis of human influence, environmental impact and socio-hydrological feedbacks. Fig. 1. Interaction between human activity and water systems. Fig. 2. Effect of natural variability and human influence on the status of water resources. Fig. 3. Water balance for the Po River watershed. 255 Research Projects and Activities 2015 REFERENCES Andrés-Doménech, I. Montanari, A., Marco, J.B., Efficiency of Storm Detention Tanks for Urban Drainage Systems under Climate Variability, Journal of Water Resources Planning and Management, ASCE, 138, 36-46, 2012. Montanari et al., “Panta Rhei—Everything Flows”: Change in hydrology and society— The IAHS Scientific Decade 2013-2022. Hydrological Sciences Journal. 58 (6), doi: 10.1080/02626667.2013.809088. Bloeschl, G., Montanari, A., Climate change impacts–throwing the dice?, Hydrological Processes, 24, 374-381, 2010. Montanari, A., Koutsoyiannis, D., A blueprint for process-based modelling of uncertain hydrological systems, Water Resources Research, 48, W09555, doi:10.1029/2011WR011412, 2012. Brandimarte, L., Di Baldassarre, G., Bruni, G., D’Odorico, P., Montanari, A., Relation Between the North-Atlantic Oscillation and Hydroclimatic Conditions in Mediterranean Areas, Water Resources Management, 25, 12691279, 2011. Wagener, T., Montanari, A., Convergence of approaches toward reducing uncertainty in predictions in ungauged basins, Water Resources Research, 47, doi:10.1029/2010WR009469, 2011. Castellarin, A., Domeneghetti, A., Brath, A., Identifying robust large-scale flood risk mitigation strategies: a quasi-2D hydraulic model as a tool for the Po River, Physics and Chemistry of the Earth, Parts A/B/C, 36, 299-308, 2011. RESEARCH PROJECTS Panta Rhei, Everything flows, IAHS Scientific Decade 2013-2022. Alberto Montanari is Chairing the research initiative in the biennium 2013-2015. Castellarin, A., Pistocchi, A., An analysis of change in alpine annual maximum discharges: implications for the selection of design discharges. Hydrological Processes, 26(10), 15171526, 2012. Di Baldassarre, G., Laio, F., Montanari, A., Design flood estimation using model selection criteria, Physics And Chemistry of the Earth. vol. 34, 606-611, 2009Di Baldassarre, G., Montanari, A., Lins, H., Koutsoyiannis, D., Brandimarte, L., Bloeschl, G., Flood fatalities in Africa: from diagnosis to mitigation, Geophysical Research Letters, 37, L22402, doi:10.1029/2010GL045467, 2010 Di Baldassarre, G., Laio, F., Montanari, A., Effect of observation errors on the uncertainty of design floods, Physics and Chemistry of the Earth, 42-44, 85-90, 2012. Project PRIN 2008 “Uncertainty Analysis for Rainfall and River Flow Data and Effects on Water Resources Management”, financed by the Italian Government. Project “Transitions to the urban water services of tomorrow” (TRUST), financed by the European Union – 7th Framework Programme, 2010-2013. Project Sharing Water Information to Tackle Changes in the Hydrosphere - for Operational Needs” (SWITCH-ON, Call ID “FP7-ENV2013-Two-stage”), financed by the European Union (2013-2017). CONTACTS [email protected] [email protected] [email protected] [email protected] 256 Water Engineering – Hydrology CATCHMENT CLASSIFICATION AND STREAMFLOW PREDICTIONS IN UNGAUGED BASINS RESEARCH GROUP: Armando Brath, Emanuele Baratti, Attilio Castellarin, Serena Ceola, Alessio Domeneghetti, Alberto Montanari, Alessio Pugliese, Elena Toth KEYWORDS: design-flood, low-flow indices, flow-duration curves, statistical regionalization, rainfall-runoff modelling The research activities aim at improving our current level of knowledge in the field of streamflow prediction (e.g. the flood occurs on average once every T years, low-flow indices, flow-duration curves, etc.) for catchment lacking streamflow observations (i.e. ungauged basins). This is a fundamental practical issue that needs to be addressed when dealing with several water related problems (e.g. flood-risk management; water-quality and water-availability assessments; feasibility of hydropower plants; design of drinking-water supply, irrigation and reclamation systems, etc.). The main research activities are: (A) Classification of river basins to improve the representation of spatio-temporal variability of streamflows. We are focusing on objective classification techniques that combine multivariate analysis techniques (e.g. Principal Component Analysis, Canonical Correlation Analysis) with unsupervised artificial neural networks, such as the Self Organising Maps (see e.g. Fig. 1). (B) Statistical regionalization. We develop and test regionalization procedures to transfer hydrological information from donor gauged basins to ungauged basins. In particular, we are currently testing the potential of innovative geostatistical procedures (e.g. Fig. 2). (C) Simulation of streamflows in ungauged catchments through mathematical rainfall-runoff models, whose parameters are