Marine Ozone and Radiation Experiment Giandomenico Pace 1, David Mateos 3, Claudia di Biagio 1,4, Giampietro Casasanta 2, Nicoletta di Genova 2, Irene Mavilia1,5, Lorenzo De Silvestri 1, Wolfgang Junkermann 6, Alcide di Sarra 1, Sandro Finardi 7, Marco Cacciani 2, Giuseppe Cremona 1 1 Italian National Agency for New Technologies, Energy and Sustainable Economic Development 2 University of Rome “La Sapienza” 3 University of Valladolid 4 University of Siena 5 University of Rome 3 6 Karlsruhe Institute of Technology 7 ARIANET s.r.l. Aircraft data Time GPS_LAT Meteorological Data PRESSURE TEMPERATURE GPS_LON ALTITUDE DEWPOINT WIND Radiation data J1D_DN_UP JNO2_DN_UP RAD_DN_DN TOT_EXCO SKR_DN_UP Photolysis frequency(s-1) (J1D_DN, Before 1606B flight data uncertain.) -1 Photolysis frequency(s ) Shortwave (W/m2) (RAD_UP, Not working properly during the campaign) -1 Total extinction, (km ) Sky Radiation at 400 nm, 550 nm, 660 nm, 996nnm (bandwidth 10 nm, W/m2) Aerosol data CNC3010 GR_03 GRIMM Total particles number > 10 nm and < 300 nm in diameter, numbers in #/cm3 Total particles number > 300 nm in diameter, numbers in #/cm3 Size distribution (particles number for size class in diameter, numbers in #/cm3) Gas data O3_AVG ppm Surface data SST Sea surface temperature (°C) IV Periodo, 11- 20 giugno First flight 12/06/2010 15:52-16:34 Second flight 13/06/2010 13:12-15:25 Third flight 15/06/2010 7:21-7:46 Fourth flight 16/06/2010 7:25-8:34 Fifth flight 16/06/2010 14:41-16:08 Sixth flight 17/06/2010 6:58-8:21 Seventh flight 17/06/2010 14:36-16:03 Temperatura nei primi 2 km di quota. Umidità relativa nei primi 10 km di quota. Eighth flight 19/06/2010 6:21-7:45 Coefficiente di backscattering volumetrico IV Periodo, 11- 20 giugno First flight 12/06/2010 15:52-16:34 Second flight 13/06/2010 13:12-15:25 Third flight 15/06/2010 7:21-7:46 Fourth flight 16/06/2010 7:25-8:34 Fifth flight 16/06/2010 14:41-16:08 Sixth flight 17/06/2010 6:58-8:21 Seventh flight 17/06/2010 14:36-16:03 Eighth flight 19/06/2010 6:21-7:45 Dati radiometrici. Dati anemometro sonico. V Periodo, 21 Giugno - 1 Luglio Ninth Flight 21-06-2010 6:32-7:09 Tenth Flight 25-06-2010 14:25-15:47 Eleventh Flight 26-06-2010 6:27-8:02 Twelfth Flight, 26-06-2010 14:46-16:15 Temperatura nei primi 2 km di quota. Umidità relativa nei primi 10 km di quota. Coefficiente di backscattering volumetrico V Periodo, 21 Giugno - 1 Luglio J(O1D) sec-1 171 3E-005 172 173 174 175 176 177 178 179 180 181 Ninth Flight 21-06-2010 6:32-7:09 182 Tenth Flight 25-06-2010 14:25-15:47 2E-005 1E-005 Eleventh Flight 26-06-2010 6:27-8:02 450 0.6 420 0.5 0.4 390 0.3 360 0.2 Total Ozone (DU) Spessore ottico degli aerosol a 500 nm (MFR7) 0.7 0 Twelfth Flight, 26-06-2010 14:46-16:15 330 0.1 0 300 Spessore ottico delle nubi (Piranometro) 100 10 CGR4_070087 Irradianza W/m2 (4,5 - 50 m) 1 650 600 550 500 Alto ozono del 21 giungo Lamina o abbassamento Tropopausa? 450 1200 CMP21_090206 Irradianza W/m2 (0,3 - 2,8 m) 400 800 400 0 171 172 173 174 175 176 177 178 179 180 181 182 Giorni da inizio anno (20 - 30 Giugno 2010) Dati radiometrici. Dati anemometro sonico. Thermal PBL behaviour Aereosol load at 1020 nm. Max particles number with 10nm<D<3.0 μm (number/cm3) Max particles number with D>0.3 μm (number/cm3) Max ozone concentration (ppm) First flight 12/06/2010 15:52-16:34 T inversion (~5 K), max T at 600m AOD1020 ~0.7 (Desert dust) 9000 65 50 Second flight 13/06/2010 13:12-15:25 T inversion (~3 K), max T at 450m AOD1020 ~0.2 (Desert dust) 15000 >100 95 Third flight 15/06/2010 T ~constant between 200 and 600 m AOD1020 ~0.3 (Desert dust) 4000 >100 75 7:21-7:46 Fourth flight 16/06/2010 7:25-8:34 T ~constant between 200 and 500 AOD1020 ~0.6 (Desert dust) 8000 >100 50 Fifth flight 16/06/2010 14:41-16:08 T inversion (~0.7 K), max T at 300m AOD1020 ~0.4 (Desert dust) 6000 80 65 T ~constant (decreasing) between 200 and 500 m AOD1020 ~0.1 12000 60 67 AOD1020 ~0.15 8000 35 80 Flight day and time (UT) Sixth flight 17/06/2010 6:58-8:21 Seventh flight 17/06/2010 14:36-16:03 Eighth flight 19/06/2010 6:21-7:45 T decreasing (~7.5 K /km, first km) AOD1020 ~0.3 (Desert dust) 7000 30 65 Ninth Flight 21-06-2010 T decreasing (~9.5 K /km, first km) AOD1020 ~0.08 2000 15 50 6:32-7:09 Tenth Flight 25-06-2010 14:25-15:47 T decreasing (~8.5 K /km) above 600 m, super adiabatic below 100 m AOD1020 ~0.09 11000 20 70 Eleventh Flight 26-06-2010 6:27-8:02 T decreasing (8.5 K /km, first km) AOD1020 ~0.1 5000 30 60 Twelfth Flight, 26-06-2010 14:46-16:15 T decreasing (9.5 K/km above 800 m), T decreasing (6K /km above 800 m) AOD1020 ~0.15 # 40 75 Flight altitude restriction!! Summarizing the campaign was characterized by two main meteorological situations. The first part of the campaign, from the beginning (12/06) to the eighth flight (17/06), was characterized by stable conditions, a well developed sea breeze regime and the presence of also considerable amount of desert dust. After the 17/06 there was a change in the general circulation inducing northerly wind regime that, from the 21/06 to the 25/06 stopped the flights, because the occurrence of rain or too strong wind conditions. The last two days of flights the 25th and 26th of June were both characterized by a continuous air flow from north. Particularly interesting for the objectives of the campaign was the afternoon flight of 16th when a synoptically southerly advection reinforce the sea breeze feature allowing to study air masses more influenced by the sea environment. 16/06/2011 Pomeriggio Desertico Rinforzo sinottico da sud ci si aspetta aria marina Pennacchio? 