identified through innovative techniques that do not require concurrent rainfall and streamflow observations for the site of interest, and are therefore suitable for ungauged basins. Research activities are carried out in close collaboration with other national and international universities and research institutes (e.g. Polytechnic of Turin, Research Institute for Geo-Hydrological Protection, Italian NRC; GeoForschungsZentrum, GFZ, Potsdam, Germany; Technische Universität Wien, Vienna, Austria; Centre for Ecology & Hydrology, Wallingford, UK; U.S. Geological Survey, Northborough, MA, U.S.; Institute for Environment and Sustainability, JRC). Fig. 1. Unsupervised classification of ~300 Italian gauged catchments into nine hydrological classes (see Di Prinzio et al., 2011). Fig. 2. Metauro river: prediction of low-flows (i.e. Q355) along the stream network through geostatistical interpolation (see Castiglioni et al., 2011). 257 Research Projects and Activities 2015 MAIN PUBLICATIONS Archfield, S.A., A. Pugliese, A. Castellarin, J. O. Skøien, and J. E. Kiang (2013): Topological and canonical kriging for design flood prediction in ungauged catchments: an improvement over a traditional regional regression approach? Hydrol. Earth Syst. Sci., 17, 1575-1588. Castellarin, A., G. Botter, D.A. Hughes, S. Liu, T.B.M.J. Ouarda, J. Parajka, D. Post, M. Sivapalan, C. Spence, A. Viglione and R. Vogel (2013): Prediction of flow duration curves in ungauged basins, Chp. 7 in Runoff Prediction in Ungauged Basins: Synthesis across Processes, Places and Scales (Eds. G. Blöschl, M. Sivapalan, T. Wagener, A. Viglione, H. Savenije, ISBN-13: 9781107028180, 135-162. Castiglioni, S., A. Castellarin, A. Montanari (2009): Prediction of low-flow indices in ungauged basins through physiographical spacebased interpolation, Journal of Hydrology, 378, 272-280. Castiglioni, S., A. Castellarin, A. Montanari, J.O. Skøien, G. Laaha, G. Blöschl (2011): Smooth regional estimation of low-flow indices: physiographical space based interpolation and top-kriging, Hydrol. Earth Syst. Sci., 15, 715-727. Castiglioni, S., L. Lombardi, E. Toth, A. Castellarin, A. Montanari (2010): Calibration of rainfall-runoff models in ungauged basins: a regional maximum likelihood approach, Advances in Water Resources, 33(10), 1235-1242. Di Prinzio, M., A. Castellarin, E. Toth (2011): Data-driven catchment classification: application to the PUB problem, Hydrol. Earth Syst. Sci., 15, 1921-1935. Guse, B., Thieken A.H., Castellarin A., Merz B. (2010): Deriving probabilistic regional envelope curves with two pooling methods, Journal of Hydrology, 380, 14-26. Lombardi, L., E .Toth, A. Castellarin, A.Montanari, A. Brath (2012): Calibration of a rainfall–runoff model at regional scale by optimising river discharge statistics: Performance analy- sis for the average/low flow regime, Physics and Chemistry of the Earth, 42-44, 77-84. Padi, P.T., G. Di Baldassarre, A. Castellarin (2011): Floodplain management in Africa: large scale analysis of flood data, Physics and Chemistry of the Earth, Parts A/B/C, 36, 292-298. Pallard, B., A. Castellarin, A. Montanari (2009): A look at the links between drainage density and flood statistics, Hydrology and Earth System Sciences, 13, 1019-1029. Toth, E.(2009) Classification of hydro-meteorological conditions and multiple artificial neural networks for streamflow forecasting, Hydrol. Earth Syst. Sci., 13, 1555-1566. Toth, E.(2013) Catchment classification based on characterisation of streamflow and precipitation time series, Hydrol. Earth Syst. Sci., 17, 1149-1159. Viglione, A., A. Castellarin, M. Rogger, R. Merz, and G. Blöschl (2012): Extreme rainstorms: Comparing regional envelope curves to stochastically generated events, Water Resources Research, 48, W01509. Wagener, T., and A. Montanari (2011), Convergence of approaches toward reducing uncertainty in predictions in ungauged basins, Water Resour. Res., 47, W06301. RESEARCH PROJECTS FP7-ENV-2013 ID. 603587-2 Project: SWITCH-ON Sharing Water-related Information to Tackle Changes in the Hydrosphere - for Operational Needs. Earth System Science and Environmental Management (ESSEM) Domain: COST Action ES0901 “European procedures for flood frequency estimation (FloodFreq)”. CONTACTS [email protected] [email protected] [email protected] [email protected] 258 Water Engineering – Hydrology RAINFALL-RUNOFF MODELLING RESEARCH GROUP: Armando Brath, Emanuele Baratti, Attilio Castellarin, Serena Ceola, Alessio Domeneghetti, Alberto Montanari, Alessio Pugliese, Elena Toth KEYWORDS: rainfall-runoff modelling; parameterisation; automatic calibration algorithms, data availability scenarios The assessment of the parameters characterising a rainfall-runoff model is crucial for a reliable simulation of streamflow values. The problem is particularly critical for systemic models, that are based exclusively on the information attainable