14.8 14.9 15 10 8 8 6 6 4 4 2 2 100 0 40 0 14.7 15.1 14.8 15.2 14.9 15.3 15 15.4 15.1 15.5 15.2 15.6 15.3 15.7 15.4 15.8 15.5 15.9 15.6 16 15.7 16.1 36 10 32 28 6000 6000 5000 5000 CNC 7000 4000 3000 2000 2000 1000 14.7 14.9 1000 14.7 15 15.1 16.1 270 270 180 180 90 90 1000 0 1000 0 800 800 600 600 400 400 200 200 80 0 80 0 70 70 60 50 60 50 40 40 14.9 15 15.1 15.2 15.3 15.4 15.5 15.6 16/06/2011 B Variabilità CNC - O3 quasi cost 55-60 Variabilità CNC - O3 quasi cost 55-60 Vento indizi circolazione locale Vento indizi circolazione locale Sottile strato di CNC? Sottile strato di CNC? 14.8 16 360 4000 3000 15.9 14.8 15.2 15.3 15.7 15.4 15.5 15.8 15.9 16/06/2011 B 15.6 16 15.7 16.1 30 15.8 30 15.9 16 16.1 OZONE PPB 7000 1 15.8 360 OZONE PPB CNC #/cm3 (300 nm, 1.0 m) 14.7 10 Complessità data da - orografia locale (vento) - evoluzione temporale (profili temperatura sul mare salita 1 rosso, salita 2 blu chiaro, discesa 4 blu scuro ). Inoltre ci sono le diverse sorgenti locali… 7 7 7.1 7.2 Wind Intensity (m/s) 2 7.4 7.7 7.5 7.8 7.6 7.9 8 7.7 8.1 7.8 8.2 7.9 8.3 T (°C) 1 270 6 4 180 2 90 600 32 8000 8000 6000 6000 4000 4000 2000 2000 0 7.78.1 7 7.1 7.2 7.3 7 7.4 7.1 7.5 7.2 7.6 7.3 7.7 7.4 7.8 7.5 7.9 7.6 8 17/06/2011 A A Bassi CNC circa 100017/06/2011 escluso spike Bassi CNC circa 1000 escluso spike O3 cost 55-60 O3 cost 55-60 Intensità maggiore in quota ma non sempre Intensità vento maggiore in quota ma nonvento sempre 90 1000 0 800 200 80 0 80 0 40 7.98.3 400 200 60 7.88.2 600 8 60 40 8.1 8.2 8.3 OZONE (PPB) - RH 10000 24 180 OZONE (PPB) - RH 0.1 10000 270 800 400 CNC 8.3 1000 0 28 0 8.2 360 8 36 10 8.1 360 40 0 100 0 8 Altitude (m) #/cm3 (300 nm, 1.0 m) 4 7.3 7.6 Altitude (m) CNC 6 7.2 7.5 Wind Dir. (degree) 8 7.1 7.4 Wind Dir. (degree) Wind Intensity (m/s) 10 107.3 14.8 14.9 15 15.1 15.2 14.6 10 8 6 4 2 15.3 14.7 15.4 14.8 15.5 14.9 15.6 15 15.7 15.1 8 15.8 15.2 15.9 15.3 16 15.4 15.5 360 270 6 180 4 90 2 10 36 T T 1 6000 6000 CNC CNC 8000 4000 0 14.6 14.7 14.8 14.9 15 15.1 15 15.6 15.1 15.7 600 400 200 200 0 80 0 80 40 14.9 15.5 90 800 4000 0 14.6 14.7 14.8 15.2 15.3 15.4 17/06/2011 B 180 800 60 2000 2000 270 15.2 15.3 15.4 15.8 15.9 16 17/06/2011 B 15.5 60 40 15.6 15.7 15.8 15.9 16 OZONE (PPB) - RH 8000 360 OZONE (PPB) - RH 10000 16 1000 0 400 28 0.1 10000 15.9 1000 0 600 32 15.8 Altitude (m) 40 0 15.7 Altitude (m) 100 0 15.6 Wind Dir. (degree) Wind Intensity (m/s) 14.7 Wind Dir. (degree) Wind Intensity (m/s) 14.6 10 14.7 Wind Intensity (m/s) 14.6 12 8 4 100 0 14.8 14.3 16 14.9 14.4 15 14.5 15.1 14.6 15.2 14.7 15.3 14.8 15.4 14.9 15.5 15.6 15.7 15.8 15.9 15 15.1 15.2 15.3 15.4 360 15.5 270 12 180 8 4 35 0 90 15.6 15.7 15.8 270 180 90 1000 0 1000 0 800 T (°C) 30 1 600 400 25 80 0 70 6000 6000 60 4000 50 2000 40 CNC 8000 14.4 14.5 14.6 14.7 0 14.8 14.414.914.5 15 14.6 15.114.7 15.214.8 15.314.9 15.415 15.5 15.1 15.6 15.2 15.7 15.3 25/06/2011 25/06/2011 30 15.8 15.4 70 60 50 40 15.5 15.6 15.7 30 15.8 OZONE (PPB) - RH 8000 OZONE (PPB) - RH 80 0 0 400 200 10000 20 2000 600 200 10000 0.1 4000 800 Altitude (m) 10 15.9 360 Wind Dir. (degree) #/cm3 (300 nm, 1.0 m) 14.5 Altitude (m) CNC 14.4 Wind Dir. (degree) Wind Intensity (m/s) 14.3 16 Esempio complessità indotta da orografia, per interpretazione modellistica meteorologia c’è bisogno di alta risoluzione……