from the calibration data, but also the choice of a physically-based approach does not generally overcome the need to calibrate at least a part of the model parameters. The research aims at obtaining indications on the quantity and quality of the calibration data that are needed for a reliable and efficient automatic parameterisation of rainfall-runoff models. Extensive experiments of calibrations and validations of rainfall-runoff models for different scenarios of historical information availability: different meteorological input variables, different methods for estimating the meteorological fields, different spatial and temporal scales of both input and output variables, different length and information content of the calibration record. Such aspects have been considered in relation to a variety of rainfall-runoff models, of deeply different nature: a physically-based distributed model, a conceptual lumped model, systemic, data-driven models based on Artificial Neural Networks. Furthermore, the Whittle maximum likelihood estimator was proposed for calibrating the parameters of hydrological models. This method may represent a valuable opportunity in the context of ungauged or scarcely gauged catchments. In fact, the only information required for model parameterization is the spectral density function of the actual process simulated by the model. When long series of calibration data are not available, the spectral density can be inferred by using old and sparse records, regionalization methods or information on the correlation properties of the process itself. Finally, an innovative regional parameterisation approach is proposed, based on the match, in the optimisation process, of a set of streamflow statistics. Such an approach allows the parameterisation of the model also for ungauged basins, based on the regionalisation of the selected statistics as a function of the climatic and geo-morphologic characterisation of the watershed. Fig. 1. Feedforward neural network for rainfall-runoff forecasting. Fig. 2. Conceptual scheme of the distributed rainfall-runoff model AFFDEF. Fig. 3. A modular approach that uses different system-theoretic rainfall-runoff models according to the situation characterising the forecast instant. 259 Research Projects and Activities 2015 MAIN PUBLICATIONS RESEARCH PROJECTS Brath A., A. Montanari, E. Toth, Analysis of the effects of different scenarios of historical data availability on the calibration of a spatially-distributed hydrological model. Journal of Hydrology. vol. 291, pp. 232-253 ISSN: 0022-1694, 2004. Italian Research Project of National Relevance 2005, “Characterisation of average and extreme flows in ungauged basins by integrated use of data-based methods and hydrological modelling”, financed by the Italian Ministry of University and Research (MIUR). Toth E., A. Brath, Use of spatially-distributed or lumped precipitation inputs in conceptual and black-box models for runoff forecasting. In: A. Brath A. Montanari E. Toth (Eds). Recent advances in peak river flow modelling, prediction and real-time forecasting - Assessment of the impacts of land-use and climate changes. (pp. 247-261). Ed. Bios (Italy), 2004. Montanari A., E. Toth, Calibration of hydrological models in the spectral domain: An opportunity for scarcely gauged basins?. Water Resources Research. vol. 43, pp. W05434 - . ISSN: 0043-1397, 2007. Italian Research Project of National Relevance 2008, “Uncertainty assessment of rainfall and streamflow measurements and impacts on the management of water scarcity conditions”, financed by the Italian Ministry of University and Research (MIUR). CONTACTS [email protected] [email protected] [email protected] [email protected] Moretti, G., e Montanari, A., Affdef: A spatially distributed grid based rainfall-runoff model for continuous time simulations of river discharge, Environmental Modelling & Software, Vol. 22(6), 823-836, 2007. Toth, E., Brath A., Multistep ahead streamflow forecasting: Role of calibration data in conceptual and neural network modeling, Water Resour. Res., 43, W11405, doi: 10.1029/2006WR005383, 2007. Toth, E., Classification of hydro-meteorological conditions and multiple artificial neural networks for streamflow forecasting, Hydrology and Earth System Sciences, 13, 1555-1566, 2009. Castiglioni, S. Lombardi, L., Toth, E., Castellarin, A., Montanari, A., Calibration of rainfall-runoff models in ungauged basins: A regional maximum likelihood approach, Advances in Water Resources, 33, 1235-1242, 2010. Lombardi, L., Toth, E., Castellarin, A., Montanari, A., Brath, A., Calibration of a rainfall-runoff model at regional scale by optimising river discharge statistics: performance analysis for the average/low flow regime, Physics and Chemistry of the Earth, 42-44, 77-84, 2012. 260 Finito di stampare nel mese di aprile 2015 presso MIG - Moderna Industrie Grafiche (Bologna)